scholarly journals Assessing Options for Remediation of Contaminated Mine Site Drainage Entering the River Teign, Southwest England

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 721 ◽  
Author(s):  
Abigail Jordan ◽  
Rachel Hill ◽  
Adrienne Turner ◽  
Tyrone Roberts ◽  
Sean Comber

The river Teign in Devon has come under scrutiny for failing to meet environmental quality standards for ecotoxic metals due to past mining operations. A disused mine known as Bridford Barytes mine, has been found to contribute a significant source of Zn, Cd and Pb to the river. Recently, studies have been focused on the remediation of such mine sites using low-cost treatment methods to help reduce metal loads to the river downstream. This paper explores the metal removal efficiency of red mud, a waste product from the aluminium industry, which has proven to be an attractive low-cost treatment method for adsorbing toxic metals. Adsorption kinetics and capacity experiments reveal metal removal efficiencies of up to 70% within the first 2 h when red mud is applied in pelletized form. Further, it highlights the potential of biochar, another effective adsorbent observed to remove >90% Zn using agricultural feedstock. Compliance of the Teign has been investigated by analysing dissolved metal concentrations and bioavailable fractions of Zn to assess if levels are of environmental concern. By applying a real-world application model, this study reveals that compressed pellets and agricultural biochar offer an effective, low-cost option to reducing metal concentrations and thus improving the quality of the river Teign.

Author(s):  
Abigail Jordan ◽  
Rachel Hill ◽  
Adrienne Turner ◽  
Tyrone Roberts ◽  
sean Comber

The river Teign in Devon has come under scrutiny for failing to meet Environmental Quality Standards for ecotoxic metals due to past mining operations. A disused mine known as Bridford Barytes mine, has been found to contribute a significant source of Zn, Cd and Pb to the river. Recently, studies have been focused on the remediation of such mine sites using low-cost treatment methods to help reduce metal loads to the river downstream. Red mud is a waste product from the aluminium industry, the utilization of this resource has proven an attractive low-cost treatment method for adsorbing toxic metals. Adsorption kinetics and capacity experiments reveal metal removal efficiencies of up to 70% within the first 2 hours when red mud is applied in pelletized form. Biochar is another effective adsorbent with the potential to remove >90% Zn using agricultural feedstock. Compliance of the Teign has been investigated by analysing dissolved metal concentrations and bioavailable fractions of Zn to assess if levels are of environmental concern. By applying a Real-World Application Model, this study reveals that compressed pellets and agricultural biochar offer an effective, low-cost option to reducing metal concentrations and thus improving the quality of the river Teign.


2019 ◽  
pp. 277-286
Author(s):  
Emma Nehrenheim

In Sweden there are many old landfills of which the content is more or less unknown, Theleachates from these are of varying quality, mirroring the waste deposited in the landfills,Metals commonly occurring in leachates are i,e, zink (Zn), lead (Pb), cupper (Cu) and nickel(Ni), Ni is of particular interest due to the un-predictable mobility of the metal, For small,weak leachates a passive low-cost treatment system can be suitable, Reactive filter technologyis one alternative and by using by-products from national and global industries theenvironmental benefit could be further increased, Pine bark (from pulp and paper industry)and blast furnace slag (from steel manufacturing) are examples of such materials, Designingfilters for removal of metals from leachate includes taking a series of parameters into accountAt the landfill site in Eskilstuna, Sweden, a facility was designed as a pilot study, Fourcolumns were filled with filter material, The materials were sand, amorphous and crystallineblast furnace slag and pine bark, The aim was to investigate parameters significant for metaluptake from landfill leachate, A screening of the metals, physio-chemical parameters andsome organic pollutants was conducted for a period of five months, A part from this, a batchexperiment was conducted, Contact time, initial concentration, other leachate components andpH are examples of parameters that have a significant influence on the metal removingcapacity of a filter,


2012 ◽  
Vol 454 ◽  
pp. 231-236
Author(s):  
Fan Na Meng ◽  
Guo Gang Zhao ◽  
Hai Jun Zhang

Mine drainage is a widespread environmental problem associated with both working and abandoned mining operations, resulting from the microbial oxidation of pyrite in presence of water and air, affording a solution that contains toxic metal ions. The present study aimed at evaluating the use of low-cost modified mordenitem to remove heavy metals ions from mine drainage. We elucidate the important parameters (including the pH, temperature, contact time, particle size and dosage) responsible for the removal the heavy metal ions. In addition, selectivity of modified mordenitem for metal removal was, in decreasing order, Pb2+> Cd2+ > Cu2+ > Zn2+. Based on these results, the use of these materials has the potential to provide improved methods for the treatment of mine drainage.


2020 ◽  
Vol 108 (11) ◽  
pp. 879-887
Author(s):  
Maha A. Youssef ◽  
Hoda E. Rizk ◽  
Mohamed F. Attallah

AbstractThe quantity of liquid organic radioactive wastes produced by the use of radioactive materials in nuclear research facilities is small compared to aqueous radioactive waste, but a special and low-cost treatment method is needed. Here we investigated the adsorption performance of five materials, namely: KU-2 resin, bentonite, charcoal (M&S) and clay adsorbents for the successful removal of 90Sr/90Y from liquid scintillation cocktail waste. The batch adsorption technique (influence of pH, contact time, and temperature), sequential, and column technique were investigated. The efficiency of these adsorbents for the removal of 90Sr/90Y is in this order, resin > bentonite > clay with removal efficiency 90 ± 5.2, 68 ± 3.25, and 65 ± 5.3%, respectively. While charcoal has lower affinity for the sorption processes. Purification of liquid scintillation (LS) cocktail by separation of 90Sr/90Y was successfully carried out by packed column with KU-2 resin. The exhausted loaded column with 90Sr/90Y is successfully regenerated by 25 mL, 1 M HNO3. Characterizations of the original and the purified LS cocktail were carried out using FTIR analysis. The efficiency of the purified liquid scintillation waste (LSW) for the determination of radionuclide is about 62.67 ± 4.8.


Author(s):  
Maria Lucia Pereira Antunes ◽  
Fabiano Tomazini Conceição ◽  
Guillermo Rafael Beltran Navarro ◽  
Alexandre Martins Fernandes ◽  
Steven Frederick Durrant

ABSTRACT Red mud, a waste product generated during alumina extraction from bauxite, could be used as a low-cost adsorbent. Here, the effect of thermal treatment on the adsorption of Reactive Blue 19 (RB19) dye by red mud was compared with the adsorption capacity of untreated red mud. Thermal treatment of red mud at 500°C results in an increase in adsorption capacity from 357 mg g-1 (untreated red mud) to 416 mg g-1, under acidic conditions. Red mud samples thermally treated at 600°C and 800°C show a reduction in adsorption capacity, however, falling to 337 mg g-1, in acid medium. The change in the maximum adsorption capacity of red mud to RB19 following thermal treatment is associated with specific surface area. Red mud subjected to 500°C can be used for the treatment of water and wastewaters with a higher efficiency than untreated red mud, thus finding possible application in the textile industry.


2017 ◽  
Vol 68 (8) ◽  
pp. 1908-1913 ◽  
Author(s):  
Ali Benlamoudi ◽  
Aeslina Abdul Kadir ◽  
Mihail Aurel Titu ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Andrei Victor Sandu

In recent years, tremendous researches have been carried out for solid waste treatment using the solidification/stabilization (S/S) method incorporated with agricultural wastes after the incineration process. These researches, although they showed efficient results, but they may be expensive due to the incineration procedure cost. In the current research, the treatment of lead (Pb) contaminated soil was studied by the incorporation of sugarcane bagasse in its fibrous state into the S/S method. Chemical properties of the materials used were determined by X-Ray Fluorescence (XRF) test. Some mechanical tests like density, water absorption and compressive strength were conducted in order to meet the regulatory limits for disposing the treated waste. Some leaching tests were also conducted, to measure the leachability of lead (Pb) from the matrices. Solidification/stabilization was found as an effective method that was able to reduce more than 99% of leachability of Pb from polluted soil. Moreover, this method can incorporate until 10% of sugarcane bagasse into the matrices. Although incorporation of sugarcane bagasse up to 10% decreases the strength of the samples and increase the leachability of Pb, but they still fit to the standard. Incorporation of sugarcane bagasse waste in its fibrous state into the solidification/stabilization method may provide an alternative low cost treatment method for Pb polluted soils and may eliminate huge amounts of this waste from the environment.


2020 ◽  
Author(s):  
Regina Filemon Irunde ◽  
◽  
Julian Ijumulana ◽  
Julian Ijumulana ◽  
Julian Ijumulana ◽  
...  

1978 ◽  
Vol 5 (1) ◽  
pp. 83-97 ◽  
Author(s):  
Robert D. Cameron

The use of cheap, locally available peat as a treatment method for landfill leachate was investigated by passing leachate through plexiglass columns filled with an amorphous-granular peat. Preliminary adjustment of pH showed that reducing pH to 4.8 dramatically reduced adsorption. Increasing the pH to 8.4, metal removal was increased owing to filtration of precipitated metals. The best adsorption of metals occurred at the 'natural' pH of 7.1. Manganese was found to be the limiting pollutant. At the 0.05 mg/ℓ maximum acceptable manganese concentration 94% of the total metals were removed, requiring 159 kg of peat per 1000 ℓ of leachate.Resting the peat for 1 month did significantly increase removal capacity.Desorption of some contaminants occurred when water was percolated through the peat. The desorption test effluent was not toxic to fish although iron, lead and COD (chemical oxygen demand) exceeded acceptable values.Chemical pretreatment using lime and ferric chloride achieved significant iron, manganese and calcium removals. Chemical pretreatment followed by peat adsorption offered no advantage other than reducing toxicity to fish.Peat treatment alone was effective in reducing concentrations to a level that was non-toxic to fish.


Author(s):  
Dana A. Da’ana ◽  
Nabil Zouari ◽  
Mohammad Y. Ashfaq ◽  
Mohammed Abu-Dieyeh ◽  
Majeda Khraisheh ◽  
...  

Abstract Purpose of Review This paper reviews various low-cost treatment techniques such as adsorption, permeable reactive barrier, and biological techniques for the simultaneous removal of chemical and microbial contaminants from groundwater and discusses treatment mechanisms of different treatment techniques. This paper also discusses the challenges of groundwater treatment, how to choose the appropriate treatment technique, and cost analysis of groundwater treatment. Recent Findings Various treatment technologies have been used for the treatment of groundwater: physical, chemical, and biological technologies with different success rates. In the literature, various adsorbents have been successfully synthesized from low-cost and environmentally friendly materials. Adsorption is considered an efficient treatment technique for the removal of both toxic elements and pathogens by utilizing different adsorbents. For example, the nanostructures of MgO with a BET surface area of up to 171 m2/g obtained a very high adsorption capacity of 29,131 mg/g for fluoride ions in water, while the incorporation of iron in activated carbon has improved its adsorption capacity to 51.3 mg/g for arsenic. Moreover, certain adsorbents have shown the capability to remove 99% of the rotavirus and adenovirus from groundwater. Summary Groundwater resources are contaminated with toxic metals and pathogens. Therefore, water treatment technologies should be evaluated for their efficiency to remove such contaminants. Determination of the most cost-effective and efficient treatment technique is not an easy task and requires the understanding of various aspects such as the contaminants present in water, the reuse options considered, and cost analysis of the treatment technique.


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