scholarly journals Distribution of Selenium in the Soil–Plant–Groundwater System: Factors Controlling Its Bio-Accumulation

Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 795
Author(s):  
George D. Eliopoulos ◽  
Ioannis-Porfyrios D. Eliopoulos ◽  
Myrto Tsioubri ◽  
Maria Economou-Eliopoulos

Selenium (Se) is an essential micronutrient for humans and animals, but both Se excess and deficiency can cause various health risks. Since Greece is among the European countries where people have very low Se-serum, the present study is focused on the Se distribution in cultivated and non-cultivated plants and relative soil coming from the Neogene basins of Greece (Assopos-Thiva and Attica), aiming to define potential Se-source/es and factors controlling Se bio-accumulation and enrichment in food. The dry weight Se values are relatively low (0.1–0.9 mg/kg) with the highest Se contents in garlic, beet and lettuce from the Assopos basin, where the translocation percentage [(mplant/msoil) × 100] for Se, P and S is much higher compared to non-cultivated Attica basin. There is a diversity between the Se source in soil and coastal groundwater which is used for irrigation in the cultivated Assopos–Thiva basin. The soil pH and oxidizing conditions (Eh) are considered the main driving force to make Se available for plant uptake. Potential sources for Se in Greece are Fe-Cu-Zn-sulphide ores and peat deposits in northern Greece, with a Se content ranging from decades to hundreds of mg/kg. Application of the leaching testing protocol is necessary to select the most appropriate proportion of additives to improve the Se deficiencies in agricultural soil.

Radiocarbon ◽  
2015 ◽  
Vol 57 (5) ◽  
pp. 807-823 ◽  
Author(s):  
Yannis Maniatis ◽  
Nerantzis Nerantzis ◽  
Stratis Papadopoulos

Radiocarbon dates obtained for the coastal hilltop settlement of Aghios Antonios Potos in south Thasos are statistically treated to define the absolute chronology for the start and the end of the various habitation and cultural phases at the site. The location was first occupied during the Final Neolithic (FN) between 3800 and 3600 BC, extending this much contested phase to the lowest up to now record for Thasos and the northern Greece. The site is continuously inhabited from Early Bronze Age I until the early Late Bronze Age (LBA; 1363 BC) when it was abandoned. Comparison with other sites in Thasos and particularly with the inland site of Kastri Theologos showed that the first occupation at Aghios Antonios came soon after the abandonment of Kastri in the beginning of the 4th millennium. In fact, after the decline and abandonment of Aghios Antonios in the LBA, the site of Kastri was reinhabited, leading to the hypothesis that part of the coastal population moved inland. The presumed chronological sequence of alternate habitation between the two settlements may evoke explanations for sociocultural and/or environmental dynamics behind population movements in prehistoric Thasos. A major conclusion of the project is that the 4th millennium occupation gap attested in many sites of Greece, especially in the north, is probably bridged in south Thasos, when the data from all sites are taken together. The mobility of people in Final Neolithic south Thasos may explain the general phenomenon of limited occupational sequences in the FN of north Greece.


2021 ◽  
Vol 8 (1) ◽  
pp. 1-5
Author(s):  
Nahla S El-Shenawy ◽  
Heba N Gad EL-Hak ◽  
Mahi A Ghobashy ◽  
Maha FM Soliman ◽  
Farida A Mansour ◽  
...  

Accumulation of heavy metals in fish is considered a critical problem for human health. Therefore, the study aimed to quantify the concentrations of iron (Fe), zinc (Zn), manganese (Mn), and lead (Pb) in Oreochromis niloticus and Clarias gariepinus from two areas in Al Sharqia governorate, Egypt, from September 2017 to August 2018. A human health risk assessment was conducted to evaluate the potential hazards associated with fish consumption. Metals concentrations (mg/kg dry weight) in muscles of catfish ranged 1.88-221.26 for Fe; 1.78-19.77 for Zn; BDL-238.51 for Mn; BDL-22.75 for Pb. In muscles of tilapia fish metals concentrations ranged 7.96-149.10 for Fe; 1.20-19.77 for Zn; BDL-230.82 for Mn; BDL-25.93 for Pb. Pb had Hazard quotients (HQs) which indicated potential health risks to tilapia consumers at both study areas and catfish consumers at the Faqous area. Fishermen were at higher risk compared to the other consumers.


2016 ◽  
Vol 34 (3) ◽  
pp. 67-74
Author(s):  
James E. Altland ◽  
James C. Locke ◽  
Wendy L. Zellner

Steel slag is a byproduct of the steel industry that can be used as a liming agent, but also has a high mineral nutrient content. While micronutrients are present in steel slag, it is not known if the mineral form of the micronutrients would render them available for plant uptake. The objective of this research was to determine if steel slag could be used as the sole micronutrient source for container-grown nursery crops. Butterfly bush (Buddleja davidii ‘Pink Delight’) and rose (Rosa ‘Radrazz’) were grown in #3 (3 gal) containers in a base substrate composed of pine bark and peatmoss (80:20, by vol). The base substrate was amended with the following treatments: with a complete controlled release fertilizer (CRF) including micronutrients (C-control), a substrate amended with a different CRF containing only N, P, and K along with a granular micronutrient package (M-control), and three additional treatments amended with the CRF (N, P, and K only) and either 1.2, 2.4, or 4.8 kg·m−3 (2, 4, and 8 lb·yd−3) of steel slag. Plants were harvested at 2 and 4 months after potting (MAP). None of the plants displayed any sign of nutrient deficiency or toxicity throughout the experiment. However, plants grown in the substrate amended with the highest slag rate [4.8 kg·m−3 (8 lb·yd−3)] had lower shoot dry weight (SDW) than both control groups. Substrate pH increased with increasing slag rate, which may have affected micronutrient availability in those substrates. Among the micronutrients analyzed, only Copper (Cu) was consistently deficient in both the substrate and foliar tissue of slag-amended treatments. Steel slag either does not provide a sufficient quantity of Cu or the concomitant increase in pH with increasing rates of steel slag renders Cu unavailable for plant uptake. Steel slag should not be used as the sole source of micronutrients for shrubs grown in pine bark-based substrates.


2020 ◽  
Vol 12 (21) ◽  
pp. 8780
Author(s):  
Muhammad Muhaymin Mohd Zuki ◽  
Noraini Md. Jaafar ◽  
Siti Zaharah Sakimin ◽  
Mohd Khanif Yusop

Nitrogen (N) fertilizer is commonly used to supply sufficient N for plant uptake, for which urea is one of the highly preferred synthetic N fertilizers due to its high N content. Unfortunately, N provided by urea is rapidly lost upon urea application to soils through ammonia volatilization, leaching, and denitrification. Thus, treatment of urea with urease inhibitor (N-(n-Butyl) Thiophosphoric Triamide (NBPT)) is among the solutions to slow down urea hydrolysis, therefore reducing loss of NH3 and saving N available for plant uptake and growth. A field study was carried out to evaluate the effects of NBPT-coated urea (NCU) at varying rates on growth, yield, and nitrogen use efficiency (NUE) of maize in tropical soil. The experiment was conducted at Field 15, Universiti Putra Malaysia, Serdang, Selangor, Malaysia, and maize (Zea mays var. Thai Super Sweet) was used as the test crop. The results showed that all maize grown in soils applied with urea coated with NBPT (NCU) (T2, T3, T4, and T5) had significantly (P ≤ 0.05) higher chlorophyll content compared to the control (T0 and T1). The surface leaf area of maize grown in NCU-treated soils at 120 kg N h−1 (T3) was recorded as the highest. NCU at and 96 kg N ha−1 (T3 and T4) were relatively effective in increasing maize plant dry weight, yield, and N uptake. Improvement of NUE by 45% over urea was recorded in the treatment of NCU at 96 kg N ha−1. NBPT-coated urea (NCU) at 96 kg N ha−1 had potential to increase the growth, yield, nitrogen uptake, and NUE of maize by increasing the availability of N for plant growth and development.


1983 ◽  
Vol 100 (1) ◽  
pp. 245-247
Author(s):  
A. Nychas ◽  
V. Skarlou

Nutritional problems for cultivated plants related to phosphorus (P) and zinc (Zn), among other elements, are common in recent alluvial calcareous soils of Greece. The negative interaction which exists between these two elements aggravates these problems.


Minerals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 324 ◽  
Author(s):  
Panagiotis Voudouris ◽  
Vasilios Melfos ◽  
Constantinos Mavrogonatos ◽  
Alexandre Tarantola ◽  
Jens Gӧtze ◽  
...  

Epithermally altered volcanic rocks in Greece host amethyst-bearing veins in association with various silicates, carbonates, oxides and sulfides. Host rocks are Oligocene to Pleistocene calc-alkaline to shoshonitic lavas and pyroclastics of intermediate to acidic composition. The veins are integral parts of high to intermediate sulfidation epithermal mineralized centers in northern Greece (e.g., Kassiteres–Sapes, Kirki, Kornofolia/Soufli, Lesvos Island) and on Milos Island. Colloform–crustiform banding with alternations of amethyst, chalcedony and/or carbonates is a common characteristic of the studied amethyst-bearing veins. Hydrothermal alteration around the quartz veins includes sericitic, K-feldspar (adularia), propylitic and zeolitic types. Precipitation of amethyst took place from near-neutral to alkaline fluids, as indicated by the presence of various amounts of gangue adularia, calcite, zeolites, chlorite and smectite. Fluid inclusion data suggest that the studied amethyst was formed by hydrothermal fluids with relatively low temperatures (~200–250 °C) and low to moderate salinity (1–8 wt % NaCl equiv). A fluid cooling gradually from the external to the inner parts of the veins, possibly with subsequent boiling in an open system, is considered for the amethysts of Silver Hill in Sapes and Kassiteres. Amethysts from Kornofolia, Megala Therma, Kalogries and Chondro Vouno were formed by mixing of moderately saline hydrothermal fluids with low-salinity fluids at relatively lower temperatures indicating the presence of dilution processes and probably boiling in an open system. Stable isotope data point to mixing between magmatic and marine (and/or meteoric) waters and are consistent with the oxidizing conditions required for amethyst formation.


1998 ◽  
Vol 13 (4) ◽  
pp. 222-226 ◽  
Author(s):  
A. C. Stergiou ◽  
D. K. Gioureli

Samples of the mineral ferroan clinozoisite from three localities of Greece (Paranesti-Drama, Xanthi, and Petritsi-Serres), with chemical formula Ca2Al3−xFexSi3O13H (x=0.55, 0.58, and 0.46, respectively), were measured by X-ray powder diffraction, using CoKa radiation. The PDF and bibliographic information were used in order to identify additional phases in the samples. Refinement combined with PDF resulted in the following: ferroan clinozoisite (100%) for the first sample, ferroan clinozoisite (97%) and malladrite (3%) for the second one, and ferroan clinozoisite (75%), clinopyroxene (20%), and malladrite (5%) for the third one. The crystal structure refinement was performed by the “Powder profile analysis (Rietveld)”. P21/m space group was chosen for the ferroan clinozoisite phases, with unit cell constants a=8.8919(5) Å, b=5.6260(3) Å, c=10.1570(6) Å, β=115.418(3)° (Paranesti), a=8.8944(7) Å, b=5.6394(4) Å, c=10.1626(8) Å, β=115.400(5)° (Xanthi) a=8.8965(8) Å, b=5.6372(4) Å, c=10.1595(9) Å, β=115.411(6)° (Petritsi) almost similar for the three samples, while the final R-p factors were 0.069, 0.064, and 0.063, respectively.


2021 ◽  
Vol 11 (2) ◽  
pp. 45
Author(s):  
Muhammad Aziz Setiawan ◽  
Sismita Sari ◽  
Mirodi Syofian

Weed control must use the right dose of herbicide so as not to leave a residual effect on cultivated plants and soil. This study ains to obtain the most appropriate dose of herbicide. Herbicide used in this study were methyl methulfuron and acetic acid combined. This study used a randomized block design (RCBD) witch 2 factors, factor A was asetic acid and factor B was methyl methulfuron and there were 12 treatment combinations with 3 replications. This research was conducted in the practicum of the Departement of Plantation Plant Cultivation, Lampung State Polytechnic. The total research plot was 36 experimentals units. The dosage levels levels of methyl methulfuron tested in this study were: 0%, 55%, 75%, and 105%. While the dose of acetic acid is: 0%, 50%, and 70%. Observations made in this study were weed vegetation analysis, weed cover percent, weed dry weight, Summed Dominance Ratio (SDR), and Community Coefficient Value (C). SDR values indicate that Panicum dicotomyflorum weed, Ricardia brasiliensis, Euphorbia heterophyla, and Cyperus rotundus are the dominant weeds. The results of this study indicate that there is no effect on the dose of methyl methulfuron herbicide, acetic acid, and interactions on methyl methulfuron herbicide and acetic acid on weed control in sugarcane fields (Saccharum officinarum L.).


2013 ◽  
Vol 47 (1) ◽  
pp. 477 ◽  
Author(s):  
P. Voudouris ◽  
I. Psimis ◽  
C. Mavrogonatos ◽  
C. Kanellopoulos ◽  
M. Kati ◽  
...  

Epithermal-altered volcanic rocks in Greece host gem-quality amethyst veins in association with various silicates, carbonates, oxides, sulfides and halides. Host rocks are Oligocene to recent calc-alkaline to shoshonitic lavas and pyroclastics of intermediate- to acid composition. The amethyst-bearing veins occur in the periphery of porphyry-type and/or high-sulfidation epithermal mineralized centers in northern Greece (e.g. Sapes, Kirki, Kornofolia/Soufli, Lesvos island) and on Milos island in the active Aegean Volcanic Arc. Hydrothermal alteration around the quartz veins includes sericitic, K-feldspar (adularia), argillic, propylitic and zeolitic types. Precipitation of amethyst in the northern Greece occurrences, took place during the final stages of the magmatic-hydrothermal activity from near-neutral to alkaline fluids, as indicated by the presence of gangue adularia, calcite, smectite, chlorite, sericite, pyrite, zeolites (laumontite, heulandite, clinoptilolite), analcime and minor amounts of barite, halite, epidote and fluorite in the quartz veins. Amethyst at Milos Island (Chondro Vouno and Kalogries-Vani areas), is accompanied by barite, smectite and lepidocrocite. Colloform-crustiform banding with alternations of amethyst, chalcedony and/or carbonates is a common characteristic of the studied amethyst-bearing veins. Fluid inclusion- and mineralogical data suggest that the studied amethyst were formed at: 174-246 °C (Sapes area), 100-175 °C (Kirki and Kornofolia areas) and 223-234°C (Lesvos island). The amethyst formation requires oxidizing conditions and is probably the result of mixing between meteoric or seawater with upwelling hydrothermal fluids. The involvement of seawater in the studied mineralization is supported by the presence of halite and abundant barite in the veins. Finally, the studied amethyst deposits should be evaluated as potential gemstone sources in Greece.


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