scholarly journals Pigeon Pea Husk for Removal of Emerging Contaminants Trimethoprim and Atenolol from Water

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3158
Author(s):  
Severin Eder ◽  
Manuel Torko ◽  
Alessia Montalbetti ◽  
Paride Azzari ◽  
Laura Nyström

The pace of industrialization and rapid population growth in countries such as India entail an increased input of industrial and sanitary organic micropollutants, the so‑called emerging contaminants (EC), into the environment. The emission of EC, such as pharmaceuticals, reaching Indian water bodies causes a detrimental effect on aquatic life and ultimately on human health. However, the financial burden of expanding sophisticated water treatment capacities renders complementary, cost‑efficient alternatives, such as adsorption, attractive. Here we show the merits of washed and milled pigeon pea husk (PPH) as low‑cost adsorbent for the removal of the EC trimethoprim (TMP) and atenolol (ATN) that are among the most detected pharmaceuticals in Indian waters. We found a linear increase in adsorption capacity of PPH for TMP and ATN at concentrations ranging from 10 to 200 μg/L and from 50 to 400 μg/L, respectively, reflecting the concentrations occurring in Indian water bodies. Investigation of adsorption kinetics using the external mass transfer model (EMTM) revealed that film diffusion resistance governed the adsorption process of TMP or ATN onto PPH. Moreover, analysis of the adsorption performance of PPH across an extensive range of pH and temperature illustrated that the highest adsorption loadings achieved concurred with actual conditions of Indian waters. We anticipate our work as starting point towards the development of a feasible adsorbent system aiming at low-cost water treatment.

2021 ◽  
Vol 12 (1) ◽  
pp. 149-169

The use of pesticides in agriculture reduces the loss of crops and increases crop productivity. Agricultural discharge into water bodies increases pesticide toxicity in water. A pesticide, when entered into water bodies, attacks non-targeting species, which disturbs the aquatic life. Because of low-cost taking, high material removal efficiency, low sludgy amount, and generated biomass for economic benefit, biological bioremediation methods are mostly preferred. Algae are used to remove pollutants from the environment or to convert them into harmless forms. Bioremediation by algae is highly preferred as biomass generated is used in biogas and biofuel production. Algae fix carbon dioxide (CO2) and release oxygen (O2) by photosynthesis and increase BOD (biological oxygen demand) in contaminated water. Therefore, it is necessary to reduce the use of pesticides or dispose of them in the best manner. To be on the safer side and make our water bodies less toxic, it is necessary to make efficient water treatment arrangements. This review paper is to discuss everything about pesticides and bioremediation, the use of microalgae and fungi for the treatment of water contaminated by pesticides, and the factors affecting pesticide bioremediation.


Author(s):  
Prof. Manish Sudhakarrao Deshmukh

The present work is designed to analyse the physico chemical properties of textile effluents and to evolve the effective and economically low-cost method for textile waste. Here the suitability of plants to remove containments are compared by two types of flow in which waste water is passed through the root zone by horizontal and vertical flow and suitability of plants to remove contaminant depends upon retention time or velocity of effluent which passes from one end to another end of the container. In India now a day, several efforts have been driven to control the pollution to enjoy the citizen, the disease-free environment. Mainly in this paper, we discuss about the pollution created by the Textile industry Effluent generated by this industry is one of the sources of pollution which contained air, soil and water. The main Contamination of soil and water bodies by the discharge of this industry are due to the Heavy metals & colour (dyes). This discharge if allowed on ground or water bodies, it percolates through the soil and pollute the fertile soil which effects the Agriculture and further this contaminates the ground water table and an aquatic life by toxication of water and this effects the human health and vegetation. The industry related with this study is of raw cotton based here cotton used is from ginning and pressing operation.


2018 ◽  
Vol 6 (3) ◽  
Author(s):  
Arie Herlambang

Clean water to poor communities who live in crowded municipal area is stillexpensive and a luxury. This condition is evidenced by the number of people whouse ground water for their daily water, because water taps still seems expensivefor them. Diarrheal disease is still relatively high for Indonesia, where nearly 16thousand people suffer from diarrhea due to poor sanitation. To help the poor inthe city, there are several alternative technologies that can be applied to publicaccess to clean water and adequate low-cost, including ground water treatmenttechnology with a filter system equipped with an ultraviolet sterilizer, or ozonegenerators, or using ultrafiltration, if possible can also use the reverse osmosismembrane that for fresh water. Arsinum is the best alternative should be chosenfor fulfilled potable water in slump area.Keywords : Sanitation, water treatment technology, portable water, low-cost, slump area


Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 215
Author(s):  
Nina Finčur ◽  
Paula Sfîrloagă ◽  
Predrag Putnik ◽  
Vesna Despotović ◽  
Marina Lazarević ◽  
...  

Pharmaceuticals and pesticides are emerging contaminants problematic in the aquatic environment because of their adverse effects on aquatic life and humans. In order to remove them from water, photocatalysis is one of the most modern technologies to be used. First, newly synthesized photocatalysts were successfully prepared using a sol–gel method and characterized by different techniques (XRD, FTIR, UV/Vis, BET and SEM/EDX). The photocatalytic properties of TiO2, ZnO and MgO nanoparticles were examined according to their removal from water for two antibiotics (ciprofloxacin and ceftriaxone) and two herbicides (tembotrione and fluroxypyr) exposed to UV/simulated sunlight (SS). TiO2 proved to be the most efficient nanopowder under UV and SS. Addition of (NH4)2S2O8 led to the faster removal of both antibiotics and herbicide fluroxypyr. The main intermediates were separated and identified for the herbicides and antibiotic ciprofloxacin. Finally, the toxicity of each emerging pollutant mixture and formed intermediates was assessed on wheat germination and biomass production.


Macromol ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 130-154
Author(s):  
Efstathios V. Liakos ◽  
Maria Lazaridou ◽  
Georgia Michailidou ◽  
Ioanna Koumentakou ◽  
Dimitra A. Lambropoulou ◽  
...  

Chitin is mentioned as the second most abundant and important natural biopolymer in worldwide scale. The main sources for the extraction and exploitation of this natural polysaccharide polymer are crabs and shrimps. Chitosan (poly-β-(1 → 4)-2-amino-2-deoxy-d-glucose) is the most important derivative of chitin and can be used in a wide variety of applications including cosmetics, pharmaceutical and biomedical applications, food, etc., giving this substance high value-added applications. Moreover, chitosan has applications in adsorption because it contains amino and hydroxyl groups in its molecules, and can thus contribute to many possible adsorption interactions between chitosan and pollutants (pharmaceuticals/drugs, metals, phenols, pesticides, etc.). However, it must be noted that one of the most important techniques of decontamination is considered to be adsorption because it is simple, low-cost, and fast. This review emphasizes on recently published research papers (2013–2021) and briefly describes the chemical modifications of chitosan (grafting, cross-linking, etc.), for the adsorption of a variety of emerging contaminants from aqueous solutions, and characterization results. Finally, tables are depicted from selected chitosan synthetic routes and the pH effects are discussed, along with the best-fitting isotherm and kinetic models.


2020 ◽  
Vol 18 (1) ◽  
pp. 1148-1166
Author(s):  
Ganjar Fadillah ◽  
Septian Perwira Yudha ◽  
Suresh Sagadevan ◽  
Is Fatimah ◽  
Oki Muraza

AbstractPhysical and chemical methods have been developed for water and wastewater treatments. Adsorption is an attractive method due to its simplicity and low cost, and it has been widely employed in industrial treatment. In advanced schemes, chemical oxidation and photocatalytic oxidation have been recognized as effective methods for wastewater-containing organic compounds. The use of magnetic iron oxide in these methods has received much attention. Magnetic iron oxide nanocomposite adsorbents have been recognized as favorable materials due to their stability, high adsorption capacities, and recoverability, compared to conventional sorbents. Magnetic iron oxide nanocomposites have also been reported to be effective in photocatalytic and chemical oxidation processes. The current review has presented recent developments in techniques using magnetic iron oxide nanocomposites for water treatment applications. The review highlights the synthesis method and compares modifications for adsorbent, photocatalytic oxidation, and chemical oxidation processes. Future prospects for the use of nanocomposites have been presented.


Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1804
Author(s):  
Guangmin Ren ◽  
Hongtao Han ◽  
Yixuan Wang ◽  
Sitong Liu ◽  
Jianyong Zhao ◽  
...  

Photocatalysis holds great promise as an efficient and sustainable oxidation technology for application in wastewater treatment. Rapid progress developing novel materials has propelled photocatalysis to the forefront of sustainable wastewater treatments. This review presents the latest progress on applications of photocatalytic wastewater treatment. Our focus is on strategies for improving performance. Challenges and outlooks in this promising field are also discussed. We hope this review will help researchers design low-cost and high-efficiency photocatalysts for water treatment.


2017 ◽  
Vol 18 (3) ◽  
pp. 843-852
Author(s):  
Travis D. Gardner ◽  
Joe D. Guggenberger

Abstract Ceramic pot filters (CPFs) are an effective point of use water treatment device in developing nations due to their low cost and effectiveness. CPFs are gravity fed, typically making water production a major limiting factor to a CPF's lifetime and acceptability. Directly connecting CPFs to in-line pumping systems or systems with an elevated storage tank would allow filter usage for constant water treatment at increased pressures, increasing the quantity of treated water. Ceramic disks were manufactured for testing in a specially designed housing apparatus. Filters of varying thicknesses and clay to sawdust mass ratios were manufactured to fit tightly. Flowrate and microbiological removal efficacy (logarithmic reduction value (LRV)) were determined over the testing period at various pressures. Flowrate values ranged from 2.44 to 9.04 L per hour, significantly higher than traditional CPF technology. LRVs ranged from 1.1 to 2.0, lower than traditional CPF technology but still effective at removing most Escherichia coli and total coliform bacteria. Filters proved effective at removing total and fecal coliforms at pressures less than 70 kilopascals. The optimum filter had a thickness of 3.2 cm and clay to sawdust ratio of 6:1 by mass. Filters proved to be ineffective if flowrates were above 5 L/h.


2015 ◽  
Vol 15 (8) ◽  
pp. 4131-4144 ◽  
Author(s):  
P. Wang ◽  
M. Allaart ◽  
W. H. Knap ◽  
P. Stammes

Abstract. A green light sensor has been developed at KNMI to measure actinic flux profiles using an ozonesonde balloon. In total, 63 launches with ascending and descending profiles were performed between 2006 and 2010. The measured uncalibrated actinic flux profiles are analysed using the Doubling–Adding KNMI (DAK) radiative transfer model. Values of the cloud optical thickness (COT) along the flight track were taken from the Spinning Enhanced Visible and Infrared Imager (SEVIRI) Cloud Physical Properties (CPP) product. The impact of clouds on the actinic flux profile is evaluated on the basis of the cloud modification factor (CMF) at the cloud top and cloud base, which is the ratio between the actinic fluxes for cloudy and clear-sky scenes. The impact of clouds on the actinic flux is clearly detected: the largest enhancement occurs at the cloud top due to multiple scattering. The actinic flux decreases almost linearly from cloud top to cloud base. Above the cloud top the actinic flux also increases compared to clear-sky scenes. We find that clouds can increase the actinic flux to 2.3 times the clear-sky value at cloud top and decrease it to about 0.05 at cloud base. The relationship between CMF and COT agrees well with DAK simulations, except for a few outliers. Good agreement is found between the DAK-simulated actinic flux profiles and the observations for single-layer clouds in fully overcast scenes. The instrument is suitable for operational balloon measurements because of its simplicity and low cost. It is worth further developing the instrument and launching it together with atmospheric chemistry composition sensors.


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