scholarly journals Antioxidant Films from Cassava Starch/Gelatin Biocomposite Fortified with Quercetin and TBHQ and Their Applications in Food Models

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1117
Author(s):  
Wirongrong Tongdeesoontorn ◽  
Lisa J. Mauer ◽  
Sasitorn Wongruong ◽  
Pensiri Sriburi ◽  
Alissara Reungsang ◽  
...  
Keyword(s):  
Food Packaging ◽  
Water Solubility ◽  
Transmission Rate ◽  
Composite Films ◽  
Barrier Properties ◽  
Cassava Starch ◽  
Active Packaging ◽  
Gelatin Films ◽  
Active Food Packaging ◽  
Ft Ir

Edible and active packaging are attractive for use in food packaging applications due to their functionality and sustainability. This research developed new antioxidant active food packaging materials from cassava starch/gelatin (7:3 w/w) composite films with varied antioxidant types (quercetin and tertiary butylhydroquinone (TBHQ)) and concentrations (0–200 mg/200 mL film-forming solution) and evaluated their properties. Antioxidant addition altered the mechanical and barrier properties of the films. At 34% relative humidity (RH), increasing the concentration of quercetin increased the tensile strength and decreased the elongation at break of the composite films. Increasing quercetin and TBHQ contents increased the film water solubility and water vapor transmission rate. Intermolecular interactions between the antioxidants and films, as found in Fourier transform infrared (FT-IR) spectra and XRD micrographs, were related to the changed film functionalities. In food application studies, the cassava starch/gelatin films containing quercetin and TBHQ retarded the oxidation of lard (more than 35 days) and delayed the redness discoloration of pork. Cassava starch/gelatin composite films integrated with quercetin and TBHQ can be utilized as active packaging that delays oxidation in foods.

scholarly journals Physical and Antioxidant Properties of Cassava Starch–Carboxymethyl Cellulose Incorporated with Quercetin and TBHQ as Active Food Packaging

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 366 ◽  
Author(s):  
Wirongrong Tongdeesoontorn ◽  
Lisa J. Mauer ◽  
Sasitorn Wongruong ◽  
Pensiri Sriburi ◽  
Pornchai Rachtanapun
Keyword(s):  
Tensile Strength ◽  
Carboxymethyl Cellulose ◽  
Food Packaging ◽  
Water Solubility ◽  
Antioxidative Activity ◽  
Antioxidant Properties ◽  
Cassava Starch ◽  
Total Phenolic ◽  
Elongation At Break ◽  
Active Food Packaging

Antioxidant integration has been advocated for in polymer films, to exert their antioxidative effects in active packaging. In this study, the new antioxidant food packaging made from cassava starch–carboxymethyl cellulose (CMC), which is biodegradable, edible and inexpensive, was developed. Their properties were determined and applied in food models for application. Antioxidants (quercetin and tertiary butylhydroquinone (TBHQ)) were added at various concentrations into cassava starch–carboxymethyl cellulose (CMC) (7:3 w/w) films containing glycerol (30 g/100 g starch–CMC) as a plasticizer. The effects of quercetin and TBHQ concentrations on the mechanical properties, solubility, antioxidative activity, and applications of the films were investigated. Addition of antioxidant improved tensile strength, but reduced elongation at break of the cassava starch–CMC film. Cassava starch–CMC films containing quercetin showed higher tensile strength, but lower elongation at break, compared to films with TBHQ. Increases in quercetin and TBHQ content decreased water solubility in the films. Both the total phenolic content and antioxidative activity (DPPH scavenging assay) still remained in films during storage time (30 days). In application, cassava starch–CMC film containing quercetin and TBHQ can retard the oxidation of lard (35–70 days) and delay the discoloration of pork.

scholarly journals Nano-Brick Wall Architectures Account for Super Oxygen Barrier PET Film by Quadlayer Assembly of Polyelectrolytes and α-ZrP Nanoplatelets

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1082 ◽  
Author(s):  
Dongmei Han ◽  
Yiqing Luo ◽  
Qing Ju ◽  
Xujing Xiao ◽  
Min Xiao ◽  
...  
Keyword(s):  
Zirconium Phosphate ◽  
Food Packaging ◽  
Transmission Rate ◽  
Composite Films ◽  
Barrier Properties ◽  
Oxygen Barrier ◽  
Brick Wall ◽  
Oxygen Transmission Rate ◽  
Repeat Units ◽  
Pet Film

Nanobrick wall hybrid coating with super oxygen barrier properties were fabricated on polyethylene terephthalate (PET) film using a quadlayer (QL) assembly of polyelectrolytes and nanoplateles. A quadlayer assembly consists of three repeat units of polyacrylic acid (PAA), poly (dimethyl diallyl ammonium chloride) (PDDA) and layered α-zirconium phosphate (α-ZrP). PDDA with positive charges can assemble alternatively with both α-ZrP and PAA with negative charges to form nanobrick wall architectures on the surface of PET film via the electrostatic interaction. The lamellar structure of α-ZrP platelets and the dense QL assembly coating can greatly reduce the oxygen transmission rate (OTR) of PET film. Compared to pristine PET film, the OTR of PET (QL)19 is reduced from 57 to 0.87 cc/m2/day. Moreover, even with 19 QLs coating, PET (QL)19 composite film is still with an optical transparency higher than 90% and a haze lower than 10%. Therefore, the transparent PET (QL)n composite films with super oxygen barrier properties show great potential application in food packaging and flexible electronic packaging.

scholarly journals Fabrication of Copper Sulfide Nanoparticles and Limonene Incorporated Pullulan/Carrageenan-Based Film with Improved Mechanical and Antibacterial Properties

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2665
Author(s):  
Swarup Roy ◽  
Jong-Whan Rhim
Keyword(s):  
Composite Film ◽  
Copper Sulfide ◽  
Food Packaging ◽  
Pathogenic Bacteria ◽  
Composite Films ◽  
Antibacterial Properties ◽  
Barrier Properties ◽  
Food Borne ◽  
Active Food Packaging ◽  
Thermal Stability Of

Edible biopolymer (pullulan/carrageenan) based functional composite films were fabricated by the addition of copper sulfide nanoparticles (CuSNP) and D-limonene (DL). The DL and CuSNP were compatible with the pullulan/carrageenan biopolymer matrix. The addition of CuSNP significantly increased the UV-blocking properties without substantially reducing the transparency of the film. The addition of CuSNP improved the film’s tensile strength by 10%; however, the DL addition did not significantly influence the strength, while the combined addition of CuSNP and DL increased the strength by 15%. The addition of the fillers did not significantly affect the thermal stability of the film, but the water vapor barrier property was slightly improved. There was no significant change in the moisture content and hydrophobicity of the composite film. Besides, the composite film showed some antimicrobial activity against food-borne pathogenic bacteria. The fabricated pullulan/carrageenan-based film with antimicrobial and UV-barrier properties is likely to be used in active food packaging applications.

scholarly journals Effects of Kappa-Carrageenan on the Physico-Chemical Properties of Thermoplastic Starch

KIMIKA ◽  
2015 ◽  
Vol 26 (1) ◽  
pp. 10-16 ◽  
Author(s):  
Annabelle C. Flores ◽  
Eric R. Punzalan ◽  
Norberto G. Ambangan
Keyword(s):  
Food Packaging ◽  
Water Solubility ◽  
Transmission Rate ◽  
Low Cost ◽  
Composite Films ◽  
Chemical Properties ◽  
Thermoplastic Starch ◽  
Polymer Chains ◽  
Physico Chemical ◽  
Wide Range

Food packaging materials derived from renewable sources are highly sought due to their low cost and wide range of functional properties. This research reports on the fabrication and physico-chemical properties of composite films from cassava starch and κ-carrageenan.Characterization of the films by FTIR indicates physical entanglements between polymer chains. The water solubility of the films showed linear dependency on the κ-carrageenan content while the moisture content diminished with the addition of κ-carrageenan. . The mechanical property of the films showed that as the amount of κ-carrageenan increases, tensile strength exhibited improvement, the water activity (aw) increased, and pH became more basic, while % elongation weakened. Water vapour transmission rate (WVTR) improved significantly from 82.73 g/(m2.day) for pure thermoplastic starch to 11.31 g/(m2.day) for 90/10 % (w/w) starch/ κ-carrageenan ratio, which is comparable to WVTR of commercial polypropylene.

scholarly journals Low-Density Polyethylene Films Carrying ferula asafoetida Extract for Active Food Packaging: Thermal, Mechanical, Optical, Barrier, and Antifungal Properties

2020 ◽  
Vol 2020 ◽  
pp. 1-15
Author(s):  
Razieh Niazmand ◽  
Bibi Marzieh Razavizadeh ◽  
Farzaneh Sabbagh
Keyword(s):  
Polymer Matrix ◽  
Food Packaging ◽  
Barrier Properties ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Optical Barrier ◽  
Leaf Extracts ◽  
Polyethylene Films ◽  
Active Food Packaging ◽  
Ferula Asafoetida

The physical, thermal, mechanical, optical, microstructural, and barrier properties of low-density polyethylene films (LDPE) containing ferula asafoetida leaf and gum extracts were investigated. Results showed a reduction in elasticity and tensile strength with increasing extract concentration in the polymer matrix. The melting temperature and enthalpy increased with increasing concentration of extracts. The films containing extracts had lower L∗ and a∗ and higher b∗ indices. The films containing leaf extract had more barrier potential to UV than the gum extracts. The oxygen permeability in films containing 5% of leaf and gum extracts increased by 2.3 and 2.1 times, respectively. The morphology of the active films was similar to bubble swollen islands, which was more pronounced at higher concentrations of gum and leaf extracts. FTIR results confirmed some chemical interactions of ferula extracts with the polymer matrix. At the end of day 14th, the growth rate of Aspergillus niger and Saccharomyces cerevisea in the presence of the PE-Gum-5 reduced more than PE-Leaf-5 (3.7 and 2.4 logarithmic cycles, respectively) compared to the first day. Our findings showed that active LDPE films have desire thermo-mechanical and barrier properties for food packaging.

Enhanced functional properties of biodegradable Polyvinyl alcohol /carboxymethyl cellulose (PVA/CMC) composite films reinforced with L-alanine surface modified CuO nanorods

2021 ◽  
Author(s):  
Yamanappagouda Amaregouda ◽  
Kantharaju Kamanna ◽  
Tilak Gasti ◽  
Vijay Kumbar
Keyword(s):  
Polyvinyl Alcohol ◽  
Carboxymethyl Cellulose ◽  
Food Packaging ◽  
Composite Films ◽  
Nanocomposite Films ◽  
Soil Burial ◽  
High Antibacterial Activity ◽  
Active Food Packaging ◽  
Surface Modified ◽  
Cuo Nanorods

Abstract Herein, we described novel biogenic preparation of the CuO nanorods and its surface modification with L-alanine amino acid accelerated by microwave irradiation. The effect of surface functionalized CuO nanorods on the polyvinyl alcohol/carboxymethyl cellulose film physico-mechanical properties were investigated through various characterization techniques. The tensile strength was improved from 28.58 ± 0.73 MPa to 43.40 ± 0.93 MPa, UV shielding ability and barrier to the water vapors were highly enhanced when PVA/CMC matrices filled with 8 wt% of CuO-L-alanine. In addition, the prepared films exhibited acceptable overall migration limit and readily undergoes soil burial degradation. Nevertheless, CuO-L-alanine incorporated films showed potent antioxidant activity against DPPH radicals and had high antibacterial activity against Staphylococcus aureus and Escherichia coli, and antifungal activity against Candida albicans and Candida tropicalis. Furthermore, the nanocomposite films showed negligible cytotoxic effect on HEK293 and Caco-2 cell lines. In these contexts, the developed nanocomposite films can be implementing as an active food packaging material.

scholarly journals Synergistic Effect of Halloysite Nanotubes and Glycerol on the Physical Properties of Fish Gelatin Films

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1258 ◽  
Author(s):  
Xiaohu Qiang ◽  
Songyi Zhou ◽  
Zhuo Zhang ◽  
Qiling Quan ◽  
Dajian Huang
Keyword(s):  
Water Resistance ◽  
Water Solubility ◽  
Composite Films ◽  
Halloysite Nanotubes ◽  
Light Transmittance ◽  
Fish Gelatin ◽  
Moisture Uptake ◽  
Casting Method ◽  
Gelatin Films ◽  
Light Region

Fish gelatin (FG)/glycerol (GE)/halloysite (HT) composite films were prepared by casting method. The morphology of the composite films was observed by scanning electron microscopy (SEM). The effects of HT and GE addition on the mechanical properties, water resistance and optical properties of the composites were investigated. Results showed that with increasing GE content, the elongation at composite breaks increased significantly, but their tensile strength (TS) and water resistance decreased. SEM results showed that GE can partly promote HT dispersion in composites. TS and water resistance also increased with the addition of HTs. Well-dispersed HTs in the FG matrix decreased the moisture uptake and water solubility of the composites. All films showed a transparency higher than 80% across the visible light region (400–800 nm), thereby indicating that light transmittance of the resulting nanocomposites was slightly affected by GE and HTs.

scholarly journals Cellulose Nanocrystal Reinforced Chitosan Based UV Barrier Composite Films for Sustainable Packaging

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 202 ◽  
Author(s):  
Mithilesh Yadav ◽  
Kartik Behera ◽  
Yen-Hsiang Chang ◽  
Fang-Chyou Chiu
Keyword(s):  
Food Industry ◽  
Water Solubility ◽  
Moisture Absorption ◽  
Composite Films ◽  
Barrier Properties ◽  
Cellulose Nanocrystal ◽  
Nanocomposite Films ◽  
Green Composite ◽  
Vapor Permeation ◽  
Sustainable Packaging

In this study, green composite films based on cellulose nanocrystal/chitosan (CNC/CS) were fabricated by solution casting. FTIR, XRD, SEM, and TEM characterizations were conducted to determine the structure and morphology of the prepared films. The addition of only 4 wt.% CNC in the CS film improved the tensile strength and Young’s modulus by up to 39% and 78%, respectively. Depending on CNC content, the moisture absorption decreased by 34.1–24.2% and the water solubility decreased by 35.7–26.5% for the composite films compared with neat CS film. The water vapor permeation decreased from 3.83 × 10−11 to 2.41 × 10−11 gm−1 s−1Pa−1 in the CS-based films loaded with (0–8 wt.%) CNC. The water and UV barrier properties of the composite films showed better performance than those of neat CS film. Results suggested that CNC/CS nanocomposite films can be used as a sustainable packaging material in the food industry.

scholarly journals Compostable Polylactide and Cellulose Based Packaging for Fresh-Cut Cherry Tomatoes: Performance Evaluation and Influence of Sterilization Treatment

Materials ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3432 ◽  
Author(s):  
Marco Rapisarda ◽  
Cristina Patanè ◽  
Alessandra Pellegrino ◽  
Angelo Malvuccio ◽  
Valeria Rizzo ◽  
...  
Keyword(s):  
Food Packaging ◽  
Transmission Rate ◽  
Chemical Properties ◽  
Oxygen Demand ◽  
Barrier Properties ◽  
Attenuated Total Reflection ◽  
Cherry Tomato ◽  
Plastic Materials ◽  
Before And After ◽  
Fresh Cut

For food packaging, plastic materials display large appeal, mostly due to their versatility, mechanical, optical and barrier properties. However, they play an important role in environmental concerns and waste management issue. Compostable bioplastics represent alternative materials designed for a lower environmental impact. In this work, a biobased compostable packaging, constituted by polylactide (PLA) trays and NatureFlex™ film, was evaluated for fresh-cut cherry tomato. A comparative analysis was accomplished using traditional packaging materials, that is, polyethylene terephtalate (PET) trays and polypropylene (PP Coex) film. Structural stability under food contact conditions, mechanical and physical-chemical properties were investigated. Tensile mechanical properties, puncture resistance, contact angle (CA) and attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR), before and after UV or radiofrequency (RF) sterilization treatment, were evaluated. UV irradiation method resulted the less invasive one. Therefore, oxygen and water vapor transmission rate (OTR and WVTR), overall chemical migration test, biodegradation assessment by biochemical oxygen demand (BOD) according to ISO 14851 and disintegration test by ISO 20200 were carried out to establish the further influence of UV sterilization on the packaging. Overall, data showed that the biobased compostable packaging for a prolonged shelf-life of fresh-cut cherry tomato has better properties that were surprisingly enhanced by the UV treatment.

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