scholarly journals Comprehending the Causes of Presence of Copper and Common Heavy Metals in Sediments of Irrigation Canals in Taiwan

Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 416
Author(s):  
Shih-Han Huang ◽  
Tien-Chin Chang ◽  
Hui-Chen Chien ◽  
Zih-Sin Wang ◽  
Yen-Chen Chang ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Irrigation Water ◽  
Agricultural Land ◽  
Water Sources ◽  
Pollution Sources ◽  
Sediment Pollution ◽  
Irrigation Canal ◽  
Irrigation Canals ◽  
Sediment Distribution

In 2019, Taiwan completed its first thorough heavy metal investigation of irrigation canal sediments by this study with the support of Taiwan Environmental Protection Administration. Box-and-whisker plots were used to analyze the sediment distribution and to define metal concentrations. Possible metal pollution sources, the polluted agricultural land, irrigation area, and water sources were also evaluated using spatial analysis to understand the possible causes of sediment pollution. Results showed that the main heavy metal in agricultural land was Cu, found in 77% of contaminated agricultural land sites. Most sites with Cu pollution in sediments were in Taoyuan City and Changhua County. The heavy metals present in the sediment pollution sites in Taoyuan were consistent with those of possible pollution sources upstream, namely, Cr, Cu, and Pb. The main heavy metals in sediment pollution sites in Changhua were Cr, Cu, Ni, Pb, and Zn, whereas those for the polluted agricultural land sites were Cr, Cu, Ni, and Zn, without Pb. The main irrigation water sources in Changhua include drainages and rivers, with some receiving most wastewater pollution mass of release of Changhua, and functions as an irrigation water source with a high release mass in Cr, Cu, Ni and Zn. These findings indicate that the sites of sediment pollution, sites of polluted agricultural land, and the sources of pollution share corresponding heavy metal characteristics. Therefore, in Changhua, the sediments were polluted mainly because (1) the irrigation canals received the highest masses of pollutant releases into drainage wastewater of the county; and (2) the return flow from irrigation and the illegal discharge of wastewater. The preliminary assessment results for sediment pollution in Taoyuan also suggest that the main causes may be irrigation by polluted rivers or drainages and return flows.

Divergent response of heavy metal bioavailability in soil rhizosphere to agricultural land use change from paddy field to various drylands

2021 ◽  
Author(s):  
Yujuan Gao ◽  
Jianli Jia ◽  
Beidou Xi ◽  
Dongyu Cui ◽  
Wenbing Tan
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Land Use ◽  
Land Use Change ◽  
Agricultural Land ◽  
Rhizosphere Soil ◽  
Agricultural Land Use ◽  
Metal Bioavailability ◽  
Soil Rhizosphere ◽  
Divergent Response

The heavy metal pollution induced by agricultural land use change has attracted great attention. In this study, the divergent response of bioavailability of heavy metals in rhizosphere soil to different...

scholarly journals Physico-chemical variability and heavy metal pollution of surface sediment in a non-channeled section of Dilúvio Stream (Southern Brazil) and the influence of channeled section in sediment pollution

2019 ◽  
Vol 14 (1) ◽  
pp. 1 ◽  
Author(s):  
Pedro Alexandre Sodrzeieski ◽  
Leonardo Capeleto de Andrade ◽  
Tales Tiecher ◽  
Flávio Anastácio de Oliveira Camargo
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Total Concentration ◽  
Mineralogical Composition ◽  
Sediment Pollution ◽  
Anthropogenic Influence ◽  
Southern Brazil ◽  
Physico Chemical ◽  
Chemical Variability ◽  
The Impact

Dilúvio Stream flows through an area with a great population density in Porto Alegre, Southern Brazil. The anthropogenic influence in the surroundings impacted negatively the quality of the sediments of Dilúvio Stream and Lake Guaíba. This study evaluated the physico-chemical variability of surface sediments in a non-channeled section of Dilúvio Stream. Additionally, we compared the concentration of several heavy metals in this section with data from previous studies in the margins of Lake Guaíba near the outflow of Dilúvio Stream in order to evaluate the impact of urbanization on sediment pollution. The pH, bulk density, particle-size distribution, electrical conductivity, organic carbon, assimilable phosphorus, total nitrogen, mineralogical composition (X-ray diffractogram) and pseudo total concentration of several metals (Fe, Al, Ca, Mg, Na, K, Mn, Ba, Zn, V, As, Pb, Cu, Cr, Co, Ni, Cd, Mo, and Se) were evaluated. The results showed that the sediments in the non-channeled section of Dilúvio Stream are predominantly sandy, with heavy metal contents below the quality reference values. Quartz and feldspar predominated in all sites. The concentration of Zn, Pb, Cu, Cr, and Ni were lower than that observed in the margins of Lake Guaíba near the outflow of Dilúvio Stream, possibly due to pollution input throughout the channeled section. The Dilúvio Stream shows indications of an anthropogenic influence in the heavy metals concentration through the channeled area.

scholarly journals Heavy metal levels in drinking water sources of Chingola District, Zambia

2020 ◽  
Author(s):  
Francis Hamwiinga ◽  
Chisala D. Meki ◽  
Patricia Mubita ◽  
Hikabasa Halwiindi
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Drinking Water ◽  
Ground Water ◽  
Water Samples ◽  
Tap Water ◽  
Water Sources ◽  
Wet Season ◽  
Drinking Water Sources ◽  
Metal Levels

Abstract Background: One of the factors impeding access to safe water is water pollution. Of particular concern is heavy metal contamination of water bodies. This study was aimed at determining the levels of heavy metals in drinking water sources of Chingola District of Zambia. Methods: A cross sectional study was employed. A total of 60 water samples were collected. Thirsty (30) samples were collected in the dry season in the month of October 2016 and another 30 in the wet season in the months of February and March, 2017. For each season 10 water samples were collected from each of the three water sources. i.e. Tap water, Urban ground water sources and Rural ground water sources. Heavy metal analysis was done using Atomic Absorption Spectrophotometer (AAS).Results: This study revealed that the concentrations of Iron, Manganese, Lead, Nickel and Arsenic were beyond maximum permissible levels in various water sources. Combined averages for both dry and wet seasons were as follows: Iron: 2.3, Copper: 0.63, Cobalt: 0.02, Manganese: 0.36, Lead: 0.04, Zinc:3.2, Nickel: 0.03, Arsenic: 0.05. Chromium and Cadmium were below detection limit in all water samples. The median concentrations of iron, arsenic, copper, manganese in drinking water from the Tap, rural and urban ground water sources were different, and this difference was statistically significant (p<0.05). The median concentrations of arsenic, nickel, manganese and cobalt were different between dry and wet season, and this difference was statistically significant (p<0.05).Conclusions: Sources of heavy metals in water seems to be both natural and from human activities. The concentration of heavy metals in different water sources in this study was found to be above the recommended levels. This calls for improvement in water monitoring to protect the health of the public. Therefore, there is need for continuous monitoring of heavy metals in drinking water sources by regulatory authorities.

scholarly journals Impact Imposed by Urbanization on Soil Heavy Metal Content of Lake Wetland and Evaluation of Ecological Risks in East Dongting Lake in China

2021 ◽  
Author(s):  
Yang Lin ◽  
Kai Luo ◽  
Zilin Su ◽  
Yang Wu ◽  
Wei Xiao ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Land Use ◽  
Metal Content ◽  
Agricultural Land ◽  
Research Area ◽  
Dongting Lake ◽  
Heavy Metal Content ◽  
Ecological Risks ◽  
Positive Correlation

Abstract The urbanization is regarded as the major factor related to human activities that may interfere with the natural ecosystem. In this study, we have selected the wetland of East Dongting Lake as the research area. We have collected 180 soil samples (within the range of 0–20 cm, and 20cm-40cm), and we have measured the contents of their physicochemical properties (including salinity, pH value, soil particle composition, soil organic carbon, nitrate nitrogen and rapidly available phosphorus) as well as heavy metal elements (including As, Hg, Cd, Pb, Ni and Cr). We have adopted the methods of multivariate statistical analysis and inverse distance weighted (IDW) interpolation, so as to to reveal the sources and distribution characteristics of heavy metal content in soil in the research area. By adopting the potential ecological risk index (PERI) method proposed by Hakanson, we intend to assess the PERI values of heavy metals. Our research findings have shown that: (1) 8 sorts of heavy metals have shown positive correlation with each other. As, Hg and Zn have shown a significantly positive correlation with SOC (P < 0.01); As, Ni, Cr and Zn have shown a significantly positive correlation with AP (P < 0.01); As and Pb have shown a significantly positive correlation with Clay (P < 0.01); whereas Hg and Zn have shown a significantly negative correlation with Silt (P < 0.01); As and Pb have shown a significantly negative correlation with Sand (P < 0.01). (2) During urbanization, the elements of Cd, Ni, As, Hg and Pb might be enriched due to agricultural and industrial activities, whereas the use of fertilizers and pesticides constitute one of the major factors contributing to the increase of Cd and Pb contents in soil. (3) Influenced by the varying land patterns and with exception to Cu, the Fe-normalized concentrations have shown significant variations among different types of land use (P < 0.05). Specifically, there is a significantly higher level of Cd, Zn, Pb and Hg contents in the agricultural land than other types of land use, whereas there is a slightly higher level of heavy metal content in the mudflats than that in the grassland. In addition, the content of heavy metals in woodland remains relatively stable, and with exception to As, the content of heavy metals in woodland is the lowest among the five types of land. (4) The average value of the comprehensive PERI in heavy metals amounts to 555.03, representing a strong degree of ecological risks. Specifically, the proportion of sampling points of Cd that have a high level of ecological risks amounts to 36.51%, which is the primary element contributing to heavy metal pollution in the region, especially in the agricultural land.

Source apportionment of heavy metal pollution in farmland soils on a regional scale using geographically weighted PCA

2021 ◽  
Author(s):  
Liu Shuyi ◽  
Gao Bingbo
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Source Apportionment ◽  
Rapid Development ◽  
Regional Scale ◽  
Analytical Framework ◽  
Pollution Sources ◽  
Entire Study ◽  
Soil Heavy Metals ◽  
Farmland Soils

&lt;p&gt;Source apportionment of soil heavy metals is an challenge and urgent work as the result of the rapid development of industrialization and urbanization. The common approach is multivariate statistical analysis, such as PCA and APCS/MLR, which infers only a single pattern of sources of heavy metals in entire study area. Due to complicated pathways and processes, patterns of pollution sources in a whole region may include two or more. Hence, we developed an analytical framework based on GWPCA to explore multiple patterns of sources of soil heavy metals on a regional scale. Xiangtan county, an important grain-producing area in China, was taken as a case study, which suffers the problem of heavy metal pollutions. Our results revealed the pollution situations of five soil heavy metals(Pb, Cd, As, Cr and Hg) in farmland soils and suggested that there exists various pollution patterns of these heavy metals in Xiangtan county. In each pattern, the structure of contamination sources is different. Our study also indicates that the analytical framework considering the spatial heterogeneity of pollution sources can help take more precise practices to solve this vital problem.&lt;/p&gt; &lt;p&gt;&amp;#160;&lt;/p&gt;

scholarly journals Sensitivity and Calibration of the FT-IR Spectroscopy on Concentration of Heavy Metal Ions in River and Borehole Water Sources

2020 ◽  
Vol 10 (21) ◽  
pp. 7785
Author(s):  
Matthew Mamera ◽  
Johan J. van Tol ◽  
Makhosazana P. Aghoghovwia ◽  
Elmarie Kotze
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Ir Spectroscopy ◽  
Water Sources ◽  
Partial Least Square ◽  
Least Square ◽  
Borehole Water ◽  
Ft Ir ◽  
Ir Calibration ◽  
Ft Ir Spectroscopy

Heavy metals in water sources can threaten human life and the environment. The analysis time, need for chemical reagents, and sample amount per analysis assist in monitoring contaminants. Application of the Fourier Transform Infrared (FT-IR) Spectroscopy for the investigation of heavy metal elements has significantly developed due to its cost effectiveness and accuracy. Use of chemometric models such as Partial Least Square (PLS) and Principle Component Regression Analysis (PCA) relate the multiple spectral intensities from numerous calibration samples to the recognized analytes. This study focused on the FT-IR calibration and quantification of heavy metals (Ag, Cd, Cu, Pb and Zn) in surveyed water sources. FT-IR measurements were compared with the atomic absorption spectrometer (AAS) measurements. Quantitative analysis methods, PCA and PLS, were used in the FT-IR calibration. The spectral analyses were done using the Attenuated Total Reflectance (ATR-FTIR) technique on three river and four borehole water sources sampled within two seasons in QwaQwa, South Africa (SA). The PLS models had good R2 values ranging from 0.95 to 1 and the PCA models ranged from 0.98 to 0.99. Significant differences were seen at 0.001 and 0.05 levels between the PLS and PCA models for detecting Cd and Pb in the water samples. The PCA models detected Ag concentrations more (˂0 mg L−1 on selected sites). Both the PLS and PCA models had lower detection only for Zn ions mostly above 45 mg L−1 deviating from the AAS measurements (<0.020 mg L−1). The FT-IR spectroscopy demonstrated good potential for heavy metal determination purposes.

Levels and Potential Sources of Heavy Metals in Major Irrigated Rice Areas of the Philippines

2015 ◽  
Vol 15 (1) ◽  
Author(s):  
Jehru C. Magahud ◽  
Rodrigo B. Badayos ◽  
Pearl B. Sanchez ◽  
Pompe C. Sta. Cruz
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Irrigation Water ◽  
The Philippines ◽  
Rice Soils ◽  
Rice Plants ◽  
Metal Levels ◽  
Farm Inputs ◽  
Soil Metal ◽  
Very High

Industrialization, urbanization and intensive use of farm inputs can pollute agricultural areas. The study was then conducted to assess the levels of chromium (Cr), nickel (Ni), copper (Cu), cobalt (Co), zinc (Zn), arsenic (As), molybdenum (Mo), cadmium (Cd), mercury (Hg), and lead (Pb) in the country’s major rice areas. The study also determined the contributions of soil properties, land uses, irrigation water, and farm inputs to the metal levels. Strategic collections of soil, plant and water samples in the country’s major soil series planted to rice, analyses of samples using x-ray fluorescence or atomic absorption spectroscopy, and farmer interviews were done. Metal levels were very high in Zambales and Negros Occidental soils due to deposition or use of metal-enriched mine tailings and irrigation water. Soil metal concentrations in Zambales far exceeded the intervention values of 180 mg/kg for Cr and 100 mg/kg for Ni. Soil metal levels in Negros Occidental exceeded the intervention value of 190 mg/kg for Cu and Mo. Rice plants in Negros Occidental exceeded the toxic levels of 30 mg/kg for Cu and 10-50 mg/kg for Mo due to the very high soil Cu and Mo concentrations in the area. Molybdenum concentrations of rice plants in Sultan Kudarat and Camarines Sur exceeded the toxic level due to the high amounts of foliar chemicals applied at >66 sprayer loads per year. The study implies that rice areas deposited with mine wastes have high heavy metal levels, and foliar chemicals can increase metal levels in rice.   Keywords - Environmental toxicology, heavy metals, heavy metal sources, rice soils, Philippines

scholarly journals Characteristics and evaluations of heavy metals content in irrigation water sources of someone suburb farmlands of the lower reaches of Xijiang River in the early busy farming period

2020 ◽  
Author(s):  
Ren Jie ◽  
Liu Xiao-wen
Keyword(s):  
Heavy Metals ◽  
Water Quality ◽  
Irrigation Water ◽  
Mercury Content ◽  
Water Sources ◽  
Management Control ◽  
Distribution Characteristics ◽  
High Background ◽  
Xijiang River ◽  
Level I

Abstract The problems of heavy metals in irrigation water are related to the management-control of heavy metals risk of farmlands and the safe production of crops. There are various sources of irrigation water in the suburb farmlands of Xijiang River. We investigated the sources and distribution characteristics of heavy metals in the irrigation water sources in the riverside and inside-dyke farmlands of Xijiang River. According to correlation analysis, distribution characteristics analysis, single/comprehensive water-quality evaluations of eight heavy metal elements in different irrigation water sources, it was found that nearly 100% of heavy metals were detected in the irrigation water sources in this study. The box plot showed that the average level of cadmium was 0.02 μg·L−1 in this area, and the contents of other elements were mostly in the range of several to dozens of μg·L−1. Most heavy metals were in relatively low concentration level in the irrigation water sources, mercury content level (Quantitative Evaluation Index) was far greater than other elements, followed by arsenic. Arsenic and mercury problems have become more significant problems in local irrigation water sources. Surface water was more likely to be affected by river water and agricultural activities, while groundwater was more likely to be affected by natural causes. The comprehensive water quality evaluation ranged from level I to level III, but the single factor index evaluations of mercury in most water samples and arsenic in two groundwater samples were ‘Inferior’ level. It was suggested that the monitoring of mercury and arsenic (groundwater) in the irrigation water should be strengthened immediately in this area, the disposal measures of farmland water inflow and drainage should be increased if necessary, and reducing the influence of human factors on the natural weathering and leaching of heavy metals is an effective risk avoidance measure in agricultural production in high background regions.

scholarly journals Evaluation of redevelopment priority of abandoned industrial and mining land based on heavy metal pollution

PLoS ONE ◽  
2021 ◽  
Vol 16 (7) ◽  
pp. e0255509
Author(s):  
Xing Gao ◽  
Junping Tian ◽  
Zheng Huo ◽  
Yanbin Wu ◽  
Chenxi Li
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Pollution ◽  
Heavy Metal Pollution ◽  
Metal Contamination ◽  
Agricultural Land ◽  
Heavy Metal Contamination ◽  
Northern China ◽  
Construction Land ◽  
Priority Assessment

Heavy metal contamination in soil is an important factor affecting the determination of safe redevelopment methods for industrial and mining land. In this paper, the soil environment of a typical mining city in northern China was taken as the research object, 148 surface soil samples were collected and the contents of heavy metals were measured. The health risk classification criteria for heavy metal contamination of soils and the method of priority assessment for redevelopment were used. The results showed that: the risk of potential utilization types of heavy metals in the abandoned industrial and mining land is different. When the utilization type is agricultural land, the soil environmental quality is good as a whole, and a small number of plots are polluted by cadmium (Cd)and mercury (Hg); When the land use type is construction land, the risk of heavy metal pollution comes from chromium (Cr); The priority of development in this study area is as follows: agricultural land > construction land > ecological land.

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