scholarly journals Simple Fabrication of Solid-State Nanopores on a Carbon Film

Micromachines ◽  
2021 ◽  
Vol 12 (9) ◽  
pp. 1135
Author(s):  
Natsumi Takai ◽  
Kan Shoji ◽  
Tei Maki ◽  
Ryuji Kawano
Keyword(s):  
Thin Film ◽  
Electron Beam ◽  
Solid State ◽  
Dielectric Breakdown ◽  
Carbon Film ◽  
Carbon Membrane ◽  
Nano Fabrication ◽  
Thin Carbon ◽  
Thin Film Preparation ◽  
Micro Grids

Solid-state nanopores are widely used as a platform for stochastic nanopore sensing because they can provide better robustness, controllable pore size, and higher integrability than biological nanopores. However, the fabrication procedures, including thin film preparation and nanopore formation, require advanced micro-and nano-fabrication techniques. Here, we describe the simple fabrication of solid-state nanopores in a commercially available material: a flat thin carbon film-coated micro-grid for a transmission electron microscope (TEM). We attempted two general methods for nanopore fabrication in the carbon film. The first method was a scanning TEM (STEM) electron beam method. Nanopores were fabricated by irradiating a focused electron beam on the carbon membrane on micro-grids, resulting in the production of nanopores with pore diameters ranging from 2 to 135 nm. The second attempt was a dielectric breakdown method. In this method, nanopores were fabricated by applying a transmembrane voltage of 10 or 30 V through the carbon film on micro-grids. As a result, nanopores with pore diameters ranging from 3.7 to 1345 nm were obtained. Since these nanopores were successfully fabricated in the commercially available carbon thin film using readily available devices, we believe that these solid-state nanopores offer great utility in the field of nanopore research.

scholarly journals Interpretational challenges related to studies of chalk particle surfaces in scanning and transmission electron microscopy

2018 ◽  
Vol 66 ◽  
pp. 151-165
Author(s):  
Morten Leth Hjuler ◽  
Vidar Folke Hansen ◽  
Ida Lykke Fabricius
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Electron Beam ◽  
Carbon Film ◽  
Burial Depth ◽  
High Electron ◽  
Ion Milling ◽  
Transmission Electron ◽  
Thin Carbon ◽  
Acceleration Voltage

Scanning and transmission electron microscopy (SEM and TEM) are capable of characterising the morphology and structure of sub-micron size substances attached to chalk particle surfaces. Some characteristics, however, may originate from sample preparation or reflect interaction between sample and the electron beam. Misinterpretation of surface features may lead to wrong conclusions regarding grain surface properties and cementation level and thus to erroneous characterisation of hydrocarbon reservoirs with respect to e.g. wettability, mechanical strength and maximum burial depth. In SEM, conductive coatings may mask surface details or generate artificial ornamentations, and carbon adhesive discs may cause the chalk surface to be covered with a thin carbon film. Electron beam acceleration voltage controls the degree of detail revealed by the electron beam, but in SEM a high electron beam acceleration voltage may provoke bending or curling of ultrathin particles. Recent organic filaments may be confused with clay flakes, and authigenic non-carbonate minerals may have formed in the pore fluid and settled during fluid removal. In TEM, the high acceleration voltage may cause beam damage to calcite and transform the outermost atomic layers into Ca oxide. Thin graphite membranes observed by TEM may be contamination from the carbon film supporting the sample, and overlapping chalk particles in samples formed by drying of a suspension may give the impression of being cemented together. In TEM residual adhesive from the ion-milling process can be confused with cementation features.

Characterization of Thin DLC Films Using Film Stress and Raman Techniques

1998 ◽  
Vol 517 ◽  
Author(s):  
J. E. Turlo ◽  
Danny Gan ◽  
Niranjan Gopinathan
Keyword(s):  
Thin Film ◽  
Thermal Cycling ◽  
Thermal Processing ◽  
Diffusion Mechanism ◽  
Carbon Film ◽  
Film Stress ◽  
Relaxation Data ◽  
Thin Film Stress ◽  
Thin Carbon ◽  
Optical Lever

AbstractDiamond like carbon (DLC) films are deposited on thin film heads in the magnetic recording industry to reduce friction and “stiction” and to provide a durable, abrasion resistant coating. The films are a mixture of graphitic phases with sp2 bonding and diamond phases with sp3 bonding. The present work provides the results of thin film stress measurements and Raman tests performed on 10 rim DLC films deposited on 75 mm silicon test wafers using standard optical lever techniques. Stress is measured after deposition and in-situ during thermal cycling. Isothermal relaxation data is also obtained. Raman is performed before and after annealing.The deposited stress of 10 nrm films was over 2000 MPa. The stress relaxed entirely to zero during thermal cycling to 500°C. Isothermal relaxation at 300°C also resulted in complete relaxation of an initial 1500 MPa stress to zero in less than 24 hours. The Raman data is consistent with prior results in the literature. The position of the G band shifts from 1513 to 1581 cm-1 during annealing, and the intensity ratio of the D band to the G band rises from 0.201 to 0.814 during annealing.The decrease of the film stress to zero during thermal processing implies that the entire thickness of the film is undergoing a structural change while the stress relaxation data implies that the stress is relaxing by a fast diffusive process. The Raman data implies that the film is becoming more graphitic and the crystallites are growing in number and size during thermal processing. We suggest that the structure of the extremely thin carbon film is modified by a surface diffusion mechanism.

scholarly journals Mechanical and Tribological Properties of Carbon Thin Film with Tungsten Interlayer Prepared by Ion Beam Assisted Deposition

2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
Petr Vlcak ◽  
Frantisek Cerny ◽  
Zdenek Tolde ◽  
Josef Sepitka ◽  
Ivan Gregora ◽  
...  
Keyword(s):  
Thin Film ◽  
Tribological Properties ◽  
Ion Beam ◽  
Carbon Film ◽  
Diffraction Method ◽  
Mechanical And Tribological Properties ◽  
Ion Beam Assisted Deposition ◽  
Carbon Thin Film ◽  
Thin Carbon ◽  
Thin Carbon Film

Mechanical and tribological properties of the thin carbon film with tungsten interlayer were investigated. The carbon film (130 nm) and the tungsten interlayer (20 nm) were prepared by ion beam assisted deposition (IBAD) method. Both layers were electron beam evaporated and were simultaneously irradiated by the beam of argon (Ar) or nitrogen (N) ions with energy of 700 eV. Mechanical properties of the thin carbon film with tungsten interlayer were investigated by the nanoindentation method. Concerning tribological properties the coefficient of friction was investigated by means of pin on disc tribometer. Phase composition was investigated by X-ray diffraction method (XRD), and bonding characterization of carbon thin film was characterized by Raman spectroscopy.

Hydrated form of some clay minerals observed using a film sealed environmental cell

1978 ◽  
Vol 36 (1) ◽  
pp. 72-73
Author(s):  
N. Kohyama ◽  
K. Fukushima ◽  
A. Fukami
Keyword(s):  
Clay Minerals ◽  
Morphological Changes ◽  
Carbon Film ◽  
Electron Microscopic Observation ◽  
Adsorbed Water ◽  
Electron Microscopic ◽  
Hydrated Form ◽  
Thin Carbon ◽  
Environmental Cell ◽  
Thin Carbon Film

Since the interlayer or adsorbed water of some clay minerals are quite easily dehydrated in dried air, in vacuum, or at moderate temperatures even in the atmosphere, the hydrated forms have not been observed by a conventional electron microscope(TEM). Recently, specific specimen chambers, “environmental cells(E.C.),” have been developed and confirmed to be effective for electron microscopic observation of wet specimen without dehydration. we observed hydrated forms of some clay minerals and their morphological changes by dehydration using a TEM equipped with an E.C..The E.C., equipped with a single hole copper-microgrid sealed by thin carbon-film, attaches to a TEM(JEM 7A) with an accelerating voltage 100KV and both gas pressure (from 760 Torr to vacuum) and relative humidity can be controlled. The samples collected from various localities in Japan were; tubular halloysite (l0Å) from Gumma Prefecture, sperical halloysite (l0Å) from Tochigi Pref., and intermediate halloysite containing both tubular and spherical types from Fukushima Pref..

Alkaline Dissociation Products of Lumbricus Terrestris Hemoglobin Viewed with the STEM

1981 ◽  
Vol 39 ◽  
pp. 434-435
Author(s):  
O. H. Kapp ◽  
M. Ohtsuki ◽  
N. Robin ◽  
S. N. Vinogradov ◽  
A. V. Crewe
Keyword(s):  
Carbon Film ◽  
Lumbricus Terrestris ◽  
Uranyl Acetate ◽  
Acetate Solution ◽  
Oxygen Carriers ◽  
Complex Molecules ◽  
Thin Carbon ◽  
Thin Carbon Film ◽  
Multiple Copies ◽  
Hill Coefficients

Annelid extracellular hemoglobins are among the largest known proteins (M.W = 3.9 x 106), and together with the hemocyanins are the largest known oxygen carriers. They display oxygen affinities generally higher than those o vertebrate hemoglobins with Hill coefficients ranging from slightly higher than unity to values as high as 5-6. These complex molecules are composed of multiple copies of as many as six different polypeptides and posse: approximately 150 hemes per molecule.The samples were diluted to 100-200 μg/ml with distilled water just before application to a thin carbon film (∽15 Å thick). One percent (w/v) uranyl acetate solution was used for negative staining for 2 minutes and dried in air. The specimens were examined with the high resolution STEM. Their general appearance is that of a hexagonal bilayer (Fig. 1), each layer consisting of six spheroidal subunits. The corner to corner hexagonal dimensic is approximately 300 Å and the bilayer thickness approximately 200 Å.

Application of electron holography to material science studies on magnetic domain states of small particles

1993 ◽  
Vol 51 ◽  
pp. 1028-1029
Author(s):  
T. Hirayama ◽  
Q. Ru ◽  
T. Tanji ◽  
A. Tonomura
Keyword(s):  
Magnetic Field ◽  
Material Science ◽  
Science Studies ◽  
Phase Distribution ◽  
Carbon Film ◽  
Objective Lens ◽  
Electron Holography ◽  
Transform Method ◽  
Transmission Electron ◽  
Thin Carbon

The observation of small magnetic materials is one of the most important applications of electron holography to material science, because interferometry by means of electron holography can directly visualize magnetic flux lines in a very small area. To observe magnetic structures by transmission electron microscopy it is important to control the magnetic field applied to the specimen in order to prevent it from changing its magnetic state. The easiest method is tuming off the objective lens current and focusing with the first intermediate lens. The other method is using a low magnetic-field lens, where the specimen is set above the lens gap.Figure 1 shows an interference micrograph of an isolated particle of barium ferrite on a thin carbon film observed from approximately [111]. A hologram of this particle was recorded by the transmission electron microscope, Hitachi HF-2000, equipped with an electron biprism. The phase distribution of the object electron wave was reconstructed digitally by the Fourier transform method and converted to the interference micrograph Fig 1.

Development of a UV Light Source using Pr:LuAG Thin Film Target Pumped by Electron Beam

2015 ◽  
Vol 135 (9) ◽  
pp. 1049-1054
Author(s):  
Norio Ichikawa ◽  
Kohei Ikeda ◽  
Yoshinori Honda ◽  
Hiroyuki Taketomi ◽  
Koji Kawai ◽  
...  
Keyword(s):  
Thin Film ◽  
Electron Beam ◽  
Light Source ◽  
Uv Light

scholarly journals Solid State NMR Spectroscopy a Valuable Technique for Structural Insights of Advanced Thin Film Materials: A Review

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1494
Author(s):  
Mustapha El Hariri El Nokab ◽  
Khaled O. Sebakhy
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Solid State Nmr ◽  
Pulse Sequences ◽  
3D Structure ◽  
Spectroscopic Techniques ◽  
Film Research ◽  
Versatile Technique ◽  
Work Done

Solid-state NMR has proven to be a versatile technique for studying the chemical structure, 3D structure and dynamics of all sorts of chemical compounds. In nanotechnology and particularly in thin films, the study of chemical modification, molecular packing, end chain motion, distance determination and solvent-matrix interactions is essential for controlling the final product properties and applications. Despite its atomic-level research capabilities and recent technical advancements, solid-state NMR is still lacking behind other spectroscopic techniques in the field of thin films due to the underestimation of NMR capabilities, availability, great variety of nuclei and pulse sequences, lack of sensitivity for quadrupole nuclei and time-consuming experiments. This article will comprehensively and critically review the work done by solid-state NMR on different types of thin films and the most advanced NMR strategies, which are beyond conventional, and the hardware design used to overcome the technical issues in thin-film research.

Photonic methods for rapid crystallization of LiMn2O4 cathodes for solid-state thin-film batteries

2021 ◽  
Vol 495 ◽  
pp. 229424
Author(s):  
Xubin Chen ◽  
Jordi Sastre ◽  
Matthias Rumpel ◽  
Andreas Flegler ◽  
Anurag Singhania ◽  
...  
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Rapid Crystallization ◽  
Thin Film Batteries ◽  
Limn2o4 Cathodes
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