scholarly journals Ladle Steel Slag in Activated Systems for Construction Use

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 687
Author(s):  
Diego Aponte ◽  
Oriol Soto Martín ◽  
Susana Valls del Barrio ◽  
Marilda Barra Bizinotto
Keyword(s):  
Mechanical Performance ◽  
Steel Slag ◽  
Value Added ◽  
Physical And Mechanical Properties ◽  
Linear Shrinkage ◽  
Alkali Activation ◽  
Optimal Dosage ◽  
Refining Steel ◽  
Different Temperatures ◽  
Industry Needs

The construction industry needs to reduce greenhouse gases, in which cement production is currently responsible for generating between 4% and 6% of the total CO2 released into the atmosphere. Similarly, many industries produce large amounts of solid waste, which often have low value-added applications or are directly taken to landfills, with consequent negative environmental impacts. One of these industries is the steel industry, which in 2016 generated 18.4 Mt of slag (melting and refining slag) among all European Union countries. In terms of refining steel slag (ladle or white slag), it is estimated that for each ton of steel, between 20 and 30 kg of slag is produced; that is, in 2016, more than 700,000 tons of white slag were generated. It is also known that this material has cementitious properties and can be used as a precursor in alkaline activation processes. Depending on the concentrations used of the activating agent, a higher or lower mechanical performance of the developed materials can be obtained. This work studied the alkali activation of a ladle slag used to manufacture mortars, subjecting them to an initial curing of 24 h at different temperatures (20, 40, and 70 °C). Sodium silicate and sodium hydroxide were used as activating agents, using percentages of Na2O between 5% and 10% to obtain an optimal dosage of the activator. The physical and mechanical properties of the mortars were evaluated at different ages of curing. In addition, monitoring was undertaken of linear shrinkage due to drying and the mineralogical changes due to activation and curing time.

Evaluation of the Physical and Mechanical Properties of Ceramic Tiles Processed Using Steel Slag

2013 ◽  
Vol 856 ◽  
pp. 257-261
Author(s):  
Benneth C. Chukwudi ◽  
Boniface A. Okorie
Keyword(s):  
Mechanical Properties ◽  
Steel Slag ◽  
Physical And Mechanical Properties ◽  
Linear Shrinkage ◽  
Modulus Of Rupture ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Ceramic Tiles ◽  
Kaolinite Clay ◽  
Surface Appearance

This present study has evaluated the physical and mechanical properties of ceramic tiles processed from steel slag. The chemical compositions of both samples were conducted using atomic absorption spectrophotometer (AAS). Steel slag in the range of 0-100wt% was added to kaolinite clay. The blended samples were hydraulic pressed into rectangular moulds, oven dried and sintered within the temperature range of 1100°C - 1200°C. Surface appearance and colouration of sintered products were observed. Linear shrinkage, apparent porosity, water absorption, bulk density, apparent specific gravity and modulus of rupture of sintered samples were examined. Phases present were identified using X-ray diffraction (XRD), while microstructural examination was conducted using scanning electron microscopy (SEM). Phases like quartz, wollastonite, enstatite, were identified. SEM showed considerable degree of vetrification at both temperatures. Results obtained showed that samples containing 25-75wt% steel slag have very good usable ceramic tile properties.

Use of Steel Slag into Clayey Ceramics

2010 ◽  
Vol 660-661 ◽  
pp. 686-691 ◽  
Author(s):  
Carlos Maurício Fontes Vieira ◽  
Sérgio Neves Monteiro
Keyword(s):  
Electron Microscopy ◽  
Steel Slag ◽  
Physical And Mechanical Properties ◽  
Linear Shrinkage ◽  
Uniaxial Pressure ◽  
Technological Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Steel Making ◽  
Scanning Electron

This work has for objective to evaluate the microstructural aspects and technological properties of a clayey ceramic incorporated with up to 30 wt.% of a waste generate during the steel-making process, denoted as steel slag. To determine the physical and mechanical properties such as linear shrinkage, water absorption and flexural strength, specimens were prepared by 18 MPa uniaxial pressure-molding and then fired in a laboratory furnace at 700, 900 and 1100oC. The microstructure of the compositions was evaluated by scanning electron microscopy and X-ray diffraction. The results showed that it is possible to recycle the finer particles of steel slag by incorporating into red ceramic as long as they are used in amounts not higher than 10 wt.% to avoid the increase in porosity and decrease of the mechanical strength.

Experimental investigation of the mechanical behavior of glass fiber/high fluidity polyamide-based composites for automotive market

2021 ◽  
pp. 073168442110140
Author(s):  
Hossein Ramezani-Dana ◽  
Moussa Gomina ◽  
Joël Bréard ◽  
Gilles Orange
Keyword(s):  
Mechanical Properties ◽  
Glass Fiber ◽  
Mechanical Performance ◽  
Physical And Mechanical Properties ◽  
Ultimate Strain ◽  
Uniaxial Tensile ◽  
Compression Tests ◽  
Automotive Market ◽  
Glass Fiber Reinforced ◽  
Glass Fiber Reinforcement

In this work, we examine the relationships between the microstructure and the mechanical properties of glass fiber–reinforced polyamide 6,6 composite materials ( V f = 54%). These materials made by thermocompression incorporate different grades of high fluidity polyamide-based polymers and two types of quasi-UD glass fiber reinforcement. One is a classic commercial fabric, while the other specially designed and manufactured incorporates weaker tex glass yarns (the spacer) to increase the planar permeability of the preform. The effects of the viscosity of the polymers and their composition on the wettability of the reinforcements were analyzed by scanning electron microscopy observations of the microstructure. The respective influences of the polymers and the spacer on the mechanical performance were determined by uniaxial tensile and compression tests in the directions parallel and transverse to the warp yarns. Not only does the spacer enhance permeability but it also improves physical and mechanical properties: tensile longitudinal Young’s modulus increased from 38.2 GPa to 42.9 GPa (13% growth), tensile strength increased from 618.9 MPa to 697 MPa (3% growth), and decrease in ultimate strain from 1.8% to 1.7% (5% reduction). The correlation of these results with the damage observed post mortem confirms those acquired from analyses of the microstructure of composites and the rheological behaviors of polymers.

scholarly journals Effects of a Twin-Screw Extruder Equipped with a Molten Resin Reservoir on the Mechanical Properties and Microstructure of Recycled Waste Plastic Polyethylene Pellet Moldings

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1058
Author(s):  
Hikaru Okubo ◽  
Haruka Kaneyasu ◽  
Tetsuya Kimura ◽  
Patchiya Phanthong ◽  
Shigeru Yao
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Value Added ◽  
Industrial Applications ◽  
Twin Screw Extruder ◽  
Screw Extruder ◽  
Polymer Properties ◽  
Wide Range ◽  
Twin Screw ◽  
Recycled Plastics

Each year, increasing amounts of plastic waste are generated, causing environmental pollution and resource loss. Recycling is a solution, but recycled plastics often have inferior mechanical properties to virgin plastics. However, studies have shown that holding polymers in the melt state before extrusion can restore the mechanical properties; thus, we propose a twin-screw extruder with a molten resin reservoir (MSR), a cavity between the screw zone and twin-screw extruder discharge, which retains molten polymer after mixing in the twin-screw zone, thus influencing the polymer properties. Re-extruded recycled polyethylene (RPE) pellets were produced, and the tensile properties and microstructure of virgin polyethylene (PE), unextruded RPE, and re-extruded RPE moldings prepared with and without the MSR were evaluated. Crucially, the elongation at break of the MSR-extruded RPE molding was seven times higher than that of the original RPE molding, and the Young’s modulus of the MSR-extruded RPE molding was comparable to that of the virgin PE molding. Both the MSR-extruded RPE and virgin PE moldings contained similar striped lamellae. Thus, MSR re-extrusion improved the mechanical performance of recycled polymers by optimizing the microstructure. The use of MSRs will facilitate the reuse of waste plastics as value-added materials having a wide range of industrial applications.

scholarly journals Impact of Prolonged Exposure of Eleven Years to Hot Seawater on the Degradation of a Thermoset Composite

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2154
Author(s):  
Amir Hussain Idrisi ◽  
Abdel-Hamid I. Mourad ◽  
Muhammad M. Sherif
Keyword(s):  
Exposure Time ◽  
Prolonged Exposure ◽  
Mechanical Performance ◽  
Matrix Cracking ◽  
Pull Out ◽  
Strength Based ◽  
Different Temperatures ◽  
River Line ◽  
Composite Samples

This paper presents a long-term experimental investigation of E-glass/epoxy composites’ durability exposed to seawater at different temperatures. The thermoset composite samples were exposed to 23 °C, 45 °C and 65 °C seawater for a prolonged exposure time of 11 years. The mechanical performance as a function of exposure time was evaluated and a strength-based technique was used to assess the durability of the composites. The experimental results revealed that the tensile strength of E-glass/epoxy composite was reduced by 8.2%, 29.7%, and 54.4% after immersion in seawater for 11 years at 23 °C, 45 °C, and 65 °C, respectively. The prolonged immersion in seawater resulted in the plasticization and swelling in the composite. This accelerated the rate of debonding between the fibers and matrix. The failure analysis was conducted to investigate the failure mode of the samples. SEM micrographs illustrated a correlation between the fiber/matrix debonding, potholing, fiber pull-out, river line marks and matrix cracking with deterioration in the tensile characteristics of the thermoset composite.

Mechanical Performance, Phase Evolution and Microstructure of Natural Feldspathic Solid Solutions Consolidated Via Alkali Activation: Effect of NaOH Concentration

Silicon ◽  
2021 ◽  
Author(s):  
Achile Nana ◽  
Sylvain Tomé ◽  
Sybilline Claudelle Djadock Anensong ◽  
Paul Venyite ◽  
Jean Noel Yankwa Djobo ◽  
...  
Keyword(s):  
Solid Solutions ◽  
Mechanical Performance ◽  
Phase Evolution ◽  
Alkali Activation ◽  
Activation Effect

scholarly journals Enhancement of Mechanical Properties and Porosity of Concrete Using Steel Slag Coarse Aggregate

Materials ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 2865
Author(s):  
Md Jihad Miah ◽  
Md. Munir Hossain Patoary ◽  
Suvash Chandra Paul ◽  
Adewumi John Babafemi ◽  
Biranchi Panda
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Microstructural Analysis ◽  
Steel Slag ◽  
Physical And Mechanical Properties ◽  
Length Change ◽  
Sustainable Building ◽  
Burnt Clay ◽  
Lower Porosity ◽  
Furnace Steel

This paper investigates the possibility of utilizing steel slags produced in the steelmaking industry as an alternative to burnt clay brick aggregate (BA) in concrete. Within this context, physical, mechanical (i.e., compressive and splitting tensile strength), length change, and durability (porosity) tests were conducted on concrete made with nine different percentage replacements (0%, 10%, 20%, 30%, 40%, 50%, 60%, 80%, and 100% by volume of BA) of BA by induction of furnace steel slag aggregate (SSA). In addition, the chemical composition of aggregate through X-ray fluorescence (XRF) analysis and microstructural analysis through scanning electron microscopy (SEM) of aggregates and concrete were performed. The experimental results show that the physical and mechanical properties of concrete made with SSA were significantly higher than that of concrete made with BA. The compressive and tensile strength increased by 73% when SSA fully replaced BA. The expansion of concrete made with SSA was a bit higher than the concrete made with BA. Furthermore, a significant lower porosity was observed for concrete made with SSA than BA, which decreased by 40% for 100% SSA concrete than 100% BA concrete. The relation between compressive and tensile strength with the porosity of concrete mixes are in agreement with the relationships presented in the literature. This study demonstrates that SSA can be used as a full replacement of BA, which is economical, conserves the natural aggregate, and is sustainable building material since burning brick produces a lot of CO2.

scholarly journals Characteristics of Warm Mix Asphalt Incorporating Coarse Steel Slag Aggregates

2021 ◽  
Vol 11 (8) ◽  
pp. 3708
Author(s):  
Adham Mohammed Alnadish ◽  
Mohamad Yusri Aman ◽  
Herda Yati Binti Katman ◽  
Mohd Rasdan Ibrahim
Keyword(s):  
Environmental Sustainability ◽  
Prediction Models ◽  
Hot Mix Asphalt ◽  
Steel Slag ◽  
Warm Mix Asphalt ◽  
Asphalt Mixes ◽  
Toxic Emissions ◽  
Comparable Performance ◽  
Different Temperatures ◽  
Production Temperature

The major goal of sustainable practices is to preserve raw resources through the utilization of waste materials as an alternative to natural resources. Decreasing the temperature required to produce asphalt mixes contributes to environmental sustainability by reducing energy consumption and toxic emissions. In this study, warm mix asphalt incorporating coarse steel slag aggregates was investigated. Warm mix asphalt was produced at different temperatures lower than the control asphalt mixes (hot mix asphalt) by 10, 20, and 30 °C. The performances of the control and warm mix asphalt were assessed through laboratory tests examining stiffness modulus, dynamic creep, and moisture sensitivity. Furthermore, a response surface methodology (RSM) was conducted by means of DESIGN EXPERT 11 to develop prediction models for the performance of warm mix asphalt. The findings of this study illustrate that producing warm mix asphalt at a temperature 10 °C lower than that of hot mix asphalt exhibited the best results, compared to the other mixes. Additionally, the warm mix asphalt produced at 30 °C lower than the hot mix asphalt exhibited comparable performance to the hot mix asphalt. However, as the production temperature increases, the performance of the warm mix asphalt improves.

scholarly journals Volcanic Ash as a Sustainable Binder Material: An Extensive Review

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1302
Author(s):  
Andrés Játiva ◽  
Evelyn Ruales ◽  
Miren Etxeberria
Keyword(s):  
Chemical Composition ◽  
Portland Cement ◽  
Urban Areas ◽  
Volcanic Ash ◽  
Mechanical Performance ◽  
Cement Clinker ◽  
Alkali Activation ◽  
Cement Production ◽  
Sustainable Solutions ◽  
Alkali Activated

The construction industry is affected by the constant growth in the populations of urban areas. The demand for cement production has an increasing environmental impact, and there are urgent demands for alternative sustainable solutions. Volcanic ash (VA) is an abundant low-cost material that, because of its chemical composition and amorphous atomic structure, has been considered as a suitable material to replace Portland cement clinker for use as a binder in cement production. In the last decade, there has been interest in using alkali-activated VA material as an alternative material to replace ordinary Portland cement. In this way, a valuable product may be derived from a currently under-utilized material. Additionally, alkali-activated VA-based materials may be suitable for building applications because of their good densification behaviour, mechanical properties and low porosity. This article describes the most relevant findings from researchers around the world on the role of the chemical composition and mineral contents of VA on reactivity during the alkali-activation reaction; the effect of synthesis factors, which include the concentration of the alkaline activator, the solution-to-binder ratio and the curing conditions, on the properties of alkali-activated VA-based materials; and the mechanical performance and durability properties of these materials.

Thermal Decomposition of Vulcanized Structures of Deformed Vulcanizates Containing Various Accelerators

1953 ◽  
Vol 26 (4) ◽  
pp. 759-763 ◽  
Author(s):  
B. Dogadkin ◽  
Z. Tarasova
Keyword(s):  
Stress Relaxation ◽  
Physical And Mechanical Properties ◽  
Heat Stability ◽  
Chemical Bonds ◽  
Structural Elements ◽  
Specific Chemical ◽  
Vulcanized Rubber ◽  
Different Temperatures ◽  
Chemical Groups ◽  
The Given

Abstract According to the hypotheses developed by the authors, vulcanized rubber is a system in which the molecular chains are united by local molecular and chemical bonds of varying intensity. The concentration, distribution, and strength of these bonds determine the principal physical and mechanical properties of the vulcanizates. Consequently the study of the structure of the vulcanizate is of primary practical value. The explanation of the nature of the bonds in a vulcanizate by chemical methods is very difficult, mainly because of the impossibility of distinguishing the specific chemical groups which enter into the composition of the different molecular chains from those bonds between the chains which are responsible for the development of spatial structures. From this view point, the thermo-mechanical method described below, which is based on the study of stress relaxation at different temperatures, is of great significance. As was shown by Dogadkin and Reznikovskii˘, the delayed stress relaxation in a vulcanizate at temperatures up to 70° C is caused by rupture of the local intermolecular bonds and the regrouping of the structural elements of the polymeric chains without destruction of the chemical bonds between them. Accordingly, after some time at these temperatures, a practically balanced stress is established, which depends on the number of the stronger bonds remaining. At temperatures above 70° C, rupture of the chemical bonds between the chains takes place; its speed increases with decrease of the energy activating the rupture of the given type of bond. Particularly in the case of sulfur vulcanizates, we can assume that the following types of bonds exist between the chains of the rubber: (1) —C—C—, which develop as a result of the polymerizationprocesses; (2) —C—S—C— monosulfide; (3) —C—S—S—C— disulfide, and (4) —C—Sn—C— polysulfide, formed as a result of the direct participation of the vulcanizing agent, sulfur, in the process of joining of the molecular chains. The energy of these chains can be estimated as 62.7 kcal, per mole for C—C, 54.5 kcal. per mole for C—S, and 27.5 kcal. per mole for the —S—S bond. Naturally, the heat stability of a vulcanizate will depend on which of the indicated types of bonds predominates.

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