scholarly journals Plasmonic Metasensors Based on 2D Hybrid Atomically Thin Perovskite Nanomaterials

Nanomaterials ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 1289 ◽  
Author(s):  
Shuwen Zeng ◽  
Guozhen Liang ◽  
Alexandre Gheno ◽  
Sylvain Vedraine ◽  
Bernard Ratier ◽  
...  
Keyword(s):  
Electric Field ◽  
Field Enhancement ◽  
Toxic Heavy Metal ◽  
Phase Gradient ◽  
Phase Singularity ◽  
Metal Insulator Metal ◽  
Nucleotide Mismatch ◽  
Phase Signal ◽  
And Biological Markers ◽  
Factor Α

In this work, we have designed highly sensitive plasmonic metasensors based on atomically thin perovskite nanomaterials with a detection limit up to 10−10 refractive index units (RIU) for the target sample solutions. More importantly, we have improved phase singularity detection with the Goos–Hänchen (GH) effect. The GH shift is known to be closely related to optical phase signal changes; it is much more sensitive and sharp than the phase signal in the plasmonic condition, while the experimental measurement setup is much more compact than that of the commonly used interferometer scheme to exact the phase signals. Here, we have demonstrated that plasmonic sensitivity can reach a record-high value of 1.2862 × 109 µm/RIU with the optimum configurations for the plasmonic metasensors. The phase singularity-induced GH shift is more than three orders of magnitude larger than those achievable in other metamaterial schemes, including Ag/TiO2 hyperbolic multilayer metamaterials (HMMs), metal–insulator–metal (MIM) multilayer waveguides with plasmon-induced transparency (PIT), and metasurface devices with a large phase gradient. GH sensitivity has been improved by more than 106 times with the atomically thin perovskite metasurfaces (1.2862 × 109 µm/RIU) than those without (918.9167 µm/RIU). The atomically thin perovskite nanomaterials with high absorption rates enable precise tuning of the depth of the plasmonic resonance dip. As such, one can optimize the structure to reach near zero-reflection at the resonance angle and the associated sharp phase singularity, which leads to a strongly enhanced GH lateral shift at the sensor interface. By integrating the 2D perovskite nanolayer into a metasurface structure, a strong localized electric field enhancement can be realized and GH sensitivity was further improved to 1.5458 × 109 µm/RIU. We believe that this enhanced electric field together with the significantly improved GH shift would enable single molecular or even submolecular detection for hard-to-identify chemical and biological markers, including single nucleotide mismatch in the DNA sequence, toxic heavy metal ions, and tumor necrosis factor-α (TNFα).

Tuning the Localized Surface Plasmon Resonance of Al-Al2O3 Nanosphere Towards NIR Region by Gold Coating

2020 ◽  
Vol 12 ◽  
Author(s):  
Jyoti Katyal ◽  
Shivani Gautam
Keyword(s):  
Electric Field ◽  
Field Distribution ◽  
Dielectric Layer ◽  
Electric Field Distribution ◽  
Active Material ◽  
Visible Region ◽  
Field Enhancement ◽  
Localized Surface Plasmon ◽  
Sers Substrate ◽  
Al Nanoparticles

Background: A relatively narrow LSPR peak and a strong inter band transition ranging around 800 nm makes Al strongly plasmonic active material. Usually, Al nanoparticles are preferred for UV-plasmonic as the SPR of small size Al nanoparticles locates in deep UV-UV region of the optical spectrum. This paper focused on tuning the LSPR of Al nanostructure towards infrared region by coating Au layer. The proposed structure has Au as outer layer which prevent the further oxidation of Al nanostructure. Methods: The Finite Difference Time Domain (FDTD) and Plasmon Hybridization Theory has been used to evaluated the LSPR and field enhancement of single and dimer Al-Al2O3-Au MDM nanostructure. Results: It is observed that the resonance mode show dependence on the thickness of Al2O3 layer and also on the composition of nanostructure. The Au layered MDM nanostructure shows two peak of equal intensities simultaneously in UV and visible region tuned to NIR region. The extinction spectra and electric field distribution profiles of dimer nanoparticles are compared with monomer to reveal the extent of coupling. The dimer configuration shows higher field enhancement ~107 at 1049 nm. By optimizing the thickness of dielectric layer the MDM nanostructure can be used over UV-visible-NIR region. Conclusion: The LSPR peak shows dependence on the thickness of dielectric layer and also on the composition of nanostructure. It has been observed that optimization of size and thickness of dielectric layer can provide two peaks of equal intensities in UV and Visible region which is advantageous for many applications. The electric field distribution profiles of dimer MDM nanostructure enhanced the field by ~107 in visible and NIR region shows its potential towards SERS substrate. The results of this study will provide valuable information for the optimization of LSPR of Al-Al2O3-Au MDM nanostructure to have high field enhancement.

scholarly journals Optically Induced Field-Emission Source Based on Aligned Vertical Carbon Nanotube Arrays

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1810
Author(s):  
Mengjie Li ◽  
Qilong Wang ◽  
Ji Xu ◽  
Jian Zhang ◽  
Zhiyang Qi ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Electric Field ◽  
Field Emission ◽  
Field Enhancement ◽  
Absorption Efficiency ◽  
Photon Absorption ◽  
Nanotube Arrays ◽  
Carbon Nanotube Arrays ◽  
Induced Field ◽  
Optically Induced

Due to the high field enhancement factor and photon-absorption efficiency, carbon nanotubes (CNTs) have been widely used in optically induced field-emission as a cathode. Here, we report vertical carbon nanotube arrays (VCNTAs) that performed as high-density electron sources. A combination of high applied electric field and laser illumination made it possible to modulate the emission with laser pulses. When the bias electric field and laser power density increased, the emission process is sensitive to a power law of the laser intensity, which supports the emission mechanism of optically induced field emission followed by over-the-barrier emission. Furthermore, we determine a polarization dependence that exhibits a cosine behavior, which verifies the high possibility of optically induced field emission.

scholarly journals Hyperspectral Molecular Orientation Mapping in Metamaterials

2021 ◽  
Vol 11 (4) ◽  
pp. 1544
Author(s):  
Meguya Ryu ◽  
Yoshiaki Nishijima ◽  
Shinya Morimoto ◽  
Naoki To ◽  
Tomoki Hashizume ◽  
...  
Keyword(s):  
Molecular Orientation ◽  
Field Enhancement ◽  
Chemical Mapping ◽  
Metal Insulator ◽  
Orientation Mapping ◽  
Metal Insulator Metal ◽  
Finger Printing ◽  
Thermal Emitter ◽  
Ir Bands ◽  
Sub Wavelength

The four polarisation method is adopted for measurement of molecular orientation in dielectric nanolayers of metal-insulator-metal (MIM) metamaterials composed of gold nanodisks on polyimide and gold films. Hyperspectral mapping at the chemical finger printing spectral range of 4–20 μμm was carried out for MIM patterns of 1–2.5 μμm period (sub-wavelength). Overlay images taken at 0,π4,π2,3π4 orientation angles and subsequent baseline compensation are shown to be critically important for the interpretation of chemical mapping results and reduction of spurious artefacts. Light field enhancement in the 60-nm-thick polyimide (I in MIM) was responsible for strong absorption at the characteristic polyimide bands. Strong absorbance A at narrow IR bands can be used as a thermal emitter (emittance E=1−R), where R is the reflectance and A=1−R−T, where for optically thick samples the transmittance is T=0.

scholarly journals Design of a Liquid-Crystal-Tunable Terahertz Demultiplexer Based on a Metal-Insulator-Metal Waveguide

2019 ◽  
Vol 9 (4) ◽  
pp. 644
Author(s):  
Xue-Shi Li ◽  
Naixing Feng ◽  
Yuan-Mei Xu ◽  
Liang-Lun Cheng ◽  
Qing Liu
Keyword(s):  
Liquid Crystal ◽  
Electric Field ◽  
Metal Insulator ◽  
Resonance Modes ◽  
External Bias ◽  
Bias Electric Field ◽  
Metal Waveguide ◽  
Metal Insulator Metal ◽  
Fabry Perot ◽  
Mim Waveguide

A tunable demultiplexer with three output channels infiltrated by liquid crystal (LC) is presented, which is based on a metal-insulator-metal (MIM) waveguide. The operating frequencies of the three output channels can be tuned simultaneously at will by changing the external bias electric field applied to the LC. By analyzing the Fabry-Pérot (FP) resonance modes of the finite-length MIM waveguide both theoretically and numerically, the locations of the three channels are delicately determined to achieve the best demultiplexing effects. Terahertz (THz) signals input from the main channel can be demultiplexed by channels 1, 2 and 3 at 0.7135 THz, 1.068 THz and 1.429 THz, respectively. By applying an external electric field to alter the tilt angle of the infiltrating LC material, the operating frequencies of channels 1, 2 and 3 can be relatively shifted up to 12.3%, 9.6% and 9.7%, respectively. The designed demultiplexer can not only provide a flexible means to demultiplex signals but also tune operating bands of output channels at the same time.

scholarly journals Study on surface enhanced Raman scattering of Au and Au@Al2O3 spherical dimers based on 3D finite element method

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Bao-xin Yan ◽  
Yan-ying Zhu ◽  
Yong Wei ◽  
Huan Pei
Keyword(s):  
Finite Element Method ◽  
Finite Element ◽  
Electric Field ◽  
Raman Scattering ◽  
Enhancement Factor ◽  
Field Enhancement ◽  
Electric Field Enhancement ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

AbstractIn this paper, the surface enhanced Raman scattering (SERS) characteristics of Au and Au@Al2O3 nanoparticle dimers were calculated and analyzed by using finite element method (3D-FEM). Firstly, the electric field enhancement factors of Au nanoparticles at the dimer gap were optimized from three aspects: the incident angle of the incident light, the radius of nanoparticle and the distance of the dimer. Then, aluminum oxide is wrapped on the Au dimer. What is different from the previous simulation is that Al2O3 shell and Au core are regarded as a whole and the total radius of Au@Al2O3 dimer is controlled to remain unchanged. By comparing the distance of Au nucleus between Au and Au@Al2O3 dimer, it is found that the electric field enhancement factor of Au@Al2O3 dimer is much greater than that of Au dimer with the increase of Al2O3 thickness. The peak of electric field of Au@Al2O3 dimer moves towards the middle of the resonance peak of the two materials, and it is more concentrated than that of the Au dimer. The maximum electric field enhancement factor 583 is reached at the shell thickness of 1 nm. Our results provide a theoretical reference for the design of SERS substrate and the extension of the research scope.

scholarly journals Broad range electric field enhancement of a plasmonic nanosphere heterodimer

2020 ◽  
Vol 10 (7) ◽  
pp. 1704
Author(s):  
Desalegn T. Debu ◽  
Qigeng Yan ◽  
Ahmad Aziz Darweesh ◽  
Mourad Benamara ◽  
Gregory Salamo
Keyword(s):  
Electric Field ◽  
Field Enhancement ◽  
Electric Field Enhancement

scholarly journals The Electrical Activity of Saharan Dust as perceived from Surface Electric Field Observations in Greece

2020 ◽  
Author(s):  
Vasiliki Daskalopoulou ◽  
Sotirios A. Mallios ◽  
Zbigniew Ulanowski ◽  
George Hloupis ◽  
Anna Gialitaki ◽  
...  
Keyword(s):  
Field Strength ◽  
Electric Field ◽  
Electric Field Strength ◽  
Field Enhancement ◽  
Electric Circuit ◽  
Saharan Dust ◽  
Backscatter Coefficient ◽  
Lidar System ◽  
Realistic Description ◽  
Atmospheric Conductivity

Abstract. We report on the electric field variations during Saharan dust advection over two atmospheric remote stations in Greece, using synergistic observations of the vertical atmospheric electric field strength (Ez) at ground and the lidar-derived particle backscatter coefficient profiles. Both parameters were monitored for the first time with the simultaneous deployment of a ground-based field mill electrometer and a multiwavelength lidar system. The field mill timeseries are processed to extract the diurnal variations of the Global Electric Circuit and remove fast field perturbations due to peak lightning activity. In order to identify the influence of the elevated dust layers on the ground Ez, we extract a Localized Reference Electric Field from the timeseries that reflects the local fair weather activity. Then, we compare it with the reconstructed daily average behaviour of the electric field and the Saharan dust layers' evolution, as depicted by the lidar system. Reported cases of enhanced vertical electric field for detached pure dust layers suggest the presence of in-layer electric charges. Although higher dust loads are expected to result in electric field enhancement, episodic cases that reduce the electric field are also observed. To quantitatively approach our results, we examine the dependency of Ez against theoretical assumptions for the distribution of separated charges within the electrified dust layer. Electrically neutral dust is approximated by atmospheric conductivity reduction, while charge separation areas within electrically active dust layers are approximated as finite extent cylinders. This physical approximation constitutes a more realistic description of the distribution of charges, as opposed to infinite extent geometries, and allows for analytical solutions of the electric field strength, so that observed electric field variations during the monitored dust outbreaks can be explained.

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