scholarly journals Aging Resistance of Silica Fume/Styrene-Butadiene-Styrene Composite-Modified Asphalt

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6536
Author(s):  
Jingrong Zhu ◽  
Wenyuan Xu

The influences of silica fume content and aging on the rheological properties of silica fume/styrene-butadiene-styrene composite-modified asphalts were investigated via rolling thin-film oven test simulations. The asphalts rheological properties before and after aging were measured using three-major-indices, dynamic shear rheology, and bending beam rheometer tests. Fourier transform infrared spectroscopy was used to examine the changes in the functional groups of the asphalt. The silica fume did not chemically react with the modified asphalt, and its original structure was maintained. The aging resistance improved significantly after adding the silica fume. At 6% silica fume content, the relaxation of the asphalt was the highest, indicating that the asphalt had the best low-temperature crack resistance at this mixing proportion. Furthermore, the carbonyl index value of this sample exhibited the smallest increment among all of the samples, and this asphalt sample had the strongest short-term aging resistance. Thus, the optimum silica fume content in the composite-modified asphalt was determined to be 6%. This information may be used to fabricate an asphalt mixture that can improve the service life and aging resistance of pavements.

2017 ◽  
Vol 50 (3) ◽  
pp. 256-275 ◽  
Author(s):  
Mahdi Delaviz Bayekolaei ◽  
Koorosh Naderi ◽  
Fereidoon Moghadas Nejad

In recent years, the use of nano materials for improving various mechanical and performance-related properties of polymer-modified asphalt binders has been growing rapidly. However, few researches investigated the effects of base binder and styrene–butadiene–styrene (SBS) structure on rutting resistance of polymer-nanocomposite-modified asphalt mixtures. This study investigated the effect of polymer–nanocomposite modification, using two different penetration grade asphalt binders and two types of SBS, on rutting properties of asphalt mixtures. Rheological properties of modified binders, Marshall stability, resilient modulus, and rut depth in wheel-tracking tests were used to evaluate the rutting performance of the modified binders and mixtures. The results indicated that both base binder type and SBS structure had significant effect on rutting resistance of polymer-nanocomposite-modified asphalt mixtures.


Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5715
Author(s):  
Bangwei Wu ◽  
Chufan Luo ◽  
Zhaohui Pei ◽  
Chuangchuang Chen ◽  
Ji Xia ◽  
...  

A wide variety of polymer additives have been widely used in recent years. However, the effect of different polymer additives on the durability of asphalt binders has not been investigated thoroughly. To evaluate the aging property of styrene-butadiene-styrene (SBS) asphalt binder with different polymer additives, three polymer modifiers, namely high modulus modifier (HMM), anti-rutting agent (ARA), and high viscosity modifier (HVM), were added to it. First, the Thin Film Over Test (TFOT) and Pressure Aging Vessel (PAV) was performed on the asphalt binders. The rheological properties of the four asphalt binders before and after aging were then checked by the Dynamic Shear Rheometer Test (DSR). The chemical compositions of the asphalt binders were determined by the Fourier Transform Infrared Spectrometer (FTIR) test. Several aging indicators were adopted to reflect the aging degree of the asphalt binders. The results show that when polymer additives are added to the SBS asphalt binder, the complex modulus, storage modulus, loss modulus, and rutting factor substantially increase and the phase angle decreases. All the test parameters become higher after aging. The phase angle of the SBS asphalt binder is the highest at both unaged and aged states, while its other parameters values are the smallest. Moreover, the Carbonyl Aging Indicator (CAI) of SBS with polymer additives becomes lower under both TFOT and PAV conditions, indicating that polymer additives can improve the aging resistance of SBS asphalt, of which HVM modifies the aging resistance best. Complex Modulus Aging Indicator (CMAI) and Storage Modulus Aging Indicator (SMAI) have the best correlation coefficients with CAI, and the two aging indicators can be used to predict the aging degree of polymer modified asphalt binders.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3780
Author(s):  
Jingyao Yang ◽  
Gang Xu ◽  
Peipei Kong ◽  
Xianhua Chen

With the growing interest in bituminous construction materials, desulfurized crumb rubber (CR)/styrene–butadiene–styrene (SBS) modified asphalts have been investigated by many researchers as low-cost environmental-friendly road construction materials. This study aimed to investigate the rheological properties of desulfurized CR/SBS composite modified asphalt within various temperature ranges. Bending beam rheometer (BBR), linear amplitude sweep (LAS), and multiple stress creep recovery (MSCR) tests were performed on conventional CR/SBS composite modified asphalt and five types of desulfurized CR/SBS modified asphalts. Meanwhile, Burgers’ model and the Kelvin–Voigt model were used to derive nonlinear viscoelastic parameters and analyze the viscoelastic mechanical behavior of the asphalts. The experimental results indicate that both the desulfurized CR/SBS composite modifier and force chemical reactor technique can enhance the crosslinking of CR and SBS copolymer, resulting in an improved high-, intermediate-, and low-temperature performance of desulfurized CR/SBS composite modified asphalt. Burgers’ model was found to be apposite in simulating the creep stages obtained from MSCR tests for CR/SBS composite modified asphalts. The superior high-temperature performance of desulfurized CR/SBS modified asphalt prepared with 4% SBS, 20% desulfurized rubber, and a force chemical reactor time of 45 min contributes to the good high-temperature elastic properties of the asphalt. Therefore, this combination is recommended as an optimal preparation process. In summary, the desulfurization of crumb rubber and using the force chemical reactor technique are beneficial to composite asphalt performance and can provide a new way of utilizing waste tire rubber.


2020 ◽  
Vol 2020 ◽  
pp. 1-14
Author(s):  
Xiaobing Chen ◽  
Juntian Wang ◽  
Xiaorui Zhang ◽  
Han Liu ◽  
Jinhu Tong ◽  
...  

To evaluate the physical and rheological properties of rejuvenated styrene-butadiene-styrene-modified asphalt (SBSMA) binders designed for rapid in-place pavement recycling, an aged SBSMA binder was rejuvenated with three rejuvenators (i.e., Types I, II, and III) in different dosages. The physical properties of rejuvenated SBSMA were obtained to determine the optimal type and dosage of rejuvenators for the first and second rejuvenation. Performance grade (PG) tests, multiple stress creep recovery (MSCR) tests, and linear amplitude sweep (LAS) tests were conducted to measure the rheological properties using the dynamic shear rheometer (DSR) and bending beam rheometer (BBR). The results exhibited that the rejuvenators could soften the multiple aged binder and enhance its high- and low-temperature performance. The rejuvenation effect of rejuvenator Type I with the optimal dosage of 6∼8% was the most appropriate for the first rejuvenation. The optimal dosage of the second rejuvenation was 10∼12%. The addition of rejuvenators decreased the rutting factor G∗/sin δ, creep stiffness (S), delta Tc (ΔTc) parameter, recovery response (R), and yield stress of rejuvenated SBSMA. On the other hand, an increase in the rate of relaxation (m-value), nonrecoverable creep compliance (Jnr), and yield strain of rejuvenated SBSMA was recorded. Overall, the study findings indicated an improvement in the elastic properties of rejuvenated SBSMA, which contributes to improving the rutting, thermal, and fatigue cracking resistance of asphalt binder and ultimately the response of asphalt pavements.


Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1092 ◽  
Author(s):  
Yongchun Cheng ◽  
He Li ◽  
Wensheng Wang ◽  
Liding Li ◽  
Haitao Wang

This paper aims at the freeze–thaw (F-T) cycles resistance of styrene-butadiene-styrene (SBS) modified asphalt mixture reinforced with basalt fiber in order to explore the performance evaluation and prediction of asphalt mixtures at seasonal frozen regions. Asphalt was firstly modified by the common SBS and then SBS-modified stone mastic asphalt (SMA) specimens with basalt fiber were prepared by using Superpave gyratory compaction (SGC) method. Next, asphalt mixture specimens processed by 0–21 F-T cycles were adopted for the high-temperature compression test, low-temperature splitting test and indirect tensile stiffness modulus test. Meanwhile, a three-dimensional model of F-T damage evolution of the mixtures was also established based on the reliability and damage theory. The test results showed that the loss rates of mechanical strength increased rapidly, and then gradually flattened; however, these indications changed significantly after 15–18 F-T cycles. In addition, the exponential function could reflect the variation trend of the mechanical performances with F-T cycles to a certain degree. The damage evolution and prediction model based on the reliability and damage theory can be established to analyze the internal degradation law better.


Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2249
Author(s):  
Bei Chen ◽  
Fuqiang Dong ◽  
Xin Yu ◽  
Changjiang Zheng

In order to solve the problems caused by asphalt diseases and prolong the life cycle of asphalt pavement, many studies on the properties of modified asphalt have been conducted, especially polyurethane (PU) modified asphalt. This study is to replace part of the styrene-butadiene-styrene (SBS) modifier with waste polyurethane (WP), for preparing WP/SBS composite modified asphalt, as well as exploring its properties and microstructure. On this basis, this paper studied the basic performance of WP/SBS composite modified asphalt with a conventional performance test, to analyze the high- and low-temperature rheological properties, permanent deformation resistance and storage stability of WP/SBS composite modified asphalt by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The microstructure of WP/SBS composite modified asphalt was also observed by fluorescence microscope (FM) and Fourier transform infrared spectroscopy (FTIR), as well as the reaction between WP and asphalt. According to the results of this study, WP can replace SBS as a modifier to prepare WP/SBS composite modified asphalt with good low-temperature resistance, whose high-temperature performance will be lower than that of SBS modified asphalt. After comprehensive consideration, 4% SBS content and 15% WPU content (4 S/15 W) are determined as the suitable types of WPU/SBS composite modified asphalt.


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