scholarly journals Lignin Extraction from Waste Pine Sawdust Using a Biomass Derived Binary Solvent System

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1090
Author(s):  
Solange Magalhães ◽  
Alexandra Filipe ◽  
Elodie Melro ◽  
Catarina Fernandes ◽  
Carla Vitorino ◽  
...  
Keyword(s):  
Morphological Changes ◽  
Extraction Time ◽  
Added Value ◽  
Binary Solvent ◽  
Waste Biomass ◽  
Biomass Waste ◽  
Fractionation Process ◽  
Pine Sawdust ◽  
Renewable Chemicals ◽  
Lignin Extraction

Lignocellulosic biomass fractionation is typically performed using methods that are somehow harsh to the environment, such as in the case of kraft pulping. In recent years, the development of new sustainable and environmentally friendly alternatives has grown significantly. Among the developed systems, bio-based solvents emerge as promising alternatives for biomass processing. Therefore, in the present work, the bio-based and renewable chemicals, levulinic acid (LA) and formic acid (FA), were combined to fractionate lignocellulosic waste (i.e., maritime pine sawdust) and isolate lignin. Different parameters, such as LA:FA ratio, temperature, and extraction time, were optimized to boost the yield and purity of extracted lignin. The LA:FA ratio was found to be crucial regarding the superior lignin extraction from the waste biomass. Moreover, the increase in temperature and extraction time enhances the amount of extracted residue but compromises the lignin purity and reduces its molecular weight. The electron microscopy images revealed that biomass samples suffer significant structural and morphological changes, which further suggests the suitability of the newly developed bio-fractionation process. The same was concluded by the FTIR analysis, in which no remaining lignin was detected in the cellulose-rich fraction. Overall, the novel combination of bio-sourced FA and LA has shown to be a very promising system for lignin extraction with high purity from biomass waste, thus contributing to extend the opportunities of lignin manipulation and valorization into novel added-value biomaterials.

scholarly journals Lignin Extraction from Waste Pine Sawdust Using a Biomass Derived Binary Solvent System

2021 ◽  
Author(s):  
Solange Magalhães ◽  
Alexandra Filipe ◽  
Elodie Melro ◽  
Catarina Fernandes ◽  
Carla Vitorino ◽  
...  
Keyword(s):  
Morphological Changes ◽  
Extraction Time ◽  
Added Value ◽  
Binary Solvent ◽  
Waste Biomass ◽  
Biomass Waste ◽  
Fractionation Process ◽  
Pine Sawdust ◽  
Renewable Chemicals ◽  
Lignin Extraction

Lignocellulosic biomass fractionation is typically performed using methods that are somehow harsh to the environment, such as in the case of the kraft pulping. In recent years, the development of new sustainable and environmentally friendly alternatives has grown significantly. Among the developed systems, bio-based solvents emerge as promising alternatives for biomass processing. Therefore, in the present work, the bio-based and renewable chemicals, levulinic acid (LA) and formic acid (FA), were combined to fractionate lignocellulosic waste (i.e., Maritime pine sawdust) and isolate lignin. Different parameters, such as LA/FA ratio, temperature, and extraction time, were optimized to boost the yield and purity of extracted lignin. The LA/FA ratio was found to be crucial regarding the superior lignin extraction from the waste biomass. Moreover, the increase in temperature and extraction time enhances the amount of extracted residue but compromises the lignin purity and reduces its molecular weight. The electron microscopy images revealed that biomass samples suffer significant structural and morphological changes, which further suggests the suitability of the new developed bio-fractionation process. Same was concluded by the FTIR analysis, in which no remaining lignin was detected in the cellulose-rich fraction. Overall, the novel combination of bio-sourced FA and LA has shown to be a very promising system for lignin extraction of high purity from biomass waste, thus contributing to extend the opportunities of lignin manipulation and valorisation into novel added-value biomaterials.

scholarly journals Potential of biomass residues from oil palm agroindustry in Indonesia

2018 ◽  
Vol 197 ◽  
pp. 13008
Author(s):  
Dwi Ermawati Rahayu ◽  
Dutarama Nasarani ◽  
Wahyono Hadi ◽  
Budisantoso Wrjodirjo
Keyword(s):  
Solid Waste ◽  
Palm Oil ◽  
Oil Palm ◽  
Palm Kernel ◽  
Added Value ◽  
Palm Tree ◽  
Waste Biomass ◽  
Biomass Waste ◽  
Empty Fruit Bunches ◽  
Palm Oil Mill

Oil Palm agroindustry is growing rapidly in Southeast Asia especially Indonesia and Malaysia. Based on GAPKI data, Indonesia's CPO production 2017 is 38.17 million tons and PKO of 3.05 million tons. Production activities in palm oil agro-industry in addition to producing PKO and CPOl produce solid waste from the plantation and palm oil mill, Palm Oil Mill Effluent (POME) from the palm oil mill. The biomass waste of oil palm agro-industry comes from activities in plantations in the form of midrib, leaves and palm tree trunks. While from the palm oil mill produced solid waste in the form of palm kernel shells (PKS), mesocarp fibers (MF) and empty fruit bunches (EFB). The waste is classified as biomass residue that can be utilized so that it has added value. Biomass potential in Indonesia can be estimated from the productivity of oil palm. The volume of biomass is 5,5-8%, empty bunches 20-23%, palm fronds 13.5-15%, 15% palm fiber from 1 ton of fresh fruit bunches. The total potential of oil palm solid waste biomass in Indonesia 2017 is 20.07 million tons and POME is 23.7 million tons. The largest distribution of biomass is in Riau, North Sumatra, South Sumatra province.

scholarly journals Agro-Industrial Avocado (Persea americana) Waste Biorefinery

2021 ◽  
Author(s):  
Anthony Mora-Sandí ◽  
Abigail Ramírez-González ◽  
Luis Castillo-Henríquez ◽  
Mary Lopretti-Correa ◽  
José Roberto Vega-Baudrit
Keyword(s):  
Global Warming ◽  
Environmental Remediation ◽  
Value Added ◽  
Persea Americana ◽  
Added Value ◽  
Biomass Waste ◽  
Physical Chemical ◽  
Biological Conversion ◽  
Medical Material ◽  
Value Added Products

Significant problems have arisen in the last years, such as climate change, global warming, and hunger. These complications are correlated with the depletion and exploitation of natural resources and environmental contamination. Due to overcrowding, the list of challenges for the next few years is growing. A comprehensive approach was made to the agro-industrial production of Avocado (Persea americana) and the management of all its biomass waste. So, bioprocesses and biorefinery can be used to produce high added-value products. A large number of residues are composed of lignin and cellulose. They have many potentials to be exploited sustainably for chemical and biological conversion; physical, chemical, and natural treatments improve the following operations. There are some applications to many fields such as pharmaceutical, medical, material engineering, and environmental remediation. Possible pathways are mentioned to take advantage of Avocado as biofuels, drugs, bioplastics, and even in the environmental part and emerging technologies such as nanotechnology using bioprocesses and biotech. In conclusion, Avocado and its waste could be transformed into high value-added products in industries above to mitigate global warming and save non-renewable energy.

scholarly journals Priorities Determination of Using Bioresources. Case Study of Heracleum sosnowskyi

2019 ◽  
Vol 23 (1) ◽  
pp. 242-256 ◽  
Author(s):  
Lauma Zihare ◽  
Julija Gusca ◽  
Kriss Spalvins ◽  
Dagnija Blumberga
Keyword(s):  
Agricultural Land ◽  
Multicriteria Analysis ◽  
Pharmaceutical Products ◽  
Added Value ◽  
Biomass Waste ◽  
Heracleum Sosnowskyi ◽  
Analysis Methodology ◽  
Pharmaceutical Industries

Abstract Multicriteria analysis methodology used in the paper allows to evaluate the use of potential bioresources with high added value by prioritizing products from invasive species. The method is applied for the hogweed Heracleum sosnowskyi Manden, which occupies large areas in Latvia and poses great problems in using agricultural land. It is combated purposefully, generating significant amount of biomass waste. The results of TOPSIS multicriteria analysis used with 14 indicators, show that hogweed can be used for production of different pharmaceutical, food, soil fertilizer and chemical materials with a high added value. Pharmaceutical products have the highest potential for production of polysaccharides that can be used in food and pharmaceutical industries.

scholarly journals Impact of Pretreatment on Hydrothermally Carbonized Spruce

Energies ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2984
Author(s):  
Anna Partridge ◽  
Ekaterina Sermyagina ◽  
Esa Vakkilainen
Keyword(s):  
Treated Wood ◽  
Hydrothermal Carbonization ◽  
Proximate Analysis ◽  
Thermochemical Conversion ◽  
Energy Yield ◽  
Strongly Correlated ◽  
Mass Yield ◽  
Biomass Waste ◽  
Heating Value ◽  
Lignin Extraction

Upgrading biomass waste streams can improve economics in wood industries by adding value to the process. This work considers use of a hydrothermal carbonization (HTC) process for the residual feedstock after lignin and hemicelluloses extraction. Batch experiments were performed at 200–240 °C temperatures and three hours residence time with an 8:1 biomass to water ratio for two feedstocks: Raw spruce and spruce after lignin extraction. The proximate analysis and heating value showed similar results for both feedstocks, indicating that the thermochemical conversion is not impacted by the removal of lignin and hemicelluloses; the pretreatment processing slightly increases the heating value of the treated feedstock, but the HTC conversion process produces a consistent upgrading trend for both the treated and untreated feedstocks. The energy yield was 9.7 percentage points higher for the treated wood on average across the range temperatures due to the higher mass yield in the treated experiments. The energy densification ratio and the mass yield were strongly correlated with reaction temperature, while the energy yield was not. Lignocellulosic composition of the solid HTC product is mainly affected by HTC treatment, the effect of lignin extraction is negligible.

scholarly journals Extraction Behaviors of Lignin and Hemicellulose-Derived Sugars During Organosolv Fractionation of Agricultural Residues Using a Bench-Scale Ball Milling Reactor

Energies ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 352
Author(s):  
Tae Hoon Kim ◽  
Hyun Kwak ◽  
Tae Hyun Kim ◽  
Kyeong Keun Oh
Keyword(s):  
Ball Milling ◽  
Agricultural Residues ◽  
Barley Straw ◽  
Conversion Yield ◽  
Fractionation Process ◽  
Molecular Weight Distributions ◽  
Lignin Extraction ◽  
Similar Chemical ◽  
Weight Distributions ◽  
Hydrolysis Of

Ethanol organosolv fractionation combined with ball milling was conducted on three major agricultural residues: Rice husk (RH), rice straw (RS), and barley straw (BS). The highest lignin extraction yields of RH, RS, and BS were 55.2%, 53.1%, and 59.4% and the purity of lignin recovered was 99.5% for RH and RS, and 96.8% for BS, with similar chemical characteristics, i.e., low molecular weight distributions (1453–1817 g/mol) and poly dispersity index (1.15–1.28). However, considering the simultaneous production of hemicellulose-derived sugars, distinctive fractionation behaviors were shown for the three agricultural residues. The highest hemicellulose-derived sugar yield was 73.8% when RH was fractionated at 170 °C for 30 min. Meanwhile, very low sugar yields of 31.9% and 35.7% were obtained from RS and BS, respectively. The highest glucan-to-glucose conversion yield from enzymatic hydrolysis of fractionated RH reached 85.2%. Meanwhile, the enzymatic digestibility of the fractionated RS and BS was 60.0% and 70.5%, respectively. Consequently, the fractionation efficiency for RH can be improved with fine refinement. For the case of RS, other fractionation process should be applied to achieve effective fractionation performance.

scholarly journals Co-Gasification of Treated Solid Recovered Fuel Residue by Using Minerals Bed and Biomass Waste Blends

Energies ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 2081
Author(s):  
Md Tanvir Alam ◽  
Se-Won Park ◽  
Sang-Yeop Lee ◽  
Yean-Ouk Jeong ◽  
Anthony De Girolamo ◽  
...  
Keyword(s):  
Low Cost ◽  
Biomass Waste ◽  
Heating Value ◽  
Pine Sawdust ◽  
Syngas Production ◽  
Cold Gas Efficiency ◽  
Natural Minerals ◽  
Lower Heating Value ◽  
Gas Efficiency ◽  
Bed Material

Solid recovered fuel (SRF) residue, which is leftovers from the SRF manufacturing process, usually is discarded in landfill because of its low heating value and high ash and moisture content. However, it could be used as a fuel after mechanical and biological treatment. Gasification experiments were conducted on treated SRF residue (TSRFR) to assess the viability of syngas production. Efforts were also made to improve the gasification performance by adding low-cost natural minerals such as dolomite and lime as bed material, and by blending with biomass waste. In the case of additive mineral tests, dolomite showed better performance compared to lime, and in the case of biomass blends, a 25 wt% pine sawdust blend with TSRFR showed the best performance. Finally, as an appropriate condition, a combined experiment was conducted at an equivalence ratio (ER) of 0.2 using a 25 wt% pine sawdust blend with TSRFR as a feedstock and dolomite as the bed material. The highest dry gas yield (1.81 Nm3/kg), with the highest amount of syngas (56.72 vol%) and highest lower heating value (9.55 MJ/Nm3) was obtained in this condition. Furthermore, the highest cold gas efficiency (48.64%) and carbon conversion rate (98.87%), and the lowest residue yield (11.56%), tar (0.95 g/Nm3), and gas pollutants content was observed.

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