scholarly journals Thermo-Structural Evolution of the Val Malenco (Italy) Peridotite: A Petrological, Geochemical and Microstructural Study

Minerals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 962
Author(s):  
Wenlong Liu ◽  
Yi Cao ◽  
Junfeng Zhang ◽  
Yanfei Zhang ◽  
Keqing Zong ◽  
...  

The Val Malenco peridotite massif is one of the largest exposed ultramafic massifs in Alpine orogen. To better constrain its tectonic history, we have performed a comprehensive petro-structural and geochemical study. Our results show that the Val Malenco serpentinized peridotite recorded both pre-Alpine extension and Alpine convergence events. The pre-Alpine extension is recorded by microstructural and geochemical features preserved in clinopyroxene and olivine porphyroblasts, including partial melting and refertilisation, high-temperature (900–1000 °C) deformation and a cooling, and fluid-rock reaction. The following Alpine convergence in a supra-subduction zone setting is documented by subduction-related prograde metamorphism features preserved in the coarse-grained antigorite and olivine grains in the less-strained olivine-rich layers, and later low-temperature (<350 °C) serpentinization in the fine-grained antigorite in the more strained antigorite-rich layers. The strain shadow structure in the more strained antigorite-rich layer composed of dissolving clinopyroxene porphyroblast and the precipitated oriented diopside and olivine suggest dissolution and precipitation creep, while the consistency between the strain shadow structure and alternating less- and more-strained serpentinized domains highlights the increasing role of strain localization induced by the dissolution-precipitation creep with decreasing temperature during exhumation in Alpine convergence events.

2010 ◽  
Vol 4 (3) ◽  
pp. 199-207 ◽  
Author(s):  
Lorena Pardo ◽  
Alvaro García ◽  
Klaus Brebøl ◽  
Lavinia Curecheriu ◽  
Liliana Mitoseriu ◽  
...  

The challenge to develop high piezoelectric sensitivity and lead-free composition ferro-piezoelectric ceramics has recently dragged new attention to some classic ferroelectrics. Here, Ba(CexTi1-x)O3 (Ce-BT) and 0.94(Bi1/2Na1/2)TiO3-0.06BaTiO3 (BNBT6) ceramics were piezoelectrically characterized from measurements of complex impedance at electromechanical resonances and their analysis by Alemany et al. software. The reconstruction of the spectra for each resonance is used as an accuracy test of the set of calculated coefficients, quantitatively characterized by the regression factor (R2) of such reconstruction to the experimental spectrum. Piezoelectric activity at room temperature (RT) was observed for Ce-BT with x=0.06 and 0.1, ferroelectrics with T(?'max)>RT, but also for x=0.2 with T(?'max)<RT, which confirms its relaxor character (Ps?0 for T?T(?'max)). BNBT6 fine grained ceramics (~1 ?m) were prepared from nanopowder obtained by sol-gel autocombustion. Results obtained for the fine grained ceramic hot-pressed at 800?C for 2 h and recrystallized at 1050?C for 1 h are d33=148 pCN-1 and kp=26.8%. Despite of its lower grain size, the properties of this material are comparable with those reported for coarse grained ceramics obtained by sintering at T>1100?C. Some measurement issues, as the role of the mode coupling on the characterization results, illustrated for the shear mode of a thickness poled plate, are discussed.


2020 ◽  
Author(s):  
Junfeng Zhang ◽  
Wenlong Liu ◽  
Yongfeng Wang

&lt;p&gt;Antigorite dehydration is well known as a key process in convergent boundaries for the genesis of mantle wedge partial melting and intermediate-depth earthquakes. However, the crystallographic preferred orientations (CPOs) of prograde minerals from antigorite dehydration and its effects on seismic anisotropy of subducting slabs remain ambiguous and controversial. Here we report hydrostatic dehydration experiments on foliated serpentinized peridotite at pressures of 0.3-6 GPa and temperatures of 700-900 &amp;#176;C. Our results show that the orientations of prograde olivine inherit orientations from adjacent olivine grains in the olivine-rich layer by epitaxial growth. In contrast, olivine CPOs evolved with the grain size from fiber-[001] featuring clear [100] point maxima and [001] girdles for fine-grained olivine to orthorhombic patterns characterized by clear [100] and [001] point maxima for coarse-grained olivine, i.e., type-C CPO. We propose that the fine-grained fiber-[001] CPO is developed by topotactic growth at the onset of dehydration, while the orthorhombic type-C CPO for the coarse-grained olivine, especially the [001] point maximum along the lineation, is mainly developed by anisotropic growth resulting from anisotropic fluid flow during the dehydration. The developed olivine type-C CPO in the antigorite-rich layer after antigorite dehydration could explain the trench or strike parallel seismic anisotropy observed at convergent plate boundaries.&lt;/p&gt;


Discourse ◽  
2019 ◽  
Vol 5 (4) ◽  
pp. 18-25
Author(s):  
A. I. Ponomarev

Introduction. In modern philosophy of perception, the issue of the content of perceptual mental states is actively discussed, in particular the possibility of nonconceptual content is one of the most significant problem. Usually conceptual activity is attributed to thinking, and perception is intended to be non-conceptual. Such an approach may deprive perception of opportunity to serve as a basis for judgment. The paper analyzes Tye’s theory of non-conceptual content of perceptual mental states, which does not deprive the perception of its epistemological function.Methodology and sources. Methodologically, the research work is based on philosophical analysis of modern theories of perception and results of cognitive research.Results and discussion. In accepted terminology, the content of perceptual mental states can be of three types: conceptual, non-conceptual detailed (fine-grained) and nonconceptual coarse (coarse-grained). Tye's position is that perceptual mental states have only the third kind of content. This approach faces a number of objections that are presented in this paper. The analysis of objections shows their surmount ability, thus, it can be concluded that the Tye’s position of nonconceptual content can be considered as reasonable. The main result of the presented research is the presentation of additional grounds for the theory of non-conceptual content of perceptual mental states.Conclusion. The problem of the content of perceptual mental states is crucial for understanding the epistemological role of perception. The theory of non-conceptual content of perceptual mental states provides new insights into perception.


2002 ◽  
Vol 8 (2) ◽  
pp. 137-145 ◽  
Author(s):  
Hyomin Lee ◽  
Robert D. Cody ◽  
Anita M. Cody ◽  
Paul G. Spry

Abstract Iowa highway concretes containing reactive dolomite, (CaMg) 2 CO 3 , aggregate, composed of fine-grained, microporous dolomite, sometimes have service lives of less than 10 years. This premature deterioration may, in part, be caused by expansive forces created by newly formed minerals such as brucite, Mg (OH) 2 , in the cement paste as a result of dedolomitization of reactive dolomite coarse aggregate. Although calcite is the most abundant secondary mineral in cements of poorly-performing concretes, the present study found no evidence that it was expansionary. Brucite is common but less abundant than calcite and occurred chiefly in and near the margins of reactive dolomite in both the aggregate and cement paste of poorly-performing concretes. Most brucite occurs in partially dedolomitized rims around dolomite coarse aggregates. This type of brucite is widely disseminated through the rims, consists of extremely small (<1 m) microcrystalline masses, and was produced by direct precipitation from pore solutions. Smaller amounts of brucite occur in the cement paste. This type is relatively coarse-grained (10 mu m-20 mu m) and most was formed primarily by crystal surface mediated (topochemical) reactions between magnesium-rich pore solutions and portlandite, Ca(OH) 2 . Numerous microcracks are present in cement paste but are not spatially associated with brucite locations. There is no direct evidence for cracking caused by brucite but this is not conclusive evidence against brucite-induced expansion. Brucite is widely disseminated so that expansion at innumerable micro-locations may cause general concrete expansion which should be relieved by cracking at weaker locations in the concretes.


Author(s):  
Wei Xu ◽  
Di-Cheng Zhu ◽  
Qing Wang ◽  
Roberto F Weinberg ◽  
Rui Wang ◽  
...  

Abstract Amphibole plays an important role in the petrogenesis and evolution of arc magmas, but its role is not completely understood yet. Here, a field, petrological, geochronological and geochemical study is carried out on ultramafic-mafic arc cumulates with textural and chemical heterogeneities and on associated host diorites from the eastern Gangdese Batholith, southern Tibet to explore the problem. The cumulates occur as a large body in diorite host-rocks. The core of the body consists of coarse-grained Cpx hornblendite with a porphyritic texture. Towards the contact with the host diorite, the coarse-grained Cpx hornblendite grades to relatively homogeneous fine-grained melagabbro. Zircon U–Pb dating indicates they all crystallized at 200 ± 1 Ma. Textural features and whole-rock and mineral chemical data reveal that both the Cpx hornblendite and the melagabbro are mixtures of two different mineral assemblages that are not in equilibrium: (1) brown amphibole and its clinopyroxene inclusions; (2) matrix clinopyroxene + green amphibole + plagioclase + quartz + accessory phases. Clinopyroxene and brown amphibole from the first assemblage are enriched in middle rare earth elements (MREE) relative to light REE (LREE) and heavy REE (HREE), and are weakly depleted in Ti, whereas clinopyroxene and green amphibole from the second assemblage are characterized by LREE enrichment over MREE-HREE and more marked Sr and Ti depletion. The higher Mg#, MgO and Cr of the late-formed green amphibole than the early-formed brown amphibole suggest that the two assemblages are not on the same liquid line of descent. Given the close relations of the three rock types in the exposed crustal section, the cumulates are interpreted to have formed in an open system, in which an ultramafic cumulate body consisting of the first assemblage reacted with the host dioritic melt to form new clinopyroxene and amphibole of the second assemblage. The melt calculated to be in equilibrium with the first mineral assemblage resembles an average continental arc basalt, that is less evolved than the host dioritic melt, responsible for the second mineral assemblage. On the basis of whole-rock Sr–Nd–Hf isotopic similarity of the cumulates and a host diorite sample, we argue that the host diorites were formed through crystal fractionation from the parent melt of the first assemblage. Results of least-squares mass-balance calculations suggest the quantities of the host dioritic melts, involved in the generation of these modified cumulates, vary from ~25% to ~44%. The presence of magmatic epidote in the host diorites and Al-in-Hb geobarometry indicate the reaction that occurred when the dioritic melts percolated through the cumulate body was at ~6 kbar. Both the brown and green amphiboles are enriched in MREE relative to HREE, and can impart residual melts with a strong geochemical signature of amphibole fractionation (low Dy/Yb). Thus, we conclude that fractional crystallization and melt-rock reaction are two mechanisms by which amphibole controls arc magma petrogenesis and evolution.


2015 ◽  
Vol 7 (4) ◽  
pp. 2953-2998
Author(s):  
G. Viegas ◽  
L. Menegon ◽  
C. J. Archanjo

Abstract. The Pernambuco shear zone (northeastern Brazil) is a large-scale strike-slip fault that, in its eastern segment, deforms granitoids at mid-crustal conditions. Initially coarse (> 50 μm) grained feldspar porphyroclasts are intensively fractured and reduced to an ultrafine-grained mixture consisting of plagioclase and K-feldspar grains (~ < 15 μm in size) localized in C' shear bands. Detailed microstructural observations and EBSD analysis do not show evidence of intracrystalline plasticity in feldspar porphyroclasts and/or fluid-assisted replacement reactions. Quartz occurs either as thick (~ 1–2 mm) monomineralic bands or as thin ribbons dispersed in the feldspathic mixture. The microstructure and c axis crystallographic preferred orientation are similar in the thick monomineralic band and in the thin ribbons, and suggest dominant subgrain rotation recrystallization and activity of prism ⟨a⟩ and rhomb ⟨a⟩ slip systems. However, the grain size in monophase recrystallized domains decreases when moving from the transposed veins to the thin ribbons embedded in the feldspathic C' bands (14 μm vs. 5 μm, respectively). The fine-grained feldspar mixture has a weak crystallographic preferred orientation interpreted as the result of oriented growth during diffusion creep, as well as the same composition as the fractured porphyroclasts, suggesting that it generated by mechanical fragmentation of rigid porphyroclasts with a negligible role of chemical disequilibrium. Assuming that the C' shear bands deformed under constant stress conditions, the polyphase feldspathic aggregate would have deformed at a strain rate one order of magnitude faster than the monophase quartz ribbons. Overall, our dataset indicates that feldspar underwent a brittle-viscous transition while quartz was deforming via crystal plasticity. The resulting rock microstructure consists of a two-phase rheological mixture (fine-grained feldspars and recrystallized quartz) in which the polyphase feldspathic material localized much of the strain. Extensive grain-size reduction and weakening of feldspars is attained in the East Pernambuco mylonites mainly via fracturing under relatively fluid-absent conditions which would trigger a switch to diffusion creep and further strain localization without a prominent role of metamorphic reactions.


2001 ◽  
Vol 34 (1) ◽  
pp. 129 ◽  
Author(s):  
Α. ΑΥΓΕΡΙΝΑΣ ◽  
Α. ΚΙΛΙΑΣ ◽  
Α. ΚΟΡΩΝΑΙΟΣ ◽  
Δ. ΜΟΥΝΤΡΑΚΗΣ ◽  
W. FRISCH ◽  
...  

The kinematic of the Cretaceous deformation and the relationship between deformation and metamorphism of the Pelagonian crystalline was studied in Voras Mt (northern Greece). The Pelagonian crystalline in this area has been subdivided into a lower, core part, consisting mainly of gneissic rocks and schists and an upper, cover part, consistine of schists and quartzites with marble intercalations. Intensely deformed granitic rocks of Upper Paleozoic age intrude the Pelagonian crystalline basement. An S j foliation is the oldest fabric recognized in the Pelagonian crystalline. Sj is mainly defined by syn-Sjgarnet(Gr1), biotite(Btj), white mica (Wnij), chloritoid, kyanite and plagioclase in the metapelitic rocks and green amphibole, epidote, plagioclase, and biotiteiBtj) in the amphibolite. Garnet grows also in some cases post-kinematically. Ilmenite and tourmaline are often found in the pelitic rocks as well. S is overprinted by an S2 foliation that developed as a crenulation cleavage. In most places, however, S2 has destroyed all earlier fabrics and a single S2 fabric is present related to, isoclinal or sheath folds intrafolial in places. S2 in the metapelitic rocks is characterized by the syn-S2 development of chlorite, white mica(Wm2) and plagioclase. In the amphibolite S2 is mainly defined by the syn-kinematic development of actinolite, plagioclase, biotite(Bt2), white mica(Wm2) and chlorite. During D2 garnet(Gr1) and biotiteiBtj) are partially replaced by chlorite, while green amphibole is replaced by actinolite and chlorite. Chloritoid remains generally stable along the S2-planes but in some places transforms to chlorite and sericite. Furthermore, D2 was locally followed by a static post-kinematic annealing indicated by polygonal quartz microfabrics with equilibrated grain boundaries and triple points. The overall orientation of S2 is dome shaped with a gentle SW-ward and NE-ward dip in the southwestern and northeastern flanks of the dome respectively. Syn-S2 minerals defined a very well exposed NW-SE trending stretching lineation. Kinematic indicators show a main top to the SE sense of movement. An S3 crenulation cleavage associated with asymmetric NW-SE trending folds is also present in most parts of the core and cover rocks, possibly, related to a constrictional type of deformation. A well developed, S4 shear band cleavage is mainly present in the upper parts of the metamorphic dome and formed under cooler conditions. S4 shear bands are associated with a NW-SE developed stretching lineation defined by elongated and dynamically recrystallized quartz grains and a preferred orientation of white mica and chlorite. Along the S4 shear bands a transformation of garnet, biotite, chloritoid and amphibole into chlorite is always observed. S4 shear bands indicate a main top to the SE sense of movement. The P-T metamorphic conditions were derived from textural equilibria and mineral assemblages, as well as from the spatial distribution of the metamorphic minerals. Syn-Dj metamorphism reached the conditions of the boundaries between greenschist and amphibolite facies. Syn-D2 retrogression took place under greenschist facie conditions. K/Ar radiometric datings on coarse-grained syn-St and younger fine-grained syn-S2 micas define an Early Cretaceous cooling age ('135Ma) for the older event and a Mid- to Late Cretaceous age ('90-80Ma) for the second event. A white mica age of ca. 65Ma correlates with S4 shear band clevage. Furthermore, the intrusion age of a granitic body into the Pelagonian crystalline is dated using the Pb/Pb single zircon evaporation method. The estimated intrusion age of 300±3Ma suggests that the Pelagonian crystalline was affected by a pre-kinematic magmatic activity relative to its Cretaceous deformation.


Author(s):  
Johann Kappacher ◽  
Oliver Renk ◽  
Daniel Kiener ◽  
Helmut Clemens ◽  
Verena Maier-Kiener

Abstract Due to their outstanding properties, ultra-fine-grained tungsten and its alloys are promising candidates to be used in harsh environments, hence it is crucial to understand their high temperature behavior and underlying deformation mechanisms. Therefore, advanced nanoindentation techniques were applied to ultra-fine-grained tungsten–rhenium alloys up to 1073 K. A continuous hardness decrease up to 0.2 $$T_{\text{m}}$$ T m is rationalized by a still dominating effect of the Peierls stress. However, the absence of well-established effects of Rhenium alloying, resulting in a reduced temperature dependence of strength for coarse-grained microstructures, was interpreted as an indication for a diminishing role of kink-pair formation in ultra-fine-grained metals with sufficiently fine grain size. Despite slight grain growth in W, dislocation–grain boundary interaction was identified as the dominating deformation mechanism above 0.2 $$T_{\text{m}}$$ T m . Interaction and accommodation of lattice dislocations with grain boundaries was affected by a reduced boundary diffusivity through alloying with Re. Graphic abstract


2018 ◽  
Vol 8 (12) ◽  
pp. 2584 ◽  
Author(s):  
Tao Wang ◽  
Sihong Liu ◽  
Yan Feng ◽  
Jidu Yu

Gap-graded soil-rock mixtures (SRMs), composed of coarse-grained rocks and fine-grained soils particles, are very inhomogeneous materials and widely encountered in geoengineering. In geoengineering applications, it is necessary to know the compaction characteristics in order to estimate the minimum void ratio of gap-graded SRMs. In this paper, the void ratios of compacted SRMs as well as the particle breakage during vibrating compaction were investigated through a series of vibrating compaction tests. The test results show that gap-graded SRMs may reach a smaller void ratio than the SRM with a continuous gradation under some circumstances. When the particles in a gap interval play the role of filling components, the absence of them will increase the void ratio of the SRM. The particle breakage of gap-graded SRMs is more prominent than the SRM with continuous gradation on the whole, especially at the gap interval of 5–20 mm. Based on the test results, a minimum void ratio prediction model incorporating particle breakage during compaction is proposed. The developed model is evaluated by the compaction test results and its validation is discussed.


Solid Earth ◽  
2016 ◽  
Vol 7 (2) ◽  
pp. 375-396 ◽  
Author(s):  
Gustavo Viegas ◽  
Luca Menegon ◽  
Carlos Archanjo

Abstract. The Pernambuco shear zone (northeastern Brazil) is a large-scale strike-slip fault that, in its eastern segment, deforms granitoids at mid-crustal conditions. Initially coarse-grained (> 50 µm) feldspar porphyroclasts are intensively fractured and reduced to an ultrafine-grained mixture consisting of plagioclase and K-feldspar grains (< 15 µm) localized in C' shear bands. Detailed microstructural observations and electron backscatter diffraction (EBSD) analysis do not show evidence of intracrystalline plasticity in feldspar porphyroclasts and/or fluid-assisted replacement reactions. Quartz occurs either as thick (∼ 1–2 mm) monomineralic veins transposed along the shear zone foliation or as thin ribbons ( ≤ 25 µm width) dispersed in the feldspathic mixture. The microstructure and c axis crystallographic-preferred orientation are similar in the thick monomineralic veins and in the thin ribbons, and they suggest dominant subgrain rotation recrystallization and activity of prism < a > and rhomb < a > slip systems. However, the grain size in monophase recrystallized domains decreases when moving from the quartz monomineralic veins to the thin ribbons embedded in the feldspathic C' bands (14 µm vs. 5 µm respectively). The fine-grained feldspar mixture has a weak crystallographic-preferred orientation interpreted as the result of shear zone parallel-oriented growth during diffusion creep, as well as the same composition as the fractured porphyroclasts, suggesting that it generated by mechanical fragmentation of rigid porphyroclasts with a negligible role of chemical disequilibrium. Once C' shear bands were generated and underwent viscous deformation at constant stress conditions, the polyphase feldspathic aggregate would have deformed at a strain rate 1 order of magnitude faster than the monophase quartz monomineralic veins, as evidenced by applying experimentally and theoretically calibrated flow laws for dislocation creep in quartz and diffusion creep in feldspar. Overall, our data set indicates that feldspar underwent a brittle-viscous transition while quartz was deforming via crystal plasticity. The resulting rock microstructure consists of a two-phase rheological mixture (fine-grained feldspars and recrystallized quartz) in which the polyphase feldspathic material localized much of the strain. Extensive grain-size reduction and weakening of feldspars is attained in the East Pernambuco mylonites mainly via fracturing which would trigger a switch to diffusion creep and strain localization without a prominent role of metamorphic reactions.


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