Recent Developments in Radical Cross‐Coupling of Redox‐Active Cycloketone Oximes

2020 ◽  
Vol 363 (1) ◽  
pp. 120-143
Author(s):  
Fang Xiao ◽  
Yu Guo ◽  
Yao‐Fu Zeng
Synthesis ◽  
2020 ◽  
Vol 52 (18) ◽  
pp. 2623-2638
Author(s):  
Joshua D. Sieber ◽  
Toolika Agrawal

Metal-catalyzed reductive coupling processes have emerged as a powerful methodology for the introduction of molecular complexity from simple starting materials. These methods allow for an orthogonal approach to that of redox-neutral strategies for the formation of C–C bonds by enabling cross-coupling of starting materials not applicable to redox-neutral chemistry. This short review summarizes the most recent developments in the area of metal-catalyzed reductive coupling utilizing catalyst turnover by a stoichiometric reductant that becomes incorporated in the final product.1 Introduction2 Ni Catalysis3 Cu Catalysis4 Ru, Rh, and Ir Catalysis4.1 Alkenes4.2 1,3-Dienes4.3 Allenes4.4 Alkynes4.5 Enynes5 Fe, Co, and Mn Catalysis6 Conclusion and Outlook


2016 ◽  
Vol 55 (33) ◽  
pp. 9676-9679 ◽  
Author(s):  
Jie Wang ◽  
Tian Qin ◽  
Tie-Gen Chen ◽  
Laurin Wimmer ◽  
Jacob T. Edwards ◽  
...  

ChemInform ◽  
2013 ◽  
Vol 44 (18) ◽  
pp. no-no
Author(s):  
Marco Blangetti ◽  
Helena Rosso ◽  
Cristina Prandi ◽  
Annamaria Deagostino ◽  
Paolo Venturello

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 703 ◽  
Author(s):  
Qi Li ◽  
Michael Horn ◽  
Yinong Wang ◽  
Jennifer MacLeod ◽  
Nunzio Motta ◽  
...  

Supercapacitors are a highly promising class of energy storage devices due to their high power density and long life cycle. Conducting polymers (CPs) and organic molecules are potential candidates for improving supercapacitor electrodes due to their low cost, large specific pseudocapacitance and facile synthesis methods. Graphene, with its unique two-dimensional structure, shows high electrical conductivity, large specific surface area and outstanding mechanical properties, which makes it an excellent material for lithium ion batteries, fuel cells and supercapacitors. The combination of CPs and graphene as electrode material is expected to boost the properties of supercapacitors. In this review, we summarize recent reports on three different CP/graphene composites as electrode materials for supercapacitors, discussing synthesis and electrochemical performance. Novel flexible and wearable devices based on CP/graphene composites are introduced and discussed, with an eye to recent developments and challenges for future research directions.


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