scholarly journals Conceptual Process Design, Energy and Economic Analysis of Solid Waste to Hydrocarbon Fuels via Thermochemical Processes

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2149
Author(s):  
Hossam A. Gabbar ◽  
Mohamed Aboughaly

Thermochemical processes use heat and series of endothermic chemical reactions that achieve thermal cracking and convert a wide range of solid waste deposits via four thermochemical processes to hydrocarbon gaseous and liquid products such as syngas, gasoline, and diesel. The four thermochemical reactions investigated in this research article are: incineration, pyrolysis, gasification, and integrated gasification combined cycle (IGCC). The mentioned thermochemical processes are evaluated for energy recovery pathways and environmental footprint based on conceptual design and Aspen HYSYS energy simulation. This paper also provides conceptual process design for four thermochemical processes as well as process evaluation and techno-economic analysis (TEA) including energy consumption, process optimization, product yield calculations, electricity generation and expected net revenue per tonne of feedstock. The techno-economic analysis provides results for large scale thermochemical process technologies at an industrial level and key performance indicators (KPIs) including greenhouse gaseous emissions, capital and operational costs per tonne, electrical generation per tonne for the four mentioned thermochemical processes.

2019 ◽  
Vol 16 (3) ◽  
pp. 117-123
Author(s):  
Tsung-Ching Huang ◽  
Ting Lei ◽  
Leilai Shao ◽  
Sridhar Sivapurapu ◽  
Madhavan Swaminathan ◽  
...  

Abstract High-performance low-cost flexible hybrid electronics (FHE) are desirable for applications such as internet of things and wearable electronics. Carbon nanotube (CNT) thin-film transistor (TFT) is a promising candidate for high-performance FHE because of its high carrier mobility, superior mechanical flexibility, and material compatibility with low-cost printing and solution processes. Flexible sensors and peripheral CNT-TFT circuits, such as decoders, drivers, and sense amplifiers, can be printed and hybrid-integrated with thinned (<50 μm) silicon chips on soft, thin, and flexible substrates for a wide range of applications, from flexible displays to wearable medical devices. Here, we report (1) a process design kit (PDK) to enable FHE design automation for large-scale FHE circuits and (2) solution process-proven intellectual property blocks for TFT circuits design, including Pseudo-Complementary Metal-Oxide-Semiconductor (Pseudo-CMOS) flexible digital logic and analog amplifiers. The FHE-PDK is fully compatible with popular silicon design tools for design and simulation of hybrid-integrated flexible circuits.


2017 ◽  
Vol 540 ◽  
pp. 464-476 ◽  
Author(s):  
Nitish Mittal ◽  
Peng Bai ◽  
J. Ilja Siepmann ◽  
Prodromos Daoutidis ◽  
Michael Tsapatsis

1994 ◽  
Vol 29 (5-6) ◽  
pp. 365-372 ◽  
Author(s):  
Åsa Malmqvist ◽  
Thomas Welander

Biological chlorate removal was studied on a laboratory and a pilot scale with the aim of optimizing process design and operating conditions with respect to process efficiency, stability and economy. The results showed a suspended-carrier biofilm process design to be suitable for biological chlorate removal. In the laboratory tests, at pH 7 and 37°C, a complete removal of chlorate could be maintained at hydraulic retention times (HRTs) as short as 24 min. A longer HRT (1.5 h) was required for complete chlorate removal in the pilot test, due to a lower degree of filling with carrier material (25% versus 50% of the reactor volume), higher process temperature, and leakage of oxygen into the process. However, it is assumed that the loading capacity of a large-scale process would approach that of the laboratory system if the operating conditions were the same. Laboratory tests showed chlorate reduction to be possible within a wide range of pH values and temperatures, although the process stability and loading capacity were strongly affected by changes in these parameters. The results of the laboratory and pilot scale studies, using a suspended-carrier process design, show biological treatment to be an economically viable and efficient process for the removal of chlorate from bleaching plant effluents.


2020 ◽  
Vol 22 (20) ◽  
pp. 7070-7079 ◽  
Author(s):  
Hyunwoo Kim ◽  
Julius Choi ◽  
Junhyung Park ◽  
Wangyun Won

A new process is developed to produce 2,5-furandicarboxylic acid from cellulose and evaluated via techno-economic analysis and life-cycle assessment.


2019 ◽  
Vol 141 ◽  
pp. 198-219 ◽  
Author(s):  
Alexandre C. Dimian ◽  
Petrica Iancu ◽  
Valentin Plesu ◽  
Alexandra-Elena Bonet-Ruiz ◽  
Jordi Bonet-Ruiz

2017 ◽  
Author(s):  
Sebastian Recker

In industrial practice, conceptual process design is typically conducted by repetitive simulation studies, which require detailed design specifications in an early design phase. Guided by heuristics, these iterative solution procedures result in high manual effort and, in addition, no guarantee concerning the quality of the solution can be given. Optimization-based design methods provide a tremendous potential to accelerate and improve conceptual process design. For this purpose, a synthesis framework for the optimization-based design of chemical processes is presented in this thesis. Powerful shortcut and rigorous evaluation methods for reaction and distillation are presented. These methods are computationally efficient in order to allow an optimization-based design of large-scale chemical processes. Various industrial case studies illustrate the application of the novel approaches and highlight their benefits. ...


Author(s):  
V. C. Kannan ◽  
A. K. Singh ◽  
R. B. Irwin ◽  
S. Chittipeddi ◽  
F. D. Nkansah ◽  
...  

Titanium nitride (TiN) films have historically been used as diffusion barrier between silicon and aluminum, as an adhesion layer for tungsten deposition and as an interconnect material etc. Recently, the role of TiN films as contact barriers in very large scale silicon integrated circuits (VLSI) has been extensively studied. TiN films have resistivities on the order of 20μ Ω-cm which is much lower than that of titanium (nearly 66μ Ω-cm). Deposited TiN films show resistivities which vary from 20 to 100μ Ω-cm depending upon the type of deposition and process conditions. TiNx is known to have a NaCl type crystal structure for a wide range of compositions. Change in color from metallic luster to gold reflects the stabilization of the TiNx (FCC) phase over the close packed Ti(N) hexagonal phase. It was found that TiN (1:1) ideal composition with the FCC (NaCl-type) structure gives the best electrical property.


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