scholarly journals Selective Separation of Arsenic from Lead Smelter Flue Dust by Alkaline Pressure Oxidative Leaching

Minerals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 308 ◽  
Author(s):  
Wei Liu ◽  
Zihan Li ◽  
Junwei Han ◽  
Wenhua Li ◽  
Xun Wang ◽  
...  
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Leach Solution ◽  
Selective Separation ◽  
Lead Smelter ◽  
Solid Ratio ◽  
Flue Dust ◽  
Calcium Arsenate ◽  
Oxidative Leaching ◽  
Leaching Efficiency

This study investigated the feasibility of using an alkaline pressure oxidative leaching process to treat lead smelter flue dust containing extremely high levels of arsenic with the aim of achieving the selective separation of arsenic. The effects of different parameters including NaOH concentration, oxygen partial pressure, liquid-to-solid ratio, temperature, and time for the extraction of arsenic were investigated based on thermodynamic calculation. The results indicated that the leaching efficiency of arsenic reached 95.6% under the optimized leaching conditions: 80 g/L of NaOH concentration, 1.0 MPa of oxygen partial pressure, 8 mL/g of liquid-to-solid ratio, 120 °C of temperature, 2.0 h of time. Meanwhile, the leaching efficiencies of antimony, cadmium, indium and lead were less than 4.0%, basically achieving the selective separation of arsenic from lead smelter flue dust. More than 99.0% of arsenic was converted into calcium arsenate product and thus separated from the leach solution by a causticization process with CaO after other metal impurities were removed from the solution with the addition of Na2S. The optimized causticization conditions were established as: 4.0 of the mole ratio of calcium to arsenic, temperature of 80 °C, reaction time of 2.0 h. The resulting product of calcium arsenate may be used for producing metallic arsenic.

scholarly journals Oxidative Leaching of Vanadium from Vanadium-Chromium Reducing Residue with MnO2

2019 ◽  
Author(s):  
Hao Peng ◽  
Liu Yang ◽  
Ya Chen ◽  
Jing Guo
Keyword(s):  
Reaction Time ◽  
Alkaline Medium ◽  
Reaction Temperature ◽  
Reaction Conditions ◽  
Solid Ratio ◽  
Leaching Process ◽  
Experimental Parameters ◽  
Oxidative Leaching ◽  
Optimal Reaction ◽  
Leaching Efficiency

This paper focused on the oxidative leaching process of vanadium from vanadium-chromium reducing residue in alkaline medium with MnO2. The effect of experimental parameters including reaction time, reaction temperature, dosage of MnO2, dosage of NaOH, and liquid-to-solid ratio on the leaching efficiency of vanadium had been studied. The results indicated that MnO2 was an efficient oxidant for leaching out of vanadium. The leaching efficiency of vanadium was up to 97.25% under optimal reaction conditions: reaction temperature of 90 ℃, reaction time of 60 min, dosage of MnO2 at 50 wt.%, concentration of NaOH at 30 wt.% and liquid-to-solid at 5:1 mL/g.

scholarly journals Effect of Hot-Dip Galvanizing Process on Selective Oxidation and Galvanizability of Medium Manganese Steel for Automotive Application

Coatings ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1265
Author(s):  
Zhang Chen ◽  
Yanlin He ◽  
Weisen Zheng ◽  
Hua Wang ◽  
Yu Zhang ◽  
...  
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Surface Oxidation ◽  
Steel Sample ◽  
Dew Point ◽  
Manganese Steel ◽  
Automotive Application ◽  
Stable Phase ◽  
Annealing Atmosphere ◽  
Medium Manganese Steel

A medium manganese steel with 7.5 wt.% Mn for automobile application was galvanized in a continuous Hot Dip Galvanizing (HDG) simulator under different galvanizing conditions. It was shown that the effects of dew point, annealing temperature and annealing atmosphere on the surface oxidation of steel could be comprehensively evaluated by the consideration of oxygen partial pressure P(O2). Although Mn2SiO4 was a thermodynamic stable phase when P(O2) varied from 10−28 to 10−21 atm, it was difficult to form Mn–Si–O composite oxide because there was no enrichment of silicon on the steel surface. So, this oxide was generally formed in the Fe substrate and had little effect on the galvanizability. With the increase in P(O2) above 10−25 atm, MnO particles in the form of the thermodynamic stable phase became coarser and tended to aggregate, which hindered the formation of a continuous inhibition layer, resulting in the defects of bare spots on the galvanized surface of the steel. When the oxygen partial pressure greater than 10−22 atm, film-like MnO layer was formed on the surface of steel sample, which obviously deteriorated the galvanizability. The galvanizability of the steel can be improved by the regulation of oxygen partial pressure; based on this, the reasonable zinc plating process parameters can be developed.

Quantitative evaluation of the oxidation behavior of ZrB2-15 vol.%SiC at a low oxygen partial pressure

Vacuum ◽  
2013 ◽  
Vol 88 ◽  
pp. 98-102 ◽  
Author(s):  
Ai Momozawa ◽  
Rong Tu ◽  
Takashi Goto ◽  
Yuuki Kubota ◽  
Hiroshi Hatta ◽  
...  
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Quantitative Evaluation ◽  
Oxidation Behavior ◽  
Low Oxygen

Decrease in Resistance of Ceria Oxygen Sensor Induced by 10 mol% Hf and Zr Doping

2005 ◽  
Vol 888 ◽  
Author(s):  
Noriya Izu ◽  
Woosuck Shin ◽  
Ichiro Matsubara ◽  
Norimitsu Murayama
Keyword(s):  
Solid State ◽  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Solid State Reaction ◽  
Pressure Range ◽  
Oxygen Sensor ◽  
Cubic Phase ◽  
Doped Ceria ◽  
Oxygen Gas ◽  
Resistive Type

ABSTRACTResistive type sensors using 10 mol% Hf-doped ceria and 10 mol% Zr-doped ceria, which had a single cubic phase obtained by solid state reaction, were fabricated and their sensing properties were investigated. The resistance and resistivity of the 10 mol% Hf-doped ceria or 10 mol% Zr-doped ceria were smaller than those of non-doped ceria. In the case of the same temperature of solid state reaction, the resistance and resistivity of the 10 mol% Hf-doped ceria were much smaller than those of the 10 mol% Zr-doped ceria. Furthermore, in the case of the same dopant, the resistance and resistivity of the sensor prepared from the solid state reaction at 1773 K were much smaller than those at 1673 K. The sensor using the 10 mol% Hf-doped ceria could be used as an oxygen gas sensor in wide oxygen partial pressure range and could be applicable to a λ sensor and a universal A/F sensor.

Sign in / Sign up

Export Citation Format

Share Document