scholarly journals Origin of the Middle Paleoproterozoic Tiksheozero Ultramafic-Alkaline-Carbonatite Complex, NE Fennoscandian Shield: Evidence from Geochemical and Isotope Sr-Nd-Hf-Pb-Os Data

Minerals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 570
Author(s):  
Maria Bogina ◽  
Boris Belyatsky ◽  
Evgenii Sharkov ◽  
Alexey Chistyakov ◽  
Robert Krymsky
Keyword(s):  
Mantle Source ◽  
Incompatible Element ◽  
Crustal Contamination ◽  
Geochemical Data ◽  
Carbonatite Complex ◽  
Karelian Craton ◽  
Nd Isotope ◽  
Isotope Studies ◽  
Element Enrichment ◽  
Silicate Rocks

This article reports new geochemical, Sr-Nd-Hf-Pb and Re-Os data on the rocks of the Middle Paleoproterozoic (1.99 Ga) Tiksheozero ultramafic-alkaline-carbonatite complex confined to the northeastern margin of the Karelian Craton. We focus on the poorly studied silicate rocks. Based on petrographic and geochemical research, the silicate rocks are subdivided into two groups: an ultramafic-mafic series depleted in REE, and other incompatible elements and an alkaline series enriched in these elements. Isotope studies showed that all rocks have juvenile isotope signatures and were likely derived from a primitive OIB-type mantle source with possible contributions of the subcontinental lithospheric mantle (SCLM). Insignificant crustal contamination is recorded by Pb and Os isotopic compositions. The incompatible element enrichment in the alkaline rocks and depletion in ultramafic-mafic rocks of the mildly alkaline series with allowance for insignificant crustal contamination confirm their derivation from different primary melts. However, a narrow range of Sr, Nd, Hf, and Pb isotope compositions and compact clusters in 207Pb/204Pb-206Pb/204Pb, Nd-87Sr/86Sr and Hf-Nd isotope diagrams indicate their origination from a common mantle source. A model of subsequent two-stage melting is being most consistent with the geochemical data for this complex.

scholarly journals Magmatic-Hydrothermal Processes Associated with Rare Earth Element Enrichment in the Kangankunde Carbonatite Complex, Malawi

Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 442 ◽  
Author(s):  
Frances Chikanda ◽  
Tsubasa Otake ◽  
Yoko Ohtomo ◽  
Akane Ito ◽  
Takaomi D. Yokoyama ◽  
...  
Keyword(s):  
Rare Earth ◽  
Geochemical Data ◽  
Carbonatite Complex ◽  
Compositional Zoning ◽  
Ree Mineralization ◽  
Hydrothermal Processes ◽  
Magmatic Stage ◽  
Isotope Study ◽  
Late Magmatic Stage ◽  
Element Enrichment

Carbonatites undergo various magmatic-hydrothermal processes during their evolution that are important for the enrichment of rare earth elements (REE). This geochemical, petrographic, and multi-isotope study on the Kangankunde carbonatite, the largest light REE resource in the Chilwa Alkaline Province in Malawi, clarifies the critical stages of REE mineralization in this deposit. The δ56Fe values of most of the carbonatite lies within the magmatic field despite variations in the proportions of monazite, ankerite, and ferroan dolomite. Exsolution of a hydrothermal fluid from the carbonatite melts is evident based on the higher δ56Fe of the fenites, as well as the textural and compositional zoning in monazite. Field and petrographic observations, combined with geochemical data (REE patterns, and Fe, C, and O isotopes), suggest that the key stage of REE mineralization in the Kangankunde carbonatite was the late magmatic stage with an influence of carbothermal fluids i.e. magmatic–hydrothermal stage, when large (~200 µm), well-developed monazite crystals grew. The C and O isotope compositions of the carbonatite suggest a post-magmatic alteration by hydrothermal fluids, probably after the main REE mineralization stage, as the alteration occurs throughout the carbonatite but particularly in the dark carbonatites.

Relative contribution of crust and mantle to flood basalt magmatism, Mahabaleshwar area, Deccan Traps

1984 ◽  
Vol 310 (1514) ◽  
pp. 627-641 ◽  
Keyword(s):  
Trace Element ◽  
Incompatible Element ◽  
Crustal Contamination ◽  
Flood Basalt ◽  
Oceanic Islands ◽  
Magma Type ◽  
Relative Contribution ◽  
History Of ◽  
Crustal Contribution ◽  
Element Enrichment

The 1200 m section of flat-lying basalts in the Mahabaleshwar area is divided into three formations on the basis of the trace elements Sr, Ba, Rb, Zr and Nb. The lowermost unit, the Poladpur Formation, is characterized by high Ba, Rb, and Zr/Nb, and low Sr. These features are accompanied by high K and Si, high and variable 87 Sr/ 86 Sr initial ratios (0.7043 - 0.7196), and low and variable e N d values (+ 2.6 to -17.4). The formation is interpreted as having developed by contamination of the overlying Ambenali magma-type with ancient granitic crust, with simultaneous fractionation of a gabbroic mineral assemblage. The more basic members of the formation are found towards the base of the succession and are more contaminated than the upper flows. The succeeding Ambenali Formation, characterized by the Ambenali magma type, has low Ba, Rb, Sr and Zr/Nb, and low and rather uniform 87 Sr/ 86 Sr initial ratios (0.7038-0.7043) coupled with high and relatively uniform e N d (+4.7 to +6.4). It is interpreted as being essentially uncontaminated and derived from a mantle source with a history of slight trace-element enrichment relative to m.o.r.b.-source. The uppermost group of flows, the Mahabaleshwar Formation, is, like the Poladpur, enriched in Ba, Rb, K and Si relative to the Ambenali, but has lower Zr/Nb and higher Sr. 87 Sr/ 86 Sr initial ratios (0.7040-0.7056) are slightly higher than in the Ambenali, and e N d lies in the range +7.1 to -3.0. In this formation Sr correlates positively with the other incompatible elements and with 87 Sr/ 86 Sr initial ratios. This is in strong contrast to the relations observed in the Poladpur, and we believe that the behaviour of Sr may be a simple pointer to the distinction between mantle and crustal contributions. Assuming that late-stage crystal fractionation processes can be allowed for, if Sr correlates positively with elements such as K, Rb and Ba then mantle enrichment processes are clearly implied. Conversely, as for example in the Poladpur, if the correlation is negative, crustal contamination is suspected because Sr is unlikely to behave as an incompatible element in most crustal derived melts or fluids because of buffering by residual plagioclase. Furthermore, the relative uniformity of the Mahabaleshwar Formation, the position on the Sr and Nd isotope diagram close to the ‘mantle array’, the fact that in terms of both incompatible element concentrations and isotopes the rocks are similar to tholeiites from oceanic islands such as Hawaii and Kerguelen, are all factors that reinforce the conclusion that these are mantle derived magmas which have suffered insignificant crustal contamination. They are, however, derived from a mantle which is trace-element enriched relative to the Ambenali source. Thus in the succession as a whole the crustal contribution appears to be small. Maximum amounts of contamination in the Poladpur Formation are difficult to determine but the average amount is probably in the region of 6-12 percentage mass. The whole sequence therefore contains a crustal contribution of about 2-3%.

The Ludicovian of the Raahe–Ladoga Zone of the Fennoscandian Shield (Isotope-Geochemical Composition and Geodynamic Nature)

2021 ◽  
Vol 62 (10) ◽  
pp. 1089-1106
Author(s):  
A.B. Vrevskii
Keyword(s):  
Isotope Composition ◽  
Geochemical Data ◽  
Island Arcs ◽  
Karelian Craton ◽  
Geochemical Composition ◽  
Nd Isotope ◽  
Tectonic Model ◽  
Isotope System ◽  
Nd Isotope Composition

Abstract —In the northern Ladoga area, the age of the Sortavala Group rocks in the southeast of the Raahe–Ladoga zone of junction of the epi-Archean Fenno-Karelian Craton and the Paleoproterozoic Svecofennian province, their relationship with dome granitoids, the age of the provenances, and the time of metamorphic processes were estimated. The study was focused on the Nd isotope composition of rocks, the geochemical and isotope-geochronological parameters of zircon from the granite-gneisses of the Kirjavalakhti dome, the basal graywackes of the lower unit and the trachytes of the middle unit of the Sortavala Group, and the plagio- and diorite-porphyry dikes cutting the volcanosedimentary units of this group. The new isotope-geochemical data show a Neoarchean age of the granitoids of the Kirjavalakhti dome (2695 ± 13 Ma) and their juvenile nature (εNd(T) = +1.5). The granitoids underwent tectonometamorphic transformations (rheomorphism) in the Paleoproterozoic (Sumian) (2.50–2.45 Ga), which are recorded in the U–Th–Pb isotope system of the rims of the ancient cores of zircon crystals. The volcanosedimentary complex of the Sortavala Group formed on the heterogeneous polychronous (3.10–2.46 Ga) continental crust of the epi-Archean Fenno-Karelian Craton. With regard to the errors in determination of the age of clastic zircon, the minimum concordant U–Th–Pb ages of 1940–1990 Ma of detrital zircon from volcanomictic graywackes of the Pitkyaranta Formation can be taken as the upper age bound of terrigenous rocks, which agrees with the maximum age of the Sortavala Group rocks estimated from the U–Th–Pb (SIMS) age of 1922 ± 11 Ma of the Tervaoya diorites (Matrenichev et al., 2006). According to the proposed new tectonic model, the accumulation of the volcanosedimentary complex of the Sortavala Group, its metamorphism, erosion, and overlapping by the Ladoga Group turbidites had already occurred in the pericratonic part of the epi-Archean Fenno-Karelian Craton by the time of the Svecofennian continent–island arc collision, subduction, and formation of bimodal volcanoplutonic complexes of the young Pyhäsalmi island arcs and felsic volcanics of the Savo schist belt (1920–1890 Ma).

Archaean crustal accretion at the northern border of the Congo Craton (South Cameroon). The charnockite-TTG link

2007 ◽  
Vol 178 (5) ◽  
pp. 331-342 ◽  
Author(s):  
André Pouclet ◽  
Rigobert Tchameni ◽  
Klaus Mezger ◽  
Max Vidal ◽  
Emmanuel Nsifa ◽  
...  
Keyword(s):  
Geochemical Data ◽  
Crustal Growth ◽  
Crustal Accretion ◽  
Nd Isotope ◽  
Northern Border ◽  
Lree Enrichment ◽  
Northwestern Margin ◽  
Isotope Studies ◽  
Greenstone Belts ◽  
Basaltic Crust

Abstract Magmatic charnockitic rocks and TTG (tonalite-trondhjemite-granodiorite) plutons intruded successively the Archaean greenstone belts of the Ntem Complex, at the northwestern margin of the Congo Craton. Geochemical data, zircon Pb-Pb ages, and Sr-Nd isotope studies, constrain the magmatic features, the genetical timing, and the geodynamic settings of these different suites. Charnockites and TTGs are characterized by high Al2O3 contents, high Na/K ratio, low Th content, LREE enrichment, HREE depletion, negative anomalies in Nb, Ta, and Ti, and positive anomalies in Sr. The Pb-Pb zircon ages indicate that charnockites were emplaced at ca. 2900 Ma and TTGs, which cross-cut the charnockites, at ca. 2830 Ma. TDM Nd mean crustal residence ages of both suites range between 3.10 and 2.93 Ga. The charnockites show slightly positive initial εNd2.9Ga (+0.3 to +1.3), whereas the TTGs have slightly negative values (+0.1 to −1.5). The charnockitic and TTG magmas may have resulted from different partial melting processes of the primitive Archaean basaltic crust and contaminated mantle, possibly in a hot slab subduction convergent regime. They contribute to a two-stage crustal growth of the Archaean craton.

The petrogenesis of metamorphosed carbonatites in the Grenville Province, Ontario

1997 ◽  
Vol 34 (9) ◽  
pp. 1185-1201 ◽  
Author(s):  
David P. Moecher ◽  
Eric D. Anderson ◽  
Claudia A. Cook ◽  
Klaus Mezger
Keyword(s):  
Rare Earth ◽  
Mantle Source ◽  
Earth Element ◽  
Minor Element ◽  
Geochemical Data ◽  
Boundary Zone ◽  
Grenville Province ◽  
Nd Isotope ◽  
Element Abundances ◽  
Depleted Mantle

Veins and dikes of calcite-rich rocks within the Central Metasedimentary Belt boundary zone (CMBbz) in the Grenville Province of Ontario have been interpreted to be true carbonatites or to be pseudocarbonatites derived from interaction of pegmatite melts and regional Grenville marble. The putative carbonatites have been metamorphosed and consist mainly of calcite, biotite, and apatite with lesser amounts of clinopyroxene, magnetite, allanite, zircon, titanite, cerite, celestite, and barite. The rocks have high P and rare earth element (REE) contents, and calcite in carbonatite has elevated Sr, Fe, and Mn contents relative to Grenville Supergroup marble and marble mélange. Values of δ18OSMOW (9.9–13.3‰) and δ13CPDB (−4.8 to −1.9‰) for calcite are also distinct from those for marble and most marble mélange. Titanites extracted from clinopyroxene–calcite–scapolite skarns formed by metasomatic interaction of carbonatites and silicate lithologies yield U–Pb ages of 1085 to 1035 Ma. Zircon from one carbonatite body yields a U–Pb age of 1089 ± 5 Ma; zircon ages from two other bodies are 1170 ± 3 and 1143 ± 8 Ma, suggesting several carbonatite formation events or remobilization of carbonatite during deformation and metamorphism around 1080 Ma. Values of εNd(T) are 1.7–3.2 for carbonatites, −1.5–1.0 for REE-rich granite dikes intruding the CMBbz, and 1.6–1.7 for marble. The mineralogy and geochemical data are consistent with derivation of the carbonatites from a depleted mantle source. Mixing calculations indicate that interaction of REE-rich pegmatites with regional marbles cannot reproduce selected major and minor element abundances, REE contents, and O and Nd isotope compositions of the carbonatites.

Co-existing low-Ti and high-Ti dolerites in two large dykes in the Gap Dyke swarm, southeastern Karoo Basin (South Africa)

2020 ◽  
Vol 123 (1) ◽  
pp. 19-34
Author(s):  
E.-R. Neumann ◽  
J.S. Marsh ◽  
C.Y. Galerne ◽  
S. Polteau ◽  
H. Svensen ◽  
...  
Keyword(s):  
Fractional Crystallization ◽  
Mantle Source ◽  
Crustal Contamination ◽  
Large Igneous Province ◽  
Dyke Swarm ◽  
The South ◽  
Southeastern Part ◽  
Nd Isotope ◽  
Karoo Basin ◽  
The North

Abstract This paper presents major, trace element and Sr-Nd isotope data on two large, east-west trending dolerite dykes in the southeastern part of the Karoo Basin, the South Gap (155 km long, ≤275 m wide) and the North Gap (150 km long, ≤190 m wide) dykes. The Gap dykes represent a rare case in the Karoo Large Igneous Province (LIP) where low-Ti (Gap1: <1.7 wt% TiO2, <130 ppm Zr, 200 to 330 ppm Sr, 6 to 17 ppm La, 87Sr/86Sr183: 0.7045 to 0.7075, ɛNd183: +0.31 to -7.5, ΔNb: +0.4 to -0.2) and high-Ti rocks (Gap2: 2.4 to 3.1 wt% TiO2, 110 to 240 ppm Zr, 260 to 390 ppm Sr, 12 to 24 ppm La, 87Sr/86Sr183: 0.7066 to 0.7074, ɛNd183: -3.2 to -4.1, ΔNb: +0.2 to -0.4) alternate along the same dykes. The aim of the study is to unravel the origin and petrogenesis of the two rock groups. The sample groups show the chemical traces of fractional crystallization in increasing concentrations of incompatible trace elements with decreasing MgO, and pivot points where elements such as Ti, Ca, P, and Sc change from trends of increasing to decreasing concentrations with decreasing MgO. Trends of increasing 87Sr/86Sr183 with decreasing ɛNd183 ratios indicate crustal contamination. However, three Gap1 samples from the South Gap dyke with the least enriched Sr-Nd isotope ratios and highest ΔNb may be derived from uncontaminated plume-type mantle melts. Modelling of Sr-Nd isotopes indicate that the Gap1 samples were subjected to assimilation of crustal melts (≤8%) and fractional crystallization in deep crustal magma chambers. There are no restrictions on the mantle source for the Gap2 rocks. However, because both geochemical signatures occur at different localities along the two Gap dykes, we favor a SA (South African) type mantle source for the two groups. The Gap2 rocks appear to have a two-stage assimilation history with one stage in the SCLM (subcontinental lithospheric mantle) or deep crust (decreasing the ɛNd183, increasing the 87Sr/86Sr183 ratios, and inducing the high-Ti character), followed by a second stage of contamination and fractional crystallization in the upper crust (increasing Sr isotope and (Sm/Yb)N ratios, with only minor decrease in ɛNd183).

scholarly journals Lead isotope constraints on the mantle sources involved in the genesis of Mesozoic high-Ti tholeiite dykes (Urubici type) from the São Francisco Craton (Southern Espinhaço, Brazil)

2016 ◽  
Vol 46 (suppl 1) ◽  
pp. 105-122 ◽  
Author(s):  
Leila Soares Marques ◽  
Eduardo Reis Viana Rocha-Júnior ◽  
Marly Babinski ◽  
Karine Zuccolan Carvas ◽  
Liliane Aparecida Petronilho ◽  
...  
Keyword(s):  
Mantle Source ◽  
Crustal Contamination ◽  
Experimental Tests ◽  
Pb Isotope ◽  
Flood Basalts ◽  
Nd Isotope ◽  
Continental Flood Basalts ◽  
Rock Fragments ◽  
Mantle Sources ◽  
First Results

ABSTRACT: The first results of Pb isotope compositions of the high-Ti Mesozoic dykes of the Southern Espinhaço are presented. The results do not show large variations and are significantly more radiogenic than the Pb isotope compositions of the high-Ti tholeiites from the Paraná Continental Flood Basalts. The data combined with published geochemical and Sr-Nd isotope results rule out crustal contamination processes in the genesis of the dykes, requiring magma generation in metasomatized subcontinental lithospheric mantle with the involvement of HIMU-type and carbonatite components. The magmas may have been also derived from a mantle source containing ~4 - 5% of pyroxenite and ~1% of carbonatite melts, agreeing with published Os isotope compositions of high-Ti rocks from the Paraná Continental Flood Basalts. These metasomatizing agents could be responsible for mantle source refertilization, as was also proposed in the literature to explain the characteristics of xenoliths of the Goiás Alkaline Province, which also occurs in the border of the São Francisco Craton. Additionally, to evaluate the risks of Pb contamination during sample preparation for analysis, several experimental tests were accomplished, which indicate the need of sawed surface removal and a careful washing of small-sized rock fragments before powdering, especially for rocks with [Pb] < 7 µg/g.

Geochemistry of Ferrar Dolerite sills and dykes at Terra Cotta Mountain, south Victoria Land, Antarctica

1995 ◽  
Vol 7 (1) ◽  
pp. 73-85 ◽  
Author(s):  
A.D. Morrison ◽  
A. Reay
Keyword(s):  
Trace Element ◽  
Mantle Source ◽  
Source Region ◽  
Crustal Component ◽  
Enriched Mantle ◽  
Victoria Land ◽  
Trace Element Signature ◽  
Geochemical Variation ◽  
Element Enrichment ◽  
Taylor Glacier

At Terra Cotta Mountain, in the Taylor Glacier region of south Victoria Land, a 237 m thick Ferrar Dolerite sill is intruded along the unconformity between basement granitoids and overlying Beacon Supergroup sedimentary rocks. Numerous Ferrar Dolerite dykes intrude the Beacon Supergroup and represent later phases of intrusion. Major and trace element data indicate variation both within and between the separate intrusions. Crystal fractionation accounts for much of the geochemical variation between the intrusive events. However, poor correlations between many trace elements require the additional involvement of open system processes. Chromium is decoupled from highly incompatible elements consistent with behaviour predicted for a periodically replenished, tapped and fractionating magma chamber. Large ion lithophile element-enrichment and depletion in Nb, Sr, P and Ti suggests the addition of a crustal component or an enriched mantle source. The trace element characteristics of the Dolerites from Terra Cotta Mountain are similar to those of other Ferrar Group rocks from the central Transantarctic Mountains and north Victoria Land, as well as with the Tasmanian Dolerites. This supports current ideas that the trace element signature of the Ferrar Group is inherited from a uniformly enriched mantle source region.

scholarly journals Ore and Geochemical Specialization and Substance Sources of the Ural and Timan Carbonatite Complexes (Russia): Insights from Trace Element, Rb–Sr, and Sm–Nd Isotope Data

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky
Keyword(s):  
Trace Element ◽  
Mantle Source ◽  
Crustal Evolution ◽  
Trace Element Data ◽  
The Urals ◽  
Nd Isotope ◽  
Enriched Mantle ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
Geochemical Specialization

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.

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