scholarly journals Technologies Employed in the Treatment of Water Contaminated with Glyphosate: A Review

Molecules ◽  
2020 ◽  
Vol 25 (23) ◽  
pp. 5550
Author(s):  
Patricio J. Espinoza-Montero ◽  
Carolina Vega-Verduga ◽  
Paulina Alulema-Pullupaxi ◽  
Lenys Fernández ◽  
Jose L. Paz

Glyphosate [N-(phosphonomethyl)-glycine] is a herbicide with several commercial formulations that are used generally in agriculture for the control of various weeds. It is the most used pesticide in the world and comprises multiple constituents (coadjutants, salts, and others) that help to effectively reach the action’s mechanism in plants. Due to its extensive and inadequate use, this herbicide has been frequently detected in water, principally in surface and groundwater nearest to agricultural areas. Its presence in the aquatic environment poses chronic and remote hazards to human health and the environment. Therefore, it becomes necessary to develop treatment processes to remediate aquatic environments polluted with glyphosate, its metabolites, and/or coadjutants. This review is focused on conventional and non-conventional water treatment processes developed for water polluted with glyphosate herbicide; it describes the fundamental mechanism of water treatment processes and their applications are summarized. It addressed biological processes (bacterial and fungi degradation), physicochemical processes (adsorption, membrane filtration), advanced oxidation processes—AOPs (photocatalysis, electrochemical oxidation, photo-electrocatalysis, among others) and combined water treatment processes. Finally, the main operating parameters and the effectiveness of treatment processes are analyzed, ending with an analysis of the challenges in this field of research.

2014 ◽  
Vol 12 (4) ◽  
pp. 601-617 ◽  
Author(s):  
Silvia Vlad ◽  
William B. Anderson ◽  
Sigrid Peldszus ◽  
Peter M. Huck

Anatoxin-a (ANTX-a) is a potent alkaloid neurotoxin, produced by several species of cyanobacteria and detected throughout the world. The presence of cyanotoxins, including ANTX-a, in drinking water sources is a potential risk to public health. This article presents a thorough examination of the cumulative body of research on the use of drinking water treatment technologies for extracellular ANTX-a removal, focusing on providing an analysis of the specific operating parameters required for effective treatment and on compiling a series of best-practice recommendations for owners and operators of systems impacted by this cyanotoxin. Of the oxidants used in drinking water treatment, chlorine-based processes (chlorine, chloramines and chlorine dioxide) have been shown to be ineffective for ANTX-a treatment, while ozone, advanced oxidation processes and permanganate can be successful. High-pressure membrane filtration (nanofiltration and reverse osmosis) is likely effective, while adsorption and biofiltration may be effective but further investigation into the implementation of these processes is necessary. Given the lack of full-scale verification, a multiple-barrier approach is recommended, employing a combination of chemical and non-chemical processes.


Molecules ◽  
2021 ◽  
Vol 26 (22) ◽  
pp. 6813
Author(s):  
Ángela Moratalla ◽  
Salvador Cotillas ◽  
Engracia Lacasa ◽  
Pablo Cañizares ◽  
Manuel A. Rodrigo ◽  
...  

The inefficiency of conventional biological processes to remove pharmaceutical compounds (PhCs) in wastewater is leading to their accumulation in aquatic environments. These compounds are characterized by high toxicity, high antibiotic activity and low biodegradability, and their presence is causing serious environmental risks. Because much of the PhCs consumed by humans are excreted in the urine, hospital effluents have been considered one of the main routes of entry of PhCs into the environment. In this work, a critical review of the technologies employed for the removal of PhCs in hospital wastewater was carried out. This review provides an overview of the current state of the developed technologies for decreasing the chemical risks associated with the presence of PhCs in hospital wastewater or urine in the last years, including conventional treatments (filtration, adsorption, or biological processes), advanced oxidation processes (AOPs) and electrochemical advanced oxidation processes (EAOPs).


Author(s):  
A.Yu. Kurbatov ◽  
E.N. Kuzin ◽  
Yu.M. Averina ◽  
M.A. Vetrova ◽  
A.V. Sitnikov

The paper aims to investigate hydrodynamic treatment processes of raw (artesian) groundwater to be used for household needs and drinking. The main advantage of hydrodynamic raw water treatment is that a single device, a so-called hydrodynamic vibration generator, is enough to perform the most important processing (deferrization, manganese removal, aeration) without any additional reactants. A hydrodynamic vibration generator contributes to accelerating mass exchange processes without using additional chemical reactants, solely by means of the kinetic energy inherent in the raw water flow undergoing treatment, which is generated when the hydrodynamic properties of the flow itself change dramatically. The generator by itself does not purify water; it processes raw water so as to derive insoluble products by recombining the forms in which the substances to be removed are found in the water, that is, by transforming dissolved manganese and iron compounds into insoluble compounds and decreasing carbon dioxide content in the water so as to precipitate insoluble calcium compounds. The resulting insoluble compounds are easy to remove via further processing in a ceramic membrane filtration system. Hydrodynamic vibration generator efficiency depends on many factors, which means that, when implementing hydrodynamic raw water treatment in real life, obtaining fundamental laws governing the treatment processes as functions of respective parametric characteristics is a necessary stage so as to ensure maximum efficiency. Our experiment confirmed that a phenomenon known as sonoluminescence occurs in raw water subjected to hydrodynamic treatment. We propose a monitoring technology indirectly confirming the efficiency of the hydrodynamic raw water treatment implemented, which is based on recording the sonoluminescence phenomenon via an acoustic technique


2021 ◽  
Vol 623 ◽  
pp. 119092
Author(s):  
Xiaolei Zhang ◽  
Xuedi Chai ◽  
Jianxin Liu ◽  
Runxin Wang ◽  
Yu Yang ◽  
...  

1983 ◽  
Vol 15 (S2) ◽  
pp. 95-101 ◽  
Author(s):  
E T Gjessing

For several reasons the surface waters in cold climate areas are coloured due to humic substances. There are two major objections against humus in drinking water, the first is concerned with aesthetical and practical problems and the second is due to indirect negative health effects. There are essentially three different methods in use today for the removal or reduction of humus colour in water: (1) Addition of chemicals with the intention of reducing the “solubility”, (2) Addition of chemicals in order to bleach or mineralize the humus, and (3) Filtration with the intention of removal of coloured particles and some of the “soluble” colour. The treatment processes are discussed.


1992 ◽  
Vol 26 (5-6) ◽  
pp. 1255-1264
Author(s):  
K. L. Martins

During treatment of groundwater, radon is often coincidentally removed by processes typically used to remove volatile organic compounds (VOCs)-for example, processes such as liquid-phase granular activated carbon (LGAC) adsorption and air stripping with vapor-phase carbon (VGAC). The removal of radon from drinking water is a positive benefit for the water user; however, the accumulation of radon on activated carbon may cause radiologic hazards for the water treatment plant operators and the spent carbon may be considered a low-level radioactive waste. To date, most literature on radon removal by water treatment processes was based on bench- or residential-scale systems. This paper addresses the impact of radon on municipal and industrial-scale applications. Available data have been used todevelop graphical methods of estimating the radioactivity exposure rates to facility operators and determine the fate of spent carbon. This paper will allow the reader to determine the potential for impact of radon on the system design and operation as follows.Estimate the percent removal of radon from water by LGAC adsorbers and packed tower air strippers. Also, a method to estimate the percent removal of radon by VGAC used for air stripper off-gas will be provided.Estimate if your local radon levels are such that the safety guidelines, suggested by USEPA (United States Environmental Protection Agency), of 25 mR/yr (0.1 mR/day) for radioactivity exposure may or may not be exceeded.Estimate the disposal requirements of the waste carbon for LGAC systems and VGAC for air stripper “Off-Gas” systems. Options for dealing with high radon levels are presented.


2000 ◽  
Vol 41 (7) ◽  
pp. 165-171 ◽  
Author(s):  
W. A. Hijnen ◽  
J. Willemsen-Zwaagstra ◽  
P. Hiemstra ◽  
G. J. Medema ◽  
D. van der Kooij

At eight full-scale water treatment plants in the Netherlands the removal of spores of sulphite-reducing clostridia (SSRC) was determined. By sampling and processing large volumes of water (1 up to 500 litres) SSRC were detected after each stage of the treatment. This enabled the assessment of the removal efficiency of the full-scale unit processes for persistent micro-organisms. A comparison with literature data on the removal of Cryptosporidium and Giardia by the same type of processes revealed that SSRC can be considered as a potential surrogate. The average Decimal Elimination Capacity (DEC) of the overall treatment plants ranged from 1.3–4.3 log. The observed actual log removal of SSRC by the unit processes and the overall treatment at one of the studied locations showed that the level of variation in removal efficiency was approximately 2 log. Moreover, from the actual log removal values it was observed that a low SSRC removal by one unit process is partly compensated by a higher removal by subsequent unit processes at this location. SSRC can be used for identification of the process conditions that cause variation in micro-organism removal which may lead to process optimization. Further research is necessary to determine the optimal use of SSRC in water quality monitoring for the production of microbiologically safe drinking water.


2021 ◽  
Vol 8 (3) ◽  
pp. 711-722
Author(s):  
Katherine E. Greenstein ◽  
Matthew R. Nagorzanski ◽  
Bailey Kelsay ◽  
Edgard M. Verdugo ◽  
Nosang V. Myung ◽  
...  

Electrospun carbon nanofibers with integrated titanium dioxide nanoparticles are used for water treatment in a photoactive membrane filtration system.


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