scholarly journals A Review on Synthesis, Structural, Flame Retardancy and Dielectric Properties of Hexasubstituted Cyclotriphosphazene

Polymers ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2916
Author(s):  
Siti Nur Khalidah Usri ◽  
Zuhair Jamain ◽  
Mohamad Zul Hilmey Makmud
Keyword(s):  
Dielectric Properties ◽  
Nitrogen Atom ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
High Potential ◽  
Research Development ◽  
Electrical Field ◽  
Active Elements ◽  
Good Ability ◽  
Low Toxicity

Hexachlorocyclotriphosphazene is a ring compound consisting of an alternating phosphorus and nitrogen atom with two chlorine substituents attached to the phosphorus atom. The six chlorine atoms attached to this cyclo compound can be substituted with any different nucleophile that leads to changes in different chemical and physical properties. The major topics that were investigated in this research are the flame retardancy and dielectric properties of cyclotriphosphazene compounds. Cyclotriphosphazene compounds have high potential to act as a flame retardant, and this compound consists of two active elements attributed to its high flame-retardant character. This compound also demonstrated good ability as a flame retardant due to its low toxicity and less smoke produced. In addition, cyclotriphosphazene compounds were also investigated for their dielectric properties. Cyclotriphosphazene has high potential in the electrical field since it has dielectric properties that can be widely studied in the investigation of any potential application. This review presented literature studies focused on recent research development and studies in the field of cyclotriphosphazene that focused on synthesis, structural, flame retardancy, and dielectric properties of hexachlorocyclotriphosphazene compounds.

scholarly journals Modified organophosphorus fire retardant with low toxicity/high flame retardancy using the pharmacophore model associated with Mamdani fuzzy inference approach

2020 ◽  
Vol 477 (23) ◽  
pp. 4655-4674
Author(s):  
Jiawen Yang ◽  
Yilin Hou ◽  
Qing Li ◽  
Yu Li
Keyword(s):  
Flame Retardant ◽  
Flame Retardancy ◽  
Density Functional ◽  
Fuzzy Inference ◽  
Reproductive Toxicity ◽  
Pharmacophore Model ◽  
Fire Retardant ◽  
3D Qsar ◽  
Comprehensive Model ◽  
Low Toxicity

The bi-directional selective low toxicity/high flame retardancy organophosphorus fire retardants (OPFRs) derivatives were designed by a comprehensive effect 3D quantitative structure-activity relationship (QSAR) pharmacophore model, and the toxicity and flame retardancy mechanism of OPFR derivatives were explored. The 3D-QSAR comprehensive pharmacophore model was constructed using the toxicity/flame retardancy comprehensive evaluation values of OPFRs for molecular modifications, which were obtained by the Mamdani fuzzy inference approach. The environment-friendly OPFR derivatives (CDPP-F, CDPP-NO2, TPHP-F, TDCIPP-CH2CH3, and TDCIPP-Br) with high flame retardancy showed significantly reduced multi-toxicity effects (biotoxicity, reproductive toxicity, and neurotoxicity) in the comprehensive model. The spatial overlapping volumes of the toxicity/flame retardancy comprehensive effect model with the toxic effect and with flame retardant effect were 1 : 1. The trend (1 : 1) was similar to the degree of improvement of toxicity and flame retardancy of the OPFR derivatives. The toxicity and flame retardancy were decreased by more than 50%. This indicated that the spatial overlapping volumes in the comprehensive model with the toxic and flame retardant mono-models have significant effects. Based on the 2D-QSAR model, molecular docking, and density functional theory, it was found that, in molecular modification, the introduction of electronegative groups to improve the electronic parameters (q+) can reduce the toxicity of OPFRs. An increase in the bond length and bond angle of the molecular side chain increased the steric parameter (MR) that improved the molecular flame retardancy of OPFRs.

scholarly journals Separation, Characterization, and Handling of Microalgae by Dielectrophoresis

2020 ◽  
Vol 8 (4) ◽  
pp. 540 ◽  
Author(s):  
Vinzenz Abt ◽  
Fabian Gringel ◽  
Arum Han ◽  
Peter Neubauer ◽  
Mario Birkholz
Keyword(s):  
Dielectric Properties ◽  
Cell Movement ◽  
Microfluidic Devices ◽  
High Potential ◽  
Label Free ◽  
Intrinsic Properties ◽  
Electrical Field ◽  
Comprehensive Review ◽  
Commercial Use ◽  
Microalgal Species

Microalgae biotechnology has a high potential for sustainable bioproduction of diverse high-value biomolecules. Some of the main bottlenecks in cell-based bioproduction, and more specifically in microalgae-based bioproduction, are due to insufficient methods for rapid and efficient cell characterization, which contributes to having only a few industrially established microalgal species in commercial use. Dielectrophoresis-based microfluidic devices have been long established as promising tools for label-free handling, characterization, and separation of broad ranges of cells. The technique is based on differences in dielectric properties and sizes, which results in different degrees of cell movement under an applied inhomogeneous electrical field. The method has also earned interest for separating microalgae based on their intrinsic properties, since their dielectric properties may significantly change during bioproduction, in particular for lipid-producing species. Here, we provide a comprehensive review of dielectrophoresis-based microfluidic devices that are used for handling, characterization, and separation of microalgae. Additionally, we provide a perspective on related areas of research in cell-based bioproduction that can benefit from dielectrophoresis-based microdevices. This work provides key information that will be useful for microalgae researchers to decide whether dielectrophoresis and which method is most suitable for their particular application.

Synthesis and characterization of flame-retardant-wrapped carbon nanotubes and its flame retardancy in epoxy nanocomposites

2021 ◽  
pp. 096739112110245
Author(s):  
Jiangbo Wang
Keyword(s):  
Carbon Nanotubes ◽  
Heat Release ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Total Heat Release ◽  
Pristine Cnts ◽  
Peak Heat Release Rate ◽  
Ep Matrix ◽  
Better Than

A novel phosphorus-silicon containing flame-retardant DOPO-V-PA was used to wrap carbon nanotubes (CNTs). The results of FTIR, XPS, TEM and TGA measurements exhibited that DOPO-V-PA has been successfully grafted onto the surfaces of CNTs, and the CNTs-DOPO-V-PA was obtained. The CNTs-DOPO-V-PA was subsequently incorporated into epoxy resin (EP) for improving the flame retardancy and dispersion. Compared with pure EP, the addition of 2 wt% CNTs-DOPO-V-PA into the EP matrix could achieve better flame retardancy of EP nanocomposites, such as a 30.5% reduction in peak heat release rate (PHRR) and 8.1% reduction in total heat release (THR). Furthermore, DMTA results clearly indicated that the dispersion for CNTs-DOPO-V-PA in EP matrix was better than pristine CNTs.

An overview of alginates as flame-retardant materials: Pyrolysis behaviors, flame retardancy, and applications

2021 ◽  
Vol 260 ◽  
pp. 117827
Author(s):  
Ying-Jun Xu ◽  
Lian-Yi Qu ◽  
Yun Liu ◽  
Ping Zhu
Keyword(s):  
Flame Retardant ◽  
Flame Retardancy

scholarly journals Dual UV-Thermal Curing of Biobased Resorcinol Epoxy Resin-Diatomite Composites with Improved Acoustic Performance and Attractive Flame Retardancy Behavior

2021 ◽  
Vol 2 (1) ◽  
pp. 24-48
Author(s):  
Quoc-Bao Nguyen ◽  
Henri Vahabi ◽  
Agustín Rios de Anda ◽  
Davy-Louis Versace ◽  
Valérie Langlois ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardancy ◽  
Sound Absorption ◽  
Flexural Modulus ◽  
Construction Materials ◽  
Acoustic Properties ◽  
Low Frequencies ◽  
Compacting Pressure

This study has developed novel fully bio-based resorcinol epoxy resin–diatomite composites by a green two-stage process based on the living character of the cationic polymerization. This process comprises the photoinitiation and subsequently the thermal dark curing, enabling the obtaining of thick and non-transparent epoxy-diatomite composites without any solvent and amine-based hardeners. The effects of the diatomite content and the compacting pressure on microstructural, thermal, mechanical, acoustic properties, as well as the flame behavior of such composites have been thoroughly investigated. Towards the development of sound absorbing and flame-retardant construction materials, a compromise among mechanical, acoustic and flame-retardant properties was considered. Consequently, the composite obtained with 50 wt.% diatomite and 3.9 MPa compacting pressure is considered the optimal composite in the present work. Such composite exhibits the enhanced flexural modulus of 2.9 MPa, a satisfying sound absorption performance at low frequencies with Modified Sound Absorption Average (MSAA) of 0.08 (for a sample thickness of only 5 mm), and an outstanding flame retardancy behavior with the peak of heat release rate (pHRR) of 109 W/g and the total heat release of 5 kJ/g in the pyrolysis combustion flow calorimeter (PCFC) analysis.

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