scholarly journals Preparation of 1-Hydroxy-2,5-hexanedione from HMF by the Combination of Commercial Pd/C and Acetic Acid

Molecules ◽  
2020 ◽  
Vol 25 (11) ◽  
pp. 2475 ◽  
Author(s):  
Yanliang Yang ◽  
Dexi Yang ◽  
Chi Zhang ◽  
Min Zheng ◽  
Ying Duan
Keyword(s):  
Aqueous Solution ◽  
Acetic Acid ◽  
Reaction Time ◽  
Catalytic System ◽  
Biomass Conversion ◽  
High Concentration ◽  
Influence Of Temperature ◽  
Catalyst Amount

The development of a simple and durable catalytic system for the production of chemicals from a high concentration of a substrate is important for biomass conversion. In this manuscript, 5-hydroxymethylfurfural (HMF) was converted to 1-hydroxy-2,5-hexanedione (HHD) using the combination of commercial Pd/C and acetic acid (AcOH) in water. The influence of temperature, H2 pressure, reaction time, catalyst amount and the concentration of AcOH and HMF on this transformation was investigated. A 68% yield of HHD was able to be obtained from HMF at a 13.6 wt% aqueous solution with a 98% conversion of HMF. The resinification of intermediates on the catalyst was characterized to be the main reason for the deactivation of Pd/C. The reusability of the used Pd/C was studied to find that most of the activity could be recovered by being washed in hot tetrahydrofuran.

scholarly journals Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2

2017 ◽  
Vol 2017 ◽  
pp. 1-7
Author(s):  
Shenggui Liu ◽  
Rongkai Pan ◽  
Guobi Li ◽  
Wenyi Su ◽  
Chunlin Ni
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Oxidation Reaction ◽  
Ruthenium Complex ◽  
Molar Ratio ◽  
Optimal Conditions ◽  
Reaction Conditions ◽  
Influence Of Temperature ◽  
Catalyst Amount ◽  
Optimal Reaction

A new ruthenium complex, Ru(bpbp)(pbb)Cl, based on 2,6-bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine (bpbp) and 2-(1-phenyl-1H-benzo[d]imidazol-2-yl)benzoate (pbb) was synthesized. The complex Ru(bpbp)(pbb)Cl could catalytically oxidize 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazol-2-yl)ethanone with H2O2 as oxidant. Influence of temperature and catalyst amount on the oxidation reaction was evaluated. The reaction optimal conditions are as follows: molar ratio of catalyst to substrate to H2O2 is 1 : 1000 : 3000, the proper reaction temperature is 50°C and reaction time lasts 5 h, and the isolated yield of 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazol-2-yl)ethanone under the optimal reaction conditions is 57%.

STUDIES ON CONTINUOUS ADSORPTION OF ACETIC ACID FROM AQUEOUS SOLUTION USING RICE HUSK ADSORBENT

2018 ◽  
Vol 14 (1) ◽  
pp. 42
Author(s):  
S. V. A. R. SASTRY ◽  
SRI ADIBATLA ANUSHA ◽  
S. VARUN ◽  
◽  
◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Acetic Acid ◽  
Rice Husk ◽  
Continuous Adsorption

An iron–nitrogen doped carbon and CdS hybrid catalytic system for efficient CO2 photochemical reduction

2021 ◽  
Vol 57 (16) ◽  
pp. 2033-2036
Author(s):  
Jin-Han Guo ◽  
Xiao-Yao Dao ◽  
Wei-Yin Sun
Keyword(s):  
Aqueous Solution ◽  
Catalytic System ◽  
Hybrid System ◽  
Photochemical Reduction ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon

A new iron–nitrogen doped carbon and CdS hybrid system was developed to efficiently reduce CO2 to CO under UV/vis light (AM 1.5G) irradiation in aqueous solution.

scholarly journals Leaching Titaniferous Magnetite Concentrate by Alkaline Aqueous Solution

2021 ◽  
Author(s):  
Ke Guo ◽  
Shaoyan Wang ◽  
Renfeng Song ◽  
Zhiqiang Zhang
Keyword(s):  
Aqueous Solution ◽  
Alkali Concentration ◽  
Water Usage ◽  
X Ray Diffraction ◽  
High Concentration ◽  
X Ray ◽  
Iron Concentrate ◽  
Titaniferous Magnetite ◽  
Magnetite Concentrate ◽  
Kinetics Of

AbstractLeaching titaniferous magnetite concentrate with alkali solution of high concentration under high temperature and high pressure was utilized to improve the grade of iron in iron concentrate and the grade of TiO2 in titanium tailings. The titaniferous magnetite concentrate in use contained 12.67% TiO2 and 54.01% Fe. The thermodynamics of the possible reactions and the kinetics of leaching process were analyzed. It was found that decomposing FeTiO3 with NaOH aqueous solution could be carried out spontaneously and the reaction rate was mainly controlled by internal diffusion. The effects of water usage, alkali concentration, reaction time, and temperature on the leaching procedure were inspected, and the products were characterized by X-ray diffraction, scanning electron microscope, and energy dispersive spectroscopy, respectively. After NaOH leaching and magnetic separation, the concentrate, with Fe purity of 65.98% and Fe recovery of 82.46%, and the tailings, with TiO2 purity of 32.09% and TiO2 recovery of 80.79%, were obtained, respectively.

Study on the Synthesis of Isoamyl Acetate Catalyzed by Strong Acidic Cation Exchange Resin

2011 ◽  
Vol 396-398 ◽  
pp. 2411-2415 ◽  
Author(s):  
Ping Lan ◽  
Li Hong Lan ◽  
Tao Xie ◽  
An Ping Liao
Keyword(s):  
Acetic Acid ◽  
Reaction Time ◽  
Cation Exchanger ◽  
Cation Exchange Resin ◽  
Isoamyl Acetate ◽  
Molar Ratio ◽  
Esterification Reaction ◽  
Reaction Conditions ◽  
Optimum Reaction

Isoamyl acetate was synthesized from isoamylol and glacial acetic acid with strong acidic cation exchanger as catalyst. The effects of reaction conditions such as acid-alcohol ratio, reaction time, catalyst dosage to esterification reaction have been investigated and the optimum reaction conditions can be concluded as: the molar ratio of acetic acid to isoamylol 0.8:1, reaction time 2h, 25 % of catalyst (quality of acetic acid as benchmark). The conversion rate can reach up to 75.46%. The catalytic ability didn’t reduce significantly after reusing 10 times and the results showed that the catalyst exhibited preferably catalytic activity and reusability.

Microwave Irradiated Acetylation of p-Anisidine: A Step towards Green Chemistry

2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Mousumi Chakraborty ◽  
Vaishali Umrigar ◽  
Parimal A. Parikh
Keyword(s):  
Acetic Acid ◽  
Reaction Time ◽  
Green Chemistry ◽  
Acetic Anhydride ◽  
Microwave Irradiation ◽  
Organic Solvent ◽  
Reaction Times ◽  
Microwave Energy ◽  
Operating Parameters ◽  
Feed Composition

The present study aims at assessing the effect of microwave irradiation against thermal heat on the production of N-acetyl-p-anisidine by acetylation of p-anisidine. The acetylation of p-anisidine under microwave irradiation produces N-acetyl-p-anisidine in shorter reaction times, which offers a benefit to the laboratories as well as industries. It also eliminates the use of excess solvent. Effects of operating parameters such as reaction time, feed composition, and microwave energy and reaction temperature on selectivity to the desired product have been investigated. The results indicate as high as a 98% conversion of N-acetyl-p-anisidine can be achieved within 12-15 minutes using acetic acid. The use of acetic acid as an acetylating agent against conventionally used acetic anhydride eliminates the handling of explosive acetic anhydride and also the energy intensive distillation step for separation of acetic acid. Organic solvent like acetic anhydride are not only hazardous to the environment, they are also expensive and flammable.

Experiments on the Kinetics of CO2 Loaded MDEA-DEA Aqueous Solution

2014 ◽  
Vol 955-959 ◽  
pp. 2306-2309
Author(s):  
Shu Bin Zhao ◽  
Pan Zhang ◽  
Xiao Tong Cai ◽  
Dong Fu
Keyword(s):  
Aqueous Solution ◽  
Mass Fraction ◽  
Absorption Rate ◽  
Normal Pressure ◽  
Influence Of Temperature ◽  
Kinetics Of

The absorption rates of CO2 in diethanolamine (DEA) promoted N-methyldiethanolamine (MDEA) aqueous solution were measured at normal pressure with temperatures ranging from 303.15-323.15K. The influence of temperature and the mass fraction of DEA on the absorption rate of CO2 was illustrated.

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