scholarly journals Rheological Properties of Aqueous Dispersions of Bacterial Cellulose

Processes ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 423
Author(s):  
Markel I. Vinogradov ◽  
Igor S. Makarov ◽  
Lyudmila K. Golova ◽  
Peter S. Gromovykh ◽  
Valery G. Kulichikhin
Keyword(s):  
Bacterial Cellulose ◽  
Loss Modulus ◽  
Time Lag ◽  
Viscoelastic Behavior ◽  
Mechanical Action ◽  
Cellulose Content ◽  
Main Indicator ◽  
Thixotropic Behavior ◽  
Absolute Viscosity ◽  
The Stability

Bacterial cellulose as polysaccharide possessing outstanding chemical purity and a unique structure compared with wood cellulose, attracts great attention as a hydrocolloid system. It was shown, that at intense mechanical action on a neat bacterial cellulose film in presence of water, the gel-like dispersions are obtained. They retain stability in time (at least, up to several months) and temperature (at least, up to 60 °C) without macro-phase separation on aqueous and cellulose phases. The main indicator of the stability is constant viscosity values in time, as well as fulfilling the Arrhenius dependence for temperature dependence of viscosity. Flow curves of diluted dispersions (BC content less than 1.23%) show strong non-Newtonian behavior over the entire range of shear rates. It is similar with dispersions of micro- and nanocrystalline cellulose, but the absolute viscosity value is much higher in the case of BC due to more long fibrils forming more dense entanglements network than in other cases. Measuring the viscosity in increase and decrease shear rate modes indicate an existence of hysteresis loop, i.e., thixotropic behavior with time lag for recovering the structural network. MCC and NCC dispersions even at cellulose content more than 5% do not demonstrate such behavior. According to oscillatory measurements, viscoelastic behavior of dispersions corresponds to gel-like systems with almost total independence of moduli on frequency and essentially higher values of the storage modulus compared with the loss modulus.

Influence of κ-Carrageenan, Modified Starch and Inulin Addition on Rheological and Sensory Properties of Non-fat and Non-added Sugar Dairy Dessert

2020 ◽  
Vol 16 (4) ◽  
pp. 462-469
Author(s):  
Zhaleh Sheidaei ◽  
Bahareh Sarmadi ◽  
Seyede M. Hosseini ◽  
Fardin Javanmardi ◽  
Kianoush Khosravi-Darani ◽  
...  
Keyword(s):  
Storage Modulus ◽  
Loss Modulus ◽  
Viscoelastic Behavior ◽  
Textural Properties ◽  
Complex Viscosity ◽  
Sensory Properties ◽  
Modified Starch ◽  
Consumer Health ◽  
Added Sugar ◽  
Textural Parameters

<P>Background: The high amounts of fat, sugar and calorie existing in dairy desserts can lead to increase the risk of health problems. Therefore, the development of functional and dietary forms of these products can help the consumer health. </P><P> Objective: This study aims to investigate the effects of &#954;-carrageenan, modified starch and inulin addition on rheological and sensory properties of non-fat and non-added sugar dairy dessert. </P><P> Methods: In order to determine the viscoelastic behavior of samples, oscillatory test was carried out and the values of storage modulus (G′), loss modulus (G″), loss angle tangent (tan &#948;) and complex viscosity (&#951;*) were measured. TPA test was used for analysis of the desserts’ texture and textural parameters of samples containing different concentrations of carrageenan, starch and inulin were calculated. </P><P> Results: All treatments showed a viscoelastic gel structure with the storage modulus higher than the loss modulus values. Increasing amounts of &#954;-carrageenan and modified starch caused an increase in G′ and G″ as well as &#951;* and a decrease in tan &#948;. Also, firmness and cohesiveness were enhanced. The trained panelists gave the highest score to the treatment with 0.1% &#954;-carrageenan, 2.5% starch and 5.5% inulin (sucralose as constant = 0.25%) and this sample was the best treatment with desirable attributes for the production of non-fat and non-added sugar dairy dessert. </P><P> Conclusion: It can be concluded that the concentration of &#954;-carrageenan and starch strongly influenced the rheological and textural properties of dairy desserts, whereas the inulin content had little effect on these attributes.</P>

Braucht die EU einen flexibleren Stabilitätspakt?

2004 ◽  
Vol 53 (1) ◽  
Author(s):  
Carsten Hefeker ◽  
Friedrich Heinemann ◽  
Klaus F. Zimmermann
Keyword(s):  
Public Awareness ◽  
Time Lag ◽  
Fiscal Rules ◽  
External Control ◽  
Public Expenditures ◽  
Stability And Growth Pact ◽  
Consolidation Process ◽  
Growth Pact ◽  
Long Run ◽  
The Stability

AbstractIn his contribution Carsten Hefeker points out that most of the official arguments concerning the necessity of the Stability and Growth Pact are not convincing. Nevertheless, a mechanism that credibly avoids excessive debts and deficits is needed in most member states. It would be more useful, however, if such rules would focus on overall debt rather than on deficits. In addition, he advocates to create an external control for such fiscal rules, independent from the Commission and ECOFIN. He concludes that the Pact does not need to become more flexible, but more credible.Friedrich Heinemann states that much of the recent reform debate on the Stability Pact is based on a fundamental misconception: The Pact has not been established as a guiding tool for welfare - maximising politicians, but in order to limit detrimental incentives from fiscal short-sightedness. “Stupid” elements like the three-per-cent deficit ceiling have a clear and beneficial strategic function as boundary within the national budgetary process. Furthermore, simple rules are superior to smart ones in increasing the political costs of high deficits in terms of public awareness. The critique on the pact′s missing flexibility is correct mainly regarding its lose logical link to long-run sustainability. Increasing flexibility in a cyclical sense, however, is not a reform priority. Already today the Pact leaves sufficient leeway for responsible politicians. Instead, the reform focus must be on depoliticising the pact in the sense of limiting Council power in the deficit procedure. More flexibility must not come without depoliticising. He recommends that any reform should only be carried into effect with a significant time lag in order to limit the reputation damage which would be the consequence of any quick institutional response to the Pact′s recent crisis.In his paper Klaus F. Zimmermann argues that the Stability and Growth Pact (SGP) has been subject to criticism ever since its inception. He points out that it overlooks business cycle developments within the framework of the consolidation process; it adopts a too short-term view of the stabilisation target which is also hardly under control of policy-makers; and it deals with policy imperfections in a sub-optimal way. Therefore, a reform of the SGP is urgent. The author suggests that the rules must be handled more flexibly. In his opinion, a mediumterm budgetary target and a focus on public expenditures to tackle the pro-cyclical bias is needed. To restore credibility, the task of supervision should be transferred to an independent European institution.

A note on the stability of uncertain time-lag systems

1995 ◽  
Vol 332 (6) ◽  
pp. 773-782
Author(s):  
Yeong-Jeu Sun ◽  
Jer-Guang Hsieh
Keyword(s):  
Time Lag ◽  
The Stability ◽  
Uncertain Time

scholarly journals Managing cost uncertainties in transportation and assignment problems

1998 ◽  
Vol 2 (1) ◽  
pp. 65-104 ◽  
Author(s):  
V. Adlakha ◽  
H. Arsham
Keyword(s):  
Time Lag ◽  
Real Life ◽  
Optimal Solution ◽  
Global Market ◽  
Solution Algorithm ◽  
Assignment Problems ◽  
The Stability ◽  
Order Assignment ◽  
Cost Parameters ◽  
The Cost

In a fast changing global market, a manager is concerned with cost uncertainties of the cost matrix in transportation problems (TP) and assignment problems (AP).A time lag between the development and application of the model could cause cost parameters to assume different values when an optimal assignment is implemented. The manager might wish to determine the responsiveness of the current optimal solution to such uncertainties. A desirable tool is to construct a perturbation set (PS) of cost coeffcients which ensures the stability of an optimal solution under such uncertainties.The widely-used methods of solving the TP and AP are the stepping-stone (SS) method and the Hungarian method, respectively. Both methods fail to provide direct information to construct the needed PS. An added difficulty is that these problems might be highly pivotal degenerate. Therefore, the sensitivity results obtained via the available linear programming (LP) software might be misleading.We propose a unified pivotal solution algorithm for both TP and AP. The algorithm is free of pivotal degeneracy, which may cause cycling, and does not require any extra variables such as slack, surplus, or artificial variables used in dual and primal simplex. The algorithm permits higher-order assignment problems and side-constraints. Computational results comparing the proposed algorithm to the closely-related pivotal solution algorithm, the simplex, via the widely-used pack-age Lindo, are provided. The proposed algorithm has the advantage of being computationally practical, being easy to understand, and providing useful information for managers. The results empower the manager to assess and monitor various types of cost uncertainties encountered in real-life situations. Some illustrative numerical examples are also presented.

scholarly journals Natural Gums to Improve the Physicochemical Stability of Cake Creams

Foods ◽  
2021 ◽  
Vol 10 (10) ◽  
pp. 2261
Author(s):  
Oscar López-Balladares ◽  
Patricio J. Espinoza-Montero ◽  
Ramiro Acosta-Sandoval
Keyword(s):  
Physicochemical Properties ◽  
Elastic Deformation ◽  
Bubble Size ◽  
Physicochemical Changes ◽  
Physicochemical Stability ◽  
Confectionery Products ◽  
Initial Appearance ◽  
Thixotropic Behavior ◽  
The Aesthetic ◽  
The Stability

The physicochemical properties of pastry and confectionery products greatly influence the aesthetic design of a cake topping, since they can be susceptible to physicochemical changes in a very short time, so maintaining a good appearance and texture of the topping becomes a challenge. Generally, cake creams deteriorate over time. The evaluation of the physicochemical properties of natural gums (arabic gum, tara gum, carrageenan, and pectin) is proposed in this work as a way to improve the physicochemical stability of butter-based cake creams (coverage creams) to maintain the initial appearance of the cream and to lengthen the separation time of their phases. For this purpose, some parameters related to the physicochemical stability of the cream, such as viscosity, density, bubble size, syneresis, volume and rheological behavior were measured. The result of the ANOVA and Tukey’s tests displayed significant differences for the measured parameters, which shows that natural gums substantially improve the stability of butter cream. The best natural gum found was the tara gum (TG) which improved viscosity 5.6 times with respect to that of the cream without gums (η¯ without gums = 15.49 Pa·s, η¯ with TG = 87.09 Pa·s), while the bubble size remained small, 1.6 times smaller compared to that of the cream without gum (BS¯) without gums = 57 μm, (BS¯) with TG = 35 μm), and the volume loss decreased two times when compared to that of the cream without gums ((ΔV¯) without gums = 1.57 cm3, (ΔV¯) with TG = 0.80 cm3). The cream with TG showed better rheology compared to that of the cream without gums (the cream without gums exhibited a plastic and thixotropic behavior, with permanent elastic deformation, while cream with TG exhibited thixotropic behavior without permanent elastic deformation). Finally, it was found that the cream with TG acquired a higher thixotropic index (TI) compared to that of the cream without gums (TI max. without gums = 17.40 y 71.78 q.u., TI max. with TG = 74.67 and 1559.90 q.u., at 4 °C and 25 °C, respectively) which demonstrates the effective contribution of cream with TG in 66.67% of the measured parameters.

Bacterial Cellulose Reinforced Flax Fibre Composites: Effect of Nanocellulose Loading on Composite Properties

2015 ◽  
Vol 825-826 ◽  
pp. 1063-1067
Author(s):  
Marta Fortea-Verdejo ◽  
Elias Bumbaris ◽  
Koon Yang Lee ◽  
Alexander Bismarck
Keyword(s):  
Tensile Strength ◽  
Bacterial Cellulose ◽  
Flax Fibre ◽  
The Other ◽  
Cellulose Content ◽  
Polypropylene Composites ◽  
Flax Fibres ◽  
Paper Making ◽  
Fibre Composites ◽  
Composite Properties

Loose hierarchical flax fibres/polypropylene composites were manufactured in a simple way based on a paper-making process in order to include nanocellulose and allow the hornification of the nanofibres in a controlled manner. The effect of flax fibre content on the flax/polypropylene composites and the influence of nanocellulose on the properties of these composites are discussed. By increasing the flax content a slight decrease of the tensile strength and an increase of the Young´s modulus were observed. On the other hand, no significant effect was noticed when increasing the bacterial cellulose content in the composites.

Modeling the Vibratory Drilling Process

1999 ◽  
Author(s):  
Stephen A. Batzer ◽  
Alexander M. Gouskov ◽  
Sergey A. Voronov
Keyword(s):  
Rotational Velocity ◽  
Time Lag ◽  
Chip Thickness ◽  
Cutting Conditions ◽  
Model Parameters ◽  
Drilling Process ◽  
Workpiece Material ◽  
Velocity Amplitude ◽  
The Stability

Abstract The dynamic behavior of deep-hole vibratory drilling is analyzed. The mathematical model presented allows the determination of axial tool and workpiece displacements and cutting forces for significant dynamic system behavior such as the entrance of the cutting tool into workpiece material and exit. Model parameters include the actual rigidity of the tool and workpiece, time-varying chip thickness, time lag for chip formation due to tool rotation and possible disengagement of drill cutting edges from the workpiece due to tool and/or workpiece axial vibrations. The main features of this model are its nonlinearity and inclusion of time lag differential equations which require numeric solutions. The specific cutting conditions (feed, tool rotational velocity, amplitude and frequency of forced vibrations) necessary to obtain discontinuous chips and reliable removal are determined. The stability conditions of excited vibrations are also investigated. Calculated bifurcation diagrams make it possible to derive the domain of system parameters along with the determination of optimal cutting conditions.

A Molecular Structure-Informed Viscoelastic Constitutive Model for Natural Rubber Materials

2021 ◽  
Author(s):  
Jiwon Jung ◽  
Chanwook Park ◽  
myungshin RYU ◽  
Gunjin Yun
Keyword(s):  
Molecular Structure ◽  
Constitutive Equation ◽  
Molecular System ◽  
Loss Modulus ◽  
Low Frequency ◽  
Viscoelastic Behavior ◽  
Material Model ◽  
Coarse Grained ◽  
Diffusivity Coefficient ◽  
Element Analysis

Abstract This paper presents a molecular structure-informed viscoelastic constitutive equation that adopts the Doi-Edward’s tube model with coarse-grained molecular dynamics (MD) simulation and primitive path analysis. Since this model contains polymer physics-related parameters directly obtained from molecular simulations, it can reflect molecular information in predictions of the viscoelastic behavior of elastomers, unlike other empirical models. The proposed incremental formulations and constitutive stiffness matrix were implemented into implicit finite element analysis (FEA) codes as a user-supplied material model and viscoelastic properties (storage, loss modulus, and tan⁡δ) were calculated from the constitutive equation. While obtaining polymer dynamics parameter of the molecular system, a relationship between self-diffusivity coefficient (D_c) and the polymerization degree of the polymer was confirmed. Furthermore, a series of parametric studies showed that increase of the primitive path length (L) and decrease of D_c have led to the strengthening of moduli and decrease of tan⁡δ peak. Moreover, under the same condition, the shift of tan⁡δ peak to low-frequency domain was observed, which implies a decline in free volume in the molecular system and an increase in the glass transition temperature.

Nonseparable Behavior in Rubber Viscoelasticity

1989 ◽  
Vol 62 (1) ◽  
pp. 68-81 ◽  
Author(s):  
J. L. Sullivan ◽  
K. A. Mazich
Keyword(s):  
Stress Relaxation ◽  
Relaxation Spectrum ◽  
Loss Modulus ◽  
Large Strain ◽  
Viscoelastic Behavior ◽  
Strain Effects ◽  
Mixed Response ◽  
Strain Stress ◽  
Necessary And Sufficient ◽  
Solid Liquid

Abstract New large-strain rubber viscoelasticity results for a filled and an unfilled IIR vulcanizate and previously published results for two NR gum vulcanizates have been discussed. The data show that the “mixed” response functions of large-strain stress relaxation, and the incremental storage and relaxation moduli do not demonstrate factorizability of time and strain effects. This is a consequence of the elastic and relaxation contributions in each of the mixed functions being different. The incremental dynamic data also show that the loss modulus for the filled IIR and unfilled NR vulcanizates (unavailable for the unfilled IIR) are separable functions of time and strain. This directly shows that the relaxation spectra for the filled IIR and unfilled NR vulcanizates are independent of strain for the deformations studied. In fact, it is argued that a necessary and sufficient condition for the relaxation spectrum to be independent of strain is that the loss modulus is a factorizable function of time and strain effects. The quantitative success of the Generalized Solid-Liquid (GSL) model in representing the viscoelastic behavior of the gum NR vulcanizate has been reviewed. Although the GSL model applies only to unfilled vulcanizates, it has also been successfully used to qualitatively interpret the results for the filled IIR compounds. Both successes are attributed to the physical assumptions intrinsic to the GSL model; more specifically, 1) the relaxation spectrum is independent of the state of strain, and 2) the deformational dependences of elastic and relaxation contributions to the overall response of the system need not be the same. Physical arguments justifying these assumptions have been covered. It has also been shown with the aid of the GSL model, that a material might exist which demonstrates factorizability in stress relaxation and incremental loss modulus behaviors but nonfactorizability in the incremental storage and relaxation moduli.

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