scholarly journals Reinforcing Linear Low-Density Polyethylene with Surfactant-Treated Microfibrillated Cellulose

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 441 ◽  
Author(s):  
Guangzhao Wang ◽  
Xiaohui Yang ◽  
Weihong Wang
Keyword(s):  
Mechanical Properties ◽  
Composite Film ◽  
Mechanical Test ◽  
Intermolecular Hydrogen Bond ◽  
Microfibrillated Cellulose ◽  
Light Transmittance ◽  
Test Results ◽  
X Ray Diffraction ◽  
Twin Screw ◽  
Ldpe Composites

Due to its excellent mechanical properties and reinforcement abilities, cellulose has become a promising candidate for developing nanocomposites. However, cellulose agglomeration is an issue that must be solved. In this study, we treated microfibrillated cellulose (MFC) with a mixture of the non-ionic surfactants Span80 and Tween80 (ratio of 1:1) in order to prevent the intermolecular hydrogen bond aggregation of MFC during the process of MFC drying. We used a conical twin-screw extruder to melt compounds for the surfactant-treated MFC and powdered LLDPE. Furthermore, the extruded mixture was hot-pressed into a film, and we also tested the properties of the composite film. We can conclude that there was no agglomeration in the composite film according to microscopic observations and light transmittance test results. Furthermore, the dispersion of the surfactant-treated MFC (STMFC) was uniform until the STMFC filler increased to 10 wt%. The mechanical test results show that when the content of STMFC filler was 10 wt%, the mechanical properties of the composite were optimal. Compared to LLDPE, the STMFC/LLDPE composite film had an increase of 41.03% in tensile strength and an increase of 106.35% in Young’s modulus. Under this system, the DSC results show that the melting point of LLDPE increased from 125 to 131 °C. X-ray diffraction (XRD) results showed that the addition of STMFC did not change the crystallinity of the STMFC/LDPE composites, although the crystallite size increased.

scholarly journals Investigation of structural and mechanical properties of BioCaCO3-LDPE composites

2019 ◽  
Vol 1 (2) ◽  
pp. 29-43 ◽  
Author(s):  
Serife Yalcın ◽  
Daniel Chateigner ◽  
Loïc Le Pluart ◽  
Stéphanie Gascoin ◽  
Sophie Eve
Keyword(s):  
Mechanical Properties ◽  
Quantitative Phase Analysis ◽  
X Ray Diffraction ◽  
Crepidula Fornicata ◽  
Dog Bone ◽  
The Matrix ◽  
Twin Screw ◽  
Injection Molded ◽  
Ldpe Composites ◽  
Acid Coating

The three different Mollusk shells, Pecten maximus, Crepidula fornicata and Crassostrea gigas, were studied and compared with synthetic and commercial powders. All samples were analysed by X-ray diffraction, Quantitative phase analysis, and quantitative line broadening (microstructure) analysis using the Combined Analysis method. LDPE-CaCO3 composites were prepared in a twin screw extruder in the composition range of 0–10.8 filler content. Ultimate Mechanical properties of dog-bone type injection molded tensile specimens (ISO-527-2-5A) were measured. Results are showing that the biogenic calcium carbonate is less efficient in improving polyethylene stiffness than the synthetic ones, independently of its crystalline form, to use stearic acid coating allows an improvement of the matrix stiffening. The yield strength is unchanged whatever the kind of filler used.

Transient liquid phase bonding of Cu and Al using metallic particles interlayers

2021 ◽  
pp. 095440542098823
Author(s):  
Alireza Zaheri ◽  
Mohammadreza Farahani ◽  
Alireza Sadeghi ◽  
Naser Souri
Keyword(s):  
Liquid Phase ◽  
Mechanical Test ◽  
Transient Liquid Phase ◽  
Transient Liquid Phase Bonding ◽  
Joint Interface ◽  
Test Results ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metallic Particles ◽  
Powder Interlayer

The bonding strength, and microstructures of Cu and Al couples using metallic powders as interlayer during transient liquid phase bonding (TLP bonding) were investigated. The interfacial morphologies and microstructures were studied by scanning electron microscopy equipped with energy dispersive X-ray spectroscopy, and X-ray diffraction. First, to explore the optimum bonding time and temperature, nine samples were bonded without interlayers in a vacuum condition. Mechanical test results indicated that bonding at 560°C in 20 min returns the highest bond strength (84% of Al). This bonding condition was used to join ten samples with powder interlayers. Powders were prepared by mixing different combinations of Cu, Al (+Fe nanoparticles) and Zn. In the bonding zone, different Cu9Al4, CuAl, and CuAl2 intermetallic co-precipitate. The strongest bonding is formed in the sample with the 70Al (+Fe)-30Cu powder interlayer. Powder interlayers present thinner and more uniform intermetallic layers at the joint interface.

scholarly journals Ecofriendly Preparation and Characterization of a Cassava Starch/Polybutylene Adipate Terephthalate Film

Processes ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 329
Author(s):  
Tan Yi ◽  
Minghui Qi ◽  
Qi Mo ◽  
Lijie Huang ◽  
Hanyu Zhao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Contact Angle ◽  
Water Vapor ◽  
Composite Film ◽  
Water Absorption ◽  
Composite Films ◽  
Thermoplastic Starch ◽  
Light Transmittance ◽  
Infrared Spectrometry ◽  
Nano Zno

Composite films of polybutylene adipate terephthalate (PBAT) were prepared by adding thermoplastic starch (TPS) (TPS/PBAT) and nano-zinc oxide (nano-ZnO) (TPS/PBAT/nano-ZnO). The changes of surface morphology, thermal properties, crystal types and functional groups of starch during plasticization were analyzed by scanning electron microscopy, synchronous thermal analysis, X-ray diffraction, infrared spectrometry, mechanical property tests, and contact Angle and transmittance tests. The relationship between the addition of TPS and the tensile strength, transmittance, contact angle, water absorption, and water vapor barrier of the composite film, and the influence of nano-ZnO on the mechanical properties and contact angle of the 10% TPS/PBAT composite film. Experimental results show that, after plasticizing, the crystalline form of starch changed from A-type to V-type, the functional group changed and the lipophilicity increased; the increase of TPS content, the light transmittance and mechanical properties of the composite membrane decreased, while the water vapor transmittance and water absorption increased. The mechanical properties of the composite can be significantly improved by adding nano-ZnO at a lower concentration (optimum content is 1 wt%).

scholarly journals Natural Mordenite from Spain as Pozzolana

Molecules ◽  
2020 ◽  
Vol 25 (5) ◽  
pp. 1220
Author(s):  
Leticia Presa ◽  
Jorge L. Costafreda ◽  
Domingo A. Martín ◽  
Isabel Díaz
Keyword(s):  
Mechanical Test ◽  
Low Cost ◽  
Principal Component ◽  
Test Results ◽  
Mechanical Compression ◽  
San Jose ◽  
X Ray Diffraction ◽  
Pozzolanic Cement ◽  
Natural Clinoptilolite ◽  
Potential Use

This work deals with anomalous concentrations of natural mordenite in the southeast of Spain. The X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies evidenced that the samples contain mainly monomineral zeolitic phase of mordenite (70% to 74%), usually accompanied by smectite (montmorillonite), the principal component of bentonite. A study of the applicability of these zeolites is presented to establish the potential use as pozzolanic cements. For comparative purposes, synthetic commercial mordenite is also characterized and tested. The initial mixtures were prepared using cement and mordenite at a 75:25 ratio. Chemical analysis and a pozzolanicity test showed the high pozzolanic character. These mixtures were further added to sand and water, yielding the cement specimens to be used as concrete. Mechanical test results showed that the mechanical compression at 7 and 28 days fall into the range of 19.23 to 43.05 MegaPascals (MPa) for the cement specimens built with natural mordenites. The obtained results fall in the same range of cement specimens prepared with natural clinoptilolite, using mixtures within the European requirement for commercial concretes. Thus, these results and the low cost of natural mordenite of San José de los Escullos deposit supports the potential use of natural mordenite as pozzolanic cement.

scholarly journals Structure and mechanical properties of GR/UHMWPE nanocomposite ropes

2019 ◽  
Vol 131 ◽  
pp. 01127
Author(s):  
Wen Wen Yu ◽  
Jian Gao Shi ◽  
Yong Li Liu ◽  
Lei Wang
Keyword(s):  
Mechanical Properties ◽  
Melt Spinning ◽  
Mechanical Test ◽  
Reactive Extrusion ◽  
Breaking Load ◽  
Hot Water ◽  
Test Results ◽  
Screw Extruder ◽  
Elongation At Break ◽  
Ultra High Molecular Weight

Ultra-high molecular weight polyethylene (UHMWPE) and graphene (GR) was melt compounded by reactive extrusion. Nanocomposite monofilaments were prepared by melt spinning through a co-rotating screw extruder and drawing at hot water. GR/UHMWPE nanocomposite ropes were twisted using nanocomposite monofilaments. A structure and mechanical properties of the GR/UHMWPE nanocomposite monofilaments and its ropes had been characterized by scanning electron microscopy (SEM), and mechanical test. Results showed that the monofilaments surface of monofilaments became rougher with introducing of GR nanosheets, which could be related to stacking of GR. The breaking load of GR/UHMWPE nanocomposite ropes was remarkably improved upon nanofiller addition, with the decrease of the elongation at break.

scholarly journals Mechanical Performance of Unstitched and Silk Fiber-Stitched Woven Kenaf Fiber-Reinforced Epoxy Composites

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4801
Author(s):  
Yasir Khaleel Kirmasha ◽  
Mohaiman J. Sharba ◽  
Zulkiflle Leman ◽  
Mohamed Thariq Hameed Sultan
Keyword(s):  
Mechanical Properties ◽  
Flexural Strength ◽  
Mechanical Performance ◽  
Mechanical Test ◽  
Natural Fibers ◽  
Silk Fiber ◽  
Epoxy Composites ◽  
Test Results ◽  
The Impact ◽  
Woven Kenaf

Fiber composites are known to have poor through-thickness mechanical properties due to the absence of a Z-direction binder. This issue is more critical with the use of natural fibers due to their low strength compared to synthetic fibers. Stitching is a through-thickness toughening method that is used to introduce fibers in the Z-direction, which will result in better through-thickness mechanical properties. This research was carried out to determine the mechanical properties of unstitched and silk fiber-stitched woven kenaf-reinforced epoxy composites. The woven kenaf mat was stitched with silk fiber using a commercial sewing machine. The specimens were fabricated using a hand lay-up method. Three specimens were fabricated, one unstitched and two silk-stitched with deferent stitching orientations. The results show that the stitched specimens have comparable in-plane mechanical properties to the unstitched specimens. For the tensile mechanical test, stitched specimens show similar and 17.1% higher tensile strength compared to the unstitched specimens. The flexural mechanical test results show around a 9% decrease in the flexural strength for the stitched specimens. On the other hand, the Izod impact mechanical test results show a significant improvement of 33% for the stitched specimens, which means that stitching has successfully improved the out-of-plane mechanical properties. The outcome of this research indicates that the stitched specimens have better mechanical performance compared to the unstitched specimens and that the decrease in the flexural strength is insignificant in contrast with the remarkable enhancement in the impact strength.

Mechanical Properties of Epoxy Clay Nanocomposites

2010 ◽  
Vol 123-125 ◽  
pp. 145-148 ◽  
Author(s):  
Sahar Ghafarloo ◽  
Mehrdad Kokabi
Keyword(s):  
Mechanical Properties ◽  
Diglycidyl Ether ◽  
Good Evidence ◽  
Layered Silicates ◽  
Clay Nanocomposites ◽  
Curing Agent ◽  
Test Results ◽  
X Ray Diffraction ◽  
Cloisite 30B ◽  
Diffraction Patterns

Achievement of exfoliated structure of polymer/ Clay nanocomposites is of particular interest for the improvement of mechanical properties. In this work, the morphology and mechanical properties of epoxy/ clay nanocomposites has been investigated. Diglycidyl ether of bis-phenol A (DGEBA) epoxy resin (EPON828) and Jeffamine D400 curing agent was used. To obtain perfect dispersion, nanoclay (Cloisite 30B) was sonicated in acetone. The mixture was then mixed with polymer. Afterwards, the curing process was performed by addition of curing agent and degassing. Disappearing of peaks in X-Ray diffraction patterns of nanocomposites containing less than 5wt% nanoclay, is a good evidence of perfect dispersion of layered silicates in matrix, i.e. formation of exfoliated morphology. Based on tensile test results, it is deduced that as the amount of nanoclay increases, the elastic modulus and elongation at break of the nanocomposites containing 1wt% and 5wt% nanoclay increases by 12% and 31%, respectively. Therefore, obtaining perfect dispersion of layered silicates in epoxy matrix and exfoliated morphology, results in better mechanical properties of the nanocomposites.

Cellulolytic Enzyme Lignin Efficiently Blended with Polycaprolactone: Thermal, Mechanical Properties and Morphological Evaluation

2014 ◽  
Vol 1070-1072 ◽  
pp. 100-106
Author(s):  
Wen Zhu Ouyang ◽  
Yong Huang
Keyword(s):  
Mechanical Properties ◽  
Mechanical Test ◽  
Cellulolytic Enzyme ◽  
Twin Screw Extrusion ◽  
Morphological Evaluation ◽  
Screw Extrusion ◽  
Thermal Mechanical Properties ◽  
Twin Screw ◽  
The Cost ◽  
The Impact

In this study, cellulolytic enzyme lignin (CEL) was blended with polycaprolactone (PCL) by twin-screw extrusion and injection molding. The thermal, mechanical properties and the morphology of the PCL/CEL blends were investigated as a function of CEL content. The results showed that the CEL in the blends acting as nucleus accelerated the crystallization of PCL when CEL was not more than 10 wt%, but retarded PCL to crystallize with more CEL addition. Thermogravimetry analysis (TGA) revealed that the thermal stability of the PCL/CEL blends was almost unaffected by increasing CEL content. Mechanical test showed that, although the elongation at break and the impact strength were decreased, the strength and the modulus of the PCL/CEL blends were significantly higher than those of the neat PCL. Scanning electron microscopy (SEM) observations indicated that the CEL and the PCL were in good miscibility and there was a good adhesion at the interface of the CEL filler and the PCL matrix, suggesting that CEL could be potential filler used in PCL-based materials to reduce the cost of the friendly material, whereas increased its strength and modulus.

Mechanical Properties and Process of ZnO Deposited Various Substrates

2005 ◽  
Vol 297-300 ◽  
pp. 533-538
Author(s):  
Hun Chae Jung ◽  
Han Ki Yoon ◽  
Yun Sik Yu
Keyword(s):  
Mechanical Properties ◽  
Elastic Modulus ◽  
Substrate Temperature ◽  
Mechanical Test ◽  
X Ray Diffraction ◽  
Electroluminescence Device ◽  
Type Semiconductor ◽  
Different Temperatures ◽  
Optimized Conditions ◽  
Substrate Hardness

ZnO is an n-type semiconductor having a hexagonal wurzite structure. ZnO exhibits good piezoelectric, photoelectric and optical properties and might be a good candidate for an electroluminescence device like an UV laser diode. But the important problems, such as substrate kinds and substrate temperature are raised its head, so they need to optimize deposit condition. Because these devices are very small and films are very thin, those are often prepared in limited quantities and shapes unsuitable for the extensive mechanical test. In this present work, ZnO thin films are prepared on the glass, GaAs (100), Si (111) and Si (100) substrates at different temperatures by the pulsed laser deposition (PLD) method. ZnO was evaluated in term of crystalline through X-ray diffraction (XRD), mechanical properties such as hardness, elastic modulus through nano-indenter. XRD measurements indicate that the substrate temperature of 200-500, 200-500, 300-500, and 300-500oC was the optimized conditions of crystalline for the glass, GaAs (100), Si (111), and Si (100) substrates, respectively. In spite of the films deposited on the different substrates, the films always show (002) orientation at the optimized conditions. Mechanical properties such as hardness and elastic modulus are influenced substrate crystallization. In case of Si (111) substrate, hardness and elastic modulus are about 10, 150GPa, respectively.

Characterization and determination of thermal and radioluminescence properties of low-density polyethylene (LDPE)-(nanozeolite + Y2O3) composite

2019 ◽  
Vol 28 (2) ◽  
pp. 112-118
Author(s):  
Murat Çanlı ◽  
İlker Çetin Keskin ◽  
Murat Türemiş ◽  
Kamil Sirin ◽  
Mehmet İsmail Katı
Keyword(s):  
Low Density Polyethylene ◽  
Low Density ◽  
X Ray Diffraction ◽  
Twin Screw ◽  
Nanocomposite Fibers ◽  
To Come ◽  
Ldpe Composites ◽  
Dispersing Medium ◽  
Extrusion Method

Nanotechnology has become one of the most popular areas of interdisciplinary research. In the vast majority of nanotechnology applications, polymer-based matrices were used as the dispersing medium of nanoparticles. The combination of polymer–zeolite nanocomposite has the potential to come out with the advantages of polymers and zeolites while coping with the deficiencies of both materials. In this study, the synthesis and properties of low-density polyethylene (LDPE) composites with nanozeolite + Y2O3 are investigated. Polyethylene nanocomposite fibers containing nanozeolite + Y2O3 at 5% by mass using a melt extrusion method were composed in a laboratory type twin screw extruder. The thermal properties of the composite fibers were determined by analysis of both thermal gravimetric and differential thermal spectra. Their structural properties were enlightened by scanning electron microscopy, Fourier transform infrared, and ultraviolet absorption. According to the results of X-ray diffraction tests, the samples contain crystals in semicrystalline and α form. The mechanical properties of LDPE matrices increased with the addition of nanoparticles. In addition, radioluminescence properties of the polymer were also improved after composing with nanozeolite and Y2O3.

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