scholarly journals Bifunctional Carbon Dots—Magnetic and Fluorescent Hybrid Nanoparticles for Diagnostic Applications

Nanomaterials ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 1384
Author(s):  
Ilana Perelshtein ◽  
Nina Perkas ◽  
Shai Rahimipour ◽  
Aharon Gedanken

There is a huge demand for materials capable of simple detection or separation after conjugation with specific biologic substances when applied as a diagnostic tools. Taking into account the photoluminescence properties of C-dots and the highly magnetic properties of Fe(0), a new hybrid composite of these components was synthesized via ultrasound irradiation. The material was fully characterized by various physicochemical techniques. The main goal of the current study was to obtain a highly magnetic and intense fluorescent hybrid material. The goal was achieved. In addition, magnetic particles tended to agglomerate. The new hybrid can be suspended in ethanol, which is an additional feature of the current research. The dispersion of the hybrid nanoparticles in ethanol was achieved by utilizing the interaction of iron particles with C-dots which were decorated with functional groups on their surface. The newly formed hybrid material has potential applications in diagnostic by conjugating with specific antibodies or with any other biologic compounds. Such application may be useful in detection of various diseases such as: cancer, tuberculosis, etc.

2008 ◽  
Vol 144 ◽  
pp. 244-249 ◽  
Author(s):  
Yousef Razouk ◽  
Eric Duhayon ◽  
Bertrand Nogarede

This paper deals with the development of a new type of composites called "magnetoactivated" polymers and the exploration of some of their potential applications. "Magnetoactivated" polymers consist of small embedding (micron-sized) magnetic particles in a high elastic silicon matrix to render it magnetically active and at the same time mechanically strong. The experimental characterizations obtained (magnetic permeability and Young modulus) were systematically compared with the values resulting from the modeling of this material.The elastic properties of our "magnetoactivated" silicon motive us to use them as pump membranes, the evolution of the displacement of the pump membrane with the applied magnetic field were verified in ANSYS and experimentally for various contents of iron particles in the silicon matrix.


Reproduction ◽  
2021 ◽  
Author(s):  
Zoe Claire Johnston ◽  
Franz S Gruber ◽  
Sean Brown ◽  
Neil R Norcross ◽  
Jason R Swedlow ◽  
...  

Despite recent advances in male reproductive health research, there remain many elements of male (in)fertility where our understanding is incomplete. Consequently, diagnostic tools and treatments for men with sperm dysfunction, other than medically assisted reproduction, are limited. On the other hand, the gaps in our knowledge of the mechanisms which underpin sperm function have hampered the development of male non-hormonal contraceptives. The study of mature spermatozoa is inherently difficult. They are a unique and highly specialised cell type which does not actively transcribe or translate proteins and cannot be cultured for long periods of time or matured in vitro. One, large scale, approach to both increasing understanding of sperm function, and the discovery and development of compounds that can modulate sperm function, is to directly observe responses to compounds with phenotypic screening techniques. These target agnostic approaches can be developed into high-throughput screening platforms with the potential to drastically increase advances in the field. Here we discuss the rationale and development of high-throughput phenotypic screening platforms for mature human spermatozoa, and the multiple potential applications these present, as well as the current limitations and leaps in our understanding and capabilities needed to overcome them. Further development and use of these technologies could lead to the identification of compounds which positively or negatively affect sperm cell motility or function, or novel platforms for toxicology or environmental chemical testing among other applications. Ultimately, each of these potential applications is also likely to increase understanding within the field of sperm biology.


2018 ◽  
Vol 36 (1) ◽  
pp. 157-161
Author(s):  
Esra Yildiz

AbstractZr0.99Gd0.01O2, Zr0.98Gd0.01Dy0.01O2 and Zr0.98Gd0.01Yb0.1O2 phosphors were synthesized by Pechini method at 1200 °C for 12 h in air. The phosphors were characterized by using X-ray powder diffraction (XRD), differential thermal analysis/thermal gravimetry (DTA/TG), scanning electron microscopy (SEM) and photoluminescence spectrofluorometer (PL). X-ray powder diffraction studies showed that the phosphors were crystallized as monoclinic and tetragonal multiphases. The particle size of the phosphors after heat treatment at 1200 °C was found to be of 200 nm to 250 nm. Luminescence studies on these phosphors have been carried out on the emission and excitation, along with lifetime measurements. The results of emission analysis indicate that the phosphors are expected to find potential applications as new optical materials.


2021 ◽  
Author(s):  
Ghfoor Muhammad ◽  
Imran Murtaza ◽  
Rehan Abid ◽  
Naeem Ahmad

Abstract Herein, we explore the photoluminescence properties of zinc silicate (Zn2SiO4) nanostructures synthesized by vapor-liquid-solid (VLS) mode of growth using three different catalysts (Sn, Ag and Mn). Different catalysts significantly influence the growth rate which in turn has an impact on the structure and hence the photoluminescence of the prepared zinc silicate nanostructures. Zn2SiO4 has a wide bandgap of about 5.5 eV and in its pure form, it does not emit in visible region due to its inner shell electronic transitions between the 3d5 energy levels. However, the incorporation of different catalysts (Sn, Ag and Mn) at different growth temperatures into the Zn2SiO4 crystal growth kinetics provides wide visible spectral range of photoluminescence (PL) emissions. PL analysis shows broad multi-band spectrum in the visible region and distinct colours (red, yellow, green, blue, cyan and violet) are obtained depending on the crystalline structure of the prepared nanostructures. The allowed transitions due to the effect of different catalysts on zinc silicate lattice offer a huge cross-section of absorption that generates strong photoluminescence. The correlation between the structural and optical properties of the synthesized nanostructures is discussed in detail. The synthesized photoluminescent nanostructures have potential applications in solid-state lighting and display devices.


2019 ◽  
Vol 9 (23) ◽  
pp. 5211 ◽  
Author(s):  
Liu ◽  
Li ◽  
Yao ◽  
He ◽  
Liu ◽  
...  

Two-dimensional (2D) layered hybrid organic–inorganic perovskites have potential applications in solar cells, electroluminescent devices and radiation detection because of their unique optoelectronic properties. In this paper, four 2D layered hybrid organic–inorganic halide perovskites of (C6H5CH2NH3)2PbCl4, (C6H5CH2NH3)2PbBr4, (C6H5CH2NH3)2PbI4 and (C4H9NH3)2PbBr4 were synthesized by solvent evaporation. Their crystal structure and surface morphology were studied. The effects of different halogens and organic amines on perovskites’ absorption spectra were investigated, and the photoluminescence (PL) properties were studied by femtosecond ultrafast spectroscopy. The experimental results show that the four perovskites are well crystallized and oriented. With the increase of halogen atom number (Cl, Br, I) in turn, the UV-Vis absorption spectra peaks of perovskites redshift due to the increasing of the layer spacing, but organic amines have little effect on the spectra of perovskites. The PL intensity increases with increasing laser power, but the lifetime decreases with increasing laser power, which is mainly due to the non-geminate recombination. This research is of great significance for realizing the spectral regulation of organic–inorganic hybrid perovskites and promoting their application in nano-photonics and optoelectronic devices.


Nanomaterials ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 510 ◽  
Author(s):  
Jianhang Shi ◽  
Yanxin Wang ◽  
Linjun Huang ◽  
Peng Lu ◽  
Qiuyu Sun ◽  
...  

A novel anhydrous preparation of silica (SiO2)-encapsulated terbium (Tb3+) complex nanoparticles has been investigated. The SiO2-Tb3+ nanoparticles are incorporated in electrospun polyvinylpyrrolidone hybrid nanofibers. Transmission electron microscopy confirms that Tb3+ complexes are uniformly and stably encapsulated in or carried by nanosilica. The influence of pH on the fluorescence of Tb3+ complexes is discussed. The properties, composition, structure, and luminescence of the resulting SiO2–Tb3+ hybrid nanoparticles are investigated in detail. There is an increase in the fluorescence lifetime of SiO2–Tb3+ nanoparticles and SiO2–Tb3+/polyvinylpyrrolidone (PVP) hybrid nanofibers compared with the pure Tb3+ complexes. Due to the enhanced optical properties, the fluorescent hybrid nanofibers have potential applications as photonic and photoluminescent materials.


2007 ◽  
Vol 334-335 ◽  
pp. 193-196
Author(s):  
Jae Lim You ◽  
B.J. Park ◽  
I.B. Jang ◽  
Hyoung Jin Choi

To enhance dispersion stability of magnetorheological (MR) fluids, hybrid magnetic particles of carbonyl iron (CI)/ poly(vinyl butyral) (PVB) with core/shell microstrcutre (CI-PVB) were prepared, since pure magnetic CI based MR fluid systems show severe sedimentation of the CI particles due to the large density mismatch with the carrier liquid and difficulties in redispersion after caking. The composite particles of CI-PVB have a lower density than that of the pure CI particles, while exhibiting almost original magnetic property of the CI. Both CI and CI-PVB particles were dispersed in mineral oil (20 vol%) and their MR characteristics were examined via a rotational rheometer with a magnetic field supplier. Various characterizations of the CI-PVB particles were performed via SEM, TEM and FT-IR. Both yield stress and flow curve of shear stress as a function of shear rate of the MR fluids were investigated under applied magnetic field strengths.


2010 ◽  
Vol 455 ◽  
pp. 161-164
Author(s):  
W.D. Li ◽  
Ming Lv ◽  
Sheng Qiang Yang

Fluid magnetic abrasivetool(FMA) is one kind of latest finishing abrasivetool which is a sort of suspended fluid composed by magnetic particles, nonmagnetic abrasive particles, surfactants in a non-magnetizable carrier liquid. After a period of working time, the performance-life of the abrasivetool ended because of the cutting- blade of the abrasives particles being passive. While the most costly component- the magnetic particles (carbonyl iron particles) can be reused. This paper has made up two recovery flows to separated carbonyl iron particles from others.


Author(s):  
Huanwu Sun ◽  
Shichun Yang

The fluid magnetic abrasive (FMA) is a new type of precision finishing abrasives, which is typically prepared by dispersing the magnetic particles, nonmagnetic abrasives, surfactants in a non-magnetizable carrier liquid. As the functional particles, the characteristics of magnetic particles have a great impact on the properties of FMA. In our experiment, the micron-sized carbonyl-iron (CI) particles (typical size: 3 μm–5 μm) are found to be ideally suited for the preparation of FMA. In this paper, the selections of micron-sized carbonyl-iron particles suitable for the FMA, the preparation techniques, the finishing mechanism and finishing process are presented. Some key parameters of FMA that may affect the finishing efficiency and the final surface roughness are analyzed theoretically. The experimental results are discussed as well in this paper.


2016 ◽  
Vol 4 (21) ◽  
pp. 3801-3814 ◽  
Author(s):  
Rivka Ben Ishay ◽  
Liron L. Israel ◽  
Esthy Levy Eitan ◽  
David M. Partouche ◽  
Jean-Paul Lellouche

Magnetic hybrid human serum albumin-based NPs were successfully fabricated, disclosing a powerful T2* contrast agent for dual therapeutic and diagnostic applications.


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