scholarly journals Cerium (IV) Ammonium Nitrate (CAN) Catalyzed One-pot Synthesis of 2-Arylbenzothiazoles

Molecules ◽  
2008 ◽  
Vol 13 (11) ◽  
pp. 2908-2914 ◽  
Author(s):  
Fawzia Al-Qalaf ◽  
Ramadan Mekheimer ◽  
Kamal Sadek
2016 ◽  
Vol 5 (4) ◽  
Author(s):  
Ramadan Ahmed Mekheimer ◽  
Abdullah Mohamed Asiri ◽  
Afaf Mohamed Abdel Hameed ◽  
Reham R. Awed ◽  
Kamal Usef Sadek

AbstractStarting from readily available 2-naphthol, aldehydes, aryl and alkylamines, a variety of Betti bases were efficiently synthesized utilizing a catalytic amount of cerium (IV) ammonium nitrate (CAN) at room temperature. This protocol has advantages of high yield, mild reaction conditions, no environmental pollution, diversity of reactants and simple work up procedure.


2010 ◽  
Vol 64 (6) ◽  
Author(s):  
Mazaahir Kidwai ◽  
Divya Bhatnagar

AbstractPolyethylene glycol was found to be an inexpensive non-toxic and effective medium for one pot synthesis of high yields of decahydroacridine-1,8-diones in the presence of ceric ammonium nitrate as the catalyst. Moreover, the solvent can be recovered and reused.


RSC Advances ◽  
2015 ◽  
Vol 5 (49) ◽  
pp. 39263-39269 ◽  
Author(s):  
Goutam Brahmachari ◽  
Bubun Banerjee

Ceric ammonium nitrate (CAN)-catalyzed one-pot synthesis of alkyl/aryl/heteroaryl-substituted bis(6-aminouracil-5-yl)methane scaffolds (3a–3u) has been developed via a pseudo three-component reaction in aqueous ethanol at room temperature.


Synlett ◽  
2006 ◽  
Vol 2006 (11) ◽  
pp. 1739-1743 ◽  
Author(s):  
René Roy ◽  
Sara Béha ◽  
Denis Giguère ◽  
Ramesh Patnam

2007 ◽  
Vol 85 (5) ◽  
pp. 400-405 ◽  
Author(s):  
Mazaahir Kidwai ◽  
Kavita Singhal

Dipyrimidine-fused pyridine derivatives were synthesized using 1,3-diketone, aldehyde, different ammonium salts, and water, as the solvent. Aromatization was observed when ammonium nitrate was used as the source of nitrogen, and thus, dipyrimidine-fused pyridine derivatives were synthesized in one-pot synthetic procedure. This environmentally benign procedure leads to high yield of products (80%–90%) in a single step, with greater purity using water as the solvent.Key words: water, aromatization, dipyrimidopyridine, ammonium salts.


2019 ◽  
Vol 23 (16) ◽  
pp. 1771-1777 ◽  
Author(s):  
Mohamed S. Behalo ◽  
Abdelmotaal Abdelmajeid ◽  
Aly A. Aly ◽  
Kaouser A. Hebash ◽  
Enas A. Mohamed

An efficient and facile synthesis of substituted pyrimidine derivatives through Biginelli type reaction was achieved in high yields via one-pot reaction of aromatic aldehydes, active methylene compounds and urea or thiourea in the presence of choline chloride- urea mixture as a deep eutectic solvent or cerium (IV) ammonium nitrate (CAN) as a catalyst at different conditions. The reaction was carried out using different ratio of CAN in different solvents to determine the optimum conditions. In addition, 2-mercapto-6-oxo- 4-(thiophen-2-yl)-1,6-dihydropyrimidine-5-carbonitrile was employed in the synthesis of pyrimidinylhydrazide and its corresponding hydrazone. The structural formula of all derivatives was confirmed and characterized by their elemental analyses and spectral data (IR, MS, 1H NMR, 13C NMR).


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