scholarly journals Effects of a Macromolecule Spirocyclic Inflatable Flame Retardant on the Thermal and Flame Retardant Properties of Epoxy Resin

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 132 ◽  
Author(s):  
Kunpeng Song ◽  
Yinjie Wang ◽  
Fang Ruan ◽  
Jiping Liu ◽  
Nianhua Li ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Phosphorus Oxychloride ◽  
Raw Materials ◽  
Smoke Suppression ◽  
Step Method ◽  
Scanning Calorimetry ◽  
New Strategy ◽  
Flame Retardant Properties

A new strategy for the preparation of an integrated three-source intumescent flame retardant (IFR) has been developed to improve the flame-retardant and smoke suppression performance of epoxy resin (EP) with a synergistic flame retardant effect. Herein, the synthesis of a macromolecular spirocyclic phosphorus/nitrogen-containing IFR poly sulfonamide spirocyclic pentaerythritol bisphosphonate (SAPC) is reported via a two-step method that uses pentaerythritol, phosphorus oxychloride and sulfonamide (SAA) as raw materials. Subsequently, the SAPC was incorporated into EP to prepare the composite to investigate its thermal stability, flame retardancy, and smoke suppression performance. Herein, a differential scanning calorimetry (DSC) analysis showed that the addition of SAPC increased the glass transition temperature (Tg) of the composite. Cone test results indicated that the incorporation of 8 wt % SAPC significantly improved the flame-retardant performance for the composite, with a 43.45% decrease in peak of heat release rate, a 28.55% reduction in total heat release, and a 30.04% decrease in total smoke release. Additionally, the composite received the V-0 rating in a UL-94 vertical burning test, accompanied by the “blowout” phenomenon. After the addition of SAPC, the amount of flammable gas products from the EP composite decomposition was obviously suppressed, and the amount of non-flammable as was increased. All of this suggests a good dilution role of SAPC. There are enough reasons to believe that the enhanced flame-retardant and toxicity suppression performance for the EP composite can be attributed to the good coordination of carbonization agent, acid source, and blowing agent in the SAPC structure.

Synthesis of a phosphorus–nitrogen-containing flame retardant and its application in epoxy resin

2018 ◽  
Vol 31 (2) ◽  
pp. 186-196 ◽  
Author(s):  
Shuang Yang ◽  
Yefa Hu ◽  
Qiaoxin Zhang
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Heat Release Rate ◽  
Flame Retardancy ◽  
Release Rate ◽  
Epoxy Resins ◽  
Proton Nuclear Magnetic Resonance ◽  
Scanning Calorimetry ◽  
Cone Calorimeter Test

In this article, a phosphorus–nitrogen-containing flame retardant (DOPO-T) was successfully synthesized by nucleophilic substitution reaction between 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and cyanuric chloride. The chemical structure of DOPO-T was characterized by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance (NMR) and phosphorous-31 NMR, and elemental analysis. DOPO-T was then blended with diglycidyl ether of bisphenol-A to prepare flame-retardant epoxy resins. Thermal properties, flame retardancy, and combustion behavior of the cured epoxy resins were evaluated by differential scanning calorimetry, thermogravimetric analysis, limited oxygen index (LOI) measurement, UL94 vertical burning test, and cone calorimeter test. The results indicated that the glass transition temperature ( Tg) and temperature at 5% weight loss of epoxy resin (EP)/DOPO-T thermosets were gradually decreased with the increasing content of DOPO-T. DOPO-T catalyzed the decomposition of EP matrix in advance. The flame-retardant performance of EP thermosets was significantly enhanced with the addition of DOPO-T. EP/DOPO-T-0.9 sample had an LOI value of 36.2% and achieved UL94 V-1 rating. In addition, the average of heat release rate, peak of heat release rate, average of effective heat of combustion, and total heat release (THR) of EP/DOPO-T-0.9 sample were decreased by 32%, 48%, 23%, and 31%, respectively, compared with the neat EP sample. Impressively, EP/DOPO-T thermosets acquired excellent flame retardancy under low loading of flame retardant.

Research on NPM Used in Flame Retardant Epoxy Potting

2012 ◽  
Vol 586 ◽  
pp. 172-176
Author(s):  
Hao Ran Zhou ◽  
Hao Cheng Yang ◽  
An Sun ◽  
Shuang Zhao
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Oxygen Index ◽  
Phosphorus Oxychloride ◽  
Gravimetric Analysis ◽  
Limiting Oxygen Index ◽  
Neopentyl Glycol ◽  
Melamine Salt ◽  
Flame Retardant Properties ◽  
Potting Compound

As the epoxy potting compound widely used, their flame retardant properties were concerned day by day.This paper neopentyl glycol phosphate melamine salt (NPM) was synthesised via phosphorus oxychloride as the acid source, neopentyl glycol as carbon source, melamine as gas source. The structure of NPM was characterized via infrared spectroscopic analysis (IR). Then the flame retardant properties of NPM/epoxy resin systerm were researched via the limiting oxygen index (LOI), vertical burning experiment, thermal gravimetric analysis (TGA) . The result shows that When the dosage of NPM is 27%, limiting oxygen index of epoxy resin have a extremum, is 32.4, char yield is 18.7% at 600°C. NPM can play a significant role in the improvement of the flame retardant properties of the epoxy.

scholarly journals Investigation on the Flame Retardant Properties and Fracture Toughness of DOPO and Nano-SiO2 Modified Epoxy Novolac Resin and Evaluation of Its Combinational Effects

Materials ◽  
2019 ◽  
Vol 12 (9) ◽  
pp. 1528 ◽  
Author(s):  
Markus Häublein ◽  
Karin Peter ◽  
Gökhan Bakis ◽  
Roi Mäkimieni ◽  
Volker Altstädt ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Novolac Resin ◽  
Nano Sio2 ◽  
Char Layer ◽  
Flame Retardant Properties ◽  
Modified Epoxy

In this study, the flame-retardant, thermal and mechanical properties of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and nano-SiO2 modified epoxy novolac resin is evaluated, and the combinational effects of both additives are verified. As a hardener, an isophorone diamine (IPDA) and polyetheramine blend is stoichiometrically added to obtain a low viscous epoxy resin system, suitable for resin injection and infusion techniques. The glass transition temperature (Tg) and the silica dispersion quality is affected by the DOPO modification and the nano silica particles. The flame-retardant (FR) and mechanical properties of the additives are investigated separately. The fracture toughness could be increased with the incorporation of both FR additives; however, the effect is deteriorated for higher DOPO amount which is referred to silica particle agglomeration and consequently reduced shear yielding mechanism. Flame-retardant properties, especially the peak heat release rate (pHRR) and the total heat release (THR) could be decreased from 1373.0 kW/m2 of neat novolac to 646.6 kW/m2 measured by resins with varying phosphorous and silica content. Thermogravimetric analysis (TGA) measurements show the formation of a high temperature stable char layer above 800 °C which is attributed to both additives. Scanning electron microscopy (SEM) images are taken to get deeper information of the flame-retardant mechanism, showing a dense and stable char layer for a certain DOPO silica mixture which restrains the combustible gases from the burning zone in the cone calorimeter test and influences the fire behavior of the epoxy resin.

scholarly journals Dual UV-Thermal Curing of Biobased Resorcinol Epoxy Resin-Diatomite Composites with Improved Acoustic Performance and Attractive Flame Retardancy Behavior

2021 ◽  
Vol 2 (1) ◽  
pp. 24-48
Author(s):  
Quoc-Bao Nguyen ◽  
Henri Vahabi ◽  
Agustín Rios de Anda ◽  
Davy-Louis Versace ◽  
Valérie Langlois ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardancy ◽  
Sound Absorption ◽  
Flexural Modulus ◽  
Construction Materials ◽  
Acoustic Properties ◽  
Low Frequencies ◽  
Compacting Pressure

This study has developed novel fully bio-based resorcinol epoxy resin–diatomite composites by a green two-stage process based on the living character of the cationic polymerization. This process comprises the photoinitiation and subsequently the thermal dark curing, enabling the obtaining of thick and non-transparent epoxy-diatomite composites without any solvent and amine-based hardeners. The effects of the diatomite content and the compacting pressure on microstructural, thermal, mechanical, acoustic properties, as well as the flame behavior of such composites have been thoroughly investigated. Towards the development of sound absorbing and flame-retardant construction materials, a compromise among mechanical, acoustic and flame-retardant properties was considered. Consequently, the composite obtained with 50 wt.% diatomite and 3.9 MPa compacting pressure is considered the optimal composite in the present work. Such composite exhibits the enhanced flexural modulus of 2.9 MPa, a satisfying sound absorption performance at low frequencies with Modified Sound Absorption Average (MSAA) of 0.08 (for a sample thickness of only 5 mm), and an outstanding flame retardancy behavior with the peak of heat release rate (pHRR) of 109 W/g and the total heat release of 5 kJ/g in the pyrolysis combustion flow calorimeter (PCFC) analysis.

scholarly journals Preparation and characterization of polydopamine/melamine microencapsulated red phosphorus and its flame retardance in epoxy resin

RSC Advances ◽  
2021 ◽  
Vol 11 (33) ◽  
pp. 20391-20402
Author(s):  
Chen Cheng ◽  
Yanling Lu ◽  
Weining Ma ◽  
Shaojie Li ◽  
Jun Yan ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Shell Structure ◽  
Composite Shell ◽  
Intumescent Flame Retardant ◽  
Smoke Suppression ◽  
Flame Retardance ◽  
Red Phosphorus ◽  
Composite Shell Structure

Red phosphorus was coated by a polydopamine/melamine composite shell structure, which constituted an intumescent flame retardant with superior flame retardance and smoke suppression performance for epoxy resin.

Smoke suppression and thermal conductivity of epoxy resin modified by Al 2 O 3 and hyperbranched flame retardant

2021 ◽  
pp. 51654
Author(s):  
Huawei Qiao ◽  
Xiuhuang Lin ◽  
Wei Zhong ◽  
Jiashui Lan ◽  
Huagui Zhang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Smoke Suppression

Ramie fiber reinforced composites with flame retardant structure design: flammability, smoke suppression, and mechanical properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Chenkai Zhu ◽  
Lei Nie ◽  
Xiaofei Yan ◽  
Jiawei Li ◽  
Dongming Qi
Keyword(s):  
Shear Strength ◽  
Iron Oxide ◽  
Heat Release ◽  
Flame Retardant ◽  
Interlaminar Shear Strength ◽  
Smoke Suppression ◽  
Strength Analysis ◽  
Ramie Fiber ◽  
Composite Surface ◽  
Interlaminar Shear

Abstract In this work, the structure of composite was designed as Core Stack and Surface Stack, which was treated with the expandable graphite (EG) and metal oxides such as iron oxide (IO), hydroxyapatite (HA), and aluminum tri-hydroxide (ATH). The mechanical performance of composites was characterized via flexural performance and interlaminar shear strength analysis. The flame retardance and smoke suppression of composite was explored in detail by LOI, UL-94, and cone calorimeter test. The findings presented that flexural properties of composites were observed to decrease due to delamination of surface stack, whilst no significant effect on interlaminar shear strength. In comparison with control composite, the loading of metal oxide into composite Surface Stack led to the reduction of peak heat release rate, total heat release, and fire growth index effectively. Moreover, the remarkable decrease in total smoke production could be observed due to the addition of iron oxide and the flame retardant mechanism was discussed. This study was the preliminary exploration of composite with flame retardant design which could be potential solution to improve flame retardancy and smoke suppression of composite with better mechanical structure preservation.

Improved flame retardant properties of epoxy resin by fluorinated MMT/MWCNT additives

2010 ◽  
Vol 89 (2) ◽  
pp. 225-232 ◽  
Author(s):  
Ji Sun Im ◽  
Sung Kyu Lee ◽  
Se Jin In ◽  
Young-Seak Lee
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardant Properties

scholarly journals Highly Efficient Composite Flame Retardants for Improving the Flame Retardancy, Thermal Stability, Smoke Suppression, and Mechanical Properties of EVA

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1251
Author(s):  
Yilin Liu ◽  
Bin Li ◽  
Miaojun Xu ◽  
Lili Wang
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Heat Release ◽  
Flame Retardant ◽  
Production Rate ◽  
Flame Retardancy ◽  
Flame Retardants ◽  
Mass Loss Rate ◽  
Smoke Suppression ◽  
Average Mass

Ethylene vinyl acetate (EVA) copolymer has been used extensively in many fields. However, EVA is flammable and releases CO gas during burning. In this work, a composite flame retardant with ammonium polyphosphate (APP), a charring–foaming agent (CFA), and a layered double hydroxide (LDH) containing rare-earth elements (REEs) was obtained and used to improve the flame retardancy, thermal stability, and smoke suppression for an EVA matrix. The thermal analysis showed that the maximum thermal degradation temperature of all composites increased by more than 37 °C compared with that of pure EVA. S-LaMgAl/APP/CFA/EVA, S-CeMgAl/APP/CFA/EVA, and S-NdMgAl/APP/CFA/EVA could achieve self-extinguishing behavior according to the UL-94 tests (V-0 rating). The peak heat release rate (pk-HRR) indicated that all LDHs containing REEs obviously reduced the fire strength in comparison with S-MgAl. In particular, pk-HRR of S-LaMgAl/APP/CFA/EVA, S-CeMgAl/APP/CFA/EVA and S-NdMgAl/APP/CFA/EVA were all decreased by more than 82% in comparison with pure EVA. Furthermore, the total heat release (THR), smoke production rate (SPR), and production rate of CO (COP) also decreased significantly. The average mass loss rate (AMLR) confirmed that the flame retardant exerted an effect in the condensed phase of the composites. Meanwhile, the combination of APP, CFA, and LDH containing REEs allowed the EVA matrix to maintain good mechanical properties.

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