scholarly journals Evaluation of New Applications of Oil Shale Ashes in Building Materials

Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 765
Author(s):  
Mustafa Cem Usta ◽  
Can Rüstü Yörük ◽  
Tiina Hain ◽  
Peeter Paaver ◽  
Ruben Snellings ◽  
...  
Keyword(s):  
Oil Shale ◽  
Building Materials ◽  
Mineralogical Composition ◽  
Accelerated Carbonation ◽  
Zero Waste ◽  
Clay Bricks ◽  
Carbon Neutral ◽  
New Applications ◽  
Future Utilization

Achieving sustainable zero-waste and carbon neutral solutions that contribute to a circular economy is critically important for the long-term prosperity and continuity of traditional carbon-based energy industries. The Estonian oil shale (OS) sector is an example where such solutions are more than welcome. The combustion of OS generates a continuous flow of ashes destined to landfills. In this study, the technical feasibility of producing monolith building materials incorporating different OS ashes from Estonia was evaluated. Three binder systems were studied: self-cementation of the ashes, ceramic sintering in clay brick production and accelerated carbonation of OS ash (OSA) compacts. Results showed that most of the OSAs studied have low self-cementitious properties and these properties were affected by ash fineness and mineralogical composition. In case of clay bricks, OSA addition resulted in a higher porosity and improved insulation properties. The carbonated OSA compacts showed promising compressive strength. Accelerated carbonation of compacted samples was found to be the most promising way for the future utilization of OSAs as sustainable zero-waste and carbon neutral solution.

Influence of Pozzolana Admixture on Long-Term Chemical Characteristic of Cement Mortars

2013 ◽  
Vol 438-439 ◽  
pp. 50-53 ◽  
Author(s):  
Daniel Dobiáš ◽  
Radka Pernicová
Keyword(s):  
Cement Mortar ◽  
Chemical Properties ◽  
Mineralogical Composition ◽  
Chemical Characteristic ◽  
Time Intervals ◽  
Clay Bricks ◽  
Cement Mortars ◽  
Aggressive Liquid ◽  
Predetermined Time

nfluence of non-flowing model sulphate solution determined for cement mortar with pozzzolana admixture are presented in this paper. In the predetermined time intervals the influence of the aggressive liquid on chemical properties and mineralogical composition was tested. The changes caused by corrosive sulphate environment on the testing specimens were determined in dependence on the different type of cement and used ground clay brick as pozzolana admixture. From the results obtained follows that the additive of ground clay bricks has positively impact on the sulphate resistance.

scholarly journals The benefic effect of Moroccan oil shale’s ash on blended cement (CMII)

2018 ◽  
Vol 149 ◽  
pp. 01023
Author(s):  
Nour El Houda Hamsi ◽  
Khadija Nabih ◽  
Redwan Barbach
Keyword(s):  
Heat Treatment ◽  
Oil Shale ◽  
Building Materials ◽  
Blended Cement ◽  
Mineralogical Composition ◽  
X Ray Diffraction ◽  
Free Lime ◽  
X Ray ◽  
Mineral Compositions ◽  
Oil Shales

Recycling of Tarfaya’s oil shales (OSA) was conducted for two essential reasons: First, to follow the change of their mineralogical composition with the heat treatment and second to investigate the possibility of their use in building materials. The mineral compositions and the mineralogical transformations of the oil shale during their thermal treatment were followed respectively by X-ray fluorescence (XRF), by X-ray diffraction analysis (XRD) and Fourier transform infrared (FTIR). The XRF showed that the mineral composition of the ash burned at 850°C is similar to that of Portland clinker and the DRX showed the presence of quartz, mayenite, gehlenite, anydrite, hematite and lime as well as the existence of some characteristics phases of the clinker as C2S, C3A and C4AF. The Infrared spectrum showed the various functional groups that exist in OSA. The substitution of cement CMII by OSA increased the content of free lime and Blaine specific surface. The ash influenced beneficially the mechanical strength of the blended cement. The best results were obtained at all times of curing (2, 7, 28 and 91 Days) for the substitution of CMII by 7 and 10 % of OSA.

scholarly journals Features of the Technology of Application of Industrial Waste in the Construction of Constructive Layers of Roadwear

2021 ◽  
Vol 25 (1) ◽  
pp. 965-977
Author(s):  
Maxat Shanbayev ◽  
Khalima Turgumbayeva ◽  
Dagnija Blumberga ◽  
Tuleuzhan Beysekova
Keyword(s):  
Industrial Waste ◽  
Building Materials ◽  
Road Construction ◽  
Mineralogical Composition ◽  
Raw Material ◽  
Material Base ◽  
Grain Composition ◽  
The Republic ◽  
Mineral Mixtures

Abstract In this article, work was carried out to study the chemical, mineralogical composition and toxicological properties of waste (phosphogypsum, phosphorus slags, overburden) of the phosphorus industry, the optimal content of the grain composition of gravel-sand mixtures in the composition of road mixtures (crushed stone, sand-gravel, sand) and structures of the Zhambyl region of the Republic of Kazakhstan. The possibilities of using slag-mineral mixtures in the year - round construction of highways were studied on the basis of a comprehensive study of the physicochemical processes of hardening and the formation of the structure of slag-mineral materials at negative temperatures. Technological regimes for the construction of roads of various technical categories from slag binding materials, reformed after long-term freezing, have been established. New, unparalleled, binding road mixtures have been created to increase the utilization of waste from the phosphorus industry and expand the raw material base of road building materials. The main directions of application of road mixtures based on industrial waste for the purposes of road construction have been developed: construction of structural layers of road pavements; construction of road bed layers.

THE FEATURES OF BIODESTRUCTION PROCESSES OF THE SURFACES OF HYDRAULIC ENGINEERING CONSTRUCTIONS

2017 ◽  
Author(s):  
Marina Vasilenko ◽  
Marina Vasilenko ◽  
Elena Goncharova ◽  
Elena Goncharova ◽  
Yury Rubanov ◽  
...  
Keyword(s):  
Surface Layer ◽  
Environmental Factors ◽  
Food Chain ◽  
Building Materials ◽  
Microbial Growth ◽  
Mineralogical Composition ◽  
Mechanical Action ◽  
Chemical Processes ◽  
Hydraulic Engineering ◽  
Optimal Conditions

The surfaces of building materials of hydrotechnical constructions undergo the process of algae biofouling. The degree of damage depends on the environmental factors that are affect-ed by the level of anthropogenic load areas. Modeling the biofouling process of concrete with algae under laboratory conditions has allowed determining their impact on the building ma-terial, accompanied by changes in chemical and mineralogical composition of the surface of products. The microscopic examination of sample’s surfaces and evaluation of the effective-ness of various ions leaching from building materials shows the results of "algal attack" relat-ed to the acceleration of biodegradation of materials under the influence of aggressive meta-bolic products, mechanical action neoplasms, creating optimal conditions for the development of subsequent aerobic microbial decomposers. To clarify the nature of chemical processes in the system “algocenosis – concrete” the changes of chemical and phase (mineralogical) com-position of the surface layer of concrete sample were studied. The effect that algae produce on hydraulic engineering constructions is due to the fact that these organisms, belonging to phototrophs and standing at the beginning of the food chain, initiate new microbial growth.

THE FEATURES OF BIODESTRUCTION PROCESSES OF THE SURFACES OF HYDRAULIC ENGINEERING CONSTRUCTIONS

2017 ◽  
Author(s):  
Marina Vasilenko ◽  
Marina Vasilenko ◽  
Elena Goncharova ◽  
Elena Goncharova ◽  
Yury Rubanov ◽  
...  
Keyword(s):  
Surface Layer ◽  
Environmental Factors ◽  
Food Chain ◽  
Building Materials ◽  
Microbial Growth ◽  
Mineralogical Composition ◽  
Mechanical Action ◽  
Chemical Processes ◽  
Hydraulic Engineering ◽  
Optimal Conditions

The surfaces of building materials of hydrotechnical constructions undergo the process of algae biofouling. The degree of damage depends on the environmental factors that are affect-ed by the level of anthropogenic load areas. Modeling the biofouling process of concrete with algae under laboratory conditions has allowed determining their impact on the building ma-terial, accompanied by changes in chemical and mineralogical composition of the surface of products. The microscopic examination of sample’s surfaces and evaluation of the effective-ness of various ions leaching from building materials shows the results of "algal attack" relat-ed to the acceleration of biodegradation of materials under the influence of aggressive meta-bolic products, mechanical action neoplasms, creating optimal conditions for the development of subsequent aerobic microbial decomposers. To clarify the nature of chemical processes in the system “algocenosis – concrete” the changes of chemical and phase (mineralogical) com-position of the surface layer of concrete sample were studied. The effect that algae produce on hydraulic engineering constructions is due to the fact that these organisms, belonging to phototrophs and standing at the beginning of the food chain, initiate new microbial growth.

scholarly journals Application of Plastic Wastes in Construction Materials: A Review Using the Concept of Life-Cycle Assessment in the Context of Recent Research for Future Perspectives

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3549
Author(s):  
Tulane Rodrigues da Silva ◽  
Afonso Rangel Garcez de Azevedo ◽  
Daiane Cecchin ◽  
Markssuel Teixeira Marvila ◽  
Mugahed Amran ◽  
...  
Keyword(s):  
Life Cycle Assessment ◽  
Life Cycle ◽  
Solid Waste ◽  
Building Materials ◽  
Construction Materials ◽  
Plastic Waste ◽  
Plastic Wastes ◽  
Solid Waste Generation ◽  
Alternative Processes

The urbanization process contributes to the growth of solid waste generation and causes an increase in environmental impacts and failures in the management of solid waste. The number of dumps is a concern due to the limited implementation and safe disposal of this waste. The interest in sustainable techniques has been growing in relation to waste management, which is largely absorbed by the civil construction sector. This work aimed to review plastic waste, especially polyethylene terephthalate (PET), that can be incorporated with construction materials, such as concrete, mortars, asphalt mixtures, and paving. The use of life-cycle assessment (LCA) is related, as a tool that allows the sustainability of products and processes to be enhanced in the long term. After analyzing the recent literature, it was identified that studies related to plastic wastes in construction materials concentrate sustainability around the alternative destination of waste. Since the plastic waste from different production chains are obtained, it was possible to affirm the need for a broader assessment, such as the LCA, providing greater quantification of data making the alternative processes and products more sustainable. The study contributes to enhance sustainability in alternative building materials through LCA.

scholarly journals Physicochemical Properties of Handere Clays and Their Use as a Building Material

2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Yasin Erdoğan
Keyword(s):  
Physicochemical Properties ◽  
Building Materials ◽  
Raw Materials ◽  
Organic Matter Content ◽  
Volcanic Glass ◽  
Mineralogical Composition ◽  
Matter Content ◽  
Loss On Ignition ◽  
X Ray Diffraction ◽  
Clay Deposits

Handere clay deposits were discovered at Adana in Turkey. These clay units primarily consist of uncoloured claystone, pebbly sandstone, sandstone, siltstone, and mudstone marl and include gypsum lenses and clay levels of various thicknesses in places. The physicochemical properties of these clays have been investigated by different techniques including Scanning Electron and Elemental Analysis (SEM and EDS), mineralogical analyses, chemical and physical analyses, X-ray diffraction (XRD), thermogravimetric differential thermal analysis (TG-DTA), and Atterberg (Consistency) Limits Test. The mineralogical composition deduced from XRD is wide (smectite + palygorskite + illite ± feldspar ± chlorite ± quartz ± calcite ± serpentine) due to the high smectite contents (≈85%). SEM studies reveal that smectite minerals are composed of irregular platy leaves and show honeycomb pattern in the form of wavy leaves in places. The leaves presenting an array with surface edge contact are usually concentrated in the dissolution voids and fractures of volcanic glass. Organic matter content and loss on ignition analysis of raw materials are good for all the studied samples. In summary, Handere clays can be used as building materials in bricks, roof tiles, and cement and as a binder.

Influences on the Hydrophobicity of Concrete Surfaces Treated with Alkyl Trialkoxysilanes

2014 ◽  
Vol 20 (6) ◽  
pp. 405-412
Author(s):  
U. Antons ◽  
M. Raupach ◽  
O. Weichold
Keyword(s):  
Uv Radiation ◽  
Cement Hydration ◽  
Alkaline Media ◽  
Water Repellent ◽  
Portland Cement Concrete ◽  
Accelerated Carbonation ◽  
Surface Layers ◽  
Hydrophobic Layer ◽  
Furnace Slag

Abstract The paper focuses on how alkaline media, UV radiation, and carbonation as well as on-going cement hydration affects hydrophobic treatments of concrete and influences the properties of these water-repellent layers. Single-sided nuclear magnetic resonance measurements show that layers formed by impregnating samples with alkyl trialkoxysilanes are stable even under long-term exposure to alkaline solution and UV radiation, with the damage of the latter being limited to the topmost surface layers. Microstructural changes during accelerated carbonation of blast furnace slag cement based concrete have a major impact on the hydrophobic layer properties, while the carbonation of Portland cement concrete has no influence. On-going hydration additionally influences the hydrophobic layer properties.

scholarly journals Use of Ash-and-Slag Wastes after Burning of Fine-Dispersed Coal-Washing Wastes

2018 ◽  
Vol 41 ◽  
pp. 01042
Author(s):  
Vasilii Murko ◽  
Veniamin Khyamyalyainen ◽  
Marina Baranova
Keyword(s):  
Power Plants ◽  
Building Materials ◽  
Negative Impact ◽  
Mineralogical Composition ◽  
Unburned Carbon ◽  
Crushed Rock ◽  
Low Carbon ◽  
Technological Parameters ◽  
Coal Fuel ◽  
Granulated Slag

Effective utilization of ash-and-slag waste generated by coalfired power plants can help significantly to reduce the negative impact on the environment and improve their economic performance. Studies have been made of the mineralogical composition of ash-and-slag wastes obtained after the combustion of water-coal fuel based on fine-dispersed coal-washing waste (filter cake) in a specially designed boiler with a vortex combustion system. The possibility of effective use of ash-and-slag wastes for the production of building materials, primarily mortar mixes, widely used for mining works on mine openings, laying the worked out space, etc. (high content of silicon oxide and aluminum oxide is combined with a low carbon content in other words a negligible unburned carbon loss). The optimum percentage ratio of the initial components of the filling mixture based on ash-and-slag wastes and crushed rock (granulated slag) has been established. The results of experimental tests of hardening tabs on the strength under uniaxial compression are presented. It has been established that a sample containing 18% of ash-and-slag wastes, 33% of a granulated slag and 19% of cement, corresponds to the required technological parameters for the strength and cement content.

scholarly journals Shell mineralogy of a foundational marine species, Mytilus californianus, over half a century in a changing ocean

2021 ◽  
Vol 118 (3) ◽  
pp. e2004769118
Author(s):  
Elizabeth M. Bullard ◽  
Ivan Torres ◽  
Tianqi Ren ◽  
Olivia A. Graeve ◽  
Kaustuv Roy
Keyword(s):  
Ocean Acidification ◽  
Historical Data ◽  
Mineralogical Composition ◽  
Marine Species ◽  
Mytilus Californianus ◽  
Negative Effects ◽  
Saturation State ◽  
Long Term Changes ◽  
Time Periods

Anthropogenic warming and ocean acidification are predicted to negatively affect marine calcifiers. While negative effects of these stressors on physiology and shell calcification have been documented in many species, their effects on shell mineralogical composition remains poorly known, especially over longer time periods. Here, we quantify changes in the shell mineralogy of a foundation species, Mytilus californianus, under 60 y of ocean warming and acidification. Using historical data as a baseline and a resampling of present-day populations, we document a substantial increase in shell calcite and decrease in aragonite. These results indicate that ocean pH and saturation state, not temperature or salinity, play a strong role in mediating the shell mineralogy of this species and reveal long-term changes in this trait under ocean acidification.

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