scholarly journals Processing Conditions of a Medical Grade Poly(Methyl Methacrylate) with the Arburg Plastic Freeforming Additive Manufacturing Process

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2677
Author(s):  
Lukas Hentschel ◽  
Frank Kynast ◽  
Sandra Petersmann ◽  
Clemens Holzer ◽  
Joamin Gonzalez-Gutierrez

The Arburg Plastic Freeforming process (APF) is a unique additive manufacturing material jetting method. In APF, a thermoplastic material is supplied as pellets, melted and selectively deposited as droplets, enabling the use of commercial materials in their original shape instead of filaments. The medical industry could significantly benefit from the use of additive manufacturing for the onsite fabrication of customized medical aids and therapeutic devices in a fast and economical way. In the medical field, the utilized materials need to be certified for such applications and cannot be altered in any way to make them printable, because modifications annul the certification. Therefore, it is necessary to modify the processing conditions rather than the materials for successful printing. In this research, a medical-grade poly(methyl methacrylate) was analyzed. The deposition parameters were kept constant, while the drop aspect ratio, discharge rate, melt temperatures, and build chamber temperature were varied to obtain specimens with different geometrical accuracy. Once satisfactory geometrical accuracy was obtained, tensile properties of specimens printed individually or in batches of five were tested in two different orientations. It was found that parts printed individually with an XY orientation showed the highest tensile properties; however, there is still room for improvement by optimizing the processing conditions to maximize the mechanical strength of printed specimens.

Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 135
Author(s):  
Stefano Zanini ◽  
Antonio Papagni ◽  
Luca Vaghi ◽  
Baljit Kaur Thatti ◽  
Stephen Barton ◽  
...  

Medical-grade poly(methyl methacrylate) (PMMA) is widely employed in the fabrication of intraocular lenses (IOLs), but suffers from opacification, a postoperative complication that leads to the failure of the implanted intraocular lenses. The opacification occurs when inorganic-based deposits accumulate on the surface of the IOL and are prevalent in hydrophilic materials. Here, the surface of medical-grade PMMA has been fluorinated by sulphur hexafluoride (SF6) plasma treatment to increase surface hydrophobicity thus improving the material lifetime in optical applications. Hydrophobic properties of the treated PMMA were investigated by means of contact angle measurements, while chemical modification was assessed by X-ray Photoelectron Spectroscopy (XPS) and Attenuated Total Reflectance Fourier Transform Infrared (ATR/FTIR) spectroscopy. Surface morphological changes due to possible etching effects were investigated by Atomic Force Microscopy (AFM). The transparency of the treated PMMA was assessed by UV/VIS spectroscopy. Finally, the influence of the plasma treatment on the inorganic salts deposition was investigated by immersion in Simulated Aqueous Humour (SAH), followed by XPS analysis. The modified samples showed less deposition on the surface than the unmodified sample, moreover, a decrease of the transmittance in the UV-violet range (300–430 nm) was detected, open the possibility of interesting applications of this treatment for the creation of a UV filter in ophthalmic optical devices.


2018 ◽  
Vol 773 ◽  
pp. 51-55
Author(s):  
Jasmine Pongkasem ◽  
Saowaroj Chuayjuljit ◽  
Phasawat Chaiwutthinan ◽  
Amnouy Larpkasemsuk ◽  
Anyaporn Boonmahitthisud

In this study, poly(lactic acid) (PLA) was melt mixed with three weight percentages (10–30wt%) of ethylene vinyl acetate copolymer (EVA) in an internal mixer, followed by a compression molding. According to a better combination of mechanical properties, the 90/10 (w/w) PLA/EVA was selected for preparing hybrid nanocomposites with three loadings (1, 3 and 5 parts per hundred of resin , phr) of poly(methyl methacrylate)-encapsulated nanosilica (PMMA-nSiO2). The nanolatex of PMMA-nSiO2 was synthesized via in situ differential microemulsion polymerization. The obtained PMMA-nSiO2 showed a core-shell morphology with nSiO2 as a core and PMMA as a shell, having an average diameter of 43.4nm. The influences of the EVA and PMMA-nSiO2 on the impact strength and the tensile properties of the PLA/EVA nanocomposites were studied and compared. It is found that the impact strength and the tensile properties of the 90/10 (w/w) PLA/EVA were improved with the appropriate amounts of the EVA and PMMA-nSiO2.


2017 ◽  
Vol 08 (02) ◽  
pp. 176-187 ◽  
Author(s):  
Baljit K. Ghatora ◽  
Peter J. S. Foot ◽  
Stephen J. Barton ◽  
Ravtej S. Thatti ◽  
Antonio Papagni ◽  
...  

2014 ◽  
Vol 04 (04) ◽  
pp. 74-83 ◽  
Author(s):  
Baljit K. Ghatora ◽  
Stephen J. Barton ◽  
Peter J. S. Foot ◽  
Philip Miller Tate

2018 ◽  
Vol 303 (9) ◽  
pp. 1800247 ◽  
Author(s):  
Dario Puppi ◽  
Andrea Morelli ◽  
Francesca Bello ◽  
Simone Valentini ◽  
Federica Chiellini

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