scholarly journals Transformation of the δ-Ferrite in SS2343 Austenitic Stainless Steel upon Annealing at 1050 °C, 1150 °C and 1250 °C

Metals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 935
Author(s):  
Boštjan Arh ◽  
Franc Tehovnik ◽  
Franci Vode
Keyword(s):  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Volume Fraction ◽  
Solute Concentration ◽  
Dendritic Morphology ◽  
Magnetic Method ◽  
Cast State ◽  
Thermodynamic Prediction ◽  
Δ Ferrite ◽  
Morphological Transformations

The solidification behaviors of laboratory cast austenitic SS2343 stainless steel in terms of the volume fraction of δ-ferrite in the as-cast state and its transformation after subsequent annealing were investigated. Monitoring of morphological transformations of δ-ferrite in the microstructure show the progress of δ-ferrite dissolution. Annealing tests were conducted at 1050 °C, 1150 °C and 1250 °C with soaking times of 5 and 40 min. The thermodynamic prediction and metallographic identification of δ-ferrite are presented. The ferrite fractions were measured using a magnetic method and determined to be in the range between 10.7% and 14.6%. The volume share of δ-ferrite decreased with an increase in temperature and the time of annealing. About 50–55% the δ-ferrite was effectively transformed. The δ-ferrite phase, originally present in a dendritic morphology, tends to break up and spheroidize. The morphology varies from vermicular, lacy and acicular shapes to globular for higher temperatures and for longer exposure times. In the δ-ferrite after annealing, concentrations of Cr and Mo decrease, and conversely the concentration of Ni increase, all by small, but significant, amounts. The observed changes in the solute concentration can be explained in terms of the transformation of ferrite into austenite and sigma phases.

scholarly journals Microstructure and Mechanical Properties of Heat-Affected Zone of Repeated Welding AISI 304N Austenitic Stainless Steel by Gleeble Simulator

Metals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 773
Author(s):  
Y.H. Guo ◽  
Li Lin ◽  
Donghui Zhang ◽  
Lili Liu ◽  
M.K. Lei
Keyword(s):  
Mechanical Properties ◽  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Impact Energy ◽  
Heat Affected Zone ◽  
Ferrite Content ◽  
Equipment Safety ◽  
Microstructure And Mechanical Properties ◽  
Δ Ferrite ◽  
The Impact

Heat-affected zone (HAZ) of welding joints critical to the equipment safety service are commonly repeatedly welded in industries. Thus, the effects of repeated welding up to six times on the microstructure and mechanical properties of HAZ for AISI 304N austenitic stainless steel specimens were investigated by a Gleeble simulator. The temperature field of HAZ was measured by in situ thermocouples. The as-welded and one to five times repeated welding were assigned as-welded (AW) and repeated welding 1–5 times (RW1–RW5), respectively. The austenitic matrices with the δ-ferrite were observed in all specimens by the metallography. The δ-ferrite content was also determined using magnetic and metallography methods. The δ-ferrite had a lathy structure with a content of 0.69–3.13 vol.%. The austenitic grains were equiaxial with an average size of 41.4–47.3 μm. The ultimate tensile strength (UTS) and yield strength (YS) mainly depended on the δ-ferrite content; otherwise, the impact energy mainly depended on both the austenitic grain size and the δ-ferrite content. The UTS of the RW1–RW3 specimens was above 550 MPa following the American Society of Mechanical Engineers (ASME) standard. The impact energy of all specimens was higher than that in ASME standard at about 56 J. The repeated welding up to three times could still meet the requirements for strength and toughness of welding specifications.

Magnetic Characterization of SUS316L Deformed by High Pressure Torsion

2011 ◽  
Vol 239-242 ◽  
pp. 1300-1303
Author(s):  
Hong Cai Wang ◽  
Minoru Umemoto ◽  
Innocent Shuro ◽  
Yoshikazu Todaka ◽  
Ho Hung Kuo
Keyword(s):  
Plastic Deformation ◽  
High Pressure ◽  
Stainless Steel ◽  
Phase Transformation ◽  
Austenitic Stainless Steel ◽  
Volume Fraction ◽  
High Pressure Torsion ◽  
Austenitic Matrix ◽  
Magnetic Characterization

SUS316L austenitic stainless steel was subjected to severe plastic deformation (SPD) by the method of high pressure torsion (HPT). From a fully austenitic matrix (γ), HPT resulted in phase transformation from g®a¢. The largest volume fraction of 70% a¢ was obtained at 0.2 revolutions per minute (rpm) while was limited to 3% at 5rpm. Pre-straining of g by HPT at 5rpm decreases the volume fraction of a¢ obtained by HPT at 0.2rpm. By HPT at 5rpm, a¢®g reverse transformation was observed for a¢ produced by HPT at 0.2rpm.

Effects of Deformation Mode on Resistivity Curve Used for Estimating Martensite Induced in Stainless Steel

2010 ◽  
Vol 638-642 ◽  
pp. 2992-2997 ◽  
Author(s):  
Hidefumi Date
Keyword(s):  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Linear Relation ◽  
Volume Fraction ◽  
Tensile Deformation ◽  
Deformation Mode ◽  
Transformation Process ◽  
Martensite Formation ◽  
Austenitic Phase ◽  
Ε Phase

The martensite induced in three types of austenitic stainless steel, which indicate the different stability of the austenitic phase (γ), were estimated by the resistivity measured during the tensile deformation or compressive deformation at the temperatures 77, 187 and 293 K. The resistivity curves were strongly dependent on the deformation mode. The volume fraction of the martensite (α’) was also affected by the deformation mode. The ε phase, which is the precursor of the martensite and is induced from the commencement of the deformation, decreased the resistivity. However, lots of defects generated by the deformation-induced martensite increased the resistivity. The experimental facts and the results shown by the modified parallelepiped model suggested a complicated transformation process depending on each deformation mode. The results shown by the model also suggested a linear relation between the resistivity and the martensite volume at the region of the martensite formation. The fact denoted that the resistivity is mostly not controlled by the austenite, ε phase and martensite, but by the defects induced due to the deformation-induced martensite.

scholarly journals Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding

Metals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1845
Author(s):  
Francesca Borgioli ◽  
Emanuele Galvanetto ◽  
Tiberio Bacci
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Austenitic Stainless Steel ◽  
Low Temperature ◽  
Stainless Steels ◽  
Volume Fraction ◽  
Surface Hardness ◽  
Austenitic Stainless Steels ◽  
Surface Layers ◽  
Modified Surface

Low-temperature nitriding allows to improve surface hardening of austenitic stainless steels, maintaining or even increasing their corrosion resistance. The treatment conditions to be used in order to avoid the precipitation of large amounts of nitrides are strictly related to alloy composition. When nickel is substituted by manganese as an austenite forming element, the production of nitride-free modified surface layers becomes a challenge, since manganese is a nitride forming element while nickel is not. In this study, the effects of nitriding conditions on the characteristics of the modified surface layers obtained on an austenitic stainless steel having a high manganese content and a negligible nickel one, a so-called nickel-free austenitic stainless steel, were investigated. Microstructure, phase composition, surface microhardness, and corrosion behavior in 5% NaCl were evaluated. The obtained results suggest that the precipitation of a large volume fraction of nitrides can be avoided using treatment temperatures lower than those usually employed for nickel-containing austenitic stainless steels. Nitriding at 360 and 380 °C for duration up to 5 h allows to produce modified surface layers, consisting mainly of the so-called expanded austenite or gN, which increase surface hardness in comparison with the untreated steel. Using selected conditions, corrosion resistance can also be significantly improved.

Promoting Isothermal Martensite Formation by High Temperature Heat Treatments in a Precipitation Hardening Austenitic Stainless Steel

2011 ◽  
Vol 172-174 ◽  
pp. 166-171 ◽  
Author(s):  
David San Martín ◽  
Carlos García-Mateo
Keyword(s):  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Precipitation Hardening ◽  
Volume Fraction ◽  
Solution Temperature ◽  
Continuous Heating ◽  
Martensite Formation ◽  
Delta Ferrite ◽  
Kinetic Measurements ◽  
Semi Empirical

This work investigates what phase transformations are taking place during a continuous heating as well as the influence of the solution temperature on the isothermal formation of martensite in a precipitation hardening semi-austenitic stainless steel. In previous studies in the stainless steel under investigation (12Cr-9Ni-4Mo-2Cu) only the isothermal mode of martensitic transformation has been experimentally detected. In this work it is shown that: 1) The AFtemperature is located around 1040 K; 2) The χ-phase present in the initial microstructure dissolves above ~1323 K; 3) above 1448 K the formation of delta ferrite is promoted at austenite grain boundaries; 4) the kinetics of isothermal martensite formation is strongly accelerated with increasing solution temperature. The kinetics has been monitored in-situ at room temperature by using high resolution dilatometry. A semi-empirical dilatometry model is used to convert the dilatometry signal into volume fraction of martensite transformed. The results are briefly compared with previous kinetic measurements under the influence of strong magnetic fields.

Study on Forging Cracks and Manufacturing Process of 022Cr19Ni10N Austenitic Stainless Steel Rod Travel Housing Forging for Control Rod Drive Mechanism

2017 ◽  
Author(s):  
Chen Mei-fang ◽  
Cao Sheng-qiang ◽  
Tao Zhi-yong
Keyword(s):  
Grain Size ◽  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Low Temperature ◽  
Manufacturing Process ◽  
Control Rod ◽  
Forging Process ◽  
The Core ◽  
Fine Grain ◽  
Δ Ferrite

In order to gain high strength, fine grain size, stronger anti-corrosion property, and especially low permeability, the material 022Cr19Ni10N was chosen to manufacture the Rod Travel Housing Forging (RTHF) for Control Rod Drive Mechanism (CRDM). But, cracks were found in some forgings failing to meet the requirements of ultrasonic testing (UT). The causes of the forging cracks of this austenitic stainless steel forging were investigated by means of metallography, scanning electron microscopy (SEM) and other experimental methodology. The results indicated that the second δ-ferrite phase leads to the forging cracks between γ-δ interface during the low temperature forging process, and finally leads to the forging failure. It’s found that the cracks are distributing along the stripe δ-ferrite, and almost distributing in the same area as the large size δ-ferrite by metallography & SEM microstructure observation. The δ-ferrite is firstly found in the electroslag ingot, and in which, the distribution and size is different from the case to the core. The largest size δ-ferrite is around the core area, and this characteristic passes on to the final forging microstructure, although the shape, quantity & distribution of the δ-ferrite changed during the manufacturing process. Most forging cracks were found around the core area of the forging by UT examination. In the final forging process, when the forging temperature drops to 750∼850°C, the δ-ferrite have been forged to stripe shape and hundreds-micron size while the plasticity of the austenite reduce. What’s more, there are large hot plasticity differences between the δ-ferrite and the austenite, so the forging cracks initiate between γ-δ interface and extend to the area around to be a long crack in the low temperature forging process. In order to avoid the forging cracks in the Rod Travel Housing Forging, it’s necessary to reduce the content of δ-ferrite or improve the final forging temperature. Improving the final forging temperature, to guarantee the plasticity of the δ-ferrite and austenite, is another process to reduce the cracks. But while the temperature improves, the grain size grows rapidly, and may form mixed structure. So the most effective mean to reduce the content of δ-ferrite is to redesign the chemical components, mainly by increasing the nitrogen content from 0.06 (wt, %) to 0.12(wt, %), which makes the low temperature forging process for fine grain size possible. In the high-nitrogen-content forging, the δ-ferrite distributed sporadically and no δ-ferrite strip is found. By increasing the austenite forming elements (especially nitrogen), the cracks during low temperature forging process are avoided. What’s more, owning to the optimization of chemical compositions and manufacturing processes, the Rod Travel Housing Forging got fine grain size, low relative permeability, and good comprehensive mechanical properties with the ultimate tensile strength up to 570MPa.

Phase Transformation and Annealing Behavior of SUS 304 Austenitic Stainless Steel Deformed by High Pressure Torsion

2010 ◽  
Vol 654-656 ◽  
pp. 334-337 ◽  
Author(s):  
Innocent Shuro ◽  
Minoru Umemoto ◽  
Yoshikazu Todaka ◽  
Seiji Yokoyama
Keyword(s):  
High Pressure ◽  
Stainless Steel ◽  
Phase Transformation ◽  
Austenitic Stainless Steel ◽  
Volume Fraction ◽  
High Pressure Torsion ◽  
Two Phase ◽  
Annealing Behavior ◽  
304 Austenitic Stainless Steel ◽  
Deformed State

SUS 304 austenitic stainless steel was subjected to severe plastic deformation (SPD) by the method of high pressure torsion (HPT). From a fully austenitic matrix (γ), HPT resulted in phase transformation to give a two phase structure of austenite (γ) and martensite (α') by the transformation γα'. The phase transformation was accompanied by an increase in hardness (Hv) from 1.6 GPa in the as annealed form to 5.4 GPa in the deformed state. Subsequent annealing in temperature range 250oC to 450oC resulted in an increase in both α' volume fraction and hardness (6.4 GPa). Annealing at 600oC resulted in a decrease in α' volume fraction hardness.

Simple Estimation of Deformation-Induced Martensite in Stainless Steel

2005 ◽  
Vol 297-300 ◽  
pp. 500-506 ◽  
Author(s):  
Hidefumi Date
Keyword(s):  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Magnetic Force ◽  
Volume Fraction ◽  
Tensile Deformation ◽  
Electric Resistivity ◽  
Electric Resistance ◽  
The Matrix ◽  
Simple Estimation ◽  
Measured Resistivity

To estimate the volume fraction of martensite induced in 304ss type austenitic stainless steel during tensile deformation, the electric resistance of the specimen was measured using the four-point-probes method at the temperatures of 77, 196 and 293K during the deformation. The magnetic force of the deformed specimen was also measured using a permanent magnet to determine the strain at which the martensite was induced initially in the specimen. The parallelepiped model was suggested to separate the effects of the deformation and transformation on the electric resistivity because the resistivity was influenced by the evolution of the martensite and the growth of the defect in the matrix at a constant temperature. The parallelepiped model consisted of m columns with n pieces of the cubic element and was assumed to be a group of small electric resistors. The volume fraction of the martensite estimated using the measured resistivity and the model was compared with the experimental results reported by other researchers and then it was clarified that the volume fraction of the martensite estimated by the model was in agreement with the volume fraction measured by the experiment.

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