scholarly journals Investigation of the Ambient Temperature Influence on the PEMFC Characteristics: Modeling from a Single Cell to a Stack

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2117
Author(s):  
Nikita Faddeev ◽  
Evgeny Anisimov ◽  
Maxim Belichenko ◽  
Alexandra Kuriganova ◽  
Nina Smirnova

Power supply systems based on air-cooled proton exchange membrane fuel cell (PEMFC) stacks are becoming more popular as power sources for mobile applications. We try to create a PEMFC model that allows for predicting the PEMFC operation in various climatic conditions. A total of two models were developed and used: the membrane electrode assemble (MEA) model and the PEMFC stack model. The developed MEA model allows to determine the influence of external factors (temperature) on the PEMFC power density. The data obtained using the developed model correlate with experimental data at low ambient temperatures (10–30 °C). The difference between the simulation and experimental data is less than 10%. However, the accuracy of the model during PEMFC operation at high (>30 °C) and negative ambient temperatures remains in doubt and requires improvement. The obtained data were integrated into the air-cooled PEMFC stack model. Data of the temperature fields distribution will help to manage the processes in the PEMFC stack. The maximum temperature is slightly above 60 °C, which corresponds to the optimal conditions for the operation of the stack. The temperature gradient across the longitudinal section is very low (<20 °C), which is a positive factor for the chemical reaction. However, the temperature gradient observed across the cross section of the PEMFC stack is 30 °C. The data obtained will help to optimize the mass-dimensional characteristics of air-cooled proton exchange membrane fuel cell and increase their performance. The synergetic effect between the MEA model and the PEMFC stack model can be successfully used in the selection of materials and the development of a thermoregulation system in the PEMFC stack.

2021 ◽  
Vol 13 (19) ◽  
pp. 10578
Author(s):  
Shusheng Xiong ◽  
Zhankuan Wu ◽  
Wei Li ◽  
Daize Li ◽  
Teng Zhang ◽  
...  

Temperature and humidity are two important interconnected factors in the performance of PEMFCs (Proton Exchange Membrane Fuel Cells). The fuel and oxidant humidity and stack temperature in a fuel cell were analyzed in this study. There are many factors that affect the temperature and humidity of the stack. We adopt the fuzzy control method of multi-input and multi-output to control the temperature and humidity of the stack. A model including a driver, vehicle, transmission motor, air feeding, electrical network, stack, hydrogen supply and cooling system was established to study the fuel cell performance. A fuzzy controller is proven to be better in improving the output power of fuel cells. The three control objectives are the fan speed control for regulating temperature, the solenoid valve on/off control of the bubble humidifier for humidity variation and the speed of the pump for regulating temperature difference. In addition, the results from the PID controller stack model and the fuzzy controller stack model are compared in this research. The fuel cell bench test has been built to validate the effectiveness of the proposed fuzzy control. The maximum temperature of the stack can be reduced by 5 °C with the fuzzy control in this paper, so the fuel cell output voltage (power) increases by an average of approximately 5.8%.


2018 ◽  
Vol 778 ◽  
pp. 275-282
Author(s):  
Noaman Khan ◽  
Saim Saher ◽  
Xuan Shi ◽  
Muhammad Noman ◽  
Mujahid Wasim Durani ◽  
...  

Highly porous ZIF-67 (Zeolitic imidazole framework) has a conductive crystalline metal organic framework (MOF) structure which was served as a precursor and template for the preparation of nitrogen-doped carbon nanotubes (NCNTs) electrocatalysts. As a first step, the chloroplatinic acid, a platinum (Pt) precursor was infiltrated in ZIF-67 with a precise amount to obtain 0.12 mg.cm-2 Pt loading. Later, the infiltrated structure was calcined at 700°C in Ar:H2 (90:10 vol%) gas mixture. Multi-walled nitrogen-doped carbon nanotubes were grown on the surface of ZIF-67 crystals following thermal activation at 700°C. The resulting PtCo-NCNTs electrocatalysts were deposited on Nafion-212 solid electrolyte membrane by spray technique to study the oxygen reduction reaction (ORR) in the presence of H2/O2 gases in a temperature range of 50-70°C. The present study elucidates the performance of nitrogen-doped carbon nanotubes ORR electrocatalysts derived from ZIF-67 and the effects of membrane electrode assembly (MEA) steaming on the performance of proton exchange membrane fuel cell (PEMFC) employing PtCo-NCNTs as ORR electrocatalysts. We observed that the peak power density at 70°C was 450 mW/cm2 for steamed membrane electrode assembly (MEA) compared to 392 mW/cm2 for an identical MEA without steaming.


2019 ◽  
Vol 7 (16) ◽  
pp. 9447-9477 ◽  
Author(s):  
Guoliang Wang ◽  
Liangliang Zou ◽  
Qinghong Huang ◽  
Zhiqing Zou ◽  
Hui Yang

This review highlights the recent progress in multidimensional nanostructured membrane electrode assemblies for PEMFCs and DMFCs.


Energy ◽  
2007 ◽  
Vol 32 (12) ◽  
pp. 2401-2411 ◽  
Author(s):  
Apichai Therdthianwong ◽  
Phochan Manomayidthikarn ◽  
Supaporn Therdthianwong

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