scholarly journals Effect of Morphologically Controlled Hematite Nanoparticles on the Properties of Fly Ash Blended Cement

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1003
Author(s):  
Pantharee Kongsat ◽  
Sakprayut Sinthupinyo ◽  
Edgar A. O’Rear ◽  
Thirawudh Pongprayoon
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Size Distribution ◽  
Cement Hydration ◽  
Blended Cement ◽  
Spherical Shape ◽  
Particle Sizes ◽  
Fe2o3 Nanoparticles ◽  
Structure And Properties ◽  
Hematite Nanoparticles

Several types of hematite nanoparticles (α-Fe2O3) have been investigated for their effects on the structure and properties of fly ash (FA) blended cement. All synthesized nanoparticles were found to be of spherical shape, but of different particle sizes ranging from 10 to 195 nm depending on the surfactant used in their preparation. The cement hydration with time showed 1.0% α-Fe2O3 nanoparticles are effective accelerators for FA blended cement. Moreover, adding α-Fe2O3 nanoparticles in FA blended cement enhanced the compressive strength and workability of cement. Nanoparticle size and size distribution were important for optimal filling of various size of pores within the cement structure.

scholarly journals Influence of Particle Size Distribution of High Calcium Fly Ash on HVFA Mortar Properties

2018 ◽  
Vol 20 (2) ◽  
pp. 51
Author(s):  
Antoni . ◽  
Hendra Surya Wibawa ◽  
Djwantoro Hardjito
Keyword(s):  
Particle Size ◽  
Compressive Strength ◽  
Fly Ash ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Setting Time ◽  
High Volume ◽  
High Volume Fly Ash ◽  
High Calcium ◽  
High Calcium Fly Ash

This study evaluates the effect of particle size distribution (PSD) of high calcium fly ash on high volume fly ash (HVFA) mortar characteristics. Four PSD variations of high calcium fly ash used were: unclassified fly ash and fly ash passing sieve No. 200, No. 325 and No. 400, respectively. The fly ash replacement ratio of the cementitious material ranged between 50-70%. The results show that with smaller fly ash particles size and higher levels of fly ash replacement, the workability of the mixture was increased with longer setting time. There was an increase in mortar compressive strength with finer fly ash particle size, compared to those with unclassified ones, with the highest strength was found at those with fly ash passing mesh No. 325. The increase was found due to better compactability of the mixture. Higher fly ash replacement reduced the mortar’s compressive strength, however, the rate was reduced when finer fly ash particles was used.

High Volume Slag and Slag-Fly Ash Blended Cement Pastes Containing Nano Silica

2019 ◽  
Vol 967 ◽  
pp. 205-213
Author(s):  
Faiz U.A. Shaikh ◽  
Anwar Hosan
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Cement Paste ◽  
Ordinary Portland Cement ◽  
Blended Cement ◽  
High Volume ◽  
Ash Content ◽  
Partial Replacement ◽  
Nano Silica ◽  
Cement Pastes

This paper presents the effect of nanosilica (NS) on compressive strength and microstructure of cement paste containing high volume slag and high volume slag-fly ash blend as partial replacement of ordinary Portland cement (OPC). Results show that high volume slag (HVS) cement paste containing 60% slag exhibited about 4% higher compressive strength than control cement paste, while the HVS cement paste containing 70% slag maintained the similar compressive strength to control cement paste. However, about 9% and 37% reduction in compressive strength in HVS cement pastes is observed due to use of 80% and 90% slag, respectively. The high volume slag-fly ash (HVSFA) cement pastes containing total slag and fly ash content of 60% exhibited about 5%-16% higher compressive strength than control cement paste. However, significant reduction in compressive strength is observed in higher slag-fly ash blends with increasing in fly ash contents. Results also show that the addition of 1-4% NS improves the compressive strength of HVS cement paste containing 70% slag by about 9-24%. However, at higher slag contents of 80% and 90% this improvement is even higher e.g. 11-29% and 17-41%, respectively. The NS addition also improves the compressive strength by about 1-59% and 5-21% in high volume slag-fly ash cement pastes containing 21% fly ash+49%slag and 24% fly ash+56%slag, respectively. The thermogravimetric analysis (TGA) results confirm the reduction of calcium hydroxide (CH) in HVS/HVSFA pastes containing NS indicating the formation of additional calcium silicate hydrate (CSH) gels in the system. By combining slag, fly ash and NS in high volumes e.g. 70-80%, the carbon footprint of cement paste is reduced by 66-76% while maintains the similar compressive strength of control cement paste. Keywords: high volume slag, nanosilica, compressive strength, TGA, high volume slag-fly ash blend, CO2 emission.

scholarly journals Evaluation of Strengths from Cement Hydration and Slag Reaction of Mortars Containing High Volume of Ground River Sand and GGBF Slag

2019 ◽  
Vol 2019 ◽  
pp. 1-12 ◽  
Author(s):  
Punnaman Norrarat ◽  
Weerachart Tangchirapat ◽  
Smith Songpiriyakij ◽  
Chai Jaturapitakkul
Keyword(s):  
Particle Size ◽  
Compressive Strength ◽  
Cement Hydration ◽  
High Volume ◽  
Inert Material ◽  
Early Age ◽  
Particle Sizes ◽  
River Sand ◽  
Reactive Material ◽  
Median Particle

This paper investigates the cement hydration, and the slag reaction contributes to the compressive strengths of mortars mixed with ground river sand (GRS) and ground-granulated blast furnace (GGBF) slag with different particle sizes. GRS (inert material) and GGBF slag (reactive material) were ground separately until the median particle sizes of 32 ± 1, 18 ± 1, and 5 ± 1 micron and used to replace Portland cement (PC) in large amount (40–60%) by weight of the binder. The results showed that, at the early age, the compressive strength obtained from the cement hydration was higher than that obtained from the slag reaction. The results of compressive strength also indicated that the GGBF slag content and particle size play important roles in the slag reaction at the later ages, whereas cement hydration is more prominent at the early ages. Although the results could be expected from the use of GGBF slag to replace PC in mortar or concrete, this study had presented the values of the compressive strength along with ages and the finenesses of GGBF slag that contributed from cement hydration and from GGBF slag reaction.

Porosity In The Microstructure Of Blended Cements Containing Fly Ash

1988 ◽  
Vol 137 ◽  
Author(s):  
H. H. Patel ◽  
P. L. Pratt ◽  
L. J. Parrott
Keyword(s):  
Compressive Strength ◽  
Image Analysis ◽  
Fly Ash ◽  
Blended Cement ◽  
Total Porosity ◽  
Major Change ◽  
Relative Volume ◽  
Blended Cements ◽  
Backscattered Electron ◽  
Electron Imaging

AbstractThe changes in porosity of OPC and an OPC-fly ash blended cement during hydration have been studied at water/solids ratios of 0.35, 0.47 and 0.59, cured for times of up to 1 year at 25°C. The porosity was measured indirectly by methanol exchange and methanol adsorption techniques and, directly, by quantitative image analysis using backscattered electron imaging in the scanning electron microscope. Measurements of porosity and of remaining anhydrous material by image analysis showed good correlation with indirect methods. Measurement of the diffusion of methanol and of the compressive strength were made in parallel with the determination of the porosity during hydration and attempts were made to relate the properties to the microstructure. For both binders the reduction of total porosity with increased reaction was small. The major change in pore structure was the subdivision of coarse pores by gel to form finer pores. Compressive strength and diffusion properties were dominated by the relative volume of coarse pores.

Preparation and Properties of Lightweight, High-Strength Insulation Materials Using Fly Ash Floating Beads

2016 ◽  
Vol 697 ◽  
pp. 599-603
Author(s):  
Ya Peng Dai ◽  
Xing Yong Gu ◽  
Wei Xia Dong ◽  
Ting Luo
Keyword(s):  
Compressive Strength ◽  
Heat Conduction ◽  
Fly Ash ◽  
High Strength ◽  
Volume Density ◽  
Particle Sizes ◽  
Heat Conduction Coefficient ◽  
Insulation Materials ◽  
Test Instrument ◽  
Save Energy

In our paper, to save energy conservation and environmental protection, and in view of waste fly ash floating bead with excellent properties such as light and refractory, lightweight insulation materials was prepared using fly ash floating beads as the main materials. Firstly, two different fly ash floating bead contents on the properties of the light and refractory material were investigated. Then, on the basis of the optimum fly ash floating bead content, effects of various different particle sizes and firing temperature on the bulk density, compressive strength and the heat conduction coefficients of the samples were studied. The microstructure of the light-weight refractory materials was characterized by XRD and SEM. The heat conduction coefficient (λ') of the samples were also measured by the self-made test instrument. The experimental results showed that the properties of the as-prepared sample using 80% fly ash floating beads was superior to that of 95 % fly ash floating beads. The optimal volume density of 0.60-1.04 g/cm3, compressive strength of 10.6-39.5 MPa and the heat conduction coefficient of 0.183-0.25 °C·g/ min·cm2 were achieved in the presence of 80% fly ash floating beads with 120-160 particle size at 1200°C-1300°C, which has the potential application in lightweight insulation materials.

Effects of Fly Ash Particle Sizes on the Compressive Strength and Fracture Toughness of High Performance Concrete

2011 ◽  
Vol 284-286 ◽  
pp. 984-988
Author(s):  
An Shun Cheng ◽  
Yue Lin Huang ◽  
Chung Ho Huang ◽  
Tsong Yen
Keyword(s):  
Fracture Toughness ◽  
Particle Size ◽  
Compressive Strength ◽  
Fly Ash ◽  
High Performance ◽  
High Performance Concrete ◽  
Concrete Strength ◽  
Bending Test ◽  
Strength Development ◽  
Particle Sizes

The study aims to research the effect of the particle size of fly ash on the compressive strength and fracture toughness of high performance concrete (HPC). In all HPC mixtures, the water-to-binder ratio selected is 0.35; the cement replacement ratios includes 0%, 10% and 20%; the particle sizes of fly ash have three types of passing through sieves No. 175, No. 250 and No. 325. Three-point-bending test was adopted to measure the load-deflection relations and the maximum loads to determine the fracture energy (GF) and the critical stress intensity factor (KSIC). Test results show that adding fly ash in HPC apparently enhances the late age strengths of HPC either for replacement ratio of 10% or 20%, in which the concrete with 10% fly ash shows the higher effect. In addition, the smaller the particle size is the better the late age concrete strength will be. The HPC with the finer fly ash can have higher strength development and the values of GF and KSIC due to the facts of better filling effect and pozzolanic reaction. At late age, the GF and KSIC values of concrete with 10% fly ash are all higher than those with 20% fly ash.

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