scholarly journals Experimental Investigation of the Macroscopic Behavior and Microstructure Property Evolution of Hardened Cement Consolidated Tailings

Minerals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 6 ◽  
Author(s):  
Xiang Sun ◽  
Yunbing Hou
Keyword(s):  
Compressive Strength ◽  
Pore Size ◽  
Pore Volume ◽  
Mercury Intrusion Porosimetry ◽  
Mining Industry ◽  
Total Pore Volume ◽  
Hardened Cement ◽  
Curing Period ◽  
Strength Tests ◽  
Curing Age

Surface cement consolidated tailings disposal has recently been proposed to manage tailings in the modern mining industry because it can reduce or eliminate the disadvantages of traditional tailings storage. In this study, the evolution of the macro performance and microstructure characteristics of cement consolidated tailing samples during the curing period were determined by unconfined compressive strength tests, permeability tests, scanning electron microscopy (SEM) observations, and mercury intrusion porosimetry (MIP) tests, respectively. The results show that the curing time notably affected the macro performance and microstructural properties of the hardened cement consolidated tailings samples. As the curing age increases, the compressive strength increases nonlinearly and the growth rate decreases; the permeability decreases rapidly first, then gradually stabilizes, and finally reaches a stable value; the morphology of the hydration products and microstructures continues to evolve with the hydration process; the total pore volume decreases slightly, whereas the critical pore size decreases significantly. The proportion of the pore volume in different pore size ranges can also be affected by the curing age, which results in a large pore (>200 nm) decrease, and the small pores (<200 nm) increased. In this process, the filling effect plays a major role.

Effects of 0-30% Wood Ashes as a Substitute of Cement on the Strength of Concretes

2022 ◽  
Author(s):  
Theodore Gautier Bikoko ◽  
Jean Claude Tchamba ◽  
Valentine Yato Katte ◽  
Divine Kum Deh
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Greenhouse Gases ◽  
Negative Influence ◽  
Wood Ash ◽  
The Other ◽  
Other Hand ◽  
Strength Tests ◽  
Compressive Strength Of Concrete ◽  
Curing Age

To fight against the high cost and the increasing scarcity of cement and at the same time to reduce the CO2 greenhouse gases emission associated with the production of Portland cement, two types of wood ashes as a substitute of cement in the production of concretes were investigated. In this paper, we substituted cement by two types of species of wood ashes namely, avocado and eucalyptus ashes following the proportions ranging from 0% to 30 % on one hand, and on the other hand, we added these two types of species of wood ashes namely, avocado and eucalyptus ashes following the proportions ranging from 0% to 10 % by weight of cement in the concrete samples. After 7, 14 and 28 days of curing, compressive strength tests were conducted on these concrete samples. The findings revealed that using wood ashes as additives/admixtures or as a substitute of cement in the production/manufacturing of concrete decreased the compressive strength of concrete. Hence, it can be said that wood ash has a negative influence on the strength of concrete. At three percent (3%) and ten percent (10%) of addition, the wood ash from eucalyptus specie offers better resistance compared to the wood ash from avocado specie, whereas at five percent (5%) of addition, the wood ash from avocado specie offers better resistance compared to the wood ash from eucalyptus specie. At thirty percent (30%) of substitution, the wood ash from eucalyptus specie offers better resistance compared to the wood ash from avocado specie. The compressive strengths increase with the increase of curing age.

scholarly journals Mineral compositional controls on the porosity of black shales from the Wufeng and Longmaxi Formations (Southern Sichuan Basin and its surroundings) and insights into shale diagenesis

2018 ◽  
Vol 36 (4) ◽  
pp. 665-685
Author(s):  
Mei Han ◽  
Chao Han ◽  
Zuozhen Han ◽  
Zhigang Song ◽  
Wenjian Zhong ◽  
...  
Keyword(s):  
Organic Matter ◽  
Pore Size ◽  
Pore Volume ◽  
Total Pore Volume ◽  
Black Shales ◽  
Carbonate Content ◽  
Pore Sizes ◽  
Pore Size Distributions ◽  
Shale Composition ◽  
The Relationship

The effects of brittle minerals in shale diagenesis on shale pores remain controversial and it is difficult to quantify directly. However, the relationship between brittle minerals and shale pores could provide indirect guidance regarding diagenesis processes in post-mature marine shales. In this study, the pore size distribution was determined, and the relationship between pore volume and shale composition was examined in shale samples with different total organic carbon contents from the Wufeng and Longmaxi Formations, with the objective of distinguishing pore size ranges in organic matter and inorganic minerals, respectively, and studying shale diagenesis. The samples of the Wufeng and Longmaxi shales are composed of clay minerals, calcite, dolomite, quartz, feldspar, and some minor components. The pore size distributions, which were determined using nitrogen adsorption isotherm analysis of shale and kerogen, show similar trends for pore sizes less than approx. 6.5 nm but different trends for larger pore sizes. Mercury injection saturation shows that macropores account for 14.4–22% of the total pore volume. Based on a series of crossplots describing the relationships between shale composition and pore volume or porosity associated with different pore sizes as well as on scanning electron microscopy observations, organic matter pores were found to comprise most of the micro-mesopores (pore diameters < 6.5 nm). Organic matter pores and intraparticle pores associated with carbonate constitute the majority of mesopores (pore diameters 6.5–50 nm). Finally, interparticle pores associated with quartz comprise the majority of the macropores. The mesopores associated with carbonate were formed by dissolution during diagenesis, whereas the macropores associated with quartz are the remainders of the original interparticle pores. Mesopore volumes increase with increasing carbonate content while macropore volumes decrease due to the ‘pore size controlled solubility’ effect, which causes dissolved calcium carbonate to precipitate in larger macropores.

Effect of Gypsum on Hydration Degree and Structure of Hardened Paste of Alite-Strontium Calcium Sulphoaluminate Cement

2011 ◽  
Vol 306-307 ◽  
pp. 1024-1028
Author(s):  
Qiu Ying Li ◽  
Ling Chao Lu ◽  
Shou De Wang
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Cement Clinker ◽  
Hardened Cement ◽  
Hydration Degree ◽  
Synthesis Conditions ◽  
Sulphoaluminate Cement ◽  
Calcium Sulphoaluminate ◽  
Calcium Sulphoaluminate Cement ◽  
Curing Age

Synthesis conditions and performance of alite-strontium calcium sulphoaluminate cement have been studied by introducing strontium calcium sulphoaluminate into Portland cement clinker. The effects of gypsum on compressive strength, hydration degree and structure of hardened alite-strontium calcium sulphoaluminate cement paste were studied in this paper. Composition and structure of the hardened cement paste were analyzed by XRD and SEM. Results show that appropriate content of gypsum could contribute to the hydration of alite-strontium calcium sulphoaluminate cement. When gypsum content is 9%, the compressive strengths for 1d, 3d and 28d curing age are 30.7MPa, 59.5MPa and 105.5MPa, and the corresponding hydration degree are 40.4%, 57.5% and 85.8%, respectively. The hydration products of alite-strontium calcium sulphoaluminate cement are mainly ettringite (AFt), Ca(OH)2, C-S-H gel. Large amount of AFt formed at early curing age provides a sound basis for early compressive strength, and a lot of C-S-H gel generated at later curing age increases the density of the hardened paste.

Methods for Porosity Characterization of Cement Based Materials

2012 ◽  
Vol 1488 ◽  
Author(s):  
M.M. Canut ◽  
M. R. Geiker
Keyword(s):  
Pore Size ◽  
Pore Volume ◽  
Mercury Intrusion Porosimetry ◽  
Degree Of Hydration ◽  
Cement Based Materials ◽  
Porosity Estimation ◽  
Portland Cement Paste ◽  
Low Temperature Calorimetry ◽  
Porosity Characterization

ABSTRACTImportant pore structure parameters related to mechanical properties and durability of cement-based materials can be determined by techniques such as scanning electron microscopy (SEM), mercury intrusion porosimetry (MIP), and low temperature calorimetry (LTC). The methods provide information on porosity characteristics as pore volume, pore thresholds and/or pore size distribution in different size ranges and do therefore to a large extent supplement each other. Pastes of w/b=0.4 with 0%, 40% or 70% slag by volume were cured saturated at 20ºC for up to two years. The porosity was characterized by LTC, MIP, and SEM. Higher volume of pores was obtained by MIP compared to results obtained using LTC and SEM. Measured porosity was correlated with predicted porosity using information on the density and degree of hydration of the cement and slag. Porosity estimation showed best agreement with the porosity data measured by MIP. The use of slag showed the same trend for all tests: a higher total volume of pores, but a lower threshold pore size when compared with Portland cement paste. The findings illustrate the importance of measuring not only pore volume but also threshold pore sizes when characterizing porosity of cement-based materials with different binder compositions.

Pore Structure Analysis on Hardened Paste of CaO-Al2O3-P2O5 Cement

2013 ◽  
Vol 591 ◽  
pp. 44-49 ◽  
Author(s):  
Xiao Dong Wang ◽  
Zhu Ding ◽  
Bi Qin Dong ◽  
Ming Zhang
Keyword(s):  
Pore Structure ◽  
Pore Diameter ◽  
Mercury Intrusion Porosimetry ◽  
Fractal Theory ◽  
Diameter Distribution ◽  
Hardened Cement ◽  
Hardened Cement Paste ◽  
Hydraulic Cement ◽  
Pore Area ◽  
Curing Age

CaO-Al2O3-P2O5cementitious material (PAC) is a type of new developed hydraulic cement, which has excellent cementitious performance and mechanical property. In cement based materials, the pore structure of hardened cement paste has a significant effect on their performance, such like strength, permeability and durability. In the current paper, pore structure parameters of hardened PAC paste samples in five different curing stages were measured respectively by MIP (Mercury Intrusion Porosimetry). The pore fractal features (pore volume, pore area, porosity) were investigated with fractal theory. Results showed that the porosity of hardened PAC paste does not exactly decline with elongation of curing age and increase of compression strength. The PAC pastes pore structures have typical fractal nature which changes with curing age and pore diameter distribution. The fractal feather of hardened PAC paste can be effectively understood by using porosity fractal dimension.

The Influence of Sinterng Temperature on the Phase, Microstructure and Textual Properties of Hollow Hydroxyapatite Microspheres

2011 ◽  
Vol 239-242 ◽  
pp. 2274-2279 ◽  
Author(s):  
Ying Chun Wang ◽  
Wen Hai Huang ◽  
Ai Hua Yao ◽  
De Ping Wang
Keyword(s):  
Specific Surface ◽  
Pore Size ◽  
Surface Area ◽  
Specific Surface Area ◽  
Pore Volume ◽  
Sintering Temperature ◽  
Total Pore Volume ◽  
Precipitation Method ◽  
Simple Method ◽  
Air Atmosphere

A simple method to prepare hollow hydroxyapatite (HAP) microspheres with mespores on the surfaces is performed using a precipitation method assisted with Li2O-CaO-B2O3(LCB) glass fabrication process. This research is concerned with the effect of sintering temperature on the microstructure evolution, phase purity, surface morphology, specific surface area, and porosity after sintering process. The microspheres were sintered in air atmosphere at temperatures ranging from 500 to 900 °C. The starting hollow HAP microspheres and the sintered specimens were characterized by scanning electron microscope, X-ray diffractometer, specific surface area analyzer, and Hg porosimetry, respectively. The as-prepared microspheres consisted of calcium deficient hydroxyapatite. The results showed that the as-prepared hollow HAP microspheres had the highest specific surface areas, and the biggest total pore volume. The pore size distribution of the as-prepared hollow HAP microspheres were mainly the mesopores in the range of 2～40 nm. The specific surface area and total pore volume of hollow HAP microspheres decreased with increasing sintering temperature. Whereas the mean pore size increased with increasing sintering temperature. It showed that at 700°C, Ca-dHAP decomposes into a biphasic mixture of HAP and β-calcium phosphate(TCP).

scholarly journals Effects of Crumb Rubber on Compressive Strength of Cement-Treated Soil

2015 ◽  
Vol 61 (4) ◽  
pp. 59-78 ◽  
Author(s):  
F. C. Wang ◽  
W. Song
Keyword(s):  
Compressive Strength ◽  
Cement Content ◽  
Rubber Particle ◽  
Crumb Rubber ◽  
Test Results ◽  
Rubber Content ◽  
Strength Tests ◽  
Strength And Stiffness ◽  
Cement Soil ◽  
Curing Age

A study was undertaken to investigate the effects of crumb rubber on the strength and mechanical behaviour of Rubberized cement soil (RCS). In the present investigation, 26 groups of soil samples were prepared at five different percentages of crumb rubber content, four different percentages of cement content and two different finenesses of crumb rubber particle. Compressive strength tests were carried out at the curing age of 7 days, 14 days, 28 days and 90 days. The test results indicated that the inclusion of crumb rubber within cement soil leads to a decrease in the compressive strength and stiffness and improves the cement soil’s brittle behaviour to a more ductile one. A reduction of up to 31% in the compressive strength happened in the 20% crumb content group. The compressive strength increases with the increase in the cement content. And the enlargement of cement content is more efficient at low cement content.

Influences of Slag and Fly Ash on the Microstructure Property and Compressive Strength of Concrete

2010 ◽  
Vol 146-147 ◽  
pp. 1690-1697 ◽  
Author(s):  
An Shun Cheng ◽  
Chung Ho Huang ◽  
Tsong Yen ◽  
Yong Lin Luo
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Pore Volume ◽  
Total Pore Volume ◽  
Pozzolanic Reaction ◽  
Test Results ◽  
Suitable Amount ◽  
Pozzolanic Materials ◽  
Microstructure And Mechanical Property ◽  
Better Than

This research aims to investigate the pore structures and the interfacial transition zone (ITZ) of concrete containing both slag and fly ash. Test variables include three water-to-binder ratios (0.35, 0.50, 0.70) and four substitute ratios of cement with pozzolanic materials (20%, 30%, 50% and 60%). The specimens were tested to determine compressive strength, MIP porosity measurement and ITZ microhardness. Test results show that concrete containing slag and fly ash produce evident filling effect and the pozzolanic reaction after 28 days. At the age of 91 days the pozzolanic materials has provided prominent contribution to the strength, the porosity and the ITZ of concrete, making the pore volume smaller and ITZ property of pozzolanic concrete better than that of normal concrete. The concrete that adds suitable amount of pozzolanic materials (ex. 10% slag + 10% fly ash) has the optimum microstructure and mechanical property. Too much pozzolanic materials (ex. 40% slag + 20% fly ash) may be disadvantage to the concrete, and the suggested substitute ratio is under 50%. It is found that the compressive strength has the closest relationship with the total pore volume, so we use the total pore volume to predict the compressive strength of pozzolanic concrete and establish a prediction model as follow: S= -662.68Vt+87.29, R2=0.946.

Effect of Heat-Treatment in Ar Atmosphere on Pore Structure of Carbonaceous Materials from Polysiloxane

2014 ◽  
Vol 602-603 ◽  
pp. 279-284
Author(s):  
Li Qun Duan ◽  
Chen Chen Zhang ◽  
Qing Song Ma ◽  
Zhao Hui Chen
Keyword(s):  
Heat Treatment ◽  
Pore Structure ◽  
Pore Size ◽  
Pore Volume ◽  
Average Pore Size ◽  
Total Pore Volume ◽  
Treatment Temperature ◽  
Carbonaceous Materials ◽  
Average Pore ◽  
Pore Size Distributions

Nanoporous carbonaceous materials derived from polysiloxane were first prepared by pyrolysis at 1300°C followed with hydrofluoric acid (HF) etching treatment. Their thermal stability of pore structure in inert condition was investigated in this paper by nitrogen adsorption technique in detail. The specific surface area (SSA) and pore volume (total pore volume, micropore volume, mesopore volume) decreased continually in the heat-treatment temperature range of 1000~1400°C. The average pore size almost kept the same with the raw sample. However, when the temperature exceeded 1400°C, the micropore interconnection began transforming to mesopore structure, which led to the decline of SSA and the increase of average pore size. Furthermore, the pore size distributions (PSDs) curves showed that heat-treatment had an advantage on the transition process of pore structure from disorder to regularity to some extent when heat-treated in the range 1000~1400°C for the most possible reason of relief of residue strain in the carbonaceous materials.

Pore Structure Of Hydrated Cement Determined By Mercury Porosimetry And Nitrogen Sorption Techniques.

1988 ◽  
Vol 137 ◽  
Author(s):  
Yahia Abdel-Jawad ◽  
Will Hansen
Keyword(s):  
Pore Structure ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Pore Volume ◽  
Mercury Porosimetry ◽  
Total Pore Volume ◽  
Curing Temperature ◽  
Vycor Glass ◽  
Degree Of Hydration

AbstractThe pore structure (i.e. total pore volume, surface area and pore-size distribution curves) was measured using mercury porosimetry and nitrogen sorption. Hydrated portland cement (type I) of water-cement (w/c) ratios 0.3, 0.4 and 0.6 by weight was analyzed at three degrees of hydration (i.e., 30%, 50% and 80%; 70% for the 0.3 w/c system) corresponding to low, intermediate and high levels of hydration. The effect of curing temperature (3°, 23°, and 43°C) on pore structure was also studied. The two techniques were evaluated as well on porous Vycor glass, which has a narrow pore size distribution in the size range accessible to both. Results obtained by both techniques on porous Vycor glass agreed well. However neither technique can be used alone to study the entire pore structure in well-hydrated cement due to the wide range in pore sizes and the presence of micropores. Due to the unstable pore structure in cement a specimen treatment procedure such as methanol replacement, combined with volume-thickness (V-t) analysis, is necessary in order to measure the micropores. At low hydration values the pore structure can be estimated by mercury intrusion porosimetry (MIP). At higher hydration values, however, this technique underestimates total pore volume and surface area due to the presence of micropores which MIP cannot determine. In the pore size range of overlap, higher pore volumes were obtained with MIP. Nitrogen V-t analysis shows that micropores are more pronounced with lower w/c ratios. This finding is consistent with pore size distribution curves obtained by MIP. For a given w/c ratio and degree of hydration the total pore volume measured by MIP was found to be independent of curing temperature in the temperature range studied. At any w/c ratio, capillary porosity is controlled by degree of hydration alone.

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