scholarly journals Effect of the Botanical Origin on Properties of RS3/4 Type Resistant Starch

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 81 ◽  
Author(s):  
Tomasz Zięba ◽  
Małgorzata Kapelko-Żeberska ◽  
Artur Gryszkin ◽  
Aleksandra Wilczak ◽  
Bartosz Raszewski ◽  
...  
Keyword(s):  
Resistant Starch ◽  
Raw Materials ◽  
Amylose Content ◽  
Potato Starch ◽  
Wheat Starch ◽  
Botanical Origin ◽  
Amylolytic Enzymes ◽  
Solubility In Water ◽  
Retrograded Starch ◽  
Water Swelling

This study aimed to compare properties of retrograded starch acetates with an identical degree of substitution, but produced from raw materials of various botanical origin. Retrograded starch was produced from potato, wheat, corn, and tapioca starch, and afterwards acetylated with an acetic acid anhydride, adjusting reagent doses to achieve an identical degree of esterification of the modified preparation (2.1 g/100 g). Preparations of retrograded starch and acetylated retrograded starch differed significantly in their properties, which was due to the disparate botanical origin of starch. The highest susceptibility to acetylation was demonstrated for potato starch, and the lowest one for wheat starch. Acetylation of retrograded starch of various botanical origin increased its solubility in water, swelling power and viscosity of its pastes, as well as decreased its amylose content. Preparations of acetylated retrograded starches of disparate botanical origins may be deemed preparations of RS3/4 type resistant starch because they exhibit significant (23.5–34.0%) resistance to the activity of amylolytic enzymes.

Digestion and physiological properties of resistant starch in the human large bowel

1996 ◽  
Vol 75 (5) ◽  
pp. 733-747 ◽  
Author(s):  
John H Cummings ◽  
Emily R Beatty ◽  
Susan M Kingman ◽  
Sheila A Bingham ◽  
Hans N Englyst
Keyword(s):  
Resistant Starch ◽  
Short Chain Fatty Acid ◽  
Chain Fatty Acid ◽  
Wheat Starch ◽  
Starch Granules ◽  
Human Gut ◽  
Physiological Properties ◽  
Retrograded Starch ◽  
Wet Weight ◽  
Stimulation Of

The digestion of four sources of resistant starch (RS) has been studied in twelve healthy volunteers who ate controlled diets for 15 d periods. RS from potato, banana, wheat and maize (17−30 g/d) was compared with a starch-free diet, a diet containing wheat starch that was fully digested in the small intestine, and with 18·4 g NSP from bran/d. RS increased stool wet weight by 1·6 g/d per g RS fed for potato, 1·7 for banana, 2·5 for wheat and 2·7 for maize, but this was significantly less than bran NSP at 4·9 g/g. RS was extensively digested in twenty-seven of thirtyfour diet periods but five subjects were unable to break down one or two of the RS sources. Faecal N and energy excretion were increased. RS decreased NSP breakdown and RS2(resistant starch granules) tended to prolong transit time. All forms of RS increased faecal total short-chain fatty acid excretion. RS2(from potato and banana) gave greater proportions of acetate in faeces, and RS3(retrograded starch from wheat and maize) more propionate. We have concluded that RS2and RS3are broken down in the human gut, probably in the colon although in 26% of cases this breakdown was impaired. RS exerts mild laxative properties, predominantly through stimulation of biomass excretion but also through some sparing of NSP breakdown.

scholarly journals The Effect of Germinated Sorghum Extract on the Pasting Properties and Swelling Power of Different Annealed Starches

Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1602
Author(s):  
Hesham Alqah ◽  
M. S. Alamri ◽  
A. A. Mohamed ◽  
S. Hussain ◽  
A. A. Qasem ◽  
...  
Keyword(s):  
Sweet Potato ◽  
Amylose Content ◽  
Potato Starch ◽  
Amorphous Region ◽  
Enzymatic Digestion ◽  
Pasting Properties ◽  
Wheat Starch ◽  
Predictive Tool ◽  
Swelling Power ◽  
Wheat Starches

Starches were extracted from chickpea (C.P.), corn (C.S.), Turkish bean (T.B.), sweet potato (S.P.S.), and wheat starches (W.S.). These starches exhibited different amylose contents. The extracted starches were annealed in excess water and in germinated sorghum extract (GSE) (1.0 g starch/9 mL water). The α-amylase concentration in the GSE was 5.0 mg/10 mL. Annealing was done at 40, 50, and 60 °C for 30 or 60 min. The pasting properties of annealed starches were studied using Rapid Visco-Analyzer (RVA), in addition to the swelling power. These starches exhibited diverse pasting properties as evidenced by increased peak viscosity with annealing, where native starches exhibited peak viscosity as: 2828, 2438, 1943, 2250, and 4601 cP for the C.P., C.S., T.B., W.S., and S.P.S., respectively, which increased to 3580, 2482, 2504, 2514, and 4787 cP, respectively. High amylose content did not play a major role on the pasting properties of the tested starches because sweet potato starch (S.P.S.) (22.4% amylose) exhibited the highest viscosity, whereas wheat starch (W.S.) (25% amylose) had the least. Therefore, the dual effects of granule structure and packing density, especially in the amorphous region, are determinant factors of the enzymatic digestion rate and product. Swelling power was found to be a valuable predictive tool of amylose content and pasting characteristics of the tested starches. The studied starches varied in their digestibility and displayed structural differences in the course of α-amylase digestion. Based on these findings, W.S. was designated the most susceptible among the starches and S.P.S. was the least. The most starch gel setback was observed for the legume starches, chickpeas, and Turkish beans (C.P. 2553 cP and T.B. 1172 cP). These results were discussed with regard to the underlying principles of swelling tests and pasting behavior of the tested starches. Therefore, GSE is an effortless economic technique that can be used for starch digestion (modification) at industrial scale.

scholarly journals Structural and Physicochemical Characteristics of Granular Malic Acid-Treated Sweet Potato Starch Containing Heat-Stable Resistant Starch

2019 ◽  
Vol 2019 ◽  
pp. 1-10 ◽  
Author(s):  
Chinwoo Kwon ◽  
Ha Ram Kim ◽  
Tae Wha Moon ◽  
Seung Hyun Lee ◽  
Chang Joo Lee
Keyword(s):  
Sweet Potato ◽  
Malic Acid ◽  
Resistant Starch ◽  
Amylose Content ◽  
Potato Starch ◽  
Physicochemical Characteristics ◽  
Partial Hydrolysis ◽  
Apparent Amylose Content ◽  
Sweet Potato Starch ◽  
Rapid Visco Analyzer

This study investigated the structural and physicochemical characteristics of malic acid-treated sweet potato starch. Sweet potato starch mixed with various concentrations of malic acid solution underwent either thermal or nonthermal treatment. Observation of samples under a light microscope ensured the maintenance of granular shape and the Maltese cross. FT-IR spectra displayed a distinct carbonyl peak at 1722 cm−1, and analysis of the degree of substitution (DS) indicated an increase in the extent of ester bonds with increasing concentrations of malic acid. The DS of 2.0M-130 (0.214) was the highest and that of 0.5M-130 was the lowest (0.088) among the reacted starches. In vitro digestion test revealed an increased amount of resistant starch when a high concentration of malic acid was used. In addition, thermally treated samples maintained a higher content of resistant starch (RS) after 30 min of cooking at 100°C. After cooking, 2.0M-130 had an RS fraction of 53.4% which was reduced to 49.9% after cooking, revealing greater heat stability compared with nonthermally treated samples. The structure of malic acid-treated starch was investigated using a differential scanning calorimeter (DSC), an X-ray diffractometer, a rapid visco analyzer (RVA), and analysis of apparent amylose content. The results showed that thermal and malic acid treatment of starch caused not only partial hydrolysis but also rearrangement of the crystalline area and helix structure of starch by esterification. Analysis of malic acid-treated starch, using a rapid visco analyzer showed no pasting properties, due to lack of its swelling caused by the malic acid cross link.

scholarly journals Almidones de Cáscara de Yuca (Manihot Esculenta) y Papa (Solanum Tuberosum) para Producción de Bioplásticos: Propiedades Mecánicas y Efecto Gelatinizante

2021 ◽  
Vol 6 (2) ◽  
pp. 137
Author(s):  
Carla Virginia Vélez Martinez ◽  
Xiomara Soledad Zambrano Murillo ◽  
María Hipatia Delgado Demera ◽  
Gabriel Alfonso Burgos Briones ◽  
Carlos Alfredo Cedeño Palacios
Keyword(s):  
Mechanical Properties ◽  
Solanum Tuberosum ◽  
Manihot Esculenta ◽  
Raw Materials ◽  
Amylose Content ◽  
Potato Starch ◽  
Molecular Structures ◽  
Large Space ◽  
Potato Peels ◽  
High Amylose

  Los productos biodegradables basados en materias primas agrícolas ocupan un gran espacio en las investigaciones para el desarrollo y mejoramiento de bioplástico a base de almidón que presentan propiedades similares a los plásticos convencionales. El objetivo de este trabajo consistió en describir la gelatinización y propiedades mecánicas de bioplásticos extraídos de almidones tanto de cáscaras de yuca (Manihot esculenta) como de cáscaras de papa (Solanum tuberosum). A partir de una revisión bibliográfica literaria complementada con aproximadamente 86 artículos científicos se logró comprobar que la gelatinización de estos residuos en función de sus propiedades fisicoquímicas y funcionales, mejoran sus propiedades mecánicas, además la adición de sustancias poliméricas sintéticas y naturales, plastificantes, materiales de relleno, aditivos, agentes acoplantes, agentes desestructurantes y agua otorgaron las propiedades mecánicas necesarias para trabajar como un termoplástico. Si bien ambos almidones presentan propiedades mecánicas viables para la elaboración de biopolímeros, se logra concluir que el almidón de cáscara de papa puede alcanzar un bioplástico con mejores propiedades mecánicas debido a que presenta gránulos más esféricos y regulares, los cuales pueden formar estructuras moleculares más estables, así como su alto contenido de amilosa favorece en la gelatinización y logra que la fuerza de tensión presente un incremento en comparación al almidón de cáscara de yuca.   Palabra clave: Almidón, gelatinización, papa, propiedades mecánicas, yuca.   Abstract Biodegradable products based on agricultural raw materials occupy a large space in research for the development and improvement of starch-based bioplastics that have properties similar to conventional plastics. The objective of this work was to describe the gelatinization and mechanical properties of bioplastics extracted from starches both from cassava peels (Manihot esculenta) and potato peels (Solanum tuberosum). From a literary bibliographic review complemented with approximately 86 scientific articles. it was possible to verify that the gelatinization of these residues based on their physicochemical and functional properties, improves their mechanical properties. Moreover, the addition of synthetic and natural polymeric substances, plasticizers, fillers, additives, coupling agents, destructuring agents, and water will give the necessary mechanical properties to work as a thermoplastic. Although both starches have viable mechanical properties for the production of biopolymers, it is possible to conclude that potato peel starch can achieve a bioplastic with better mechanical properties due to the fact that it presents more spherical and regular granules, which can form more stable molecular structures; as well as, its high amylose content favors gelatinization and achieves an increase in the tensile strength compared to cassava shell starch.  Keywords: Gelatinization, mechanical properties, yucca, potato, starch.

scholarly journals Both raw and retrograded starch decrease serum triacylglycerol concentration and fat accretion in the rat

1995 ◽  
Vol 73 (2) ◽  
pp. 287-298 ◽  
Author(s):  
Emile A. M. de Deckere ◽  
Willem J. Kloots ◽  
Johan M. M. van Amelsvoort
Keyword(s):  
Total Cholesterol ◽  
Energy Absorption ◽  
Resistant Starch ◽  
Potato Starch ◽  
Serum Total Cholesterol ◽  
Cholesterol Concentration ◽  
Raw Starch ◽  
Triacylglycerol Concentration ◽  
Retrograded Starch ◽  
Fat Pads

Male Wistar rats were meal-fed on diets containing various amounts of resistant starch in the form of raw starch (either amylomaize starch, potato starch or modified high-amylose starch) or retrograded starch (prepared from each of the starches) for 6 weeks. Two diets containing normal maize starch were fed as diets poor in resistant starch. Energy absorption (energy consumption minus faecal energy loss), growth, weight of the epididymal fat pads, serum total cholesterol and triacylglycerol concentrations and a number of intestinal and faecal variables were determined. The resistant starches affected all the variables determined except the serum total cholesterol concentration. Relationships were found between energy absorption and both growth and the weight of the fat pads, and between the weight of the fat pads and both the serum triacylglycerol concentration and the serum total cholesterol concentration. No clear differences between the effects of ihe two types of resistant starch (raw starch ν. retrograded starch) were found except that raw potato starch hardly stimulated H2 excretion and led to lower amounts of propionic and butyric acids in the caecal contents than the other starches. The results suggest that dietary resistant starch reduces energy absorption leading to less abdominal depot fat and lower serum triacylglycerol concentrations.

scholarly journals Potato Starch Extrusion and Roasting with Apple Distillery Wastewater as a New Method for Resistant Starch Production

2021 ◽  
Vol 11 (19) ◽  
pp. 9169
Author(s):  
Tomasz Zięba ◽  
Dominika Solińska ◽  
Artur Gryszkin ◽  
Małgorzata Kapelko-Żeberska ◽  
Bartosz Raszewski ◽  
...  
Keyword(s):  
Resistant Starch ◽  
Potato Starch ◽  
Chemical Agent ◽  
Amylolytic Enzymes ◽  
Starch Properties ◽  
Starch Extrusion ◽  
Distillery Wastewater ◽  
Novel Method ◽  
Esterification Degree ◽  
Starch Production

Potato starch was extruded and roasted with apple distillery wastewater to produce starch esters substituted with malic acid residues. The starch esterification degree was higher at the higher roasting temperatures. Starch modification contributed to its darker color, its increased resistance to the action of amylolytic enzymes, and its decreased solubility and heat of phase transition. The changes in the other starch properties examined depended on the extrusion and roasting temperatures. The process, which was conducted without a chemical agent—in this case, the process of starch extrusion and roasting with apple distillery wastewater—should be deemed a novel method for resistant starch production.

The Study on Gelatinization Pressure of Starch by Ultra-High Pressure Processing

2011 ◽  
Vol 295-297 ◽  
pp. 131-134 ◽  
Author(s):  
Yan Qi Liu ◽  
Yan Na Liu ◽  
Hong Li ◽  
Rei Ling Shen ◽  
Xue Hong Li ◽  
...  
Keyword(s):  
Corn Starch ◽  
Raw Materials ◽  
Potato Starch ◽  
Atmospheric Temperature ◽  
High Pressure Processing ◽  
Wheat Starch ◽  
Rice Starch ◽  
Waxy Wheat ◽  
Water Chestnut ◽  
Glutinous Rice

To study the gelatinization pressures of different kinds of starch at atmospheric temperature, eight different starches chosen as raw materials for this paper (5%w/w, at 20°C) by different pressure were treated, then analysed the relations between pressure and starch gelatinization by X-ray diffraction. The study showed that the gelatinization pressure range of different starches respectively in this experiment was: corn starch (~450 - ~550MPa), wheat starch (~ 450 - ~500MPa), tapioca starch (>450 - ~500MPa), water chestnut starch (>500 - ~550MPa), glutinous rice starch (>500 - ~550MPa), waxy wheat starch (~500 - ~550MPa), waxy maize starch (~550 - ~650MPa), potato starch (~700 - ~750MPa).

scholarly journals Effect of process parameters on slowly digestible and resistant starch content in extrudates

2014 ◽  
Vol 32 (No. 5) ◽  
pp. 503-508 ◽  
Author(s):  
P. Smrčková ◽  
M. Saglamtas ◽  
T. Hofmanová ◽  
J. Koláček ◽  
D. Chena ◽  
...  
Keyword(s):  
Compression Ratio ◽  
Resistant Starch ◽  
Raw Materials ◽  
Starch Content ◽  
Wheat Starch ◽  
Water Addition ◽  
Mixture Ratio ◽  
Chemically Modified ◽  
Pea Flour ◽  
Total Starch

A laboratory single-screw Kompaktextruder KE 19/25 was used at speeds 120–140 rpm of the screw with either a 2 : 1 or 3 : 1 compression ratio; the head had a 3 or 4 mm die. The temperature of the head was set at 131–144°C. The applied raw materials were maize grits, and mixtures with wheat starch, pea flour or chemically modified starch. Input mixtures differed in water addition (50 or 100 g water/kg). The highest amount of resistant starch (3.1% per total starch) in extrudate was found for mixture of pea flour and maize grits (with addition of 100 g water/kg of dry mixture), the output(extrudate)/input(mixture) ratio of the resistant starch was 45.8%. The highest SDS content was obtained for the maize grits and addition of 100 g water/kg using a die with a 3 mm diameter and a screw with a 3 : 1 compression ratio; the temperature of the head was approximately 140°C. Transportation rates: screw 140 rpm, dosing 15 rpm.  

PREPARATION AND CHARACTERISATION OF ACETYLATED WHEAT STARCH SUPPORTING FOR DIABETES TREATMENT

2018 ◽  
Vol 8 (5) ◽  
pp. 78-84
Author(s):  
Uyen Tran Thi Ngoc ◽  
Nam Nguyen Khac ◽  
Dung Tran Huu
Keyword(s):  
Physicochemical Properties ◽  
Resistant Starch ◽  
Starch Content ◽  
Degree Of Substitution ◽  
Wheat Starch ◽  
Diabetes Treatment ◽  
Glucose Response ◽  
Swelling Capacity ◽  
Wheat Starches

Background: The purpose of the study was to prepare acetylated wheat starches which have amylase hydrolysis resistant capacity to use as functional food supporting for diabetes treatment. Method: Acetate wheat starches were prepared by acetylation reaction of native wheat starch with different mole ratios of acetic anhydride. These starches were determined for the physicochemical properties by 1H-NMR, SEM, X-ray, DSC, solubility and swelling capacity, the resistant capacity by amylase hydrolysis in-vitro. Results: Acetate wheat starches were prepared successfully with the increase in acetyl content and degree of substitution corresponding with the increase of anhydride acetic, which resulted in the change of physicochemical properties of the wheat starches, including constitution, solubility, swelling capacity and contributed to the increase in resistant starch content in the acetate wheat starches. The AC150-9 containing 2.42% acetyl with degree of substitution 0,094 and resistant starch 32,11% is acceptable by FDA guideline about food safety. Conclusion: Acetate wheat starches contain low rate of digestive starch, while containing a higher proportion of resistant starch than natural wheat starch, possessing a high resistance to amylase activities. Thus, it is hope that this kind of starch to control the rapid increase of postprandual blood glucose response for diabetes treatments effectively. Key words: Acetate wheat starch, substitution, DS, RS, amylase

PSIII-12 In vitro Evaluation of Purified Fiber Sources for Production of Short-chain Fatty Acids Using Pig Cecal Content as an Inoculum

2021 ◽  
Vol 99 (Supplement_1) ◽  
pp. 177-177
Author(s):  
Gabriela E Martinez Padilla ◽  
Rajesh Jha ◽  
Vivek Fellner ◽  
Eric van Heugten
Keyword(s):  
Fatty Acids ◽  
Enzymatic Hydrolysis ◽  
Resistant Starch ◽  
Potato Starch ◽  
Short Chain ◽  
Gas Liquid Chromatography ◽  
Citrus Peel ◽  
Starch Potato ◽  
Chain Fatty Acids

Abstract This study evaluated short-chain fatty acid (SCFA) production from purified fiber sources when fermented in vitro using pig cecal contents as an inoculum. Fiber sources of interest were inulin from chicory root (native and long-chain inulin with 90 and 98% fiber, respectively), pectin from citrus peel (high methoxyl pectin), resistant starch (native starch), potato starch (commercial grade), and β-glucan (β-1,3;β-1,6 yeast-derived). Cellulose and cornstarch were used as indigestible and highly digestible carbohydrates, respectively. Triplicate samples of substrates (2 g) were subjected to enzymatic hydrolysis with pepsin and pancreatin for 6 h. Subsequently, hydrolyzed residues (200 mg) were incubated under anaerobic conditions at 39°C with 30 mL solution of cecal inoculum collected from 3 sows fed a standard commercial diet and buffered mineral solution. After 48 h of incubation, solutions from fermented samples were analyzed for pH, SCFA, and branched-chain fatty acids (BCFA) using gas-liquid chromatography. Enzymatic hydrolysis had no effect on digestion of β-glucan, but total SCFA concentration after fermentation was highest (26.13 mmol/g) followed by resistant starch (22.61 mmol/g) and potato starch (22.20 mmol/g) and was lowest for cellulose (13.91 mmol/g). In contrast, native inulin was highly digested during enzymatic hydrolysis, resulting in the lowest substrate available for fermentation (11.84% DM) and the highest pH (5.98). Enzymatic hydrolysis and fermentation of resistant starch increased (P< 0.001) concentrations of acetate (0.60 mg/g), whereas potato starch and β-glucan yielded more butyrate (0.60 and 0.54 mg/g respectively), and β-glucan resulted in greater (P< 0.001) propionate concentrations (0.69 mg/g). Pectin resulted in the highest fermentation (82.38% DM disappearance) and the lowest pH (4.03) compared to the other fiber sources (P< 0.001) and yielded the lowest BCFA concentration (1.89 mM, P< 0.001). Results suggest that fermentation of resistant starch, potato starch, and β-glucan produced higher SCFA concentrations, while pectin resulted in a decreased pH of fermentation solution.

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