scholarly journals Forensic Engineering of Advanced Polymeric Materials—Part VII: Degradation of Biopolymer Welded Joints

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1167
Author(s):  
W. Sikorska ◽  
M. Zięba ◽  
M. Musioł ◽  
M. Kowalczuk ◽  
H. Janeczek ◽  
...  

Welding technology may be considered as a promising processing method for the formation of packaging products from biopolymers. However, the welding processes used can change the properties of the polymer materials, especially in the region of the weld. In this contribution, the impact of the welding process on the structure and properties of biopolymer welds and their ability to undergo hydrolytic degradation will be discussed. Samples for the study were made from polylactide (PLA) and poly(3-hydroxyalkanoate) (PHA) biopolymers which were welded using two methods: ultrasonic and heated tool welding. Differential scanning calorimetry (DSC) analysis showed slight changes in the thermal properties of the samples resulting from the processing and welding method used. The results of hydrolytic degradation indicated that welds of selected biopolymers started to degrade faster than unwelded parts of the samples. The structure of degradation products at the molecular level was confirmed using mass spectrometry. It was found that hydrolysis of the PLA and PHA welds occurs via the random ester bond cleavage and leads to the formation of PLA and PHA oligomers terminated by hydroxyl and carboxyl end groups, similarly to as previously observed for unwelded PLA and PHA-based materials.

Materials ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 2005 ◽  
Author(s):  
Joanna Rydz ◽  
Jakub Włodarczyk ◽  
Jennifer Gonzalez Ausejo ◽  
Marta Musioł ◽  
Wanda Sikorska ◽  
...  

The use of (bio)degradable polymers, especially in medical applications, requires a proper understanding of their properties and behavior in various environments. Structural elements made of such polymers may be exposed to changing environmental conditions, which may cause defects. That is why it is so important to determine the effect of processing conditions on polymer properties and also their subsequent behavior during degradation. This paper presents original research on a specimen’s damage during 70 days of hydrolytic degradation. During a standard hydrolytic degradation study of polylactide and polylactide/polyhydroxyalkanoate dumbbell-shaped specimens obtained by 3D printing with two different processing build directions, exhibited unexpected shrinkage phenomena in the last degradation series, representing approximately 50% of the length of the specimens irrespective of the printing direction. Therefore, the continuation of previous ex-ante research of advanced polymer materials is presented to identify any possible defects before they arise and to minimize the potential failures of novel polymer products during their use and also during degradation. Studies on the impact of a specific processing method, i.e., processing parameters and conditions, on the properties expressed in molar mass and thermal properties changes of specimens obtained by three-dimensional printing from polyester-based filaments, and in particular on the occurrence of unexpected shrinkage phenomena after post-processing heat treatment, are presented.


Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1010 ◽  
Author(s):  
Valentina Linares ◽  
Cristhian J. Yarce ◽  
Juan D. Echeverri ◽  
Elkin Galeano ◽  
Constain H. Salamanca

The commercial copolymers Eudragit® E 100 and Eudragit® PO are widely used materials in the pharmaceutical field as coating systems. Such materials derived from amino-methacrylate groups under acidulated conditions may acquire an ionisable fraction or undergo hydrolytic degradation of the polymeric structure. This work focused on establishing the chemical, physical, and surface changes of two reprocessed polymeric materials, here named as EuCl-E-100 and EuCl-E-PO, which were obtained from the commercial Eudragit® E 100 and Eudragit® E PO, respectively. The commercial materials were exposed to extreme acid conditions, where the polymers were solubilised and subsequently dried by the refractance window method. The materials obtained were chemically characterised by potentiometric titration, nuclear magnetic resonance spectroscopy (1H NMR and 13C NMR) in one and two dimensions (COSY, HSQC, and HMBC), infrared spectroscopy, X-ray diffraction, and differential scanning calorimetry. Changes in the physical properties of the materials were evaluated through studies of flowability, compactability, and their ability to gain and lose humidity. Surface thermodynamic studies were carried out through contact angle measurements using the sessile drop method. The results showed that the processed polymeric materials acquired a substantial degree of ionisation without undergoing hydrolysis of the esterified groups. Furthermore, such changes improved the flow characteristics of the material and the solubility in aqueous media at pH > 5, while also maintaining the hydrophobicity degree of the polymeric surface.


2021 ◽  
Vol 91 (11-12) ◽  
pp. 1419-1435
Author(s):  
Wei Wei ◽  
Eunkyoung Shim ◽  
William Barnes ◽  
Behnam Pourdeyhimi

Spinning technology using melt extrusion and spin-draw processes transforms polymeric materials into highly oriented, crystallized polymeric fibers. Thermoplastic isotactic polypropylene compound with ground CaCO3 (GCC) and precipitate CaCO3 (PCC) with stearic acid surface coating treatment was used in this study. This product was developed in masterbatch form, which contained 70% GCC in resin and 50% PCC in resin. The resulting (masterbatch pellets) polymer can be spun into fibers through a single-screw extruder. Surface and cross-sectional images of fibers were captured by optical microscopy and scanning electronic microscopy for identifying the organic/inorganic interface of fibers. The melt-spun fibers have a distinctive morphology, the particles impact on spinnability, and productivity in the spunbond will alter the mechanical property, thermal property and optical property of fiber-based products. Processing parameters, including spinning speed, throughput rate and take-up roll velocity, were systematically study to understand the structure formation. Meanwhile, different loading concentrations are applied for varied factor comparison of particle size and shape. The Weibull distribution model is applied for determining the tensile property of fibers containing high GCC dosages of 20–40%. Meanwhile, a few more steps of gauge length are utilized for studying the probability of a weak link in polymer materials. Through a systematic discussion of the GCC and PCC comparison study in changing fiber properties, the impact of the particle size on agglomeration formation is emphasized, as well as the breaking mechanism of fibers.


2020 ◽  
Vol 15 (55) ◽  
Author(s):  
Djilali Benyerou ◽  
El Bahri Ould Chikh ◽  
Habib Khellafi ◽  
Hadj Miloud Meddah ◽  
Ali Benhamena ◽  
...  

Friction stir spot welding (FSSW) is a very important part of conventional friction stir welding (FSW) which can be a replacement for riveted assemblies and resistance spot welding. This technique provides high quality joints compared to conventional welding processes. Friction stir spot welding (FSSW) is a new technology adopted to join various types of metals such as titanium, aluminum, magnesium. It is also used for welding polymer materials which are difficult to weld by the conventional welding process. In various industrial applications, high density polyethylene (HDPE) becomes the most used material. The parameters and mechanical properties of the welds are the major problems in the welding processes. In this paper, we have presented a contribution in finite element modeling of the friction stir spot welding process (FSSW) using Abaqus as a finite element solver. The objective of this paper is to study the HDPE plates resistance of stir spot welding joints (FSSW). First, we show the experimental tests results of high-density polyethylene (HDPE) plates assembled by friction stir spot welding (FSSW). Three-dimensional numerical modeling by the finite element method makes it possible to determine the best representation of the weld joint for a good prediction of its behavior. Comparison of the results shows that there is a good agreement between the numerical modeling predictions and the experimental results.


2020 ◽  
Vol 128 ◽  
pp. 81-88 ◽  
Author(s):  
Paweł Kowalik ◽  
Mariusz Fabijański

The purpose of this study is to present the requirements, methodology, and results of research on the impact of biodegradable oil on plastic components used in the construction of a railway turnout. Briefly discussed are what railroad turnouts are, how they work, and what problems occur with substances used for their lubrication. They have an impact on the mechanical properties and durability of products made of polymeric materials. These types of materials absorb various kinds of chemicals, to a greater or lesser degree, and this affects their properties. For the tests, we used a universal lubrication oil with biodegradable properties, which is its most significant advantage. However, it may not cause deterioration of the turnout operation and change the properties of materials used for its construction. These types of oils require more frequent applications on cooperating components. We used the two most popular polymer materials. The first is high-density polyethylene (HDPE), used to make all kinds of rail spacers, dowels for fixing rails, sleeves, etc. The second, polyurethane (PUR) is most commonly used for rail pads of various shapes. The methodology and results of testing the impact of a lubricant (biodegradable oil) on the change of mechanical properties such as strength and hardness are presented. The tests were carried out at various temperatures; the time of exposure to oil was seven days; the results were referred to samples conditioned under standard conditions. The tests carried out on the impact of the biodegradable lubricant on polymeric materials (HDPE and PUR) showed little effect on the change of strength parameters of these materials. Celem niniejszego opracowania jest przedstawienie wymagań, metodyki oraz wyników badań oddziałania biodegradowalnego oleju na elementy z tworzyw sztucznych stosownych w budo-wie rozjazdu kolejowego. Krótko omówiono czym są rozjazdy kolejowe i jak działają oraz jakie występują problemy z substancjami używanymi do ich smarowania, które nie pozostają bez wpływu na właściwości mechaniczne i trwałość wyrobów z materiałów polimerowych. Materiały tego typu wchłaniają różnego rodzaju substancje chemiczne w większym lub mniejszym stopniu, a to ma wpływ na ich właściwości. Do badań został wykorzystany uniwersalny olej do smarowania o biodegradowalnych właściwościach, co jest jego największą zaletą. Jednak nie może on powodować pogorszenia pracy rozjazdu oraz zmieniać właściwości materiałów użytych do jego budowy. Tego typu oleje wymagają częstszego aplikowania na elementy współpracujące ze sobą. W pracy wykorzystano dwa najbardziej popularne materiały polimerowe. Pierw-szy to polietylen o dużej gęstości (HDPE), z którego wykonuje się wszelkiego rodzaju przekładki podszynowe, dyble do mocowania szyn, tuleje, itp. Drugi to poliuretan (PUR) stosowany najczęściej na przekładki podszynowe o różnym kształcie. Zaprezentowano metodykę i wyniki ba-dań oddziaływania środka smarnego (biodegradowalnego oleju) na zmianę właściwości mechanicznych takich jak wytrzymałość oraz twardość. Badania zostały przeprowadzone w różnych temperaturach, a czas ekspozycji na olej wynosił 7 dób, wyniki odniesiono do próbek klimatyzowanych w standardowych warunkach. Przeprowadzone badania oddziaływania biodegradowalnego środka smarnego na tworzywa polimerowe (HDPE i PUR), wykazały niewielki wpływ na zmianę parametrów wytrzymałościowych tych materiałów.


2020 ◽  
Vol 57 (3) ◽  
pp. 41-51
Author(s):  
Aleksandra Kalwik ◽  
Przemyslaw Postawa ◽  
Marcin Nabialek

The article presents the influence of accelerated UV ageing on the structural properties of selected polymer materials. In this study, 3 types of materials from a group of thermoplastics known as PP30T, PE, POM were used. The test samples were prepared by injection moulding. In turn, an accelerated UV ageing process (600 h) was carried out in the UV Test chamber with fluorescent lamps characterized by a wavelength of 313 nm. Changes in the structure of the tested materials were observed by using an optical microscope. Measurements of gloss on the surface of primary samples that were exposed to UV rays were also taken. In addition, the structure of primary and aged samples was tested by differential scanning calorimetry (DSC). The conducted studies have demonstrated the impact of UV radiation on the changes in the surface layer of tested materials.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Jian Wang ◽  
Chunzheng Wang ◽  
Mingtao Run

For preparing good performance polymer materials, poly(trimethylene terephthalate)/CaCO3nanocomposites were prepared and their morphology, rheological behavior, mechanical properties, heat distortion, and crystallization behaviors were investigated by transmission electron microscopy, capillary rheometer, universal testing machine, impact tester, heat distortion temperature tester, and differential scanning calorimetry (DSC), respectively. The results suggest that the nano-CaCO3particles are dispersed uniformly in the polymer matrix. PTT/CaCO3nanocomposites are pseudoplastic fluids, and the CaCO3nanoparticles serve as a lubricant by decreasing the apparent viscosity of the nanocomposites; however, both the apparent viscosity and the pseudoplasticity of the nanocomposites increase with increasing CaCO3contents. The nanoparticles also have nucleation effects on PTT’s crystallization by increasing the crystallization rate and temperature; however, excessive nanoparticles will depress this effect because of the agglomeration of the particles. The mechanical properties suggest that the CaCO3nanoparticles have good effects on improving the impact strength and tensile strength with proper content of fillers. The nanofillers can greatly increase the heat distortion property of the nanocomposites.


Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2200
Author(s):  
Marta Musioł ◽  
Sebastian Jurczyk ◽  
Michał Sobota ◽  
Magdalena Klim ◽  
Wanda Sikorska ◽  
...  

The need for a cost reduction of the materials derived from (bio)degradable polymers forces research development into the formation of biocomposites with cheaper fillers. As additives can be made using the post-consumer wood, generated during wood products processing, re-use of recycled waste materials in the production of biocomposites can be an environmentally friendly way to minimalize and/or utilize the amount of the solid waste. Also, bioactive materials, which possess small amounts of antimicrobial additives belong to a very attractive packaging industry solution. This paper presents a study into the biodegradation, under laboratory composting conditions, of the composites that consist of poly[(R)-3-hydroxybutyrate-co-4-hydroxybutyrate)] and wood flour as a polymer matrix and natural filler, respectively. Thermogravimetric analysis, differential scanning calorimetry and scanning electron microscopy were used to evaluate the degradation progress of the obtained composites with different amounts of wood flour. The degradation products were characterized by multistage electrospray ionization mass spectrometry. Also, preliminary tests of the antimicrobial activity of selected materials with the addition of nisin were performed. The obtained results suggest that the different amount of filler has a significant influence on the degradation profile.


Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 994 ◽  
Author(s):  
Joanna Rydz ◽  
Wanda Sikorska ◽  
Marta Musioł ◽  
Henryk Janeczek ◽  
Jakub Włodarczyk ◽  
...  

Knowledge of degradation and impairment phenomena of (bio)degradable polymeric materials under operating conditions, and thus the selection of test procedures and prediction of their behavior designates the scope and capabilities as well as possible limitations of both: the preparation of the final product and its durability. The main novelty and objective of this research was to determine the degradation pathways during testing of polylactide and polylactide/polyhydroxyalkanoate materials made with three-dimensional printing and the development of a new strategy for the comprehensive characterization of such complex systems including behavior during waste disposal. Prototype objects were subjected to tests for damage evolution performed under simulating operating conditions. The reference samples and the tested items were characterized by gel permeation chromatography and differential scanning calorimetry to determine changes in material properties. The studies showed that: polyhydroxyalkanoate component during accelerated aging and degradation in environments rich in microorganisms accelerated the degradation of the material; paraffin accelerates polylactide degradation and slows degradation of polyhydroxyalkanoate-based material; under the influence of an environment rich in enzymes, paraffin contamination accelerates biodegradation; under the influence of natural conditions, paraffin contamination slowed degradation; the processing conditions, in particular the printing orientation of individual parts of the container, influenced the material properties in its various regions, affecting the rate of degradation of individual parts.


2018 ◽  
Vol 4 (1) ◽  
pp. 583-585 ◽  
Author(s):  
Olga Sahmel ◽  
Daniela Arbeiter ◽  
Kerstin Schümann ◽  
Niels Grabow ◽  
Stefan Siewert ◽  
...  

AbstractAlthough current drug eluting stents show low risks of in-stent restenosis and stent thrombosis, the presence of a permanent foreign body inside the vessel represents a major limitation. In order to overcome this limitation, stents made of biodegradable polymeric materials are currently being developed. The present work describes an optimized fabrication process for tubular semi-finished products for manufacturing of stents made of poly-L-lactide (PLLA). The impact of the haul-off speed as a major parameter during extrusion processing on the cross-sectional area of tubular specimens was analyzed. It could be shown that the crosssection of the extrudate, in particular the tubing diameter and wall thickness, can be adjusted by varying haul-off speed. In a subsequent blow molding process the influence of the holding time on polymer cold crystallization was analyzed. Thermal properties of the polymeric material after processing were examined by differential scanning calorimetry (DSC). The results showed that there is almost no cold crystallization using a holding time of at least 20 minutes. The investigations showed that semi-finished products with variable geometry and improved mechanical properties can be produced with the described extrusion and blow molding process.


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