scholarly journals Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 98 ◽  
Author(s):  
Yi Cui ◽  
Shuyi Gao ◽  
Ruiyun Zhang ◽  
Longdi Cheng ◽  
Jianyong Yu
Keyword(s):  
Moisture Content ◽  
Thermal Performance ◽  
Water Sorption ◽  
Moisture Absorption ◽  
Bound Water ◽  
Absorption Process ◽  
Heating Performance ◽  
Hygroscopic Behavior ◽  
Water Sorption Capacity ◽  
Main Factor

The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water–fiber/water–water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water–fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption.

EFFECT OF WET TROPICAL WEATHERING ON THE STRENGTH OF SANDSTONE

2015 ◽  
Vol 76 (2) ◽  
Author(s):  
Edy Tonnizam Mohamad ◽  
Maybelle Liang ◽  
Nurmunirah Mohd Akhair
Keyword(s):  
Moisture Content ◽  
Moisture Absorption ◽  
Initial Moisture Content ◽  
Point Load ◽  
Engineering Properties ◽  
Strength Index ◽  
Tropical Weathering ◽  
Load Tests ◽  
Grade Ii ◽  
Weathering Grades

 The influence of moisture content to the strength of wet tropically weathered sandstone of Jurong Formation found in Nusajaya, Johor was studied. The rock materials have been affected by weathering action; hence the alteration of its engineering properties is incontestable due to these effects. A total of 36 samples representing various weathering grades were collected from the field and tested at various moisture content by immersing them in water at different duration of time, ranging from 15, 30 and 60 minutes. Point load tests for the determination of the strength index Is(50) of the rock were then carried out. For weathered sandstone (Grade II to IV), the mean initial moisture content ranges from 0.15% to 11.00% respectively, while the initial mean strength index has maximum and minimum values of 7.76 MPa and 0.38 MPa. The results reveal that there is a significant relationship between the weathering grades, moisture absorption and strength. The moisture absorption is dependent on the amount of clay minerals present in the rock material, which indirectly affects the strength, as observed with the increment of weathering state. In conclusion, this study indicates that sandstone with higher moisture content and increase in weathering grade exhibits lower strength values. 

scholarly journals Operating parameters affecting the thermal performance of biomass boilers

TAPPI Journal ◽  
2017 ◽  
Vol 16 (08) ◽  
pp. 453-461
Author(s):  
Naz Orang ◽  
Honghi Tran ◽  
Andy Jones ◽  
F. Donald Jones
Keyword(s):  
Moisture Content ◽  
Thermal Performance ◽  
Excess Oxygen ◽  
Operating Parameters ◽  
Pulp Mills ◽  
Furnace Temperature ◽  
Bubbling Fluidized Bed ◽  
Oil Flow ◽  
Induced Draft Fan ◽  
Content Range

Operating data of a bubbling fluidized bed (BFB) boiler and three stoker grate (SG) biomass boilers from different pulp mills were analyzed over a 2-year period. The results show that in all cases, the thermal performance decreases markedly from 5.5 to 4 lb steam/lb dry biomass as the feedstock moisture content increases from 40% to 60%. The BFB boiler had better thermal performance, although it operated in a higher moisture content range compared with the SG boilers. Multivariate analysis was also performed on one of the SG boilers to determine operating parameters that affect thermal performance. The results show that furnace temperature, oil flow rate, and induced draft fan current positively correlate with thermal performance, while the feedstock moisture content, total air flow, and excess oxygen (O2) negatively correlate with thermal performance. This implies that when making modifications to improve thermal performance, it is important to take into account correlations among various parameters. In some cases, one positively correlated parameter might cause an increase in a negatively correlated parameter. The net effect might be a decrease in thermal performance.

scholarly journals Thermodynamic properties and moisture sorption isotherms of two pharmaceutical compounds

2018 ◽  
Author(s):  
Amel Zammouri ◽  
M. Ben Zid ◽  
N. Kechaou ◽  
N. Boudhrioua Mihoubi
Keyword(s):  
Experimental Data ◽  
Thermodynamic Properties ◽  
Moisture Content ◽  
Equilibrium Moisture Content ◽  
Water Sorption ◽  
Pharmaceutical Preparations ◽  
Sorption Isotherms ◽  
Integral Enthalpy ◽  
Isotherm Models ◽  
Water Sorption Isotherms

This investigation examines and compares the water sorption isotherms and the thermodynamic properties of two pharmaceutical preparations (Hypril and Azix) intended to be manufactured with the same process plant and equipment. The moisture equilibrium isotherms were determined at 50, 60 and 70 °C using a gravimetric technique. Five isotherm models were explored for their fitting to the experimental data. Azix showed sigmoid type II isotherms while Hypril showed type III isotherms according to the BET classification. All investigated models fitted well the water sorption isotherms of Hypril. By contrast, only GAB and Adam and Shove equations gave appropriate fit to the experimental data of Azix. For both formulations, the isosteric heat and the differential entropy decreased sharply with the increase of equilibrium moisture content to minimum values and thereafter remain constant. In the case of Azix, the integral enthalpy decreased with equilibrium moisture content while the integral entropy increased until reaching a constant value. Contrariwise, Hypril showed decreasing of the integral enthalpy and entropy with the equilibrium moisture content. Keywords: sorption isotherm, enthalpy, entropy, spreading pressure, pharmaceutical formulations  

Assessing Freeze-Thaw Damage in Segmental Retaining Walls Units by Mass Loss, Moisture Gain, and Relative Dynamic Modulus

2019 ◽  
Vol 2673 (11) ◽  
pp. 309-318
Author(s):  
Cesar T. Chan ◽  
Kenneth C. Hover
Keyword(s):  
Moisture Content ◽  
Mass Loss ◽  
Dynamic Modulus ◽  
Moisture Absorption ◽  
Surface Damage ◽  
Mass Gain ◽  
Retaining Walls ◽  
Freeze Thaw ◽  
Cast Concrete ◽  
The Relationship

Segmental retaining walls (SRWs) constructed of dry-cast concrete masonry units are used in transportation-related applications for which freeze-thaw (FT) durability is evaluated on the basis of percent mass-loss accumulated after multiple FT cycles as per ASTM C1262. This study compared mass loss, mass gain owing to absorption during (FT) exposure, and relative dynamic modulus (RDM) as per ASTM C215. Application of RDM required accounting for the influence of the shape and moisture content of SRW coupons on resonant frequency, with corrections that are likewise applicable to ASTM C666 for ordinary concrete. It was demonstrated that mass loss does not exclusively indicate surface damage, and the relationship between mass loss and RDM is unique to each specimen. Mass gain (as moisture absorption) during testing emerged as a key index of damage, with rapid escalation of mass loss and reduction in RDM at the number of FT cycles required to increase the moisture content of the residual coupon by about 1%.

Experimental Design of Surface Modification of Expanded Obsidian and Determination of Water Sorption Capacity

2014 ◽  
Vol 1020 ◽  
pp. 823-826
Author(s):  
G.Sh. Hovsepyan ◽  
M.A. Kalantaryan ◽  
T.V. Yedoyan
Keyword(s):  
Experimental Data ◽  
Surface Modification ◽  
Sorption Capacity ◽  
Water Sorption ◽  
Structural Changes ◽  
Ir Spectrometry ◽  
Water Capacity ◽  
Series Of Experiments ◽  
Water Sorption Capacity

The aim of this paper is to study the possibility of expanded obsidian and its modified product use for oil sorption, in that tetraethoxisilane (TEOS) has been used as a modifier. The optimal concentration of the modifier was determined by 50 per cent weight of expanded obsidian. The expanded obsidian was previously activated with 0,1 M solution of hydrochloric acid. IR spectrometry was used to characterise structural changes in the modified expanded obsidian samples. To determine water sorption capacity a series of experiments has been carried out. The analysis of obtained experimental data showed that after surface modification of expanded obsidian water capacity is reduced 3 times after the surface modification of EO.

scholarly journals Environmental Durability Enhancement of Natural Fibres Using Plastination: A Feasibility Investigation on Bamboo

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 474
Author(s):  
Daanvir K. Dhir ◽  
Armin Rashidi ◽  
Grant Bogyo ◽  
Ron Ryde ◽  
Sepideh Pakpour ◽  
...  
Keyword(s):  
Moisture Content ◽  
Moisture Absorption ◽  
Natural Fibers ◽  
Natural Fibre ◽  
Natural Fibres ◽  
Residual Moisture Content ◽  
Micro Computed Tomography ◽  
Residual Moisture ◽  
X Ray ◽  
Degradation Rates

Natural fibers are gaining wide attention due to their much lower carbon footprint and economic factors compared to synthetic fibers. The moisture affinity of these lignocellulosic fibres, however, is still one of the main challenges when using them, e.g., for outdoor applications, leading to fast degradation rates. Plastination is a technique originally used for the preservation of human and animal body organs for many years, by replacing the water and fat present in the tissues with a polymer. This article investigates the feasibility of adapting such plastination to bamboo natural fibres using the S-10 room-temperature technique in order to hinder their moisture absorption ability. The effect of plastination on the mechanical properties and residual moisture content of the bamboo natural fibre samples was evaluated. Energy dispersive x-ray spectroscopy (EDS) and X-ray micro-computed tomography (Micro-CT) were employed to characterize the chemical composition and 3-dimensional morphology of the plastinated specimens. The results clearly show that, as plastination lessens the hydrophilic tendency of the bamboo fibres, it also decreases the residual moisture content and increases the tensile strength and stiffness of the fibers.

Effect of blank pre-conditioning humidity on the dimensional accuracy and rigidity of paperboard trays

2018 ◽  
Vol 33 (2) ◽  
pp. 348-357
Author(s):  
Sami-Seppo Ovaska ◽  
Panu Tanninen ◽  
Esa Saukkonen ◽  
Kaj Backfolk
Keyword(s):  
Moisture Content ◽  
Dimensional Accuracy ◽  
Storage Conditions ◽  
Fiber Network ◽  
Bursting Strength ◽  
Press Forming ◽  
Layer Structures ◽  
A Minor ◽  
Moisture Conditions ◽  
Hygroscopic Behavior

Abstract Optimization of storage conditions is essential for successful converting of paperboard. This paper investigates the effect of blank moisture content on the dimensional accuracy and rigidity of press-formed paperboard trays. The trays were manufactured from uncoated, pigment-coated and extrusion-coated paperboards and multi-layer materials using fixed process parameters. Because of the different layer structures and coatings, the paperboards showed different hygroscopic behavior. Prior to converting trials, the bursting strength of paperboards under different moisture conditions was assessed. It was found that the moisture content has only a minor influence on bursting strength, but moisture affects blank curling tendency and dimensional accuracy of the tray. A high blank moisture content led to a loss of the dimensional stability and load-bearing capacity of trays, although based on earlier knowledge it is evident that the moisture content should be high for successful press-forming. As expected, a low blank moisture content increased the prevalence of ruptures in forming but the resulting trays were stiffer and their dimensional accuracy was better. It was suggested that the increased stiffness is related to a more efficient moisture removal during the press-forming, so that the fiber network is more effectively consolidated due to e. g. the formation of hydrogen bonds.

scholarly journals Moisture Absorption Effects on Mode II Delamination of Carbon/Epoxy Composites

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2162
Author(s):  
King Jye Wong ◽  
Mahzan Johar ◽  
Seyed Saeid Rahimian Koloor ◽  
Michal Petrů ◽  
Mohd Nasir Tamin
Keyword(s):  
Fracture Toughness ◽  
Moisture Content ◽  
Composite Structures ◽  
Moisture Absorption ◽  
Peak Load ◽  
Epoxy Composites ◽  
Mode Ii ◽  
Damage Initiation ◽  
Residual Properties ◽  
Mode Ii Fracture Toughness

It is necessary to consider the influence of moisture damage on the interlaminar fracture toughness for composite structures that are used for outdoor applications. However, the studies on the progressive variation of the fracture toughness as a function of moisture content M (%) is rather limited. In this regard, this study focuses on the characterization of mode II delamination of carbon/epoxy composites conditioned at 70 °C/85% relative humidity (RH). End-notched flexure test is conducted for specimens aged at various moisture absorption levels. Experimental results reveal that mode II fracture toughness degrades with the moisture content, with a maximum of 23% decrement. A residual property model is used to predict the variation of the fracture toughness with the moisture content. Through numerical simulations, it is found that the approaches used to estimate the lamina and cohesive properties are suitable to obtain reliable simulation results. In addition, the damage initiation is noticed during the early loading stage; however, the complete damage is only observed when the numerical peak load is achieved. Results from the present research could serve as guidelines to predict the residual properties and simulate the mode II delamination behavior under moisture attack.

Sign in / Sign up

Export Citation Format

Share Document