scholarly journals Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments

Molecules ◽  
2013 ◽  
Vol 18 (1) ◽  
pp. 1188-1213 ◽  
Author(s):  
Marco Blangetti ◽  
Heléna Rosso ◽  
Cristina Prandi ◽  
Annamaria Deagostino ◽  
Paolo Venturello
Keyword(s):  
Cross Coupling ◽  
Recent Developments ◽  
Acylation Reactions

ChemInform Abstract: Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments

ChemInform ◽  
2013 ◽  
Vol 44 (18) ◽  
pp. no-no
Author(s):  
Marco Blangetti ◽  
Helena Rosso ◽  
Cristina Prandi ◽  
Annamaria Deagostino ◽  
Paolo Venturello
Keyword(s):  
Cross Coupling ◽  
Recent Developments ◽  
Acylation Reactions

Recent Developments in C–C Bond Formation Using Catalytic Reductive Coupling Strategies

Synthesis ◽  
2020 ◽  
Vol 52 (18) ◽  
pp. 2623-2638
Author(s):  
Joshua D. Sieber ◽  
Toolika Agrawal
Keyword(s):  
Bond Formation ◽  
Cross Coupling ◽  
Short Review ◽  
Reductive Coupling ◽  
Recent Developments ◽  
Molecular Complexity ◽  
Metal Catalyzed ◽  
Coupling Processes ◽  
Coupling Strategies

Metal-catalyzed reductive coupling processes have emerged as a powerful methodology for the introduction of molecular complexity from simple starting materials. These methods allow for an orthogonal approach to that of redox-neutral strategies for the formation of C–C bonds by enabling cross-coupling of starting materials not applicable to redox-neutral chemistry. This short review summarizes the most recent developments in the area of metal-catalyzed reductive coupling utilizing catalyst turnover by a stoichiometric reductant that becomes incorporated in the final product.1 Introduction2 Ni Catalysis3 Cu Catalysis4 Ru, Rh, and Ir Catalysis4.1 Alkenes4.2 1,3-Dienes4.3 Allenes4.4 Alkynes4.5 Enynes5 Fe, Co, and Mn Catalysis6 Conclusion and Outlook

Silicon-Based Reagents for Difluoromethylation and Difluoromethylenation Reactions

Synthesis ◽  
2017 ◽  
Vol 49 (15) ◽  
pp. 3394-3406 ◽  
Author(s):  
Sankarganesh Krishnamoorthy ◽  
G. Prakash
Keyword(s):  
Nucleophilic Substitution ◽  
Oxidative Coupling ◽  
Nucleophilic Addition ◽  
Cross Coupling ◽  
Terminal Alkynes ◽  
Group Transfer ◽  
Recent Developments ◽  
Perfluoroalkyl Group ◽  
Activation Conditions ◽  
Silicon Based

There have been significant developments in the area of perfluoroalkyl group transfer using silicon reagents, specifically in nucleo­philic trifluoromethylation. The mild and versatile activation conditions bestow significant synthetic prowess to the silicon reagents in the area of fluoroalkylations. Owing to the importance of difluoromethylene (CF2) containing compounds in pharmaceuticals, materials, and agrochemicals, several CF2 group transfer methods using related silicon reagents have been developed and studied in detail. This review summarizes the recent developments and trends in this area.1 Introduction2 Trimethyl(trifluoromethyl)silane (Me3SiCF3)3 (Difluoromethyl)trimethylsilane (Me3SiCF2H)3.1 Nucleophilic Addition3.2 Nucleophilic Substitution3.3 Nucleophilic Difluoromethylation of Electron-Deficient Hetero­cycles3.4 Metal-Mediated Cross Coupling3.5 Oxidative Coupling of Terminal Alkynes4 Post-functionalizable Difluoromethyl Transfer Reagents4.1 (Chlorodifluoromethyl)trimethylsilane (Me3SiCF2Cl)4.2 (Bromodifluoromethyl)trimethylsilane (Me3SiCF2Br)4.3 [Difluoro(iodo)methyl]trimethylsilane (Me3SiCF2I)4.4 [Difluoro(phenylthio)methyl]trimethylsilane (Me3SiCF2SPh)4.5 [Difluoro(phenylsulfonyl)methyl]trimethylsilane (Me3SiCF2SO2Ph)4.6 Diethyl [Difluoro(trimethylsilyl)methyl]phosphonate [Me3SiCF2P(O)(OEt)2]4.7 Ethyl Difluoro(trimethylsilyl)acetate (Me3SiCF2CO2Et)4.8 Difluoro(trimethylsilyl)acetamides (Me3SiCF2CONR2)4.9 Difluoro(trimethylsilyl)acetonitrile (Me3SiCF2CN)5 Others6 Conclusions

Recent Developments in Radical Cross‐Coupling of Redox‐Active Cycloketone Oximes

2020 ◽  
Vol 363 (1) ◽  
pp. 120-143
Author(s):  
Fang Xiao ◽  
Yu Guo ◽  
Yao‐Fu Zeng
Keyword(s):  
Cross Coupling ◽  
Redox Active ◽  
Recent Developments

scholarly journals Recent advances in the application of nano-catalysts for Hiyama cross-coupling reactions

RSC Advances ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 3185-3202 ◽  
Author(s):  
Aazam Monfared ◽  
Robab Mohammadi ◽  
Sheida Ahmadi ◽  
Mohammad Nikpassand ◽  
Akram Hosseinian
Keyword(s):  
Cross Coupling ◽  
Metal Nanoparticle ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Recent Advances ◽  
Recent Developments ◽  
Nano Catalysts

This mini-review highlights the recent developments in the field of metal nanoparticle (NP) catalyzed Hiyama cross-coupling reactions.

Sonochemistry in Transition Metal Catalyzed Cross-coupling Reactions: Recent Developments

2020 ◽  
Vol 23 (28) ◽  
pp. 3137-3153 ◽  
Author(s):  
Sankuviruthiyil M. Ujwaldev ◽  
K. R. Rohit ◽  
Sankaran Radhika ◽  
Gopinathan Anilkumar
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Reaction Rates ◽  
Coupling Reactions ◽  
Reaction Conditions ◽  
Cross Coupling Reactions ◽  
Recent Developments ◽  
Ultrasound Assisted ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

: Transition metal catalyzed cross-coupling reactions have always been very important in synthetic organic chemistry due to their versatility in forming all sorts of carbon-carbon and carbon-hetero atom bonds. Incorporation of ultrasound assistance to these protocols resulted in milder reaction conditions, faster reaction rates, etc. This review focuses on the contributions made by ultrasound-assisted protocols towards transition metal catalyzed crosscoupling reactions.

C—O Selective Cross-Coupling of Chlorinated Phenol Derivatives

Synlett ◽  
2021 ◽  
Author(s):  
John E. A. Russell ◽  
Sharon Rose Neufeldt
Keyword(s):  
Oxidative Addition ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Dft Studies ◽  
Phenol Derivatives ◽  
Recent Developments

Chemoselective cross-coupling of phenol derivatives is valuable for generating products that retain halides. Here we discuss recent developments in selective cross couplings of chloroaryl phenol derivatives, with a particular focus on reactions of chloroaryl tosylates. The first example of a C—O-selective Ni-catalyzed Suzuki-Miyaura coupling of chloroaryl tosylates is discussed in detail. 1. Introduction 2. DFT Studies on Oxidative Addition at Ni(0) 3. Stoichiometric Oxidative Addition Studies 4. Development of a Tosylate-Selective Suzuki Coupling 5. Conclusion and Outlook

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