scholarly journals Synthesis and Photoinduced Anisotropy of Polymers Containing Nunchaku-Like Unit with an Azobenzene and a Mesogen

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 600 ◽  
Author(s):  
Lingling Wang ◽  
Yingchuan Zhang ◽  
Chenhao Zhan ◽  
Yong You ◽  
Hongxing Zhang ◽  
...  
Keyword(s):  
Optical Materials ◽  
Raft Polymerization ◽  
Polarized Light ◽  
Gel Permeation Chromatography ◽  
Photoinduced Anisotropy ◽  
Photoinduced Birefringence ◽  
Linearly Polarized ◽  
Azo Chromophore ◽  
Photoinduced Isomerization

A series of polymers containing nunchaku-like unit with an azo chromophore and a mesogen group was successfully prepared and photoinduced anisotropy of the obtained polymers was minutely investigated. Firstly, monomers containing nunchaku-like unit with an azo chromophore and a mesogen group linked by flexible group were synthesized. The structure of the monomers was confirmed via NMR COSY spectra. Subsequently, the obtained monomers were polymerized into corresponding polymers through RAFT polymerization. The prepared polymer samples were characterized through NMR, FTIR, gel permeation chromatography (GPC), and UV-vis testing while the thermal properties of the samples were investigated through differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA) measurements. The photoinduced isomerization of the polymers, which was researched in situ via measuring UV-vis spectra of the polymer solutions and spin-coated films under irradiation with 450 nm light or putting in darkness, demonstrated the rapid trans-cis-trans isomerization of the polymers. When irradiated with a linearly polarized light, significant photoinduced birefringence and dichroism were observed, suggesting photoinduced isomerization of azobenzene can drive orientation of mesogen in the system. This study blazes a way to design the optical materials with light-controllable birefringence and dichroism.

TEMPERATURE DEPENDENCE OF PHOTOINDUCED ANISOTROPY IN THE PHOTOCONDUCTIVITY OF As2Se3 AND Sb2S3 THIN FILMS

2008 ◽  
Vol 22 (20) ◽  
pp. 1951-1957
Author(s):  
K. ATAK ◽  
G. AKTAŞ ◽  
Y. SKARLATOS ◽  
M. N. INCI
Keyword(s):  
Thin Films ◽  
Temperature Dependence ◽  
Polarized Light ◽  
Photoinduced Anisotropy ◽  
Linearly Polarized ◽  
Increasing Temperature

The temperature dependence of photoinduced anisotropy in the photoconductivity of As 2 Se 3 and Sb 2 S 3 thin films was investigated, in the interval between -50 and 70°C. Our results demonstrate that for both As 2 Se 3 and Sb 2 S 3 thin films, the anisotropy percentage falls with increasing temperature. We surmise that the aligning effect of the linearly polarized light was diluted with increasing temperature, because the latter induces similar mechanisms to those induced by polarized light, but in an isotropic fashion.

scholarly journals Metasurface of Combined Semicircular Rings with Orthogonal Slit Pairs for Generation of Dual Vector Beams

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1718
Author(s):  
Qian Kong ◽  
Manna Gu ◽  
Xiangyu Zeng ◽  
Rui Sun ◽  
Yuqin Zhang ◽  
...  
Keyword(s):  
Time Domain ◽  
Finite Difference Time Domain ◽  
Polarized Light ◽  
Orientation Angle ◽  
Fdtd Simulation ◽  
Dual Vector ◽  
Vector Beams ◽  
Linearly Polarized ◽  
Potential Applications ◽  
Difference Time

Manipulation of multichannel vector beams (VBs) with metasurfaces is an important topic and holds potential applications in information technology. In this paper, we propose a novel metasurface for the generation of dual VBs, which is composed of orthogonal slit pairs arranged on multiple groups of combined semicircular rings (CSRs). A group of CSRs include a right-shifted set and a left-shifted set of semicircular rings, and each set of semicircular rings has two halves of circles with different radii, sharing the same shifted center. Under the illumination of linearly polarized light, the two shifted sets of semicircular rings generate the two VBs at the shifted center positions on the observation plane. The slit units of each set are designed with independent rotation order and initial orientation angle. By adjusting the linear polarization of illumination, both two VBs with their orders and polarization states are independently controlled simultaneously. The principle and design are demonstrated by the finite-difference time domain (FDTD) simulation. The work is of significance for miniatured devices of VB generators and for related applications.

scholarly journals Formation of half-period surface relief gratings in azobenzene containing polymer films

2020 ◽  
Vol 126 (9) ◽  
Author(s):  
Joachim Jelken ◽  
Carsten Henkel ◽  
Svetlana Santer
Keyword(s):  
Polymer Film ◽  
Polymer Films ◽  
Surface Relief ◽  
Incident Light ◽  
Glassy State ◽  
Polarized Light ◽  
Half Period ◽  
Polarization Distribution ◽  
Linearly Polarized ◽  
Set Up

Abstract We study the peculiar response of photo-sensitive polymer films irradiated with a certain type of interference pattern where one interfering beam is S-polarized, while the second one is P-polarized. The polymer film, although in a glassy state, deforms following the local polarization distribution of the incident light, and a surface relief grating (SRG) appears whose period is half the optical one. All other types of interference patterns result in the matching of both periods. The topographical response is triggered by the alignment of photo-responsive azobenzene containing polymer side chains orthogonal to the local electrical field, resulting in a bulk birefringence grating (BBG). We investigate the process of dual grating formation (SRG and BBG) in a polymer film utilizing a dedicated set-up that combines probe beam diffraction and atomic force microscopy (AFM) measurements, and permits acquiring in situ and in real-time information about changes in local topography and birefringence. We find that the SRG maxima appear at the positions of linearly polarized light (tilted by 45° relative to the grating vector), causing the formation of the half-period topography. This permits to inscribe symmetric and asymmetric topography gratings with sub-wavelength period, while changing only slightly the polarization of one of the interfering beams. We demonstrate an easy generation of sawtooth profiles (blazed gratings) with adjustable shape. With these results, we have taken a significant step in understanding the photo-induced deformation of azo-polymer films.

In Situ Magnetic-Circular-X-Ray-Dichroism Measurements: An Epitaxial Fe Wedge on Cu(100)

MRS Bulletin ◽  
1999 ◽  
Vol 24 (1) ◽  
pp. 41-45 ◽  
Author(s):  
M.E. Dávila ◽  
D. Arvanitis ◽  
J. Hunter Dunn ◽  
N. Mårtensson ◽  
P. Srivastava ◽  
...  
Keyword(s):  
Ultrathin Films ◽  
Magnetic Circular Dichroism ◽  
Polarized Light ◽  
Measured Quantity ◽  
Easy Magnetization ◽  
Magnetization Direction ◽  
Core Electron ◽  
Circularly Polarized ◽  
X Ray

Circularly polarized x-ray radiation is attracting increasing interest as a tool for the characterization of the electronic, magnetic, and chiral properties of low-dimensional structures. Using circular light (with electric field vector parallel to the orbital plane), a dependence of the measured quantity by changing either the orientation of the light polarization or the magnetization is indicative of the existence of magnetic circular dichroism. It can be observed in x-ray absorption spectroscopy (XAS), in which the photon energy is scanned through an absorption threshold exciting a core electron into an unoccupied valence state using circularly polarized light. Synchrotron radiation sources have made this technique possible. It can also be observed in photo-emission spectroscopy from core and valence levels. Here we focus on magnetic circular x-ray dichroism (MCXD) in XAS as an element-specific tool to investigate magnetic properties of ultrathin films in situ. The application of magneto-optical sum rules enables the determination of the orbital and spin magnetic moments per atom from XAS spectra, as well as the easy magnetization direction.MCXD-based magnetometry in XAS is extensively used by measuring the L absorption edges of 3d-transition metals, where large intensity changes (up to 60%) of the L-edge white lines are observed upon reversal of either the sample magnetization or the light helicity. The high magnetic contrast obtained, combined with the elemental specificity of the technique, allows for the study of very dilute samples such as ultrathin films. We first concentrate on the selection rules governing MCXD in XAS.

Study of orientational order of some nematogenic compounds by spectroscopy methods using linearly polarized light

2005 ◽  
Vol 744-747 ◽  
pp. 307-313 ◽  
Author(s):  
D. Bauman ◽  
E. Chrzumnicka ◽  
E. Mykowska ◽  
M. Szybowicz ◽  
N. Grzelczak
Keyword(s):  
Orientational Order ◽  
Polarized Light ◽  
Linearly Polarized

Preparation of nano-TiO2/polyurethane emulsions via in situ RAFT polymerization

2010 ◽  
Vol 69 (4) ◽  
pp. 534-538 ◽  
Author(s):  
Xiang-Chen Che ◽  
Yu-Zi Jin ◽  
Youn-Sik Lee
Keyword(s):  
Raft Polymerization ◽  
Nano Tio2

scholarly journals Constraints on Lorentz Invariance Violation with Multiwavelength Polarized Astrophysical Sources

Galaxies ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 44
Author(s):  
Qi-Qi Zhou ◽  
Shuang-Xi Yi ◽  
Jun-Jie Wei ◽  
Xue-Feng Wu
Keyword(s):  
Gamma Ray ◽  
Lorentz Invariance ◽  
Polarized Light ◽  
Polarization Plane ◽  
Polarization Angle ◽  
Intrinsic Polarization ◽  
Frequency Dependent ◽  
Invariance Violation ◽  
Linearly Polarized ◽  
Order Of Magnitude

Possible violations of Lorentz invariance (LIV) can produce vacuum birefringence, which results in a frequency-dependent rotation of the polarization plane of linearly polarized light from distant sources. In this paper, we try to search for a frequency-dependent change of the linear polarization angle arising from vacuum birefringence in the spectropolarimetric data of astrophysical sources. We collect five blazars with multiwavelength polarization measurements in different optical bands (UBVRI). Taking into account the observed polarization angle contributions from both the intrinsic polarization angle and the rotation angle induced by LIV, and assuming that the intrinsic polarization angle is an unknown constant, we obtain new constraints on LIV by directly fitting the multiwavelength polarimetric data of the five blazars. Here, we show that the birefringence parameter η quantifying the broken degree of Lorentz invariance is limited to be in the range of −9.63×10−8<η<6.55×10−6 at the 2σ confidence level, which is as good as or represents one order of magnitude improvement over the results previously obtained from ultraviolet/optical polarization observations. Much stronger limits can be obtained by future multiwavelength observations in the gamma-ray energy band.

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