scholarly journals REE Tetrad Effect and Sr-Nd Isotope Systematics of A-Type Pirrit Hills Granite from West Antarctica

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 792
Author(s):  
Hyo Min Lee ◽  
Seung-Gu Lee ◽  
Hyeoncheol Kim ◽  
Jong Ik Lee ◽  
Mi Jung Lee

The Pirrit Hills are located in the Ellsworth–Whitmore Mountains of West Antarctica. The Pirrit Hills granite exhibits significant negative Eu anomalies (Eu/Eu* = 0.01~0.25) and a REE tetrad effect indicating intensive magmatic differentiation. Whole-rock Rb-Sr and Sm-Nd geochronologic analysis of the Pirrit Hills granite gave respective ages of 172.8 ± 2.4 Ma with initial 87Sr/86Sr = 0.7065 ± 0.0087 Ma and 169 ± 12 Ma with initial 144Nd/143Nd = 0.512207 ± 0.000017. The isotopic ratio data indicate that the Pirrit Hills granite formed by the remelting of Mesoproterozoic mantle-derived crustal materials. Both chondrite-normalized REE patterns and Sr-Nd isotopic data indicate that the Pirrit Hills granite has geochemical features of chondrite-normalized REE patterns indicating that REE tetrad effects and negative Eu anomalies in the highly fractionated granites were produced from magmatic differentiation under the magmatic-hydrothermal transition system.

1989 ◽  
Vol 26 (3) ◽  
pp. 446-466 ◽  
Author(s):  
Kenneth D. Collerson ◽  
Malcolm T. McCulloch ◽  
Allan P. Nutman

Sr and Nd isotopic data for middle to late Archean polymetamorphic felsic gneisses from localities in the Nuuk area, West Greenland, are compared and contrasted with new isotopic results for early Archean Amîtsoq gneisses and with data for isotopically reworked Kiyuktok gneisses from the Saglek area, Labrador. Sr isotopic data for individual suites of felsic gneisses record the time-integrated effect of variable Rb–Sr fractionation during prograde and retrograde events as well as the effect of source inhomogeneity.Contrasting petrologic and Sr–Nd isotopic characteristics are the result of differences in level of exposure, caused partially by juxtaposition of terranes of different metamorphic character by movement on ductile shear zones and post-shearing folding deformation. Sm–Nd systematics of felsic gneisses from Nordafar, Ikerasakitsup akornga, Tinissaq, and Kangimut sammisoq – Qasigianguit define a geologically meaningless ca. 3280 Ma Nd "isochron", which is the result of mixing of samples from unrelated suites and the effect of open-system behaviour. Gneisses lying on this pseudoisochron were variably affected by ca. 2800–2900 Ma prograde granulite-facies metamorphism and structurally controlled retrogression under amphibolite- to greenschist-facies conditions.The study shows that Sr–Nd isotope systematics of geologically identifiable units may be modified by open-system behaviour during prograde and retrograde metamorphism. Isotopic data from gneiss complexes metamorphosed under granulite-facies conditions may therefore yield equivocal information concerning isochron interpretation, significance of model ages, and estimates of crustal residence time.


Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 326
Author(s):  
Tae-Hyeon Kim ◽  
Seung-Gu Lee ◽  
Jae-Young Yu

Carbonate formations of the Cambro-Ordovician Period occur in the Taebaek and Jeongseon areas, located in the central–eastern part of the Korean Peninsula. This study analyzed the rare earth element (REE) contents and Sr–Nd isotope ratios in these carbonates to elucidate their depositional environment and diagenetic history. The CI chondrite-normalized REE patterns of the carbonates showed negative Eu anomalies (EuN/(SmN × GdN)1/2 = 0.50 to 0.81), but no Ce anomaly (Ce/Ce* = CeN/(LaN2 × NdN)1/3 = 1.01 ± 0.06). The plot of log (Ce/Ce*) against sea water depth indicates that the carbonates were deposited in a shallow-marine environment such as a platform margin. The 87Sr/86Sr ratios in both Taebaek and Jeongseon carbonates were higher than those in the seawater at the corresponding geological time. The 87Sr/86Sr ratios and the values of (La/Yb)N and (La/Sm)N suggest that the carbonates in the areas experienced diagenetic processes several times. Their 143Nd/144Nd ratios varied from 0.511841 to 0.511980. The low εNd values and high 87Sr/86Sr ratios in the carbonates may have resulted from the interaction with the hydrothermal fluid derived from the intrusive granite during the Cretaceous Period.


Author(s):  
James Flinders ◽  
John D. Clemens

ABSTRACT:Most natural systems display non-linear dynamic behaviour. This should be true for magma mingling and mixing processes, which may be chaotic. The equations that most nearly represent how a chaotic natural system behaves are insoluble, so modelling involves linearisation. The difference between the solution of the linearised and ‘true’ equation is assumed to be small because the discarded terms are assumed to be unimportant. This may be very misleading because the importance of such terms is both unknown and unknowable. Linearised equations are generally poor descriptors of nature and are incapable of either predicting or retrodicting the evolution of most natural systems. Viewed in two dimensions, the mixing of two or more visually contrasting fluids produces patterns by folding and stretching. This increases the interfacial area and reduces striation thickness. This provides visual analogues of the deterministic chaos within a dynamic magma system, in which an enclave magma is mingling and mixing with a host magma. Here, two initially adjacent enclave blobs may be driven arbitrarily and exponentially far apart, while undergoing independent (and possibly dissimilar) changes in their composition. Examples are given of the wildly different morphologies, chemical characteristics and Nd isotope systematics of microgranitoid enclaves within individual felsic magmas, and it is concluded that these contrasts represent different stages in the temporal evolution of a complex magma system driven by nonlinear dynamics. If this is true, there are major implications for the interpretation of the parts played by enclaves in the genesis and evolution of granitoid magmas.


2008 ◽  
Vol 461 (1-4) ◽  
pp. 202-214 ◽  
Author(s):  
Rafael López-Guijarro ◽  
Maider Armendáriz ◽  
Cecilio Quesada ◽  
Javier Fernández-Suárez ◽  
J. Brendan Murphy ◽  
...  

Lithos ◽  
2017 ◽  
Vol 290-291 ◽  
pp. 48-59 ◽  
Author(s):  
Marco G. Malusà ◽  
Jiangang Wang ◽  
Eduardo Garzanti ◽  
Zhi-Chao Liu ◽  
Igor M. Villa ◽  
...  

1989 ◽  
Vol 26 (5) ◽  
pp. 956-968 ◽  
Author(s):  
D. B. Clarke ◽  
B. I. Cameron ◽  
G. K. Muecke ◽  
J. L. Bates

Fine- to medium-grained, phyric and aphyric basalt samples from ODP Leg 105, site 647A, in the Labrador Sea show little evidence of alteration. Chemically, these rocks are low-potassium (0.01–0.09 wt.% K2O), olivine- to quartz-normative tholeiites that compare closely with the very depleted terrestrial Paleocene volcanic rocks in the Davis Strait region of Baffin Island and West Greenland. However, differences exist in the Sr–Nd isotope systematics of the two suites; the Labrador Sea samples have ε Nd values (+9.3) indicative of a more depleted source, and are higher in 87Sr/86Sr (0.7040), relative to the Davis Strait basalts (ε Nd +2.54 to +8.97; mean 87Sr/86Sr 0.7034). The higher 87Sr/86Sr in the Labrador Sea samples may reflect seawater exchange despite no petrographic evidence for significant alteration. The Labrador Sea and early Davis Strait basalts may have been derived from a similar depleted mantle source composition; however, the later Davis Strait magmas were generated from a different mantle. None of the Baffin Island, West Greenland, or Labrador Sea samples show unequivocal geochemical evidence for contamination with continental crust.


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