scholarly journals Alcohol Dehydration by Extractive Distillation with Use of Aminoethers of Boric Acid

Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1466
Author(s):  
Alexander V. Klinov ◽  
Alexander V. Malygin ◽  
Alina R. Khairullina ◽  
Sergey E. Dulmaev ◽  
Ilsiya M. Davletbaeva

Aminoethers of boric acid (AEBA) were studied as potential extractants for the separation of aqueous–alcoholic azeotropic mixtures by extractive distillation. The conditions of vapor–liquid equilibrium in aqueous solutions of ethanol and isopropanol in the presence of AEBA were studied. The division of AEBA molecules into group components was proposed, and previously unknown geometric parameters of the boron group and the energetic pair parameters of the boron group with the alkane group, ether group, amine-3d group, and alcohol group were determined within the framework of the Universal Functional Group Activity Coefficient (UNIFAC) model. The modeling of the extractive rectification process of an ethanol–water mixture with AEBA as extractant has been carried out. The dependences of the cost function on the extractant flow rate, the residual water content in it and the number of theoretical trays were obtained. A technological scheme for ethanol dehydration has been proposed, and its technological characteristics have been calculated.

2018 ◽  
Vol 2 (3) ◽  
pp. 121-135
Author(s):  
Jordan Andres P. Pinoargote ◽  
Jennifer Tatiana R. Alcivar ◽  
Carlos G. Villacreses Viteri

The work proposes the reuse of wastewater from the Faculty of Agronomic Engineering of the Technical University of Manabí, located in the Lodana parish in the city of Portoviejo, to irrigate the diversity of plantations that exist in the institution as a banana, cocoa and lemon. In the work, the results of the physical-chemical and bacteriological analysis carried out on the residual water generated in the institution are offered, being able to verify that it does not meet the parameters required to be used in the irrigation of crops. The technical scheme of the proposed treatment system is shown, specifying the structure of the zeolite filter. The calculations made for the technical and structural design of each of the devices that make up the proposed treatment system are provided. The analysis of the performance of the system that is illustrated with a series of data reflected in tables is exposed and where an efficiency between 84% and 88% can be verified. A review of compliance with environmental regulations is carried out and an economic analysis is provided on the cost of the investment for the introduction of the system in the Faculty of Agricultural Engineering of the Technical University of Manabí.


2008 ◽  
Vol 42 (5) ◽  
pp. 507-516 ◽  
Author(s):  
L. A. Serafimov ◽  
A. K. Frolkova ◽  
D. I. Bushina

2005 ◽  
Vol 39 (1) ◽  
pp. 16-23 ◽  
Author(s):  
L. V. Ivanova ◽  
A. V. Timoshenko ◽  
V. S. Timofeev

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