scholarly journals Precipitation Criterion for Inhibiting Austenite Grain Coarsening during Carburization of Al-Containing 20Cr Gear Steels

Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 504
Author(s):  
Huasong Liu ◽  
Yannan Dong ◽  
Hongguang Zheng ◽  
Xiangchun Liu ◽  
Peng Lan ◽  
...  

AlN precipitates are frequently adopted to pin the austenite grain boundaries for the high-temperature carburization of special gear steels. For these steels, the grain coarsening criterion in the carburizing process is required when encountering the composition optimization for the crack-sensitive steels. In this work, the quantitative influence of the Al and N content on the grain size after carburization is studied through pseudocarburizing experiments based on 20Cr steel. According to the grain structure feature and the kinetic theory, the abnormal grain growth is demonstrated as the mode of austenite grain coarsening in carburization. The AlN precipitate, which provides the dominant pinning force, is ripened in this process and the particle size can be estimated by the Lifshitz−Slyosov−Wagner theory. Both the mass fraction and the pinning strength of AlN precipitate show significant influence on the grain growth behavior with the critical values indicating the grain coarsening. These criteria correspond to the conditions of abnormal grain growth when bearing the Zener pinning, which has been analyzed by the multiple phase-field simulation. Accordingly, the models to predict the austenite grain coarsening in carburization were constructed. The prediction is validated by the additional experiments, resulting in accuracies of 92% and 75% for the two models, respectively. Finally, one of the models is applied to optimize the Al and N contents of commercial steel.

2007 ◽  
Vol 539-543 ◽  
pp. 4167-4172 ◽  
Author(s):  
Toshio Murakami ◽  
Hitoshi Hatano ◽  
Yosuke Shindo ◽  
Mutsuhiro Nagahama ◽  
Hiroshi Yaguchi

In order to investigate the effects of Nb carbo-nitride precipitation conditions on abnormal grain growth behavior during high temperature carburizing, size of Nb carbo-nitride precipitates was controlled by precipitation treatment at 1173-1273K for 0.6-54ks, and the specimens were quasi-carburized at 1323K. Abnormal grain growth was enhanced when the size of Nb precipitates was fine or coarse, so there is a suitable size range in Nb precipitates to suppress abnormal grain growth. The reason why abnormal grain growth was enhanced is the lack of pinning force as the conventional theory proposed by Hillert or Gladman; however, it cannot be explained by this theory that small precipitates promote abnormal grain growth. It is considered that Ostwald ripening rate of precipitates is also an important factor in controlling abnormal grain growth in addition to the amount and size of precipitates and austenite grain size, which were parameters in the Gladman‘s theory on abnormal grain growth behavior.


Metals ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 1004 ◽  
Author(s):  
Xianguang Zhang ◽  
Kiyotaka Matsuura ◽  
Munekazu Ohno

The occurrence of abnormal grain growth (AGG) of austenite during annealing is a serious problem in steels with carbide and/or nitride particles, which should be avoided from a viewpoint of mechanical properties. The effects of cold deformation prior to annealing on the occurrence of AGG have been investigated. It was found that the temperature range of the occurrence of AGG is shifted toward a low temperature region by cold deformation, and that the shift increases with the increase of the reduction ratio. The lowered AGG occurrence temperature is attributed to the fine and near-equilibrium AlN particles that are precipitated in the cold-deformed steel, which is readily dissolved during annealing. In contrast, coarse and non-equilibrium AlN particles precipitated in the undeformed steel, which is resistant to dissolution during annealing.


10.30544/463 ◽  
2020 ◽  
Vol 25 (04) ◽  
pp. 315-323
Author(s):  
Tamara Radetić ◽  
Miljana Popović ◽  
Bojan Gligorijević ◽  
Ana Alil ◽  
Endre Romhanji

The occurrence of abnormal grain growth (AGG) in AA5182 alloy during annealing imposes severe restrictions on processing parameters and deteriorates mechanical properties. In this work, we investigated the effect of chemical composition on the appearance of abnormal grain growth by varying Mg and Mn content in the range of composition limits for standard AA5182 alloy, 4.0-5.0% Mg, and 0.2-0.5% Mn, respectively. Thermo-mechanical processing of alloys included cold rolling with reductions ranging from 40 to 85%, followed by annealing in the temperature range from 350 to 520 °C. The results showed that the rise in alloying elements content drives the onset of abnormal grain growth toward higher temperatures. The increase in the cold rolling reduction degree promotes abnormal grain growth and lowers its onset temperature. Abnormal grain growth and grain boundary mobility showed strong anisotropy related to rod-like shape and alignment of Al6Mn(Fe) dispersoids through Zener pinning.


2013 ◽  
Vol 5 ◽  
pp. 762890 ◽  
Author(s):  
Lin Wang ◽  
Dongsheng Qian ◽  
Jun Guo ◽  
Yan Pan

2007 ◽  
Vol 558-559 ◽  
pp. 717-722 ◽  
Author(s):  
J. Dennis ◽  
Pete S. Bate ◽  
John F. Humphreys

Grain growth may occur in two forms, normal grain growth, characterized by a constant grain size distribution during growth, and abnormal grain growth, where one or more abnormally large grains may form in the microstructure. The presence of abnormally large grains in an otherwise uniform microstructure may be detrimental to the mechanical properties of a polycrystalline structure. Little is understood of the exact cause of abnormal grain growth. The annealing conditions leading to the onset of abnormal grain growth have been investigated via a series of grain growth experiments carried out on an Al-4wt%Cu alloy. The structure of which consisted of equiaxed grains (<8μ) pinned by a fine dispersion of sub-micron second phase particles, which may dissolve upon annealing. Minority texture components may experience accelerated growth due to a higher energy and mobility compared to the surrounding grain structure. The combination of these two events may result in the abnormal growth of some grains. SEM imaging and EBSD data has then made it possible to characterize the influence of particle dissolution and grain boundary misorientation on the onset of abnormal grain growth. The stability of ‘island grains’ found to exist internally in abnormally large grains has also been investigated in relation to the misorientation relationship and localized second phase volume fraction found there. There was only weak evidence of special misorientation relationships between the island grains and the abnormally large grains in which they exist, and although there was evidence of an enhanced fraction of pinning particles at island grain boundaries, this was also true of boundaries in general. The larger size of island grains is their dominant characteristic, and grains which become island grains may have been incipient abnormal grains.


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