scholarly journals Characterization of Pyrolysis Products and Kinetic Analysis of Waste Jute Stick Biomass

Processes ◽  
2020 ◽  
Vol 8 (7) ◽  
pp. 837
Author(s):  
Jayanto Kumar Sarkar ◽  
Qingyue Wang
Keyword(s):  
Fixed Bed ◽  
Maximum Temperature ◽  
Heating Rates ◽  
Pyrolysis Products ◽  
Thermogravimetric Analyzer ◽  
Potential Source ◽  
Thermochemical Process ◽  
Bio Oil ◽  
Derivative Thermogravimetry

Thermochemical process of biomass is being considered as a latest technique for the restoration of energy source and biochemical products. In this study, the influence of the different heating rates on pyrolysis behaviors and kinetic of jute stick were investigated to justify the waste jute stick biomass as a potential source of bioenergy. Pyrolysis experiments were carried out at four several heating rates of 10, 20, 30 and 40 °C/min, by utilizing the thermogravimetric analyzer (TG-DTA) and a fixed-bed pyrolysis reactor. Two different kinetic methods, Kissinger–Akahira–Sunose (KAS) and Ozawa–Flynn–Wall (OFW) were used to determine the distinct kinetic parameters. The experimental results showed that, the heating rates influenced significantly on the position of TG curve and maximum Tm peaks and highest decomposition rate of the jute stick biomass. Both the highest point of TG and the lowest point of Derivative thermogravimetry (DTG) curves were shifted towards the maximum temperature. However, the heating rates also influenced the products of pyrolysis yield, including bio-char, bio-oil and the non-condensable gases. The average values of activation energy were found to be 139.21 and 135.99 kJ/mol based on FWO and KAS models, respectively.

scholarly journals Pyrolysis and Kinetic Analysis of CO2 Fixation Marine (Isochrysis sp.) and Freshwater (Monoraphidium c.) Microalgae

2021 ◽  
Author(s):  
Noridah B. Osman ◽  
Umi Syahirah Binti Mohd Amina ◽  
David Onoja Patrick ◽  
Nurul Asyikin Binti Bad ir Noon Zamana ◽  
Syazmi Zul Arif n Hakimi Saado ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Fixed Bed ◽  
Product Yield ◽  
Marine Species ◽  
Pyrolysis Process ◽  
Heating Rates ◽  
Nitrogen Flow Rate ◽  
Freshwater Microalgae ◽  
Thermogravimetric Analyzer ◽  
Bio Oil

Abstract Marine and freshwater microalgae grow in two different ecosystems, which influence their properties thus requires attention prior to determining its application. This paper has successfully disclosed the thermal, chemical, and physical properties of two types of microalgae on carbon dioxide (CO2) fixation and underwent pyrolysis process. Slow pyrolysis process for marine and freshwater microalgae (Isochrysis sp. and Monoraphidium c.) was performed in the fixed bed pyrolysis reactor and TGA (thermogravimetric analyzer) to determine the product yield and study their thermal decomposition profile. The pyrolysis was completed at various temperatures (400, 450, 500, and 550°C) at a heating rate of 15 °Cmin-1 and nitrogen flow rate of 200 ml min-1. Pyrolysis in TGA analyzer ran from 27 to 800°C at three heating rates (10, 20, and 40 °Cmin-1). For chemical composition, Fourier-transform Infrared (FTIR) analysis was performed on both microalgae samples. The highest yield (up to 33.9%) of bio-oil was obtained from Isochrysis sp. for all temperatures while the highest average yield (65.78%) of bio-char was collected from Monoraphidium c. species. From TGA pyrolysis, the major decomposition occurred between 200-400°C for Monoraphidium c. species. On the other hand, the decomposition profile of Isochrysis sp. was slightly slower, which may be due to the differences in lipid composition (FTIR peak 2929 cm-1). The activation energy of all tests is lower (33.6-40.3 kJ mol-1) compared to several other biomasses. Marine species fixed with CO2 showed promising results even without addition of catalyst and no additional cost needed.

Energia da Biomassa: termoconversão e seus produtos

2020 ◽  
Author(s):  
Lisiane dos Santos Freitas ◽  
Roberta Menezes Santos ◽  
Diego Fonseca Bispo ◽  
Thainara Bovo Massa ◽  
Thiago Vinícius Barros ◽  
...  
Keyword(s):  
Economic Value ◽  
Thermal Conversion ◽  
Chemical Characteristics ◽  
Pyrolysis Process ◽  
New Techniques ◽  
Pyrolysis Products ◽  
Critical Knowledge ◽  
Thermochemical Process ◽  
Bio Oil

In this book, the authors briefly present a description of the main pyrolysis process, the pretreatment of biomass, the characteristics of biomass, and pyrolysis products through an upgraded methods and its application. The book is divided into ten chapters dedicated to showing the potential of the thermochemical process to convert biomass into biogas, bio-oil, pyrolysis water, and biochar, which are products that can be used as intermediates in the chemical industry, in agriculture, or as biofuels. The critical knowledge of the characteristics of the biomass and possible pretreatment methods before pyrolysis can be used to help determine the routes to obtain products with superior economic value. The main types of thermal conversion, the technologies, reactors, and catalyst used to upgrade the bio-oil into biofuels, is presented is a didactic form. The characterization of classic and new techniques is addressed in order to clarify the main information obtained about the chemical characteristics of biomass and pyrolysis products. The content also shows the importance and main applications of pyrolysis products for the economy and the environment.

scholarly journals Effect of Ceria Addition to Na2O-ZrO2 Catalytic Mixtures on Lignin Waste Ex-Situ Pyrolysis

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 827
Author(s):  
Adam Yeardley ◽  
Giuseppe Bagnato ◽  
Aimaro Sanna
Keyword(s):  
Catalytic Pyrolysis ◽  
Fixed Bed ◽  
Xrd Analysis ◽  
Fixed Bed Reactor ◽  
Ex Situ ◽  
Mixed Metal Oxide ◽  
Pyrolysis Products ◽  
Potential Source ◽  
Bio Oil ◽  
Remarkable Reduction

Waste lignin is a potential source of renewable fuels and other chemical precursors under catalytic pyrolysis. For this purpose, four mixed metal oxide catalytic mixtures (Cat) derived from Na2CO3, CeO2 and ZrO2 were synthesised in varying compositions and utilised in a fixed bed reactor for catalytic vapour upgrading of Etek lignin pyrolysis products at 600 °C. The catalytic mixtures were analysed and characterised using XRD analysis, whilst pyrolysis products were analysed for distribution of products using FTIR, GC-MS and EA. Substantial phenolic content (20 wt%) was obtained when using equimolar catalytic mixture A (Cat_A), however the majority of these phenols were guaiacol derivatives, suggesting the catalytic mixture employed did not favour deep demethoxylation. Despite this, addition of 40–50% ceria to NaZrO2 resulted in a remarkable reduction of coke to 4 wt%, compared to ~9 wt% of NaZrO2. CeO2 content higher than 50% favoured the increase in conversion of the holo-cellulose fraction, enriching the bio-oil in aldehydes, ketones and cyclopentanones. Of the catalytic mixtures studied, equimolar metal oxides content (Cat_A) appears to showcase the optimal characteristics for phenolics production and coking reduction.

scholarly journals Bio-Oil Characterizations of Spirulina Platensis Residue (SPR) Pyrolysis Products for Renewable Energy Development

2020 ◽  
Vol 849 ◽  
pp. 47-52
Author(s):  
Siti Jamilatun ◽  
Aster Rahayu ◽  
Yano Surya Pradana ◽  
Budhijanto ◽  
Rochmadi ◽  
...  
Keyword(s):  
Renewable Energy ◽  
Spirulina Platensis ◽  
Pyrolysis Temperature ◽  
Renewable Energy Sources ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Oil Yield ◽  
Optimum Temperature ◽  
Pyrolysis Products ◽  
Bio Oil

Nowadays, energy consumption has increased as a population increases with socio-economic developments and improved living standards. Therefore, it is necessary to find a replacement for fossil energy with renewable energy sources, and the potential to develop is biofuels. Bio-oil, water phase, gas, and char products will be produced by utilizing Spirulina platensis (SPR) microalgae extraction residue as pyrolysis raw material. The purpose of this study is to characterize pyrolysis products and bio-oil analysis with GC-MS. Quality fuel is good if O/C is low, H/C is high, HHV is high, and oxygenate compounds are low, but aliphatic and aromatic are high. Pyrolysis was carried out at a temperature of 300-600°C with a feed of 50 grams in atmospheric conditions with a heating rate of 5-35°C/min, the equipment used was a fixed-bed reactor. The higher the pyrolysis temperature, the higher the bio-oil yield will be to an optimum temperature, then lower. The optimum temperature of pyrolysis is 550°C with a bio-oil yield of 23.99 wt%. The higher the pyrolysis temperature, the higher the H/C, the lower O/C. The optimum condition was reached at a temperature of 500°C with the values of H/C, and O/C is 1.17 and 0.47. With an increase in temperature of 300-600°C, HHV increased from 11.64 MJ/kg to 20.63 MJ/kg, the oxygenate compound decreased from 85.26 to 37.55 wt%. Aliphatics and aromatics increased, respectively, from 5.76 to 36.72 wt% and 1.67 to 6.67 wt%.

scholarly journals Characterization of selected pyrolysis products of diseased orange wood

BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 7118-7126
Author(s):  
Carolina Kravetz ◽  
Carlos Leca ◽  
José Otávio Brito ◽  
Daniel Saloni ◽  
David C. Tilotta
Keyword(s):  
Value Added ◽  
Chemical Compounds ◽  
Gas Chromatography Mass Spectrometry ◽  
Pyrolysis Products ◽  
Bio Oil ◽  
Potential Applications ◽  
Domestic Use ◽  
Immediate Analysis ◽  
Orange Trees

Orange trees in Brazil are often burned as a means of eradication when they become infected with Huanglongbing disease. Rather than destroying them, which is a low-value proposition, one potential option is to utilize the biomass through pyrolysis. In this preliminary work, orange trees (Citrus sinensis) otherwise selected for purging, were sampled and pyrolyzed at 500 °C, and the charcoal and bio-oil were evaluated for potential value-added use. The results showed that the pyrolysis process resulted in 26.3% charcoal, 57.6% bio-oil, and 16.0% non-condensable gases. Qualitative analysis of the bio-oil by gas chromatography/mass spectrometry found 178 chemical compounds; however, only 25% of those compounds could be reliably identified. Potential applications of the compounds identified in the bio-oil were determined by examining the published literature, and it was found that at least 73% of them showed promise. Finally, initial studies on the immediate analysis of the pyrolysis charcoal showed that it potentially meets the standards set forth for Brazilian domestic use.

scholarly journals Optimization and Characterization of Bio-oil Produced from Rice Husk Using Surface Response Methodology

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Ige Ayodeji Rapheal ◽  
Elinge Cosmos Moki ◽  
Aliyu Muhammad ◽  
Gwani Mohammed ◽  
Lawal Hassan Gusau
Keyword(s):  
Particle Size ◽  
Rice Husk ◽  
Fixed Bed ◽  
Production Optimization ◽  
Fixed Bed Reactor ◽  
Pyrolysis Process ◽  
Surface Response Methodology ◽  
Chemical Efficiency ◽  
Bio Oil

AbstractThe study depicts the production, optimization and characterization of bio-oil from pyrolyzed rice husk using a fabricated fixed bed reactor. The pyrolysis process was conducted with bio-oil response, bio-char response and non-condensable gases response as products. The effect of pyrolysis variables were observed by the production of the bio-oil as the response. Sixty runs of pyrolysis experiments were suggested by Box Benkhen design indicated optimum pyrolysis conditions at particle size of 2.03mm mesh, reaction time of 81.80 mins and temperature of 650oC for rice husk. The maximum bio-oil yield was obtained with 38.39% at optimum condition of the variables. The bio-oil sample obtained had better performance compared with ASTM standard. Such a determination would contribute so immensely to a significant comprehension of the chemical efficiency of the pyrolysis reaction.

Pyrolysis of waste animal fats in a fixed-bed reactor: Production and characterization of bio-oil and bio-char

2014 ◽  
Vol 34 (1) ◽  
pp. 210-218 ◽  
Author(s):  
A. Ben Hassen-Trabelsi ◽  
T. Kraiem ◽  
S. Naoui ◽  
H. Belayouni
Keyword(s):  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Animal Fats ◽  
Bio Oil ◽  
Reactor Production

Characterization of the bio-oil and bio-char produced by fixed bed pyrolysis of the brown alga Saccharina japonica

2016 ◽  
Vol 33 (9) ◽  
pp. 2691-2698 ◽  
Author(s):  
Jae Hyung Choi ◽  
Seung-Soo Kim ◽  
Dong Jin Suh ◽  
Eun-Jung Jang ◽  
Kyung-Il Min ◽  
...  
Keyword(s):  
Brown Alga ◽  
Fixed Bed ◽  
Saccharina Japonica ◽  
Bio Oil
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