scholarly journals Efficient Chain Formation of Magnetic Particles in Elastomers with Limited Space

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 290
Author(s):  
Shota Akama ◽  
Yusuke Kobayashi ◽  
Mika Kawai ◽  
Tetsu Mitsumata

The magnetic response of the storage modulus for bimodal magnetic elastomers containing magnetic particles with a diameter of 7.0 μm and plastic beads with a diameter of 200 μm were investigated by varying the volume fraction of plastic beads up to 0.60 while keeping the volume fraction of the magnetic particles at 0.10. The storage modulus at 0 mT for monomodal magnetic elastomers was 1.4 × 104 Pa, and it slightly increased with the volume fraction of plastic beads up to 0.6. The storage modulus at 500 mT for bimodal magnetic elastomers at volume fractions below 0.25 was constant, which was equal to that for the monomodal one (=7.9 × 104 Pa). At volume fractions of 0.25–0.40, the storage modulus significantly increased with the volume fraction, showing a percolation behavior. At volume fractions of 0.40-0.60, the storage modulus was constant at 2.0 × 105 Pa, independently of the volume fraction. These results indicate that the enhanced increase in the storage modulus was caused by the chain formation of the magnetic particles in vacancies made of plastic beads.

Biomimetics ◽  
2019 ◽  
Vol 4 (4) ◽  
pp. 68 ◽  
Author(s):  
Kobayashi ◽  
Akama ◽  
Ohori ◽  
Kawai ◽  
Mitsumata

A magnetic-responsive elastomer consisting of magnetic elastomer and zinc oxide with a tetrapod shape and long arms was fabricated mimetic to the tissue of sea cucumber in which collagen fibrils are dispersed. Only the part of magnetic elastomer is active to magnetic fields, zinc oxide plays a role of reinforcement for the chain structure of magnetic particles formed under magnetic fields. The magnetic response of storage modulus for bimodal magnetic elastomers was measured when the magnetic particle was substituted to a nonmagnetic one, while keeping the total volume fraction of both particles. The change in storage modulus obeyed basically a mixing rule. However, a remarkable enhancement was observed at around the substitution ratio of 0.20. In addition, the bimodal magnetic elastomers with tetrapods exhibited apparent change in storage modulus even at regions with a high substitution ratio where monomodal magnetic elastomers consist of only magnetic particles with less response to the magnetic field. This strongly indicates that discontinuous chains of small amounts of magnetic particles were bridged by the nonmagnetic tetrapods. On the contrary, the change in storage modulus for bimodal magnetic elastomers with zinc oxide with irregular shape showed a mixing rule with a substitution ratio below 0.30. However, it decreased significantly at the substitution ratio above it. The structures of bimodal magnetic elastomers with tetrapods and the tissue of sea cucumber with collagen fibrils are discussed.


2017 ◽  
Vol 46 (11) ◽  
pp. 1628-1630
Author(s):  
Jinta Nanpo ◽  
Shota Abe ◽  
Mika Kawai ◽  
Tetsu Mitsumata

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Wijittra Wichiansee ◽  
Anuvat Sirivat

AbstractElectromechanical properties of crosslinked polydimethylsiloxane (PDMS) and PDMS_PEDOT/PSS blends were investigated as potential actuator materials. Experiments were carried out under the oscillatory shear mode and with applied electric filed strength varying from 0 to 2 kV/mm. The storage modulus, G', of the crosslinked PDMS increases with increasing electric filed strength with a scaling behavior: ΔG' α Eα where the scaling exponent α is equal to 0.88. With PEDOT/PSS particles added at volume fractions of 5, 10, 15, and 20 vol%, the storage modulus G' of the polymer blends, are higher than that of the pristine crosslinked PDMS. The scaling exponent of the scaling behavior decreases from 0.88 to 0.10 as the volume fraction increases from 0 to 20 vol%. The storage modulus sensitivity,, attains maximum values of 8%, 9%, 10%, and 9%, at particle volume fractions of 5, 10, 15, and 20 vol%, respectively at the electric field strength of 2 kV/mm. Temporal response of the crosslinked PDMS system is irreversible, but the response of the PDMS_PEDOT/PSS system is evidently reversible


Author(s):  
Hassan Mohamed Abdelalim Abdalla ◽  
Daniele Casagrande

AbstractOne of the main requirements in the design of structures made of functionally graded materials is their best response when used in an actual environment. This optimum behaviour may be achieved by searching for the optimal variation of the mechanical and physical properties along which the material compositionally grades. In the works available in the literature, the solution of such an optimization problem usually is obtained by searching for the values of the so called heterogeneity factors (characterizing the expression of the property variations) such that an objective function is minimized. Results, however, do not necessarily guarantee realistic structures and may give rise to unfeasible volume fractions if mapped into a micromechanical model. This paper is motivated by the confidence that a more intrinsic optimization problem should a priori consist in the search for the constituents’ volume fractions rather than tuning parameters for prefixed classes of property variations. Obtaining a solution for such a class of problem requires tools borrowed from dynamic optimization theory. More precisely, herein the so-called Pontryagin Minimum Principle is used, which leads to unexpected results in terms of the derivative of constituents’ volume fractions, regardless of the involved micromechanical model. In particular, along this line of investigation, the optimization problem for axisymmetric bodies subject to internal pressure and for which plane elasticity holds is formulated and analytically solved. The material is assumed to be functionally graded in the radial direction and the goal is to find the gradation that minimizes the maximum equivalent stress. A numerical example on internally pressurized functionally graded cylinders is also performed. The corresponding solution is found to perform better than volume fraction profiles commonly employed in the literature.


1995 ◽  
Vol 4 (1) ◽  
pp. 096369359500400
Author(s):  
T.D. Papathanasiou

The predictions of the Halpin equation concerning the effect of fibre volume fraction and fibre aspect ratio on the effective tensile modulus of uniaxially aligned short-fibre composites are compared with computational experiments on three-dimensional, multiparticle composite samples. The method of boundary elements is used to model the mechanical behaviour of composite specimens consisting of up to 40 discrete aligned fibres randomly dispersed in an elastic matrix. Statistical averages of computational results relating the effective tensile modulus to the aspect ratio and volume fraction of the fibres are found to agree very well with the predictions of the Halpin equation for fibre aspect ratio up to 10 and fibre volume fractions up to 20%. Computational results seem to indicate that the predictions of the Halpin equation fall bellow those of micro-mechanical models at higher volume fractions.


2011 ◽  
Vol 311-313 ◽  
pp. 201-204
Author(s):  
Hong Zhong Ru ◽  
Ran Ran Zhao

Electrical conductive carbon black-filled cement-based composites are significant as multifunctional structural materials. Double percolation in carbon black-filled cement-based composites involves both carbon black particle percolation and cement paste percolation, which has great effect on the resistivity of composites. Based on double percolation theory, the influences of sand-binder ratio and carbon black volume fraction on the resistivity of carbon black-filled cement-based composites are investigated. The results show that besides carbon black volume fraction, sand-binder ratio is a key factor affecting double percolation behavior in carbon black-filled cement-based composites. At a fixed carbon black content in overall mortar, with increasing sand-binder ratio, the cement paste percolation though aggregate phase increases due to high obstruction of aggregate but the carbon black particle percolation in cement paste decreases. This is because that the microstructure of aggregate is impenetrable so that the carbon black particles are limited in cement paste, that is, the carbon black content in paste is compacted and large amount of conductive paths are generated by lapped adjacent carbon black particles in paste. The double percolation in the electrical conduction in carbon black-filled cement-based composites is observed when the carbon black volume fraction is 7.5% and sand-binder ratio is 1.4, and its resistivity is only 3200 Ωcm, so that a sand-binder ratio of 1.4 and 7.5% carbon black volume fraction or more are recommended for attaining high conductivity with a compromise between workability and conductivity.


2005 ◽  
Vol 105 ◽  
pp. 133-138 ◽  
Author(s):  
Pierre Barbéris ◽  
Frank Montheillet ◽  
Cédric Chauvy

The elastic energy of a set of the twelve variants generated during the b ® a transformation of zirconium, with volume fractions fi, i=1..12, is derived with simplifying assumptions and the conditions on the fi to reach the energy minimum are established analytically. The minimum number of variants needed to reach this minimum is shown to be 6, and in this case, the variants have very specific volume fractions. Another result is that the maximum volume fraction of any variant is 1/3.


Author(s):  
Ke Niu ◽  
Armin Abedini ◽  
Zengtao Chen

This paper investigates the influence of multiple inclusions on the Cauchy stress of a spherical particle-reinforced metal matrix composite (MMC) under uniaxial tensile loading condition. The approach of three-dimensional cubic multi-particle unit cell is used to investigate the 15 non-overlapping identical spherical particles which are randomly distributed in the unit cell. The coordinates of the center of each particle are calculated by using the Random Sequential Adsorption algorithm (RSA) to ensure its periodicity. The models with reinforcement volume fractions of 10%, 15%, 20% and 25% are evaluated by using the finite element method. The behaviour of Cauchy stress for each model is analyzed at a far-field strain of 5%. For each reinforcement volume fraction, four models with different particle spatial distributions are evaluated and averaged to achieve a more accurate result. At the same time, single-particle unit cell and analytical model were developed. The stress-strain curves of multi-particle unit cells are compared with single-particle unit cells and the tangent homogenization model coupled with the Mori-Tanaka method. Only little scatters were found between unit cells with the same particle volume fractions. Multi-particle unit cells predict higher response than single particle unit cells. As the volume fraction of reinforcements increases, the Cauchy stress of MMCs increases.


2021 ◽  
Vol 879 ◽  
pp. 284-293
Author(s):  
Norliana Bakar ◽  
Siew Choo Chin

Fiber Reinforced Polymer (FRP) made from synthetic fiber had been widely used for strengthening of reinforced concrete (RC) structures in the past decades. Due to its high cost, detrimental to the environment and human health, natural fiber composites becoming the current alternatives towards a green and environmental friendly material. This paper presents an investigation on the mechanical properties of bamboo fiber reinforced composite (BFRC) with different types of resins. The BFRC specimens were prepared by hand lay-up method using epoxy and vinyl-ester resins. Bamboo fiber volume fractions, 30%, 35%, 40%, 45% and 50% was experimentally investigated by conducting tensile and flexural test, respectively. Results showed that the tensile and flexural strength of bamboo fiber reinforced epoxy composite (BFREC) was 63.2% greater than the bamboo fiber reinforced vinyl-ester composite (BFRVC). It was found that 45% of bamboo fiber volume fraction on BFREC exhibited the highest tensile strength compared to other BFRECs. Meanwhile, 40% bamboo fiber volume fraction of BFRVC showed the highest tensile strength between bamboo fiber volume fractions for BFRC using vinyl-ester resin. Studies showed that epoxy-based BFRC exhibited excellent results compared to the vinyl-ester-based composite. Further studies are required on using BFRC epoxy-based composite in various structural applications and strengthening purposes.


2018 ◽  
Vol 10 (5) ◽  
pp. 19
Author(s):  
Ferdusee Akter ◽  
Md. Bhuyan ◽  
Ujjwal Deb

Two phase flows in pipelines are very common in industries for the oil transportations. The aim of our work is to observe the effect of oil volume fraction in the oil in water two phase flows. The study has been accomplished using a computational model which is based on a Finite Element Method (FEM) named Galerkin approximation. The velocity profiles and volume fractions are performed by numerical simulations and we have considered the COMSOL Multiphysics Software version 4.2a for our simulation. The computational domain is 8m in length and 0.05m in radius. The results show that the velocity of the mixture decreases as the oil volume fraction increases. It should be noted that if we gradually increase the volume fractions of oil, the fluid velocity also changes and the saturated level of the volume fraction is 22.3%.


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