scholarly journals 3D-Printed Polyester-Based Prototypes for Cosmetic Applications—Future Directions at the Forensic Engineering of Advanced Polymeric Materials

Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 994 ◽  
Author(s):  
Joanna Rydz ◽  
Wanda Sikorska ◽  
Marta Musioł ◽  
Henryk Janeczek ◽  
Jakub Włodarczyk ◽  
...  
Keyword(s):  
Material Properties ◽  
Three Dimensional ◽  
Accelerated Aging ◽  
Polymeric Materials ◽  
Gel Permeation Chromatography ◽  
Operating Conditions ◽  
Test Procedures ◽  
Scanning Calorimetry ◽  
New Strategy ◽  
Forensic Engineering

Knowledge of degradation and impairment phenomena of (bio)degradable polymeric materials under operating conditions, and thus the selection of test procedures and prediction of their behavior designates the scope and capabilities as well as possible limitations of both: the preparation of the final product and its durability. The main novelty and objective of this research was to determine the degradation pathways during testing of polylactide and polylactide/polyhydroxyalkanoate materials made with three-dimensional printing and the development of a new strategy for the comprehensive characterization of such complex systems including behavior during waste disposal. Prototype objects were subjected to tests for damage evolution performed under simulating operating conditions. The reference samples and the tested items were characterized by gel permeation chromatography and differential scanning calorimetry to determine changes in material properties. The studies showed that: polyhydroxyalkanoate component during accelerated aging and degradation in environments rich in microorganisms accelerated the degradation of the material; paraffin accelerates polylactide degradation and slows degradation of polyhydroxyalkanoate-based material; under the influence of an environment rich in enzymes, paraffin contamination accelerates biodegradation; under the influence of natural conditions, paraffin contamination slowed degradation; the processing conditions, in particular the printing orientation of individual parts of the container, influenced the material properties in its various regions, affecting the rate of degradation of individual parts.

scholarly journals A New Strategy for the Synthesis of Hydroxyl Terminated Polystyrene-b-Polybutadiene-b-Polystyrene Triblock Copolymer with High Cis-1, 4 Content

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 598 ◽  
Author(s):  
Xin Min ◽  
Xiaodong Fan
Keyword(s):  
Triblock Copolymer ◽  
Gel Permeation Chromatography ◽  
Hydroxyl Group ◽  
The Novel ◽  
Scanning Calorimetry ◽  
Gel Permeation ◽  
New Strategy ◽  
Ft Ir ◽  
Novel Catalyst ◽  
Lower Glass Transition Temperature

This work reports the preparation of a hydroxyl terminated polystyrene-b-polybutadiene-b-polystyrene triblock copolymer (SBS) with high cis-1, 4 content via a novel nickel catalyst, [η3-Ni(CH2CHCHCH2OOCH3)][BPhF4]. FT-IR, 1H-NMR, and 13C NMR indicated that the polybutadiene segment of the copolymer contains greater than 90% cis-1, 4 structure, indicating achievement of the objective. Toward the functionalization goal, a hydroxyl group was successfully introduced at the end of the triblock copolymer (HO–SBS–OH). The results of gel permeation chromatography (GPC) revealed that the polymer is indeed a triblock copolymer, with no traces of homopolymer. Differential scanning calorimetry (DSC) showed that HO–SBS–OH synthesized using the novel catalyst had a lower glass transition temperature (Tg) than HO–SBS–OH synthesized with an alkyl lithium catalyst. Therefore, the polymer synthesized via the novel catalyst contains high cis-1,4 content and displays excellent low-temperature mechanical properties.

scholarly journals Forensic Engineering of Advanced Polymeric Materials—Part VII: Degradation of Biopolymer Welded Joints

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1167
Author(s):  
W. Sikorska ◽  
M. Zięba ◽  
M. Musioł ◽  
M. Kowalczuk ◽  
H. Janeczek ◽  
...  
Keyword(s):  
Degradation Products ◽  
Bond Cleavage ◽  
Hydrolytic Degradation ◽  
Welding Process ◽  
Polymeric Materials ◽  
Polymer Materials ◽  
Scanning Calorimetry ◽  
Forensic Engineering ◽  
The Impact ◽  
Welding Processes

Welding technology may be considered as a promising processing method for the formation of packaging products from biopolymers. However, the welding processes used can change the properties of the polymer materials, especially in the region of the weld. In this contribution, the impact of the welding process on the structure and properties of biopolymer welds and their ability to undergo hydrolytic degradation will be discussed. Samples for the study were made from polylactide (PLA) and poly(3-hydroxyalkanoate) (PHA) biopolymers which were welded using two methods: ultrasonic and heated tool welding. Differential scanning calorimetry (DSC) analysis showed slight changes in the thermal properties of the samples resulting from the processing and welding method used. The results of hydrolytic degradation indicated that welds of selected biopolymers started to degrade faster than unwelded parts of the samples. The structure of degradation products at the molecular level was confirmed using mass spectrometry. It was found that hydrolysis of the PLA and PHA welds occurs via the random ester bond cleavage and leads to the formation of PLA and PHA oligomers terminated by hydroxyl and carboxyl end groups, similarly to as previously observed for unwelded PLA and PHA-based materials.

scholarly journals Parameter Optimization in High-Throughput Testing for Structural Materials

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3439 ◽  
Author(s):  
Alexander Bader ◽  
Anastasiya Toenjes ◽  
Nicole Wielki ◽  
Andreas Mändle ◽  
Ann-Kathrin Onken ◽  
...  
Keyword(s):  
Design Of Experiments ◽  
High Throughput ◽  
Process Parameters ◽  
Material Properties ◽  
Functional Materials ◽  
Structural Materials ◽  
Major Influence ◽  
Test Procedures ◽  
Scanning Calorimetry ◽  
Target Values

High-throughput screenings are established evaluation methods in the development of functional materials and pharmaceutical active ingredients. The transfer of this approach to the development of structural materials requires extensive adaptations. In addition to the investigation of new test procedures for the determination of material properties and the treatment of metallic materials, the design of experiments is a research focus. Based on given descriptor target values, the statistical design of experiments determines investigations and treatments for the investigation of these materials. In this context, process parameters also have to be determined, as these have a major influence on the later material properties, especially during the treatment of samples. In this article, a method is presented which determines the process parameters iteratively. The validation of the calculated process parameters takes place based on differential scanning calorimetry used as the furnace for the heat treatment of small batches and particle-oriented peening as the characterization method.

scholarly journals PLGA Coatings and PLGA Drug-Loading Coatings for Cardiac Stent Samples: Degradation Characteristics and Blood Compatibility

Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1427
Author(s):  
Ziyang Jia ◽  
Chunyang Ma ◽  
Hongbin Zhang
Keyword(s):  
Thermal Properties ◽  
Blood Compatibility ◽  
Spray Deposition ◽  
Drug Loading ◽  
Three Dimensional ◽  
Gel Permeation Chromatography ◽  
Relative Molecular Mass ◽  
Scanning Calorimetry ◽  
Electrostatic Spray Deposition ◽  
316 L Stainless Steel

PLGA (Poly lactic-co-glycolic acid) and PLGA drug-loading coatings were prepared on 316 L stainless steel by electrostatic spray deposition (ESD). The surface morphology, three-dimensional morphology, and crystal structures of the coatings were observed by scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray diffraction (XRD). Thermal properties, molecular weight, and coating composition were studied by differential scanning calorimetry (DSC), gel permeation chromatography (GPC), and NMR. The degradation behaviors of the coatings were studied by mass changes, relative molecular mass and distributions, polymer compositions, thermal properties, and surface morphologies. The blood compatibilities of the coatings were investigated by platelet adhesion testing and dynamic coagulation times. SEM results indicated the drug-loading coating with 33% RAPA had the smoothest and most compact morphology. Addition of RAPA decreased the Tg of the PLGA coating, accompanied by partial crystallization that slowed the degradation rate of the drug-loaded coating. Microscopically, the morphology of the PLGA drug-loaded coating was coarser than the PLGA coating. The average surface roughness values of line and surface scannings were 16.232 nm and 39.538 nm, respectively. The surface of the drug-loading coating was micro uneven, and the macro smooth and micro multiphase separation structure helped improve its blood compatibility.

Pavement Damage Due to Conventional and New Generation of Wide-Base Super Single Tires

2005 ◽  
Vol 33 (4) ◽  
pp. 210-226 ◽  
Author(s):  
I. L. Al-Qadi ◽  
M. A. Elseifi ◽  
P. J. Yoo ◽  
I. Janajreh
Keyword(s):  
Carrying Capacity ◽  
Material Properties ◽  
Three Dimensional ◽  
Fe Analysis ◽  
Load Carrying Capacity ◽  
Inflation Pressure ◽  
3D Finite Element ◽  
Load Carrying ◽  
Pavement Damage ◽  
New Generation

Abstract The objective of this study was to quantify pavement damage due to a conventional (385/65R22.5) and a new generation of wide-base (445/50R22.5) tires using three-dimensional (3D) finite element (FE) analysis. The investigated new generation of wide-base tires has wider treads and greater load-carrying capacity than the conventional wide-base tire. In addition, the contact patch is less sensitive to loading and is especially designed to operate at 690kPa inflation pressure at 121km/hr speed for full load of 151kN tandem axle. The developed FE models simulated the tread sizes and applicable contact pressure for each tread and utilized laboratory-measured pavement material properties. In addition, the models were calibrated and properly validated using field-measured stresses and strains. Comparison was established between the two wide-base tire types and the dual-tire assembly. Results indicated that the 445/50R22.5 wide-base tire would cause more fatigue damage, approximately the same rutting damage and less surface-initiated top-down cracking than the conventional dual-tire assembly. On the other hand, the conventional 385/65R22.5 wide-base tire, which was introduced more than two decades ago, caused the most damage.

scholarly journals Study on improving three-dimensional dynamic simulation model and equation of flexible fabric

2019 ◽  
Vol 11 (6) ◽  
pp. 168781401985284
Author(s):  
Meiliang Wang ◽  
Mingjun Wang ◽  
Xiaobo Li
Keyword(s):  
Simulation Model ◽  
Dynamic Simulation ◽  
Material Properties ◽  
Three Dimensional ◽  
Equation Solving ◽  
Study Results ◽  
Essential Properties ◽  
Dynamic Simulation Model ◽  
Novel Model ◽  
Simulation Equation

The use of the traditional fabric simulation model evidently shows that it cannot accurately reflect the material properties of the real fabric. This is against the background that the simulation result is artificial or an imitation, which leads to a low simulation equation. In order to solve such problems from occurring, there is need for a novel model that is designed to enhance the essential properties required for a flexible fabric, the simulation effect of the fabric, and the efficiency of simulation equation solving. Therefore, the improvement study results will offer a meaningful and practical understanding within the field of garment automation design, three-dimensional animation, virtual fitting to mention but a few.

scholarly journals Is Micro X-ray Computer Tomography a Suitable Non-Destructive Method for the Characterisation of Dental Materials?

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1271
Author(s):  
Andreas Koenig ◽  
Leonie Schmohl ◽  
Johannes Scheffler ◽  
Florian Fuchs ◽  
Michaela Schulz-Siegmund ◽  
...  
Keyword(s):  
Flexural Strength ◽  
Computer Tomography ◽  
Mechanical Performance ◽  
Dental Materials ◽  
Three Dimensional ◽  
X Rays ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Multiple Measurements ◽  
High Doses

The aim of the study was to investigate the effect of X-rays used in micro X-ray computer tomography (µXCT) on the mechanical performance and microstructure of a variety of dental materials. Standardised bending beams (2 × 2 × 25 mm3) were forwarded to irradiation with an industrial tomograph. Using three-dimensional datasets, the porosity of the materials was quantified and flexural strength was investigated prior to and after irradiation. The thermal properties of irradiated and unirradiated materials were analysed and compared by means of differential scanning calorimetry (DSC). Single µXCT measurements led to a significant decrease in flexural strength of polycarbonate with acrylnitril-butadien-styrol (PC-ABS). No significant influence in flexural strength was identified for resin-based composites (RBCs), poly(methyl methacrylate) (PMMA), and zinc phosphate cement (HAR) after a single irradiation by measurement. However, DSC results suggest that changes in the microstructure of PMMA are possible with increasing radiation doses (multiple measurements, longer measurements, higher output power from the X-ray tube). In summary, it must be assumed that X-ray radiation during µXCT measurement at high doses can lead to changes in the structure and properties of certain polymers.

scholarly journals Proof-of-Concept of Detection of Counterfeit Medicine through Polymeric Materials Analysis of Plastics Packaging

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2185
Author(s):  
Mohammad Salim ◽  
Riyanto Teguh Widodo ◽  
Mohamed Ibrahim Noordin
Keyword(s):  
Polymeric Materials ◽  
Proof Of Concept ◽  
Scanning Calorimetry ◽  
Counterfeit Drug ◽  
Drug Products ◽  
Counterfeit Medicines ◽  
Counterfeit Medicine ◽  
Counterfeit Pharmaceuticals ◽  
Purge Gas ◽  
Sample Set

The detection of counterfeit pharmaceuticals is always a major challenge, but the early detection of counterfeit medicine in a country will reduce the fatal risk among consumers. Technically, fast laboratory testing is vital to develop an effective surveillance and monitoring system of counterfeit medicines. This study proposed the combination of Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) and Differential Scanning Calorimetry (DSC) for the quick detection of counterfeit medicines, through the polymer analysis of blister packaging materials. A sample set containing three sets of original and counterfeit medicine was analyzed using ATR-FTIR and DSC, while the spectra from ATR-FTIR were employed as a fingerprint for the polymer characterization. Intending to analyze the polymeric material of each sample, DSC was set at a heating rate of 10 °C min−l and within a temperature range of 0- 400 °C, with nitrogen as a purge gas at a flow rate of 20 ml min−an. The ATR-FTIR spectra revealed the chemical characteristics of the plastic packaging of fake and original medicines. Further analysis of the counterfeit medicine’s packaging with DSC exhibited a distinct difference from the original due to the composition of polymers in the packaging material used. Overall, this study confirmed that the rapid analysis of polymeric materials through ATR-FTIR and comparing DSC thermograms of the plastic in their packaging effectively distinguished counterfeit drug products.

scholarly journals Electrochemically Produced Copolymers of Pyrrole and Its Derivatives: A Plentitude of Material Properties Using “Simple” Heterocyclic Co-Monomers

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 281
Author(s):  
Tomasz Jarosz ◽  
Przemyslaw Ledwon
Keyword(s):  
Biological Activity ◽  
Material Properties ◽  
Building Block ◽  
Conjugated Polymer ◽  
Chemical Structure ◽  
Heterocyclic System ◽  
Repeat Unit ◽  
Polymeric Materials ◽  
Pyrrole Derivatives ◽  
Pyrrole Monomer

Polypyrrole is a classical, well-known conjugated polymer that is produced from a simple heterocyclic system. Numerous pyrrole derivatives exhibit biological activity, and the repeat unit is a common building block present in the chemical structure of many polymeric materials, finding wide application, primarily in optoelectronics and sensing. In this work, we focus on the variety of copolymers and their material properties that can be produced electrochemically, even though all these systems are obtained from mixtures of the “simple” pyrrole monomer and its derivatives with different conjugated and non-conjugated species.

scholarly journals Biocompatibility studies of polyurethane electrospun membranes based on arginine as chain extender

2021 ◽  
Vol 32 (9) ◽  
Author(s):  
Georgina Alejandra Venegas-Cervera ◽  
Andrés Iván Oliva ◽  
Alejandro Avila-Ortega ◽  
José Manuel Cervantes-Uc ◽  
Leydi Maribel Carrillo-Cocom ◽  
...  
Keyword(s):  
Fourier Transforms ◽  
Cell Attachment ◽  
Human Fibroblasts ◽  
Gel Permeation Chromatography ◽  
Electrospinning Process ◽  
Chain Extender ◽  
Cellular Interaction ◽  
Scanning Calorimetry ◽  
Polyurethane Membranes ◽  
Electrospun Membranes

AbstractElectrospun polymers are an example of multi-functional biomaterials that improve the material-cellular interaction and aimed at enhancing wound healing. The main objective of this work is to fabricate electrospun polyurethane membranes using arginine as chain extender (PUUR) in order to test the fibroblasts affinity and adhesion on the material and the polymer toxicity. Polyurethane membranes were prepared in two steps: (i) the polyurethane synthesis, and ii) the electrospinning process. The membranes were characterized by scanning electron microscopy (SEM), Fourier transforms infrared spectroscopy, gel permeation chromatography, and differential scanning calorimetry techniques. The evaluation of PUUR as a scaffolding biomaterial for growing and developing of cells on the material was realized by LIVE/DEAD staining. The results show that the fluorescent surface area of human fibroblasts (hFB), was greater in control dense membranes made from Tecoflex than in electrospun and dense PUUR. From SEM analysis, the electrospun membranes show relatively uniform attachment of cells with a well-spread shape, while Tecoflex dense membranes show a non-proliferating round shape, which is attributed to the fiber’s structure in electrospun membranes. The cell morphology and the cell attachment assay results reveal the well spreading of hFB cells on the surface of electrospun PUUR membranes which indicates a good response related to cell adhesion.

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