scholarly journals Synthesis of Urea-Formaldehyde Microcapsule Containing Fluororesin and Its Effect on Performances of Waterborne Coatings on Wood Surface

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1674
Author(s):  
Xiaoxing Yan ◽  
Yan Han ◽  
Taiyu Yin
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Impact Resistance ◽  
Great Influence ◽  
Shell Material ◽  
Waterborne Coatings ◽  
The Core ◽  
The Impact ◽  
Addition Amount ◽  
Core Materials

In order to self-repair the cracks of waterborne coatings on Basswood at room temperature, with fluororesin and waterborne coatings embedded in the shell structure of urea formaldehyde (UF) resin, the microcapsules were fabricated via in-situ polymerization, and the effect of microcapsules on the chroma, gloss, mechanics and repair effect for waterborne coatings on wood was discussed. The results indicated that the coating effect was the most significant when the ratio value of the core materials to the shell material of microcapsules in mass was 0.75, and the agglomeration of particles was the least and the surface was the smoothest when the content of microcapsules was 1.0%. It was negative between the gloss of the film and microcapsule content. The ratio value of the core materials to the shell material in mass and the amount of microcapsules had great influence on the film hardness and adhesion, but had little effect on the impact resistance. When the ratio value of the core materials to the shell material of microcapsules in mass was 0.65 and the addition amount was 4.0–10.0%, the aging resistance of the film was improved most significantly. When the ratio value of the core materials to the shell material of microcapsules in mass was 0.65 and the addition amount was 7.0%, the overall properties of topcoat film on Basswood board was the most significant. It is for the application of fluororesin microcapsules possessing self-repairing effect in waterborne coating on Basswood board that a technical groundwork is provided by this study.

scholarly journals Effect of Microcapsule Concentration with Different Core-Shell Ratios on Waterborne Topcoat Film Properties for Tilia europaea

Coatings ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1013
Author(s):  
Xiaoxing Yan ◽  
Wenting Zhao ◽  
Lin Wang ◽  
Xingyu Qian
Keyword(s):  
Urea Formaldehyde ◽  
Paint Film ◽  
Impact Resistance ◽  
Great Influence ◽  
Acrylic Resin ◽  
Color Difference ◽  
Core Shell ◽  
Self Healing ◽  
The Core ◽  
The Impact

The effects of the core-shell ratio and concentration of urea formaldehyde (UF) resin-coated waterborne acrylic resin microcapsules on the optical properties, mechanical properties and liquid resistance of waterborne topcoat coatings on the surface of Tilia europaea were investigated. With the increase of microcapsule concentration, the color difference and hardness of the paint film gradually increased, the gloss and adhesion of the paint film gradually decreased, and the impact resistance and elongation at break of the paint film increased first and then decreased. With the increase of the core-shell ratio, the hardness and impact resistance of the paint film increased first and then decreased, and the adhesion of the paint film decreased gradually. Red ink had a great influence on the liquid resistance of paint film. When the core-shell ratio of UF-coated waterborne acrylic resin microcapsule was 0.58:1 and the microcapsule concentration was 10.0%, the comprehensive performance of paint film on Tilia europaea was better. The prepared self-healing microcapsules applied to the waterborne coatings committed to prolonging the service life of the paint film.

scholarly journals Effect of Microcapsules with Different Core–Wall Ratios on Properties of Waterborne Primer Coating for European Linden

Coatings ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 826 ◽  
Author(s):  
Xiaoxing Yan ◽  
Lin Wang ◽  
Xingyu Qian
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Impact Resistance ◽  
Acrylic Resin ◽  
Self Healing ◽  
Property A ◽  
Wood Coatings ◽  
Healing Property ◽  
Optical And Mechanical Properties ◽  
The Impact

Waterborne acrylic-resin-filled urea–formaldehyde-based microcapsules with core–wall ratios of 0.42:1, 0.50:1, 0.58:1, 0.67:1, 0.75:1, 0.83:1 and 0.92:1 were prepared via in situ polymerization. Microcapsules were added into the primer to investigate the optical and mechanical properties of the coating on European linden. The results indicated that under the condition of the same core–wall ratio, chroma differences increased gradually with increasing concentration. The coating gloss decreased with increasing concentration. The hardness of 10.0–15.0% microcapsules increased more obviously, with the highest elongations at the break of the coating. At the 0.58:1 core–wall ratio and the 10.0% concentration, the coating adhesion was level 1 and the impact resistance was 10.0 kg cm. Microcapsule concentration did not affect the coating’s liquid resistance. The coating with 10.0% microcapsules added at a 0.58:1 core–wall ratio had a better self-healing property, a good stability and aging resistance. This paper lays a technical basis for the manufacturing and utilization of self-healing waterborne wood coatings.

scholarly journals Preparation of Microcapsules of Urea Formaldehyde Resin Coated Waterborne Coatings and Their Effect on Properties of Wood Crackle Coating

Coatings ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 764 ◽  
Author(s):  
Xiaoxing Yan ◽  
Wenwen Peng
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Impact Resistance ◽  
Acrylic Resin ◽  
Chromatic Aberration ◽  
Protective Role ◽  
The Self ◽  
Formaldehyde Resin ◽  
Self Healing ◽  
The Core

Urea formaldehyde coated waterborne acrylic resin microcapsules with core-wall ratios of 0.30, 0.45, 0.60, 0.67, and 0.75, and mass fractions of 1.0%, 4.0%, 7.0%, 10.0%, 13.0%, and 16.0% were prepared by in situ polymerization. Their micro morphology was examined by scanning electron microscope and infrared spectrum measurements. The gloss, color difference, adhesion, hardness, and impact resistance of the coating surface were investigated in detail. The influence of the core-wall ratio on the performance of the waterborne crackle coating on the wood surface and the self-healing performance were examined. The results showed that when the core-wall ratio of microcapsules was 0.67, an evenly dispersed powder state with particle size of about 3 μm microcapsules was obtained, and the highest coverage was achieved. When the mass fraction of the microcapsule was 4.0%, it had the optimum effect on surface performance. The adhesion was grade two, gloss was 10.9%, impact resistance was 15 kg·cm, chromatic aberration was 1.0, hardness was H, and it had the best effect on the healing of microcracks in the wood coating. As the coating added with microcapsules can inhibit the microcracks of the coating and plays a protective role for the substrate to achieve a self-healing effect, this study lays a technical foundation for the self-healing of surface cracks in coatings for wood.

Microencapsulation of diglycidyl 1,2-cyclohexanedicarboxylate by in situ polymerization: preparation and characterization

e-Polymers ◽  
2015 ◽  
Vol 15 (6) ◽  
pp. 377-383 ◽  
Author(s):  
Hai-Ping Wang ◽  
Meng-Qiang Li ◽  
Chang Guo ◽  
Si-Qian Hu
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Particle Size Analysis ◽  
Size Analysis ◽  
Shell Material ◽  
The Core ◽  
The Mean ◽  
Decomposition Behavior ◽  
Shell Wall Thickness

AbstractMicrocapsules containing a glycidyl ester-type epoxy resin were successfully synthesized by in situ polymerization, with poly(melamine-urea-formaldehyde) as the shell material and diglycidyl 1,2-cyclohexanedicarboxylate (DGCHD) as the core substance. Scanning electron microscopy was performed to investigate the surface morphology and shell wall thickness of the microcapsule. The fabrication, diameters and thermal decomposition behavior of the resultant microcapsules were studied by means of Fourier transform infrared spectroscopy, laser particle size analysis, and thermogravimetric analysis (TGA), respectively. Results indicated that the highest loading of DGCHD in the as-prepared microcapsules was about 89.1 wt.% and that the mean diameter of the capsules was in the range of 50–130 μm, which can be adjusted by changing the feeding mass ratio of the core/shell material and emulsifying rate, respectively. TGA results showed that the microencapsulated DGCHD degraded in two distinguishable stages.

scholarly journals Effect of Urea-Formaldehyde (UF) with Waterborne Emulsion Microcapsules on Properties of Waterborne Acrylic Coatings Based on Coating Process for American Lime

2020 ◽  
Vol 10 (18) ◽  
pp. 6341 ◽  
Author(s):  
Xiaoxing Yan ◽  
Wenting Zhao ◽  
Xingyu Qian
Keyword(s):  
Urea Formaldehyde ◽  
Paint Film ◽  
Coating Process ◽  
Self Healing ◽  
Waterborne Coatings ◽  
Aging Resistance ◽  
Acrylic Coatings ◽  
Waterborne Emulsion ◽  
The Impact ◽  
Good Coating

The purpose of this paper is to explore the effect of urea-formaldehyde (UF) with waterborne emulsion microcapsules on the optical, mechanical and aging resistance properties of waterborne coatings from the perspective of coating process. In this paper, the microcapsules were prepared with UF resin as the wall materials and waterborne emulsion as the core materials. Based on the coating process, the optical, mechanical and aging resistance properties of the waterborne acrylic coatings with microcapsules for American lime were tested. The good coating process is three layers of primer, two layers of topcoat, and adding microcapsules into primer. The results showed that the coating process had little effect on the color difference of the paint film with microcapsules, the gloss of the paint film prepared by the good coating process was basically not changed, and the mechanical properties of the paint film were good. At this time, the hardness grade of the paint film was 3H, the adhesion was grade 0, the impact resistance was 110.0 N·cm−2, and the elongation at break was 29.7%. The microcapsules added to the primer had better liquid resistance than those added to the topcoat. The paint film had good stability and aging resistance, and could inhibit the generation of microcracks to a certain extent. The paint film prepared by the good coating process had better comprehensive performance. This work provides a technical reference for self-healing of the waterborne coatings on American lime.

scholarly journals Effect of Coating Process on Performance of Reversible Thermochromic Waterborne Coatings for Chinese Fir

Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 223 ◽  
Author(s):  
Xiaoxing Yan ◽  
Lin Wang ◽  
Xingyu Qian
Keyword(s):  
Impact Resistance ◽  
Color Difference ◽  
Chinese Fir ◽  
Coating Process ◽  
Practical Applications ◽  
Waterborne Coatings ◽  
Layered Coatings ◽  
Wood Coatings ◽  
Grade 3 ◽  
The Impact

The effect of the coating process on the properties of reversible thermochromic waterborne coating on the surface of Chinese fir was examined. The results demonstrated that the most critical process parameter affecting the color difference and gloss of the coating was the way of adding thermochromic ink. The coating process had little influence on the adhesion, impact resistance adding, liquid resistance, and original properties of the coating. There was no obvious gloss variation in the coating under different coating processes. For the (3+3) layered coatings, when the thermochromic ink was added to the topcoats, the discoloration performance was the most obvious and the comprehensive performance of coating was better. Meanwhile, the gloss was 55.6%, the adhesion grade was grade 0, the impact resistance was 5.0 kg·cm, the liquid resistance grade of the coating to sodium chloride, ethanol and detergent was grade 1, and the liquid resistance grade to red ink was grade 3. The discoloration performance of the coating was stable under the conditions of aging and time change. This study provides new insight into preparing thermochromic intelligent waterborne wood coatings with potential practical applications on Chinese fir wood surfaces, and also lays a foundation for its application in furniture engineering.

scholarly journals Preparation and Optimization of Waterborne Acrylic Core Microcapsules for Waterborne Wood Coatings and Comparison with Epoxy Resin Core

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2366 ◽  
Author(s):  
Xiaoxing Yan ◽  
Yu Tao ◽  
Xingyu Qian
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Paint Film ◽  
Bath Temperature ◽  
Water Bath ◽  
Core Material ◽  
Wall Material ◽  
Formaldehyde Resin ◽  
The Core ◽  
Resin Core

Microcapsules were prepared by in situ polymerization with urea formaldehyde resin as the wall material and Dulux waterborne acrylic acid as the core material. The effects of the core–wall ratio, water bath temperature and depositing time on the morphology, particle size, yield and encapsulation ratio of microcapsules were investigated by orthogonal experiment of three factors and two levels. The results showed that the core–wall ratio had the greatest influence on the performance of microcapsules. When the core–wall ratio was 0.58:1, the water bath temperature was 70 °C, and the depositing time was 5 d, the microcapsule performance was the best. With the increase in depositing time, the yield of microcapsule particles increased gradually, and the microcapsules appeared to show an adhesive phenomenon. However, the long-term depositing time did not lead to complete deposition and agglomeration of microcapsules. When 10.0% concentration of the waterborne acrylic microcapsules with 0.58:1 of core–wall ratio was added to the coatings, the mechanical and optical properties of the coatings did not decrease significantly, but the elongation at break increased significantly. Therefore, this study offers a new prospect for using waterborne acrylic microcapsules to improve the toughness of waterborne paint film which can be cured at room temperature on a wood surface.

The influence of different types of core materials on the impact behaviour of sandwich composites

2018 ◽  
pp. 78-83
Author(s):  
Cihan Kaboglu
Keyword(s):  
Sandwich Structures ◽  
Core Material ◽  
Sandwich Composite ◽  
Balsa Wood ◽  
Impact Behaviour ◽  
The Core ◽  
Glass Fibre Reinforced Polymer ◽  
Glass Fibre Reinforced ◽  
The Impact ◽  
Core Materials

Sandwich structures are popular in applications in which the weight of the component affects the efficiency, especially in the aviation and aerospace industries. This study aims to understand the impact behaviour of sandwich structures with different core materials. Sandwich structures are manufactured with glass fibre reinforced polymer skins and balsa wood, polyethylene terephthalate (PET) and polyvinyl chloride (PVC) core through resin infusion under flexible tools. Three different core materials were tested and compared using the damaged area of the back face of the sample. The effect of the core materials on the mechanical behaviour of the structures is crucial. The results showed that the microstructure of the core materials plays an important role, because althoughthe density of balsa wood is greater than the density of PET and PVC, the structures having PVC and PET as core materials undergo less damage than those having balsa wood as a core material. Keywords: Sandwich composite, impact behaviour, core materials.

scholarly journals Experiment and Simulation Study on the Dynamic Response of RC Slab under Impact Loading

2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Yue Wang ◽  
Jun Liu ◽  
Zhimin Xiao ◽  
Futian Zhao ◽  
Yi Cheng
Keyword(s):  
Dynamic Response ◽  
Impact Loading ◽  
Impact Resistance ◽  
Great Influence ◽  
Time History ◽  
Reinforcement Ratio ◽  
Slab Thickness ◽  
Drop Hammer ◽  
Rc Slab ◽  
The Impact

Reinforced concrete (RC) slab is an important component in civil construction and protection engineering, and its dynamic response under impact loading is a complex mechanical problem, especially for two or multiple continuous impact loads. In this paper, a series of drop hammer impact tests were carried out to investigate the dynamic response of RC slabs with two successive impacts. The time history of impact force and the failure characteristic of the slab surface were recorded. Moreover, four influence factors, including slab thickness, reinforcement ratio, impact location, and drop hammer height have been discussed. Besides, a 3D numerical model based on the finite element method (FEM) was established to expand the research of constrained force, deflection, and vertical stress of an RC slab. The results show that increasing the slab thickness and reinforcement ratio can improve the impact resistance of an RC slab. The impact point location and drop hammer height have a great influence on the dynamic response of the RC slab. In addition, the RC slab will have more obvious damage under the second impact, but the dynamic response becomes weaker. It may be because of the local damage in the concrete caused by the first impact that would weaken the propagation of vibration.

scholarly journals Investigation of the Properties of Color-Changing Powder Water-Based Coating

Coatings ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 815 ◽  
Author(s):  
Xiaoxing Yan ◽  
Yijuan Chang
Keyword(s):  
Paint Film ◽  
Impact Resistance ◽  
Color Difference ◽  
Chinese Fir ◽  
Coating Process ◽  
Waterborne Coating ◽  
Resistance Level ◽  
Waterborne Coatings ◽  
Film Adhesion ◽  
The Impact

The suitable coating process and discoloration effect of the waterborne paint added with color-changing powder on the surface of Chinese fir were investigated using an orthogonal method from three factors of the number of primers, topcoats, and the way of adding color-changing powder. It was found that the number of primers showed the greatest significance on the color difference of paint film, and the method of adding the color-changing powder had the most influence on the gloss of the paint film. Meanwhile, the impact resistance, paint film adhesion, liquid film resistance level, the gloss of coatings, and the composition of waterborne coatings were not affected by the three factors. The results indicated that two primers, two topcoats with color-changing powder, were the most suitable coating technologies for the reversible color waterborne coating to obtain a stable and sustainable discoloration effect. These results will provide a reference for the construction and application of a color-changing coating.

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