scholarly journals Anti-Bacterial and Anti-Fouling Capabilities of Poly(3,4-Ethylenedioxythiophene) Derivative Nanohybrid Coatings on SUS316L Stainless Steel by Electrochemical Polymerization

Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1467 ◽  
Author(s):  
Chuan-Chih Hsu ◽  
Yu-Wei Cheng ◽  
Che-Chun Liu ◽  
Xin-Yao Peng ◽  
Ming-Chi Yung ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Photoelectron Spectroscopy ◽  
Negative Charge ◽  
Electrochemical Polymerization ◽  
Inhibition Zone ◽  
Lower Surface ◽  
Water Contact ◽  
Force Microscopy ◽  
Cardiovascular Stents ◽  
Atomic Force

We have successfully fabricated poly(3,4-ethylenedioxythiophene) (PEDOT) derivative nanohybrid coatings on flexible SUS316L stainless steel by electrochemical polymerization, which can offer anti-fouling and anti-bacterial capabilities. PEDOT derivative nanohybrids were prepared from polystyrene sulfonates (PSS) and graphene oxide (GO) incorporated into a conducting polymer of PEDOT. Additionally, the negative charge of the PEDOT/GO substrate was further modified by poly-diallyldimethylammonium chloride (PDDA) to form a positively charged surface. These PEDOT derivative nanohybrid coatings could provide a straightforward means of controlling the surface energy, roughness, and charges with the addition of various derivatives in the electrochemical polymerization and electrostatically absorbed process. The characteristics of the PEDOT derivative nanohybrid coatings were evaluated by Raman spectroscopy, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), water contact angle, and surface potential (zeta potential). The results show that PEDOT/PSS and PEDOT/GO nanohybrid coatings exhibit excellent anti-fouling capability. Only 0.1% of bacteria can be adhered on the surface due to the lower surface roughness and negative charge surface by PEDOT/PSS and PEDOT/GO modification. Furthermore, the anti-bacterial capability (7 mm of inhibition zone) was observed after adding PDDA on the PEDOT/GO substrates, suggesting that the positive charge of the PEDOT/GO/PDDA substrate can effectively kill bacteria (Staphylococcus aureus). Given their anti-fouling and anti-bacterial capabilities, PEDOT derivative nanohybrid coatings have the potential to be applied to biomedical devices such as cardiovascular stents and surgical apparatus.

scholarly journals Synthesis of amphiphilic ABA triblock oligomer via ATRP and its surface properties

2017 ◽  
Vol 95 (5) ◽  
pp. 605-611 ◽  
Author(s):  
Lei Wang ◽  
Shaoqing Wen ◽  
Zhanxiong Li
Keyword(s):  
Photoelectron Spectroscopy ◽  
Microphase Separation ◽  
Gel Permeation Chromatography ◽  
Contact Angles ◽  
Chemical Compositions ◽  
Water Contact ◽  
Force Microscopy ◽  
Atomic Force ◽  
Poly Ethylene ◽  
Magnetic Resonances

A series of novel amphiphilic ABA-type poly(tridecafluorooctylacrylate)-poly(ethylene glycol)-poly(tridecafluorooctylacrylate) (henceforth referred to as p-TDFA-PEG-p-TDFA) triblock oligomers were successfully synthesized via atom transfer radical polymerization (ATRP) using well-defined Br-PEG-Br as macroinitiator and copper as catalyst. The block oligomers were characterized by Fourier transform infrared (FTIR) spectroscopy and 1H and 19F nuclear magnetic resonances (NMR). Gel permeation chromatography (GPC) showed that the block oligomers have been obtained with narrow molecular weight distributions of 1.22–1.33. X-ray photoelectron spectroscopy (XPS) was carried out to confirm the attachment of p-TDFA-PEG-p-TDFA onto the silicon substrate, together with the chemical compositions of p-TDFA-PEG-p-TDFA. The wetabilities of the oligomer films were measured by water contact angles (CAs). Water CAs of p-TDFA-PEG-p-TDFA film were measured and their morphologies were tested by atomic force microscopy (AFM). The result showed that the CAs of the oligomer films, which possess fluoroalkyl groups assembled on the outer surface, increase after heating due to the migration of fluoroalkyl groups and the resulted microphase separation of the p-TDFA-PEG-p-TDFA.

scholarly journals Superhydrophilic Coating with Antibacterial and Oil-Repellent Properties via NaIO4-Triggered Polydopamine/Sulfobetaine Methacrylate Polymerization

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2008
Author(s):  
Hsiu-Wen Chien ◽  
Hong-Yu Lin ◽  
Chau-Yi Tsai ◽  
Tai-Yu Chen ◽  
Wei-Nian Chen
Keyword(s):  
Surface Modification ◽  
Photoelectron Spectroscopy ◽  
Deposition Process ◽  
Water Contact ◽  
Water Separation ◽  
Force Microscopy ◽  
Atomic Force ◽  
Oil Water Separation ◽  
One Step ◽  
Oil Repellent

Superhydrophilic coatings have been widely used for the surface modification of membranes or biomedical devices owing to their excellent antifouling properties. However, simplifying the modification processes of such materials remains challenging. In this study, we developed a simple and rapid one-step co-deposition process using an oxidant trigger to fabricate superhydrophilic surfaces based on dopamine chemistry with sulfobetaine methacrylate (SBMA). We studied the effect of different oxidants and SBMA concentrations on surface modification in detail using UV–VIS spectrophotometry, dynamic light scattering, atomic force microscopy, X-ray photoelectron spectroscopy, and surface plasmon resonance. We found that NaIO4 could trigger the rate of polymerization and the optimum ratio of dopamine to SBMA is 1:25 by weight. This makes the surface superhydrophilic (water contact angle < 10°) and antifouling. The superhydrophilic coating, when introduced to polyester membranes, showed great potential for oil/water separation. Our study provides a complete description of the simple and fast preparation of superhydrophilic coatings for surface modification based on mussel-inspired chemistry.

scholarly journals Electropolishing of Stainless Steel in Laboratory and Industrial Scale

Metals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 854 ◽  
Author(s):  
Paweł Lochyński ◽  
Sylwia Charazińska ◽  
Edyta Łyczkowska-Widłak ◽  
Andrzej Sikora
Keyword(s):  
Stainless Steel ◽  
Photoelectron Spectroscopy ◽  
Passive Layer ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Process Scale ◽  
Metallographic Images ◽  
Industrial Samples ◽  
Difficult Issue

Transposing the process scale from laboratory to industrial conditions is a difficult issue that applies to many sectors of the industry. As far as electropolishing of stainless steel is concerned, the limitations connected with a significant increase in the area of electropolished surface should be considered, along with the possibility of defects that may emerge. This paper compares the results of electropolishing of stainless steel in the laboratory and in industrial conditions. For the analyzed conditions, it was determined that the best results, both in laboratory and industrial conditions, were obtained at temperature of 35 °C and current density of 8 A·dm−2. High temperatures resulted in the emergence of defects on the surface, in particular for industrial samples. The defects were visualized by metallographic images with Nomarski contrast and atomic force microscopy. X-ray photoelectron spectroscopy tests were used to analyze the composition of the passive layer on the electropolished surfaces.

scholarly journals Effect of Sputtering Temperature on Fluorocarbon Films: Surface Nanostructure and Fluorine/Carbon Ratio

Nanomaterials ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 848 ◽  
Author(s):  
Qi Zhao ◽  
Feipeng Wang ◽  
Kaizheng Wang ◽  
Guibai Xie ◽  
Wanzhao Cui ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Target Material ◽  
Chemical Compositions ◽  
Water Contact ◽  
Force Microscopy ◽  
Fluorocarbon Films ◽  
Atomic Force ◽  
Surface Nanostructure ◽  
Deposited Film ◽  
Fluorocarbon Film

In this work, fluorocarbon film was deposited on silicon (P/100) substrate using polytetrafluoroethylene (PTFE) as target material at elevated sputtering temperature. Field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS) were employed to investigate the surface morphology as well as structural and chemical compositions of the deposited film. The surface energy, as well as the polar and dispersion components, were determined by water contact angle (WCA) measurement. The experimental results indicated that increasing sputtering temperature effectively led to higher deposition rate, surface roughness and WCA of the film. It was found that the elevated temperature contributed to increasing saturated components (e.g., C–F2 and C–F3) and decreasing unsaturated components (e.g., C–C and C–CF), thus enhancing the fluorine-to-carbon (F/C) ratio. The results are expected aid in tailoring the design of fluorocarbon films for physicochemical properties.

scholarly journals Electrophoretic coating of amphiphilic chitosan colloids on regulating cellular behaviour

2013 ◽  
Vol 10 (86) ◽  
pp. 20130411 ◽  
Author(s):  
Yen-Jen Wang ◽  
Teng-Yuan Lo ◽  
Chieh-Hsi Wu ◽  
Dean-Mo Liu
Keyword(s):  
Stainless Steel ◽  
Umbilical Vein ◽  
Biochemical Properties ◽  
Stainless Steel Surface ◽  
Texture Surface ◽  
Force Microscopy ◽  
Cardiovascular Stents ◽  
Atomic Force ◽  
Cellular Behaviour ◽  
Umbilical Vein Endothelial Cells

In this communication, we report a facile nanotopographical control over a stainless steel surface via an electrophoretic deposition of colloidal amphiphilic chitosan for preferential growth, proliferation or migration of vascular smooth muscle cells (VSMCs) and human umbilical vein endothelial cells (HUVECs). Atomic force microscopy revealed that the colloidal surface exhibited a deposition time-dependent nanotopographical evolution, wherein two different nanotopographic textures indexed by ‘kurtosis’ ( R kur ) value were easily designed, which were termed as ‘sharp’ (i.e. high peak-to-valley texture) surface and ‘flat’ (i.e. low peak-to-valley texture) surface. Cellular behaviour of VSMCs and HUVECs on both surfaces demonstrated topographically dependent morphogenesis, adherent responses and biochemical properties in comparison with bare stainless steel. The formation of a biofunctionalized surface upon a facile colloidal chitosan deposition envisions the potential application towards numerous biomedical devices, and this is especially promising for cardiovascular stents wherein a new surface with optimized texture can be designed and is expected to create an advantageous environment to stimulate HUVEC growth for improved healing performance.

scholarly journals Surface Modification of Polyethersulfone (PES) with UV Photo-Oxidation

Technologies ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 36
Author(s):  
Ibrahim Cisse ◽  
Sarah Oakes ◽  
Shreen Sachdev ◽  
Marc Toro ◽  
Shin Lutondo ◽  
...  
Keyword(s):  
Surface Roughness ◽  
Contact Angle ◽  
Atomic Force Microscopy ◽  
Photoelectron Spectroscopy ◽  
Water Contact ◽  
X Ray ◽  
Force Microscopy ◽  
Photo Oxidation ◽  
Atomic Force ◽  
Modified Surfaces

Polyethersulfone (PES) films are widely employed in the construction of membranes where there is a desire to make the surface more hydrophilic. Therefore, UV photo-oxidation was studied in order to oxidize the surface of PES and increase hydrophilicity. UV photo-oxidation using low pressure mercury lamps emitting both 253.7 and 184.9 nm radiation were compared with only 253.7 nm photons. The modified surfaces were characterized using X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and water contact angle (WCA) measurements. Both sets of lamps gave similar results, showing an increase of the oxygen concentration up to a saturation level of ca. 29 at.% and a decrease in the WCA, i.e., an increase in hydrophilicity, down to ca. 40°. XPS detected a decrease of sp2 C-C aromatic group bonding and an increase in the formation of C-O, C=O, O=C-O, O=C-OH, O-(C=O)-O, and sulphonate and sulphate moieties. Since little change in surface roughness was observed by AFM, the oxidation of the surface caused the increase in hydrophilicity.

scholarly journals Self-organization of gold nanoparticles on silanated surfaces

2015 ◽  
Vol 6 ◽  
pp. 2345-2353 ◽  
Author(s):  
Htet H Kyaw ◽  
Salim H Al-Harthi ◽  
Azzouz Sellai ◽  
Joydeep Dutta
Keyword(s):  
Gold Nanoparticles ◽  
Photoelectron Spectroscopy ◽  
The Self ◽  
Self Organization ◽  
Water Contact ◽  
Force Microscopy ◽  
Sensor Applications ◽  
Glass Substrates ◽  
Angle Measurements ◽  
Atomic Force

The self-organization of monolayer gold nanoparticles (AuNPs) on 3-aminopropyltriethoxysilane (APTES)-functionalized glass substrate is reported. The orientation of APTES molecules on glass substrates plays an important role in the interaction between AuNPs and APTES molecules on the glass substrates. Different orientations of APTES affect the self-organization of AuNps on APTES-functionalized glass substrates. The as grown monolayers and films annealed in ultrahigh vacuum and air (600 °C) were studied by water contact angle measurements, atomic force microscopy, X-ray photoelectron spectroscopy, UV–visible spectroscopy and ultraviolet photoelectron spectroscopy. Results of this study are fundamentally important and also can be applied for designing and modelling of surface plasmon resonance based sensor applications.

scholarly journals UV Photo-Oxidation of Polybenzimidazole (PBI)

Technologies ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 52
Author(s):  
Devon Shedden ◽  
Kristen M. Atkinson ◽  
Ibrahim Cisse ◽  
Shin Lutondo ◽  
Tyshawn Roundtree ◽  
...  
Keyword(s):  
Contact Angle ◽  
Photoelectron Spectroscopy ◽  
Treatment Time ◽  
Aerospace Industry ◽  
Water Contact ◽  
X Ray ◽  
Force Microscopy ◽  
Photo Oxidation ◽  
Redox Flow Batteries ◽  
Atomic Force

Since polybenzimidazole (PBI) is often used in the aerospace industry, high-temperature fuel cells, and in redox flow batteries, this research investigated the surface modification of PBI film with 253.7 and 184.9 nm UV photo-oxidation. As observed by X-ray photoelectron spectroscopy (XPS), the oxygen concentration on the surface increased up to a saturation level of 20.2 ± 0.7 at %. With increasing treatment time, there were significant decreases in the concentrations of C-C sp2 and C=N groups and increases in the concentrations of C=O, O-C=O, O-(C=O)-O, C-N, and N-C=O containing moieties due to 253.7 nm photo-oxidation of the aromatic groups of PBI and reaction with ozone produced by 184. 9 nm photo-dissociation of oxygen. Because no significant changes in surface topography were detected by Atomic Force Microscopy (AFM) and SEM measurements, the observed decrease in the water contact angle down to ca. 44°, i.e., increase in hydrophilic, was due to the chemical changes on the surface.

Surface Modification of Polyvinylidenefluoride-Trifluoroethylene Film Using Argon Gas Plasma

2012 ◽  
Vol 626 ◽  
pp. 317-323 ◽  
Author(s):  
Rozana Mohd Dahan ◽  
Muhamad Naiman Sarip ◽  
Yap Seong Ling ◽  
Mohamad Hafiz Mohd Wahid ◽  
Adillah Nurashikin Arshad ◽  
...  
Keyword(s):  
Surface Roughness ◽  
Contact Angle ◽  
Photoelectron Spectroscopy ◽  
Argon Plasma ◽  
Water Contact ◽  
Force Microscopy ◽  
Atomic Force ◽  
Gas Plasma ◽  
Good Biocompatibility ◽  
Surface Modified

This study investigates the surface properties of plasma surface modified spin coated PVDF-TrFE (70/30) film using Atomic Force Microscopy (AFM), Water Contact Angle (WCA) and X-ray Photoelectron Spectroscopy (XPS). The surfaces of the spin coated PVDF-TrFE film were modified using 13.56 MHz rf Argon plasma. The exposure time of the charged particle PVDF-TrFE films were varied for 1, 3 and 5mins. Prior to modification, the average surface roughness obtained was 8.615nm, but upon modification, the surface roughness was found to increase to 12.466nm. The value of the contact angle of the modified film was reduced from 90o to 43o and the XPS analysis showed dehydrofluorination of PVDF-TrFE films surfaces. The improved in surface roughness and the increased in wettability of the modified film, resulted in good biocompatibility of the modified PVDF-TrFE thin films. This phenomenon has created interest in researchers for developing functional polymer used for applications in areas such are biomedical, bio-analytical assays, textile and even food industry.

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