scholarly journals Use of Phosphate Solubilizing Bacteria to Leach Rare Earth Elements from Monazite-Bearing Ore

Minerals ◽  
2015 ◽  
Vol 5 (2) ◽  
pp. 189-202 ◽  
Author(s):  
Doyun Shin ◽  
Jiwoong Kim ◽  
Byung-su Kim ◽  
Jinki Jeong ◽  
Jae-chun Lee
2021 ◽  
Author(s):  
Laura Castro ◽  
M. Luisa Blázquez ◽  
Felisa González ◽  
Jesús A. Muñoz

Rare earth elements (REEs) are critical raw materials and are attracting interest because of their applications in novel technologies and green economy. Biohydrometallurgy has been used to extract other base metals; however, bioleaching studies of REE mineral extraction from mineral ores and wastes are yet in their infancy. Mineral ores have been treated with a variety of microorganisms. Phosphate-solubilizing microorganims are particularly relevant in the bioleaching of monazite because transform insoluble phosphate into more soluble form which directly and/or indirectly contributes to their metabolism. The increase of wastes containing REEs turns them into an important alternative source. The application of bioleaching techniques to the treatment of solid wastes might contribute to the conversion towards a more sustainable and environmental friendly economy minimizing the amount of tailings or residues that exert a harmful impact on the environment.


Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 978
Author(s):  
Laura Castro ◽  
Maria Luisa Blázquez ◽  
Felisa González ◽  
Jesús Angel Muñoz

Rare earth elements (REE) are essential in high-technology and environmental applications, where their importance and demand have grown enormously over the past decades. Many lanthanide and actinide minerals in nature are phosphates. Minerals like monazite occur in small concentrations in common rocks that resist weathering. Turquoise is a hydrous phosphate of copper and aluminum scarcely studied as copper ore. Phosphate-solubilizing microorganisms are able to transform insoluble phosphate into a more soluble form which directly and/or indirectly contributes to their metabolism. In this study, bioleaching of heavy metals from phosphate minerals by using the fungus Aspergillus niger was investigated. Bioleaching experiments were examined in batch cultures with different mineral phosphates: aluminum phosphate (commercial), turquoise, and monazite (natural minerals). The experiments were performed at 1% pulp density and the phosphorous leaching yield was aluminum phosphate > turquoise > monazite. Bioleaching experiments with turquoise showed that A. niger was able to reach 8.81 mg/l of copper in the aqueous phase. Furthermore, the fungus dissolved the aluminum cerium phosphate hydroxide in monazite, reaching up to 1.37 mg/L of REE when the fungus was grown with the mineral as the sole phosphorous source. Furthermore, A. niger is involved in the formation of secondary minerals, such as copper and REE oxalates.


2017 ◽  
Vol 262 ◽  
pp. 294-298 ◽  
Author(s):  
Melissa K. Corbett ◽  
Jacques J. Eksteen ◽  
Xi Zhi Niu ◽  
Elizabeth L.J. Watkin

A large number of microbial species commonly called phosphate solubilizing microorganisms (PSMs) are efficient at converting insoluble phosphate to soluble forms to prevent phosphorus limitation. This study examined the impact that PSMs had on a sterile and non-sterile monazite source and determined that they could be applied for bioleaching purposes to recover rare earth elements (REEs). On sterile monazite, Penicillum sp. released a total REE concentration of 12.32 mg L-1 after incubation for 8 days, however, this doubled when inoculated on to non-sterile ore (23.7 mg L-1). Similar results were recorded with Enterobacter aerogenes, Pantoea agglomerans and Pseudomonas putida. Abiotic controls leached a total REE level of 0.65 mg L-1. Examination of the leachate by HPLC identified several low molecular weight organic acids that corresponded with decreases in the media pH. The presence of a native consortia from the monazite ore combined with a known PSMs was more effective at leaching REEs from the monazite matrix than a single isolates or by the native population alone.


1962 ◽  
Vol 18 (4) ◽  
pp. 1127-1153
Author(s):  
V FASSEL ◽  
R CURRY ◽  
R KNISELEY

2020 ◽  
Vol 4 (2) ◽  
pp. 599-604
Author(s):  
Michael A. Onoja ◽  
P. H. Bukar ◽  
C. U. Omeje ◽  
A. M. Adamu

Instrumental neutron activation analysis (INAA) technique was used to investigate the abundance and distribution of rare earth elements (REE) in soil around Kaduna Refinery. The aim of the study is to assess the rare elements potential of Nigeria for economic exploitation. Five REEs (La, Dy, Eu, Yb, and Lu) were detected in varying concentrations ranging from a minimum of 0.6 µg/g (Lu) to a maximum of 249.0 µg/g (La). The elements existed with trends consistent with the natural pattern of REEs in soil, showing significant Eu and Dy anomalies which characterize upper plains and flood plains. The levels of REEs in soil in the study area were generally slightly above background levels, with minimal (La, Dy, and Eu), moderate (Yb), and significant (Lu) enrichments and trending: Lu ˃Yb ˃ Eu ˃ Dy ˃ La. The abundance of the REEs investigated cannot establish a potential of Nigeria for economic exploitation of the mineral, hence, rare earth project in the study area is not viable at the moment.


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