HIGH ALUMINA REFRACTORIES DEGRADATION AS FUNCTION OF OXYGEN PARTIAL PRESSURE IN SOAKING-PITS FURNACES

1986 ◽  
Vol 47 (C1) ◽  
pp. C1-575-C1-580
Author(s):  
E. CRIADO ◽  
F. J. VALLE ◽  
A. CABALLERO
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
High Alumina

scholarly journals Precious metal recoveries in secondary copper smelting with high-alumina slags

2019 ◽  
Vol 22 (3) ◽  
pp. 642-655 ◽  
Author(s):  
Katri Avarmaa ◽  
Hugh O’Brien ◽  
Lassi Klemettinen ◽  
Pekka Taskinen
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Copper Alloy ◽  
Trace Element Analysis ◽  
Precious Metals ◽  
Copper Smelting ◽  
High Alumina ◽  
Element Analysis ◽  
Gold Silver ◽  
Secondary Copper Smelting

AbstractWaste electrical and electronic equipment (WEEE) represents a significant urban resource for precious metals. To maximize the recoveries and sustainable use of these metals, their behavior needs to be characterized in the secondary copper smelting of WEEE. The current study experimentally determined the distributions of gold, silver, platinum and palladium between copper alloy and FeOx–SiO2–Al2O3/FeOx–SiO2–Al2O3–CaO slags (LCu/s[M] = [M]Copper/[M]Slag) over the oxygen partial pressure range of 10−5 – 10−10 atm at 1300 °C. In addition, the equilibria of copper alloy, slag and Al–Fe spinel system are presented and discussed. The experiments were conducted employing an equilibration—drop-quenching technique followed by major element analysis with Electron Probe MicroAnalysis (EPMA) and trace element analysis with sensitive Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). The results showed that the distribution coefficient of silver increased from 10 to 103 as a function of decreasing oxygen partial pressure. For gold, platinum and palladium, the distribution coefficients were at minimum 105. Lime addition improved the recovery of silver notably and had a small positive effect on gold recovery into copper. Overall, the precious metals can be recovered very efficiently in copper alloy via secondary copper smelting with alumina-rich iron-silicate slags.

scholarly journals Effect of Hot-Dip Galvanizing Process on Selective Oxidation and Galvanizability of Medium Manganese Steel for Automotive Application

Coatings ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1265
Author(s):  
Zhang Chen ◽  
Yanlin He ◽  
Weisen Zheng ◽  
Hua Wang ◽  
Yu Zhang ◽  
...  
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Surface Oxidation ◽  
Steel Sample ◽  
Dew Point ◽  
Manganese Steel ◽  
Automotive Application ◽  
Stable Phase ◽  
Annealing Atmosphere ◽  
Medium Manganese Steel

A medium manganese steel with 7.5 wt.% Mn for automobile application was galvanized in a continuous Hot Dip Galvanizing (HDG) simulator under different galvanizing conditions. It was shown that the effects of dew point, annealing temperature and annealing atmosphere on the surface oxidation of steel could be comprehensively evaluated by the consideration of oxygen partial pressure P(O2). Although Mn2SiO4 was a thermodynamic stable phase when P(O2) varied from 10−28 to 10−21 atm, it was difficult to form Mn–Si–O composite oxide because there was no enrichment of silicon on the steel surface. So, this oxide was generally formed in the Fe substrate and had little effect on the galvanizability. With the increase in P(O2) above 10−25 atm, MnO particles in the form of the thermodynamic stable phase became coarser and tended to aggregate, which hindered the formation of a continuous inhibition layer, resulting in the defects of bare spots on the galvanized surface of the steel. When the oxygen partial pressure greater than 10−22 atm, film-like MnO layer was formed on the surface of steel sample, which obviously deteriorated the galvanizability. The galvanizability of the steel can be improved by the regulation of oxygen partial pressure; based on this, the reasonable zinc plating process parameters can be developed.

Quantitative evaluation of the oxidation behavior of ZrB2-15 vol.%SiC at a low oxygen partial pressure

Vacuum ◽  
2013 ◽  
Vol 88 ◽  
pp. 98-102 ◽  
Author(s):  
Ai Momozawa ◽  
Rong Tu ◽  
Takashi Goto ◽  
Yuuki Kubota ◽  
Hiroshi Hatta ◽  
...  
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Quantitative Evaluation ◽  
Oxidation Behavior ◽  
Low Oxygen

Decrease in Resistance of Ceria Oxygen Sensor Induced by 10 mol% Hf and Zr Doping

2005 ◽  
Vol 888 ◽  
Author(s):  
Noriya Izu ◽  
Woosuck Shin ◽  
Ichiro Matsubara ◽  
Norimitsu Murayama
Keyword(s):  
Solid State ◽  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Solid State Reaction ◽  
Pressure Range ◽  
Oxygen Sensor ◽  
Cubic Phase ◽  
Doped Ceria ◽  
Oxygen Gas ◽  
Resistive Type

ABSTRACTResistive type sensors using 10 mol% Hf-doped ceria and 10 mol% Zr-doped ceria, which had a single cubic phase obtained by solid state reaction, were fabricated and their sensing properties were investigated. The resistance and resistivity of the 10 mol% Hf-doped ceria or 10 mol% Zr-doped ceria were smaller than those of non-doped ceria. In the case of the same temperature of solid state reaction, the resistance and resistivity of the 10 mol% Hf-doped ceria were much smaller than those of the 10 mol% Zr-doped ceria. Furthermore, in the case of the same dopant, the resistance and resistivity of the sensor prepared from the solid state reaction at 1773 K were much smaller than those at 1673 K. The sensor using the 10 mol% Hf-doped ceria could be used as an oxygen gas sensor in wide oxygen partial pressure range and could be applicable to a λ sensor and a universal A/F sensor.

Changes in Transcutaneous Oxygen Partial Pressure as an Index of Response to Inhaled Methacholine in Asthmatic Patients

CHEST Journal ◽  
1993 ◽  
Vol 103 (5) ◽  
pp. 1375-1380 ◽  
Author(s):  
Giovanni A. Fontana ◽  
Salvatore Cardellicchio ◽  
Gianna Camiciottoli ◽  
Pasquale Panuccio ◽  
Wien Boddi
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Transcutaneous Oxygen ◽  
Asthmatic Patients
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