scholarly journals Surface Treatments of Coffee Husk Fiber Waste for Effective Incorporation into Polymer Biocomposites

Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3428
Author(s):  
Bárbara Maria Mateus Gonçalves ◽  
Mayara de Oliveira Camillo ◽  
Michel Picanço Oliveira ◽  
Lilian Gasparelli Carreira ◽  
Jordão Cabral Moulin ◽  
...  

Natural lignocellulose fibers have been extensively investigated and applied as a reinforcement of polymer composites in industrial applications from food packing to automotive parts. Among the advantages of natural fibers stands their relatively low cost and sustainable characteristics. These are accentuated in the case of residual fibers such as those obtained from coffee husks, an agribusiness waste, usually burnt or disposed into the environment. As composite reinforcement, hydrophilic natural fibers display adhesion problems to the most hydrophobic polymer matrices. This adhesion might be improved with distinct types of fibers surface treatments. In the present work, the effectiveness of three surface treatments applied to coffee husk fiber wastes (CHFW) were investigated, aiming to improve the tensile performance of castor oil-based polyurethane (COPU) biocomposites. The effects of treatments associated with (i) chemical with sodium hydroxide, (ii) physical by temperature and pressure and hydrothermic treatment, and (iii) biological by fermentation with Phanerochaete Chrysosporium fungus were evaluated by means of Fourier transformed infrared spectroscopy, X-ray diffraction, thermal analyses and morphology by scanning electron microscopy for different concentration of NaOH, different hydrothermic times at 121 °C/98 kPa and exposition to P. chrysosporium. The most effective treatment was the hydrothermal one at 121 °C and 98.06 kPa for 30 min. Preliminary tensile tests were performed in COPU biocomposites reinforced with 20% CHFWs subjected to the optimized conditions for each distinct type of treatment. The results indicated that the hydrothermal treatment promoted significant enhancement in the fiber/matrix interfacial bond, increasing the tensile strength up to 60% compared to COPU reinforced with in natura CHFWs fibers. It is important to mention that these composites can be applied as plastic wood for household items’ internal parts and in the automobile industry.

2015 ◽  
Vol 766-767 ◽  
pp. 173-177
Author(s):  
J.M. Prabhudass ◽  
K. Palanikumar

Composite materials are preferred in all engineering applications, nowadays, because of their superior properties over the traditional materials. Among Composite materials, Natural fiber reinforced polymer finds rapid development in Industrial applications and many areas of research. The main advantageous features of these composites are Renewability, Biodegradability and low cost. They are less dense and also easily available. These Natural fibers replace synthetic fibers in many important applications like Automobiles, Aerospace, etc. This paper reviews the research work carried on different types of Natural fibers reinforced polymer along with their preparation and properties, especially Sisal and Banana fibers.


Author(s):  
Mahdi Mohammadizadeh ◽  
Hao Lu ◽  
Ismail Fidan ◽  
Khalid Tantawi ◽  
Ankit Gupta ◽  
...  

Metal additive manufacturing (AM) has gained much attentions in recent years due to its advantages including geometric freedom and design complexity, appropriate to a wide range of potential industrial applications. However, conventional metal AM methods have high-cost barriers due to the initial cost of the capital equipment, support and maintenance, etc. This study presents a unique low-cost metal material extrusion (MME) technology. The filaments used have polylactic acid (PLA) as the matrix and metal powders (copper, bronze, stainless steel, high carbon iron, and aluminum) as reinforcements. Using the proposed fabrication technology, test specimens were built by extruding polymer/metal composite filaments, which were then sintered in an open-air furnace to produce solid metallic parts. In this research, the mechanical and thermal properties of the built parts are examined using tensile tests, thermogravimetric-, thermomechanical- and microstructural analysis.


Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1301
Author(s):  
Federico Cavedo ◽  
Parisa Esmaili ◽  
Michele Norgia

A low-cost optical reflectivity sensor is proposed in this paper, able to detect the presence of objects or surface optical properties variations, at a distance of up to 20 m. A collimated laser beam is pulsed at 10 kHz, and a synchronous digital detector coherently measures the back-diffused light collected through a 1-inch biconvex lens. The sensor is a cost-effective solution for punctual measurement of the surface reflection at different distances. To enhance the interference immunity, an algorithm based on a double-side digital baseline restorer is proposed and implemented to accurately detect the amplitude of the reflected light. As results show, the sensor is robust against ambient light and shows a strong sensitivity on a wide reflection range. The capability of the proposed sensor was evaluated experimentally for object detection and recognition, in addition to dedicated measurement systems, like remote encoders or keyphasors, realized far from the object to be measured.


Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2299
Author(s):  
Jéssica P. Silva ◽  
Alonso R. P. Ticona ◽  
Pedro R. V. Hamann ◽  
Betania F. Quirino ◽  
Eliane F. Noronha

Lignocellulosic residues are low-cost abundant feedstocks that can be used for industrial applications. However, their recalcitrance currently makes lignocellulose use limited. In natural environments, microbial communities can completely deconstruct lignocellulose by synergistic action of a set of enzymes and proteins. Microbial degradation of lignin by fungi, important lignin degraders in nature, has been intensively studied. More recently, bacteria have also been described as able to break down lignin, and to have a central role in recycling this plant polymer. Nevertheless, bacterial deconstruction of lignin has not been fully elucidated yet. Direct analysis of environmental samples using metagenomics, metatranscriptomics, and metaproteomics approaches is a powerful strategy to describe/discover enzymes, metabolic pathways, and microorganisms involved in lignin breakdown. Indeed, the use of these complementary techniques leads to a better understanding of the composition, function, and dynamics of microbial communities involved in lignin deconstruction. We focus on omics approaches and their contribution to the discovery of new enzymes and reactions that impact the development of lignin-based bioprocesses.


Electronics ◽  
2021 ◽  
Vol 10 (9) ◽  
pp. 1099
Author(s):  
Ye-Ji Han ◽  
Se Hyeong Lee ◽  
So-Young Bak ◽  
Tae-Hee Han ◽  
Sangwoo Kim ◽  
...  

Conventional sol-gel solutions have received significant attention in thin-film transistor (TFT) manufacturing because of their advantages such as simple processing, large-scale applicability, and low cost. However, conventional sol-gel processed zinc tin oxide (ZTO) TFTs have a thermal limitation in that they require high annealing temperatures of more than 500 °C, which are incompatible with most flexible plastic substrates. In this study, to overcome the thermal limitation of conventional sol-gel processed ZTO TFTs, we demonstrated a ZTO TFT that was fabricated at low annealing temperatures of 350 °C using self-combustion. The optimized device exhibited satisfactory performance, with μsat of 4.72 cm2/V∙s, Vth of −1.28 V, SS of 0.86 V/decade, and ION/OFF of 1.70 × 106 at a low annealing temperature of 350 °C for one hour. To compare a conventional sol-gel processed ZTO TFT with the optimized device, thermogravimetric and differential thermal analyses (TG-DTA) and X-ray photoelectron spectroscopy (XPS) were implemented.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Guhankumar Ponnusamy ◽  
Hajar Farzaneh ◽  
Yongfeng Tong ◽  
Jenny Lawler ◽  
Zhaoyang Liu ◽  
...  

AbstractHeterogeneous catalytic ozonation is an effective approach to degrade refractory organic pollutants in water. However, ozonation catalysts with combined merits of high activity, good reusability and low cost for practical industrial applications are still rare. This study aims to develop an efficient, stable and economic ozonation catalyst for the degradation of Ibuprofen, a pharmaceutical compound frequently detected as a refractory pollutant in treated wastewaters. The novel three-dimensional network-structured catalyst, comprising of δ-MnO2 nanosheets grown on woven carbon microfibers (MnO2 nanosheets/carbon microfiber), was synthesized via a facile hydrothermal approach. Catalytic ozonation performance of Ibuprofen removal in water using the new catalyst proves a significant enhancement, where Ibuprofen removal efficiency of close to 90% was achieved with a catalyst loading of 1% (w/v). In contrast, conventional ozonation was only able to achieve 65% removal efficiency under the same operating condition. The enhanced performance with the new catalyst could be attributed to its significantly increased available surface active sites and improved mass transfer of reaction media, as a result of the special surface and structure properties of this new three-dimensional network-structured catalyst. Moreover, the new catalyst displays excellent stability and reusability for ibuprofen degradation over successive reaction cycles. The facile synthesis method and low-cost materials render the new catalyst high potential for industrial scaling up. With the combined advantages of high efficiency, high stability, and low cost, this study sheds new light for industrial applications of ozonation catalysts.


e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 613-623
Author(s):  
José Manuel Sandoval-Díaz ◽  
Francisco Javier Rivera-Gálvez ◽  
Marta Fernández-García ◽  
Carlos Federico Jasso-Gastinel

AbstractIn this work, for a semicontinuous emulsion polymerization reaction, it is shown that using a redox initiation system at 40°C, substantial modifications in copolymer chain composition with conversion can be easily obtained. To test controllable trajectories for comonomer feeding, linear and parabolic profiles were chosen to get different types of chain composition variations for the 50/50 w/w styrene/n-butyl acrylate system. For the “forced composition copolymers,” the molecular weight averages and distribution were obtained by size exclusion chromatography. The composition along conversion was followed by proton nuclear magnetic resonance to determine the weight composition distribution (WCD) of the copolymer chains. Mechanodynamic (dynamic-mechanical analysis), tensile, and hardness tests exhibited consistent results depending on the WCD that outcomes from the respective feeding profile. The results confirm that this methodology is of great potential for industrial applications when looking for synergy in copolymer properties, and low-cost processes.


Author(s):  
Philipp Andreazza ◽  
Andreas Gericke ◽  
Knuth-Michael Henkel

AbstractArc brazing with low-melting copper-based filler materials, which has long been established and standardized in the thin sheet sector, offers numerous advantages in the processing of predominantly electrolytically galvanized steel structures. In steel and shipbuilding, on the other hand, equipment parts made of thick steel sheets are hot-dip galvanized at low cost and with good corrosion-inhibiting properties. Quality welding of such constructions is not possible without special precautions such as removing the zinc layer and subsequent recoating. With regard to greater plate thicknesses, arc brazing was analyzed in these investigations as an alternative joining method with regard to its suitability for practical use. Within the scope of the investigations, CuSi3Mn, CuMn12Ni2, and four different aluminum bronzes were examined on different sheet surface conditions with regard to the geometrical and production parameters. This was carried out by build-up and connection brazing, executed as butt and cross joints. Quasi-static tensile tests and fatigue tests were used to assess the strength behavior. In addition, metallographic analyses are carried out as well as hardness tests. The suitability for multi-layer brazing and the tendency to distortion were also investigated, as well as the behavior of arc brazed joints under corrosive conditions.


2013 ◽  
Vol 592-593 ◽  
pp. 643-646 ◽  
Author(s):  
Marko Šori ◽  
Tomaž Verlak ◽  
Srečko Glodež

Low cost, low material waste and good accuracy in components with complex geometry are the main reasons for powder metallurgy to be considered as a promising manufacturing process for the future. Like wrought steel, sintered steel can also be heat treated to increase surface hardness and to improve strength. This paper compares mechanical properties of the hardened sintered steel with the sintered steel of the same powder metal SINT D30. Firstly, the static strength of both samples is determined by quasi-static tensile tests. Results are compared in stress strain diagram and they show that the tensile strength of the hardened sintered steel SINT D30 can surpass 700 MPa. The main focus of this study is however fatigue behaviour of the sintered steel. Both sets of samples are tested on a pulsating test machine with the load ratio of R = 0. The first sample is subjected to a load that corresponds to 90 % of the yield strength and is then gradually lowered to achieve one million stress cycles without breakage. Obtained results are then presented as Wöhler curves and compared in S-N diagram.


Author(s):  
G A Parker ◽  
Y B Sun

The work presented in this paper deals mainly with a mechatronic approach to compact disc valve design and concentrates on improvements to the disc valve electromagnetic characteristics, the diaphragm design and the dynamic performance. A novel diaphragm-disc force motor has been successfully developed incorporating a pair of permanent ring magnets. It has the advantages of low electric power consumption at the null position, dual-lane electrical structure for fail-safe operation, high control accuracy and should be competitive with existing torque motors due to its low cost and simple construction. The research involved designing and testing a prototype disc pilot valve with a dual-lane operating mode. The test results showed that the valve has satisfactory static and dynamic characteristics for industrial applications.


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