scholarly journals Deacidification of Palm Oil Using Betaine Monohydrate-Carboxylic Acid Deep Eutectic Solvents: Combined Extraction and Simple Solvent Recovery

Processes ◽  
2020 ◽  
Vol 8 (5) ◽  
pp. 543 ◽  
Author(s):  
Kamarza Mulia ◽  
Mohammad Nasikin ◽  
Elsa Anisa Krisanti ◽  
Ida Zahrina
Keyword(s):  
Solvent Extraction ◽  
Palmitic Acid ◽  
Distribution Coefficient ◽  
Palm Oil ◽  
Natural Antioxidants ◽  
Deep Eutectic Solvents ◽  
Extraction Process ◽  
Effect Of Temperature ◽  
Palmitic Acid Content ◽  
Lower Temperature

Steam stripping is commonly used to remove free fatty acids from crude palm oil. An alternative deacidification method, solvent extraction performed at a much lower temperature, would preserve the natural antioxidants in the refined palm oil. In this work, palmitic acid was extracted using betaine monohydrate-propionic acid and betaine monohydrate-acetic acid deep eutectic solvents (DESs). The effect of temperature (40 °C to 80 °C), mass ratio of palm oil to solvent (2:1 to 1:2), and palmitic acid content in the palm oil feed (2% to 8% mass) on the distribution coefficient values of palmitic acid (0.44–0.93) was investigated. For the first time, a facile recovery of DESs could be accomplished by a cooling process where up to 98% of the palmitic acid separates as solid. A solvent extraction process for palm oil deacidification, employing a DES with a distribution coefficient value much higher than unity, will provide advantages over the steam stripping process.

scholarly journals Green Extraction of Palmitic Acid from Palm Oil using Betaine-Based Natural Deep Eutectic Solvents

2018 ◽  
Vol 9 (2) ◽  
pp. 335 ◽  
Author(s):  
Kamarza Mulia, Ph.D ◽  
Dezaldi Adam ◽  
Ida Zahrina ◽  
Elsa Krisanti, Ph.D
Keyword(s):  
Palmitic Acid ◽  
Palm Oil ◽  
Deep Eutectic Solvents ◽  
Green Extraction ◽  
Natural Deep Eutectic Solvents

scholarly journals Food-Safe Process for High Recovery of Flavonoids from Cocoa Beans: Antioxidant and HPLC-DAD-ESI-MS/MS Analysis

Antioxidants ◽  
2020 ◽  
Vol 9 (5) ◽  
pp. 364 ◽  
Author(s):  
Said Toro-Uribe ◽  
Elena Ibañez ◽  
Eric A. Decker ◽  
Arley René Villamizar-Jaimes ◽  
Luis Javier López-Giraldo
Keyword(s):  
Radical Scavenging Activity ◽  
Total Concentration ◽  
Radical Scavenging ◽  
Natural Antioxidants ◽  
Extraction Process ◽  
Degree Of Polymerization ◽  
Effect Of Temperature ◽  
Cocoa Beans ◽  
Recovery Method ◽  
Esi Ms

Considering the increasing interest in the incorporation of natural antioxidants in enriched foods, this work aimed to establish a food-grade and suitable procedure for the recovery of polyphenols from cocoa beans avoiding the degreasing process. The results showed that ultrasound for 30 min with particle sample size < 0.18 mm changed the microstructure of the cell, thus increasing the diffusion pathway of polyphenols and avoiding the degreasing process. The effect of temperature, pH, and concentration of ethanol and solute on the extraction of polyphenols was evaluated. Through a 24 full factorial design, a maximum recovery of 122.34 ± 2.35 mg GAE/g, 88.87 ± 0.78 mg ECE/g, and 62.57 ± 3.37 mg ECE/g cocoa beans, for total concentration of polyphenols (TP), flavonoids (TF), and flavan-3-ols (TF3), respectively, was obtained. Based on mathematical models, the kinetics of the solid–liquid extraction process indicates a maximum equilibrium time of 45 min. Analysis by HPLC-DAD-ESI-MS/MS showed that our process allowed a high amount of methylxanthines (10.43 mg/g), catechins (7.92 mg/g), and procyanidins (34.0 mg/g) with a degree of polymerization >7, as well as high antioxidant activity determined by Oxygen Radical Absorbance Capacity (1149.85 ± 25.10 µMTrolox eq/g) and radical scavenging activity (DPPH•, 120.60 ± 0.50 µM Trolox eq/g). Overall, the recovery method made possible increases of 59.7% and 12.8% in cocoa polyphenols content and extraction yield, respectively. This study showed an effective, suitable and cost-effective process for the extraction of bioactive compounds from cocoa beans without degreasing.

scholarly journals Correction: Gómez-Cruz et al. Valorisation of Exhausted Olive Pomace by an Eco-Friendly Solvent Extraction Process of Natural Antioxidants. Antioxidants 2020, 9, 1010

Antioxidants ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 948
Author(s):  
Irene Gómez-Cruz ◽  
Cristóbal Cara ◽  
Inmaculada Romero ◽  
Eulogio Castro ◽  
Beatriz Gullón
Keyword(s):  
Solvent Extraction ◽  
Natural Antioxidants ◽  
Extraction Process ◽  
Olive Pomace

The author wishes to make the following correction to this paper [...]

scholarly journals Karakteristik Antioksidan pada Kelopak Bunga Rosella (Hibiscus sabdariffa Linn.)

2018 ◽  
Vol 2 (3) ◽  
Author(s):  
Maria Inggrid ◽  
Yansen Hartanto ◽  
Jesslyn Fedora Widjaja
Keyword(s):  
Radical Reaction ◽  
Natural Antioxidants ◽  
Extraction Process ◽  
Differential Method ◽  
Effect Of Temperature ◽  
Anthocyanin Content ◽  
Free Radical Reaction ◽  
Total Anthocyanin ◽  
Batch Extraction ◽  
Extraction Solvent

ABSTRAKBunga rosella mengandung senyawa bioaktif dengan kadar antosianin yang tinggi. Antosianin termasuk golongan senyawa flavonoid yang dapat berperan sebagai antioksidan alami, mampu menghambat radikal bebas serta dapat mencegah terjadinya degeneratif sel dan penyakit lain. Tujuan penelitian adalah mempelajari pengaruh jenis pelarut dan temperatur pada ekstraksi rosella terhadap aktivitas dan kadar antosianin. Manfaat penelitian ini adalah menerapkan hasil peneliti ekstraksi antioksidan pada rosella bagi dunia usaha. Metode penelitian terdiri dari persiapan bahan baku, ekstraksi antosianin dan analisis. Rosella yang telah dikeringkan diekstraksi masing-masing menggunakan campuran pelarut etanol:air dengan variasi 0:100, 50:50 dan 70:30 % v/v , ekstraksi dilakukan masing-masing pada temperatur 30 ˚C, 45 ˚C, dan 60 ˚C. Analisis kimia meliputi penentuan kadar antosianin dengan metode pH differensial, penentuan aktivitas antioksidan dilakukan dengan metode DPPH (1,1-difenil-2 pikrilhidrazil). Hasil penelitian pada kondisi optimum ekstraksi adalah menggunakan pelarut etanol:air (50:50 v/v) pada temperatur 45 ˚C, kadar antosianin dan rendemen tertinggi masing-masing adalah 88,9 mg/L dan 53,2 %. Aktivitas antioksidan tertinggi ditunjukan dengan nilai IC50 yaitu 67,3 ppm. Penentuan kestabilan antosianin dilakukan dengan memberi perlakuan termal pada temperatur 30 ˚C, 45 ˚C, dan 60 ˚C, dari persamaan Arhenius diperoleh nilai energi aktivasi 18,3 kJ/mol.Kata Kunci: Rosella, ekstraksi, pelarut, temperatur, analisis, antioksidanABSTRACTRoselle contains bioactive compounds and has high quantity of anthocyanin. Anthocyanins, including flavonoid compounds that can be used as natural antioxidants, that has the ability to inhibit free radical reaction, in human body can prevent degenerative cell and various diseases. The objective of this research is to study the effect of solvent and temperature in a batch extraction of roselle to the anthocyanin product. The benefit of this research is to give the transfer of extraction product for the benefit of industry. Method used in this research consisting of the preparation of size reduction of roselle into smallest size followed by drying process, and extraction of roselle. Extraction can be done by two variables, namely ratio ethanol and water of 0:100 ; 50:50 ; 70:30 v/v respectively and temperature of 30oC, 45oC and 60oC. Analysis anthocyanin content was evaluated by the pH differential method, and the activity of antioxidant using a method of DPPH (1,1-diphenyl-2-picrylhydrazil). The research results can be shown that the optimum condition of temperature 45oC and ethanol water ratio of 50:50 followed by total anthocyanin of 88.9 mg/L, and yield content of 53.2%. The highest antioxidant activity indicated by IC50 value of 67.3 mg/L. The effect of temperature in a batch extraction process followed Arrhenius equation with energy activation of 18.3 kJ/mol.Keywords: Roselle, extraction, solvent, temperature, analysis, antioxidant

scholarly journals PENGARUH SUHU, RASIO BAHAN BAKU TERHADAP PELARUT DAN KECEPATAN PENGADUKAN PADA PROSES FRAKSINASI TRIPALMITIN DARI FRAKSI PADAT MINYAK SAWIT

2017 ◽  
Vol 6 (2) ◽  
pp. 95
Author(s):  
Fiqih Azis Pangestu ◽  
Tri Yuni Hendrawati ◽  
Wiwik Handayani
Keyword(s):  
Fatty Acids ◽  
Organic Solvent ◽  
Palmitic Acid ◽  
Palm Oil ◽  
Unsaturated Fatty Acids ◽  
Liquid Fraction ◽  
Saturated Fatty Acids ◽  
Solvent Ratio ◽  
Palmitic Acid Content ◽  
Fractionation Method

ABSTRAKMinyak sawit merupakan minyak yang paling banyak diproduksi di Indonesia. Minyak sawit mempunyai dua jenis produk yaitu fraksi padat (Stearin) dan fraksi cair (Olein). Asam lemak pada minyak sawit dibedakan menjadi dua golongan yaitu asam lemak jenuh dan asam lemak tak jenuh. Penelitian ini  bertujuan untuk memisahkan Tripalmitin dari fraksi padat minyak sawit melalui metode fraksinasi dengan pelarut organik. Variabel dalam penelitian ini menggunakan variasi rasio bahan baku / pelarut organik 1:10 (w/v) dan 1:12 (w/v) dengan suhu 2oC, 10oC, 20oC, 30oC, 40oC dan kecepatan pengadukan 300 rpm dan 500 rpm. Setelah itu sampel dianalisa dengan GC-MS untuk mengetahui kandungan asam palmitatnya dan didapatkan kandungan asam palmitat paling tinggi jika dimasukkan dalam rumus regresi sebagai berikut y = -0,0333x2 + 1,4518x + 67,617 dengan R² = 0,8431 dengan kandungan asam palmitat 84,91%. Kata kunci: Asam Palmitat, Fraksinasi, Pelarut Organik, Stearin ABSTRACTPalm oil is the most oil in Indonesia. Palm oil contains two types of products: solid fraction (Stearin) and liquid fraction (Olein). Fatty acids in palm oil are divided into two groups, namely saturated fatty acids and unsaturated fatty acids. This study aims to separate Tripalmitin from the hardness fraction of palm oil by fractionation method with organic solvent. The variables in this study used variation of organic / organic solvent ratio 1:10 (w / v) and 1:12 (w / v) with temperature 2oC, 10oC, 20oC, 30oC, 40oC and stirring speed 300 rpm and 500 rpm. After that the sample was analyzed with GC-MS to determine the content of palmitic acid and get the highest palmitic acid content if in the regression formula as follows y = -0.0333x2 + 1.4518x + 67,617 with R² = 0.8431 with the content of palmitic acid 84 , 91%. Keywords: Fractination, Organic Solvent, Palmitic Acid, Stearin

DEACIDIFICATION OF PALM OIL USING SOLVENT EXTRACTION INTEGRATED WITH MEMBRANE TECHNOLOGY

2016 ◽  
Vol 78 (12) ◽  
Author(s):  
S. O. Lai ◽  
S. L. Heng ◽  
K. C. Chong ◽  
W. J. Lau
Keyword(s):  
Fatty Acid ◽  
Solvent Extraction ◽  
Palmitic Acid ◽  
Palm Oil ◽  
Membrane Technology ◽  
Experimental Results ◽  
Solvent Ratio ◽  
Crude Palm Oil ◽  
Acid Reduction

In this work, the efficiency of crude palm oil (CPO) deacidification using solvent extraction integrated with membrane technology is studied. Different solvents including ethanol, hexane and methanol were selected to extract the palmitic acid from model fatty system in the model fatty system to solvent ratio of 1:2. Experimental results showed that ethanol was the best solvent to extract palmitic acid from the model fatty system, recording about 65.5% fatty acid reduction in the model fatty system. Three commercial solvent resistant nanofiltration (SRNF) membranes (SolSep NF010206, NF030306, and NF030705) were then selected to examine their respective performance in recovering ethanol from palmitic acid-rich ethanol solvent. The results revealed that the combination of solvent extraction and membrane technology is remarkable simple and waste-free approach to overcome major drawbacks of conventional refinery operation.  

scholarly journals Environmentally Friendly Techniques and Their Comparison in the Extraction of Natural Antioxidants from Green Tea, Rosemary, Clove, and Oregano

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1869
Author(s):  
Mariel Calderón-Oliver ◽  
Edith Ponce-Alquicira
Keyword(s):  
Green Tea ◽  
Electric Fields ◽  
Antioxidant Activities ◽  
Environmentally Friendly ◽  
Natural Antioxidants ◽  
Deep Eutectic Solvents ◽  
Extraction Methods ◽  
Extraction Techniques ◽  
Health Trends ◽  
Food Applications

Many current food and health trends demand the use of more ecological, sustainable, and environmentally friendly techniques for the extraction of bioactive compounds, including antioxidants. However, extraction yields and final antioxidant activities vary between sources and are highly influenced by the given extraction method and nature and ratio of the employed solvent, especially for total polyphenols, flavonoids, and anthocyanins, which are well recognized as natural antioxidants with food applications. This review focused on the most common extraction techniques and potential antioxidant activity in the food industry for various natural antioxidant sources, such as green tea, rosemary, clove, and oregano. Green extraction techniques have been proven to be far more efficient, environmentally friendly, and economical. In general, these techniques include the use of microwaves, ultrasound, high hydrostatic pressure, pulsed electric fields, enzymes, and deep eutectic solvents, among others. These extraction methods are described here, including their advantages, disadvantages, and applications.

scholarly journals Study on the Effect and Mechanism of Impurity Aluminum on the Solvent Extraction of Rare Earth Elements (Nd, Pr, La) by P204-P350 in Chloride Solution

Minerals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 61
Author(s):  
Wenjie Zhang ◽  
Xian Xie ◽  
Xiong Tong ◽  
Yunpeng Du ◽  
Qiang Song ◽  
...  
Keyword(s):  
Rare Earth ◽  
Solvent Extraction ◽  
Rare Earth Elements ◽  
Organic Phase ◽  
Extraction Process ◽  
Industrial Applications ◽  
Separation And Purification ◽  
Aluminum Ion ◽  
Hydrochloric Acid Medium ◽  
Impurity Ion

Solvent extraction is the most widely used method for separation and purification of rare earth elements, and organic extractants such as di(2-ethylhexyl) phosphoric acid (P204) and di(1-methyl-heptyl) methyl phosphonate (P350) are most commonly used for industrial applications. However, the presence of impurity ions in the feed liquid during extraction can easily emulsify the extractant and affect the quality of rare earth products. Aluminum ion is the most common impurity ion in the feed liquid, and it is an important cause of emulsification of the extractant. In this study, the influence of aluminum ion was investigated on the extraction of light rare earth elements by the P204-P350 system in hydrochloric acid medium. The results show that Al3+ competes with light rare earths in the extraction process, reducing the overall extraction rate. In addition, the Al3+ stripping rate is low and there is continuous accumulation of Al3+ in the organic phase during the stripping process, affecting the extraction efficiency and even causing emulsification. The slope method and infrared detection were utilized to explore the formation of an extraction compound of Al3+ and the extractant P204-P350 that entered the organic phase as AlCl[(HA)2]2P350(o).

Sign in / Sign up

Export Citation Format

Share Document