scholarly journals The Competitive Adsorption of Chromate and Sulfate on Ni-Substituted Magnetite Surfaces: An ATR-FTIR Study

Minerals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 88
Author(s):  
Xiaoju Lin ◽  
Gaoling Wei ◽  
Xiaoliang Liang ◽  
Jing Liu ◽  
Lingya Ma ◽  
...  
Keyword(s):  
Competitive Adsorption ◽  
Chemical Properties ◽  
Outer Sphere ◽  
Mineral Surfaces ◽  
Similar Chemical ◽  
Adsorption Affinity ◽  
Individual Adsorption ◽  
Alkaline Conditions ◽  
Ph Range

With similar chemical properties and geometrical configurations, sulfate and chromate display interesting competitive adsorption on mineral surfaces. Although such issues have been investigated on several Fe (hydr)oxide surfaces, e.g., ferrihydrite, goethite and hematite, the competitive adsorption on magnetite surfaces and the constraint mechanism have seldom been studied. This impedes the understanding of the transfer and fate of chromate and sulfate on magnetite surfaces, as magnetite is not only a useful adsorbent but also an efficient reductant to decrease the mobility and toxicity of chromium. In the present study, the geometries of the competitive adsorption of chromate and sulfate on Ni-substituted magnetite surfaces over a pH range of 4–9 were investigated using in situ attenuated total reflectance Fourier transform infrared spectroscopy and two-dimensional correlation analysis. In individual adsorption, nonprotonated monodentate mononuclear (NMM) complexes dominated chromate adsorption, accompanied by a few bidentate binuclear (BB) complexes. For sulfate, NMM complexes and outer-sphere (OS) species predominated under acidic and neutral–alkaline conditions, respectively. The above variation in adsorption configuration resulted in the different adsorption competitiveness between chromate and sulfate at different pH values. Specifically, the NMM complexes of chromate were substituted by NMM sulfate complexes under acidic conditions and vice versa. However, under neutral and alkaline conditions, the OS species of sulfate scarcely affected the adsorption of chromate. The adsorption affinity of chromate and sulfate on Ni-substituted magnetite increased in the following order: OS complex (sulfate) < NMM complexes (chromate) < NMM complexes (sulfate).

Sorption of Eu(III) at feldspar/water interface: effects of pH, organic matter, counter ions, and temperature

2017 ◽  
Vol 105 (12) ◽  
Author(s):  
Ping Li ◽  
Hanyu Wu ◽  
Jianjun Liang ◽  
Zhuoxin Yin ◽  
Duoqiang Pan ◽  
...  
Keyword(s):  
Organic Matter ◽  
Outer Sphere ◽  
Potassium Feldspar ◽  
Low Ph ◽  
High Ionic Strength ◽  
Counter Ions ◽  
Effects Of Ph ◽  
Alkaline Conditions ◽  
Ph Range ◽  
Interface Effects

AbstractThe sorption of Eu(III) on potassium feldspar (K-feldspar) was studied under various physicochemical conditions such as pH, temperature, counter ions and organic matter. The results showed that the sorption of Eu(III) on K-feldspar significantly increased with the increase of pH, and high Eu(III) concentration can inhibit such immobility to some extent. The presence of humic acid (HA) can increase the sorption of Eu(III) on K-feldspar in low pH range; while inhibit to a large extent under alkaline conditions. It is very interesting that at pH ~6.5, high ionic strength can promote the sorption of Eu(III) on K-feldspar in the presence of HA. In contrast, Eu(III) sorption was restricted obviously by NaCl in the absence of HA. The sorption procedure was involved with ion exchange and/or outer-sphere complexation as well as inner-sphere complexation. The presence of F

Cathodoluminescence of Catalyst Crystallites

1982 ◽  
Vol 40 ◽  
pp. 664-665
Author(s):  
E.D. Boyes ◽  
P.L. Gai ◽  
D.B. Darby ◽  
C. Warwick
Keyword(s):  
Defect Density ◽  
Chemical Properties ◽  
Operating Conditions ◽  
Semiconductor Materials ◽  
Environmental Cell ◽  
High Resolution Structure ◽  
Commercially Important ◽  
Crystallographic Defects ◽  
Resolution Structure

The extended crystallographic defects introduced into some oxide catalysts under operating conditions may be a consequence and accommodation of the changes produced by the catalytic activity, rather than always being the origin of the reactivity. Operation without such defects has been established for the commercially important tellurium molybdate system. in addition it is clear that the point defect density and the electronic structure can both have a significant influence on the chemical properties and hence on the effectiveness (activity and selectivity) of the material as a catalyst. SEM/probe techniques more commonly applied to semiconductor materials, have been investigated to supplement the information obtained from in-situ environmental cell HVEM, ultra-high resolution structure imaging and more conventional AEM and EPMA chemical microanalysis.

scholarly journals Shellfish Chitosan Potential in Wine Clarification

2021 ◽  
Vol 11 (10) ◽  
pp. 4417
Author(s):  
Veronica Vendramin ◽  
Gaia Spinato ◽  
Simone Vincenzi
Keyword(s):  
Molecular Structure ◽  
Chemical Properties ◽  
Allergic Reactions ◽  
Chitin Content ◽  
Deacetylation Degree ◽  
Physical Chemical ◽  
Similar Chemical ◽  
Fungal Chitosan ◽  
Significant Difference ◽  
Fish Industry

Chitosan is a chitin-derived fiber, extracted from the shellfish shells, a by-product of the fish industry, or from fungi grown in bioreactors. In oenology, it is used for the control of Brettanomyces spp., for the prevention of ferric, copper, and protein casse and for clarification. The International Organisation of Vine and Wine established the exclusive utilization of fungal chitosan to avoid the eventuality of allergic reactions. This work focuses on the differences between two chitosan categories, fungal and animal chitosan, characterizing several samples in terms of chitin content and degree of deacetylation. In addition, different acids were used to dissolve chitosans, and their effect on viscosity and on the efficacy in wine clarification were observed. The results demonstrated that even if fungal and animal chitosans shared similar chemical properties (deacetylation degree and chitin content), they showed different viscosity depending on their molecular weight but also on the acid used to dissolve them. A significant difference was discovered on their fining properties, as animal chitosans showed a faster and greater sedimentation compared to the fungal ones, independently from the acid used for their dissolution. This suggests that physical–chemical differences in the molecular structure occur between the two chitosan categories and that this significantly affects their technologic (oenological) properties.

scholarly journals Enhanced Tensile Strength of Monolithic Epoxy with Highly Dispersed TiO2-Graphene Nanocomposites

2021 ◽  
Vol 5 (7) ◽  
pp. 191
Author(s):  
Yanshuai Wang ◽  
Siyao Guo ◽  
Biqin Dong ◽  
Feng Xing
Keyword(s):  
Tensile Strength ◽  
Epoxy Resin ◽  
Mechanical Performance ◽  
Chemical Properties ◽  
High Mechanical Property ◽  
Graphene Nanocomposites ◽  
Highly Dispersed ◽  
Dispersion State ◽  
Physical And Chemical

The functionalization of graphene has been reported widely, showing special physical and chemical properties. However, due to the lack of surface functional groups, the poor dispersibility of graphene in solvents strongly limits its engineering applications. This paper develops a novel green “in-situ titania intercalation” method to prepare a highly dispersed graphene, which is enabled by the generation of the titania precursor between the layer of graphene at room temperature to yield titania-graphene nanocomposites (TiO2-RGO). The precursor of titania will produce amounts of nano titania between the graphene interlayers, which can effectively resist the interfacial van der Waals force of the interlamination in graphene for improved dispersion state. Such highly dispersed TiO2-RGO nanocomposites were used to modify epoxy resin. Surprisingly, significant enhancement of the mechanical performance of epoxy resin was observed when incorporating the titania-graphene nanocomposites, especially the improvements in tensile strength and elongation at break, with 75.54% and 176.61% increases at optimal usage compared to the pure epoxy, respectively. The approach presented herein is easy and economical for industry production, which can be potentially applied to the research of high mechanical property graphene/epoxy composite system.

In situ dual crosslinking strategy to improve the physico-chemical properties of thermoplastic starch

2021 ◽  
pp. 118250
Author(s):  
Hamed Peidayesh ◽  
Abolfazl Heydari ◽  
Katarína Mosnáčková ◽  
Ivan Chodák
Keyword(s):  
Chemical Properties ◽  
Thermoplastic Starch ◽  
Physico Chemical

Revealing the structural transformation of rutile RuO2via in situ X-ray absorption spectroscopy during the oxygen evolution reaction

2019 ◽  
Vol 48 (21) ◽  
pp. 7122-7129 ◽  
Author(s):  
Chia-Jui Chang ◽  
You-Chiuan Chu ◽  
Hao-Yu Yan ◽  
Yen-Fa Liao ◽  
Hao Ming Chen
Keyword(s):  
Oxygen Evolution ◽  
Structural Transformation ◽  
Absorption Spectroscopy ◽  
Oxygen Evolution Reaction ◽  
The State ◽  
X Ray ◽  
Alkaline Conditions ◽  
X Ray Absorption ◽  
State Of Art

The state-of-art RuO2 catalyst for the oxygen evolution reaction (OER) is measured by using in situ X-ray absorption spectroscopy (XAS) to elucidate the structural transformation during catalyzing the reaction in acidic and alkaline conditions.

scholarly journals In-Situ Cosmogenic 14C: Production and Examples of its Unique Applications in Studies of Terrestrial and Extraterrestrial Processes

Radiocarbon ◽  
2001 ◽  
Vol 43 (2B) ◽  
pp. 731-742 ◽  
Author(s):  
D Lal ◽  
A J T Jull
Keyword(s):  
Half Life ◽  
Earth Science ◽  
Chemical Properties ◽  
Radioactive Isotopes ◽  
Earth’S Atmosphere ◽  
The Earth ◽  
Wide Range ◽  
History Of ◽  
Earth's Atmosphere

Nuclear interactions of cosmic rays produce a number of stable and radioactive isotopes on the earth (Lai and Peters 1967). Two of these, 14C and 10Be, find applications as tracers in a wide variety of earth science problems by virtue of their special combination of attributes: 1) their source functions, 2) their half-lives, and 3) their chemical properties. The radioisotope, 14C (half-life = 5730 yr) produced in the earth's atmosphere was the first to be discovered (Anderson et al. 1947; Libby 1952). The next longer-lived isotope, also produced in the earth's atmosphere, 10Be (half-life = 1.5 myr) was discovered independently by two groups within a decade (Arnold 1956; Goel et al. 1957; Lal 1991a). Both the isotopes are produced efficiently in the earth's atmosphere, and also in solids on the earth's surface. Independently and jointly they serve as useful tracers for characterizing the evolutionary history of a wide range of materials and artifacts. Here, we specifically focus on the production of 14C in terrestrial solids, designated as in-situ-produced 14C (to differentiate it from atmospheric 14C, initially produced in the atmosphere). We also illustrate the application to several earth science problems. This is a relatively new area of investigations, using 14C as a tracer, which was made possible by the development of accelerator mass spectrometry (AMS). The availability of the in-situ 14C variety has enormously enhanced the overall scope of 14C as a tracer (singly or together with in-situ-produced 10Be), which eminently qualifies it as a unique tracer for studying earth sciences.

Enhanced electrocatalytic activity of in situ carbon encapsulated molybdenum phosphide derived from a hybrid POM for the HER over a wide pH range

2022 ◽  
Author(s):  
Balasingh Thangadurai Jebaslinhepzybai ◽  
Elavarasan Samaraj ◽  
Thangaian Kesavan ◽  
Manickam Sasidharan ◽  
J. Arockia Selvi
Keyword(s):  
Electrocatalytic Activity ◽  
Molybdenum Phosphide ◽  
Wide Ph Range ◽  
Ph Range

Hybrid polyoxometalate derived in situ carbon encapsulated molybdenum phosphide (HPOM-MoP/C) exhibits excellent HER activity in a wide pH range.

scholarly journals Soil physico-chemical characterization in the different soil layers of National Maize Research Program, Rampur, Chitwan, Nepal

2018 ◽  
Vol 3 (1) ◽  
pp. 28-44
Author(s):  
Dinesh Khadka ◽  
Sushil Lamichhane ◽  
Amit P Timilsina ◽  
Bandhu R Baral ◽  
Kamal Sah ◽  
...  
Keyword(s):  
Research Program ◽  
Soil Structure ◽  
Sandy Loam ◽  
Chemical Properties ◽  
Single Layer ◽  
Chemical Characterization ◽  
Bottom Layer ◽  
Soil Parameters ◽  
Physico Chemical

Soil pit digging and their precise study is a decision making tool to assess history and future of soil management of a particular area. Thus, the present study was carried out to differentiate soil physico-chemical properties in the different layers of excavated pit of the National Maize Research Program, Rampur, Chitwan, Nepal. Eight pits were dug randomly from three blocks at a depth of 0 to 100 cm. The soil parameters were determined in-situ, and in laboratory for texture, pH, OM, N, P (as P2O5), K (as K2O), Ca, Mg, S, B, Fe, Zn, Cu and Mn of collected soils samples of different layers following standard analytical methods at Soil Science Division, Khumaltar. The result revealed that soil structure was sub-angular in majority of the layers, whereas bottom layer was single grained. The value and chrome of colour was increasing in order from surface to bottom in the majority pits. Similarly, the texture was sandy loam in majority layers of the pits. Moreover, four types of consistence (loose to firm) were observed. Furthermore, mottles and gravels were absent in the majority layers. Likewise, soil was very to moderately acidic in observed layers of majority pits, except bottom layer of agronomy block was slightly acidic. Regarding fertility parameters (OM, macro and micronutrients), some were increasing and vice-versa, while others were intermittent also. Therefore, a single layer is not dominant for particular soil physico-chemical parameters in the farm. In overall, surface layer is more fertile than rest of the layers in all the pits.     

Group III-Sb Metamorphic Buffer on Si for p-Channel all-III-V CMOS: Electrical Properties, Growth and Surface Defects

2015 ◽  
Vol 1790 ◽  
pp. 13-18
Author(s):  
Shun Sasaki ◽  
Shailesh Madisetti ◽  
Vadim Tokranov ◽  
Michael Yakimov ◽  
Makoto Hirayama ◽  
...  
Keyword(s):  
Surface Defects ◽  
Lattice Mismatch ◽  
Chemical Properties ◽  
Antiphase Domain ◽  
Hole Transport ◽  
Heteroepitaxial Growth ◽  
Group Iii ◽  
Similar Chemical ◽  
Unintentional Doping ◽  
P Type

ABSTRACTGroup III-Sb compound semiconductors are promising materials for future CMOS circuits. Especially, In1-xGaxSb is considered as a complimentary p-type channel material to n-type In1-xGaxAs MOSFET due to the superior hole transport properties and similar chemical properties in III-Sb’s to those of InGaAs. The heteroepitaxial growth of In1-xGaxSb on Si substrate has significant advantage for volume fabrication of III-V ICs. However large lattice mismatch between InGaSb and Si results in many growth-related defects (micro twins, threading dislocations and antiphase domain boundaries); these defects also act as deep acceptor levels. Accordingly, unintentional doping in InGaSb films causes additional scattering, increase junction leakages and affects the interface properties. In this paper, we studied the correlations between of defects and hole carrier densities in GaSb and strained In1-xGaxSb quantum well layers by using various designs of metamorphic superlattice buffers.

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