scholarly journals Castor Oil-Based Polyurethane Resin for Low-Density Composites with Bamboo Charcoal

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1100 ◽  
Author(s):  
Yi-Chun Chen ◽  
Wei Tai
Keyword(s):  
Water Absorption ◽  
Castor Oil ◽  
Volume Expansion ◽  
Dibutyltin Dilaurate ◽  
Phyllostachys Pubescens ◽  
Low Density ◽  
Bamboo Charcoal ◽  
Blowing Agent ◽  
Pu Foam ◽  
Pu Foams

Polyurethane (PU) foam adhesives were prepared from castor oil as a polyol with isocyanate poly(4,4’-methylene diphenyl isocyanate) (PMDI) using a solvent-free process. The NCO/OH molar ratio used for the preparation of PU foams was 1.5. Water, organosiloxane and dibutyltin dilaurate were used as the blowing agent, surfactant and catalyst, respectively. The ratio of blowing agent and catalyst were adjusted to optimize the properties. The results show that PU foam prepared with 4 wt % of castor oil catalyst and blowing agent has minimal water absorption and maximal volume expansion in the PU foams. FT-IR analysis shows that a urethane bond was formed by the hydroxyl group of castor oil and the –NCO group of isocyanate PMDI. More blowing agent and catalyst could improve the volume expansion ratio and reduce water retention of PU foams. It was found that Moso bamboo charcoal (Phyllostachys pubescens) and China fir wood particle (Cunninghamia lanceolate) composites with setting densities of 500 and 600 kg/m3 can be prepared from optimized castor oil-based PU foam adhesive at 100 °C for 5 min under a pressure of 1.5 MPa. Increasing the amount of bamboo charcoal decreases the equilibrium moisture content, water absorption and internal bonding strength of the composite. Notably, bamboo charcoal composite exhibits excellent dimensional stability. The optimized density and bamboo charcoal percentages of the composite were 500 kg/m3 and 50–100%, respectively. The castor oil-based PU composites containing bamboo charcoal fulfilled the CNS 2215 standards for particleboard. This dimensionally stable, low-density bamboo charcoal composite has high potential to replace current indoor building materials.

scholarly journals Castor Oil-Based Polyurethane Resin for Low-Density Composites with Bamboo Charcoal

2018 ◽  
Author(s):  
Yi-Chun Chen ◽  
Wei Tai
Keyword(s):  
Water Absorption ◽  
Castor Oil ◽  
Volume Expansion ◽  
Dibutyltin Dilaurate ◽  
Phyllostachys Pubescens ◽  
Low Density ◽  
Bamboo Charcoal ◽  
Blowing Agent ◽  
Pu Foam ◽  
Pu Foams

Polyurethane (PU) foam adhesives were prepared from castor oil as a polyol with isocyanate poly (4,4′-methylene diphenyl isocyanate) (PMDI) using a solvent-free process. The NCO/OH molar ratio used for the preparation of PU foams was 1.5. Water, organosiloxane and dibutyltin dilaurate were blowing agent, surfactant and catalyst, respectively. Effects of the ratio of blowing agent and catalyst were adjusted to optimize the properties. The results show that 4 wt% of castor oil of catalyst and blowing agent minimizes water absorption and maximizes volume expansion in the PU foams. FT-IR analysis shows that urethane bond was formed by hydroxyl group of castor oil and –NCO group of isocyanate PMDI. More blowing agent and catalyst could improve the volume expansion ratio and reduce water retention of PU foams. It was found that Moso bamboo charcoal (Phyllostachys pubescens) or/and China fir wood particle (Cunninghamia lanceolate) composites with setting densities of 500 and 600 kg/m3 can be prepared from optimized castor oil-based PU foam adhesive at 100 °C for 5 min under a pressure of 1.5 MPa. Increasing the amount of bamboo charcoal decreases the equilibrium moisture content, water absorption and internal bonding strength of the composite. Notably, bamboo charcoal composite exhibits excellent dimensional stability. The optimized density and bamboo charcoal percentages of the composite were 500 kg/m3 and 50 to 100%. The castor oil-based PU composites containing bamboo charcoal fulfilled the CNS 2215 standards for particleboard. This dimensionally stable, low-density bamboo charcoal composite has high potential to replace current indoor building materials.

The Effects of Henna Fillers on the Properties of Polyurethane Foam Composites

2020 ◽  
Vol 1010 ◽  
pp. 520-525
Author(s):  
Sinar Arzuria Adnan ◽  
Firuz Zainuddin ◽  
Nur Hidayah Ahmad Zaidi ◽  
Nur Afikah Zulkeply ◽  
Nur Maizatul Shima Adzali ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Cell Wall ◽  
Water Absorption ◽  
Cell Structure ◽  
Natural Fibers ◽  
Diphenylmethane Diisocyanate ◽  
Core Density ◽  
Blowing Agent ◽  
Pu Foam ◽  
Absorption Percentage

Polyurethane (PU) foam were produced from polyol (PolyGreen R3110) and 4,4- diphenylmethane diisocyanate (Maskiminate 80) with distilled water as a blowing agent. Natural fibers have received more attention from researchers due to their ability to increase the properties of the polymer composites. In this work, PU/Henna foam composites were prepared by used Henna fibers at different loading of 5, 10, 15 and 20 wt. %. The effect of different Henna loading on PU foam were investigated by density, compression test, morphology and water absorption. Core density of PU/Henna foam composites increased with addition Henna compared to control PU and showed highest core density of 85.10 kgm-3. Compressive strength decreased to 0.53 MPa after Henna addition at 5 % PU/Henna foam composites. Henna addition to 20 % PU/Henna foam composites were reduced the compressive strength to 0.97 MPa due to stiffness effect of Henna that contributed to embrittlement of the cell wall. The distorted cell wall and less uniform of cell structure were proved by SEM due to Henna addition as compared to control PU. Water absorption percentage of PU/Henna foam composites were increased with Henna addition as compared to control PU. It is because hydrophilic properties of Henna tendency to absorb moisture.

scholarly journals The Influence of Neem Oil and Its Glyceride on the Structure and Characterization of Castor Oil-Based Polyurethane Foam

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 2020
Author(s):  
Yi-Han Liao ◽  
You-Lin Su ◽  
Yi-Chun Chen
Keyword(s):  
Compressive Strength ◽  
Castor Oil ◽  
Ricinus Communis ◽  
Hexamethylene Diisocyanate ◽  
Synthesis Process ◽  
Neem Oil ◽  
Solvent Resistance ◽  
Molar Ratios ◽  
Pu Foam ◽  
Pu Foams

Neem (Azadirachta indica) oil is a non-edible oil that contains azadirachtin, which can be used as a biopesticide. This study synthesizes bio-based polyurethane (PU) foam from neem and castor (Ricinus communis L.) oil at normal temperature and pressure. Neem oil can be reacted to narrow-distribution polyol by transesterification of oil and glycerol. Neem oil glyceride (NOG) can be used as polyol for bio-based PU foams and can be blended with castor oil homogeneously to reduce the cost of production. The composition of polyol was castor oil and 0 to 20% molar ratios of NOG. Hexamethylene diisocyanate trimer (Desmodur N) was used as isocyanate. The molar ratios of NCO/OH were set as 1.0, 1.5 and 2.0. The average hydroxyl contents of castor oil, neem oil and NOG were 2.7 mmol/g, 0.1 mmol/g and 5.1 mmol/g, respectively. The reaction time of bio-based PU foam could be adjusted between 5 to 10 min, which is acceptable for manufacturing. The densities of PU foams were between 49.7 and 116.2 kg/m3 and decreased with increasing NCO/OH and NOG ratios and decreasing neem oil. The ranges of specific compressive strength of foams were from 0.0056 to 0.0795 kPa·m3/kg. Increasing the NOG and neem oil ratio significantly enhanced the specific compressive strength in the low NCO/OH ratio. The solvent resistance and thermogravimetric (TG) results showed that the foams have high water and thermal stability. NOG can help to increase solvent resistance. Adding neem oil reduces the solvent resistance. The results indicated that increasing NCO/OH and NOG ratios increases the cross-linking density and hard segment content of PU foams. This investigation demonstrated that castor oil-based PU foams are improved by adding NOG to the polyol mixture. PU foam has excellent properties. Neem oil can be used in manufacturing processes to produce high-performance foams via a green synthesis process.

Mechanical Properties of Polyurethane Foam Compared With Values for Normal and Osteoporotic Human Cancellous Bone

2007 ◽  
Author(s):  
Purvi S. D. Patel ◽  
Duncan E. T. Shepherd ◽  
David W. L. Hukins
Keyword(s):  
Cancellous Bone ◽  
Standard Test ◽  
Test Material ◽  
Osteoporotic Bone ◽  
Low Density ◽  
Open Cell ◽  
Pu Foam ◽  
Human Cancellous Bone ◽  
Bone Deposition ◽  
Pu Foams

Rigid polyurethane (PU) foam is widely used as a test medium for mimicking human cancellous bone e.g. for investigating fixation of bone screws [1,2]. Whilst the solid and higher density PU foams are used as standard test materials [3], very little work has been carried out to date on modelling human osteoporotic bone. Osteoporosis (OP) is a bone disease in which bone resorption exceeds bone deposition, resulting in bone loss. Various low density, open cell rigid PU foams are available for use as OP bone models, but none of these has been standardised or universally accepted as a test material. In this study the objective was to determine whether low density PU foam might be suitable for mimicking human osteoporotic bone.

scholarly journals Water Resistance and Creep Behavior of Heat-Treated Moso Bamboo Determined by the Stepped Isostress Method

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1264
Author(s):  
Teng-Chun Yang ◽  
Tung-Lin Wu ◽  
Chin-Hao Yeh
Keyword(s):  
Heat Treatment ◽  
Water Absorption ◽  
Creep Behavior ◽  
Heat Treatment Temperature ◽  
Water Resistance ◽  
Absorption Efficiency ◽  
Treatment Temperature ◽  
Moso Bamboo ◽  
Phyllostachys Pubescens ◽  
Heat Treated

The influence of heat treatment on the physico-mechanical properties, water resistance, and creep behavior of moso bamboo (Phyllostachys pubescens) was determined in this study. The results revealed that the density, moisture content, and flexural properties showed negative relationships with the heat treatment temperature, while an improvement in the dimensional stability (anti-swelling efficiency and anti-water absorption efficiency) of heat-treated samples was observed during water absorption tests. Additionally, the creep master curves of the untreated and heat-treated samples were successfully constructed using the stepped isostress method (SSM) at a series of elevated stresses. Furthermore, the SSM-predicted creep compliance curves fit well with the 90-day full-scale experimental data. When the heat treatment temperature increased to 180 °C, the degradation ratio of the creep resistance (rd) significantly increased over all periods. However, the rd of the tested bamboo decreased as the heat treatment temperature increased up to 220 °C.

scholarly journals The Effect of Polymer Waste Addition on the Compressive Strength and Water Absorption of Geopolymer Ceramics

2021 ◽  
Vol 11 (8) ◽  
pp. 3540
Author(s):  
Numfor Linda Bih ◽  
Assia Aboubakar Mahamat ◽  
Jechonias Bidossèssi Hounkpè ◽  
Peter Azikiwe Onwualu ◽  
Emmanuel E. Boakye
Keyword(s):  
Public Health ◽  
Compressive Strength ◽  
Fracture Surface ◽  
Water Absorption ◽  
Chemical Bonding ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Polymer Waste ◽  
Pull Out

The quantity of polymer waste in our communities is increasing significantly. It is therefore necessary to consider reuse or recycling waste to avoid an increase in the risk to public health. This project is aimed at using pulverized low-density polyethylene (LDPE) waste as a source to reinforce and improve compressive strength, and to reduce the water absorption of geopolymer ceramics (GC). Clay:LDPE composition consisting of 5%, 10%, and 15% LDPE was geopolymerized with an NaOH/Na2SiO3 solution and cured at 30 °C and 50 °C. Characterization of the geopolymer samples was carried out using XRF and XRD. The microstructure was analyzed by SEM and chemical bonding by FTIR. The SEM micrographs showed LDPE particle pull-out on the geopolymer ceramics’ fracture surface. The result showed that the compressive strength increases with the addition of pulverized polymer waste compared to the controlled without LDPE addition. Water absorption decreased with an increase in LDPE addition in the geopolymer ceramics composite.

scholarly journals Properties of Low-Cost WPCs Made from Alien Invasive Trees and rLDPE for Interior Use in Social Housing

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2436
Author(s):  
Abubakar Sadiq Mohammed ◽  
Martina Meincken
Keyword(s):  
Tensile Strength ◽  
Water Absorption ◽  
Social Housing ◽  
Low Cost ◽  
Production Costs ◽  
Low Density Polyethylene ◽  
Low Grade ◽  
Low Density ◽  
Invasive Trees ◽  
Recycled Low Density Polyethylene

Low-cost wood–plastic composites (WPCs) were developed from invasive trees and recycled low-density polyethylene. The aim was to produce affordable building materials for low-cost social housing in South Africa. Both raw materials are regarded as waste materials, and the subsequent product development adds value to the resources, while simultaneously reducing the waste stream. The production costs were minimised by utilising the entire biomass of Acacia saligna salvaged from clearing operations without any prior processing, and low-grade recycled low-density polyethylene to make WPCs without any additives. Different biomass/plastic ratios, particle sizes, and press settings were evaluated to determine the optimum processing parameters to obtain WPCs with adequate properties. The water absorption, dimensional stability, modulus of rupture, modulus of elasticity, tensile strength, and tensile moduli were improved at longer press times and higher temperatures for all blending ratios. This has been attributed to the crystallisation of the lignocellulose and thermally induced cross-linking in the polyethylene. An increased biomass ratio and particle size were positively correlated with water absorption and thickness swelling and inversely related with MOR, tensile strength, and density due to an incomplete encapsulation of the biomass by the plastic matrix. This study demonstrates the feasibility of utilising low-grade recycled polyethylene and the whole-tree biomass of A. saligna, without the need for pre-processing and the addition of expensive modifiers, to produce WPCs with properties that satisfy the minimum requirements for interior cladding or ceiling material.

Mechanical and water absorption properties of sawdust-low density polyethylene nanocomposite

2012 ◽  
Vol 127 (2) ◽  
pp. 1295-1300 ◽  
Author(s):  
Catherine Esnaashari ◽  
Saied Nouri Khorasani ◽  
Mehdi Entezam ◽  
Shahla Khalili
Keyword(s):  
Water Absorption ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Absorption Properties
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