scholarly journals The Preparation of Dense Materials in the MgO–ZrO2 System by the Application of Nanometric Powders

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5478
Author(s):  
Kamil Wojteczko ◽  
Krzysztof Haberko ◽  
Katarzyna Berent ◽  
Paweł Rutkowski ◽  
Mirosław M. Bućko ◽  
...  

Crystallization under hydrothermal conditions allowed us to prepare nanometric powders in the MgO–ZrO2 system of different magnesia concentrations. Sintering runs of these powder compacts studied using dilatometry measurements during heating and cooling revealed essential differences in their behavior. The microstructure of the resulting polycrystal is strongly related to the magnesia content in the starting powder, which strongly influences the phase composition of the resulting material and its mechanical properties. It should be emphasized that the novel processing method of such materials differs from the usual applied technology and leads to magnesia–zirconia materials of a different microstructure than that of “classical” materials of this kind.

2021 ◽  
pp. 002199832098387
Author(s):  
Priya Venkatraman ◽  
Nick Bohmann ◽  
Dina Gadalla ◽  
Chris Rader ◽  
E. Johan Foster

Utilizing a novel processing method of PEEK foam that produces hierarchical mesoporosity, we explore the use of hydroxyapatite (HA)/PEEK composites for mimicking the structure of human bone. The effect of HA content and processing parameters on the porosity, and interconnective network are studied with respect to the corresponding morphology, mechanical properties, and ultimately the cell viability. Having achieved hierarchical structuration with pore sizes ranging from approx. a hundred nanometers all the way to a few hundred microns, the HA/PEEK composites produced desirable mechanical properties and promising cell proliferation. A strong correlation was not seen with HA loading and the resulting properties, but a combination of the HA loading and variance in porosity is shown to be significant. The development and analysis of this bone mimic structure opens up the potential for this processing method and material as a treatment to bone injuries and bone diseases.


2018 ◽  
Vol 18 (1) ◽  
pp. 125-135
Author(s):  
Sattar H A Alfatlawi

One of ways to improve properties of materials without changing the product shape toobtain the desired engineering applications is heating and cooling under effect of controlledsequence of heat treatment. The main aim of this study was to investigate the effect ofheating and cooling on the surface roughness, microstructure and some selected propertiessuch as the hardness and impact strength of Medium Carbon Steel which treated at differenttypes of heat treatment processes. Heat treatment achieved in this work was respectively,heating, quenching and tempering. The specimens were heated to 850°C and left for 45minutes inside the furnace as a holding time at that temperature, then quenching process wasperformed in four types of quenching media (still air, cold water (2°C), oil and polymersolution), respectively. Thereafter, the samples were tempered at 200°C, 400°C, and 600°Cwith one hour as a soaking time for each temperature, then were all cooled by still air. Whenthe heat treatment process was completed, the surface roughness, hardness, impact strengthand microstructure tests were performed. The results showed a change and clearimprovement of surface roughness, mechanical properties and microstructure afterquenching was achieved, as well as the change that took place due to the increasingtoughness and ductility by reducing of brittleness of samples.


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 779
Author(s):  
Mohamed Gomah ◽  
Guichen Li ◽  
Salah Bader ◽  
Mohamed Elkarmoty ◽  
Mohamed Ismael

The awareness of the impact of high temperatures on rock properties is essential to the design of deep geotechnical applications. The purpose of this research is to assess the influence of heating and cooling treatments on the physical and mechanical properties of Egyptian granodiorite as a degrading factor. The samples were heated to various temperatures (200, 400, 600, and 800 °C) and then cooled at different rates, either slowly cooled in the oven and air or quickly cooled in water. The porosity, water absorption, P-wave velocity, tensile strength, failure mode, and associated microstructural alterations due to thermal effect have been studied. The study revealed that the granodiorite has a slight drop in tensile strength, up to 400 °C, for slow cooling routes and that most of the physical attributes are comparable to natural rock. Despite this, granodiorite thermal deterioration is substantially higher for quick cooling than for slow cooling. Between 400:600 °C is ‘the transitional stage’, where the physical and mechanical characteristics degraded exponentially for all cooling pathways. Independent of the cooling method, the granodiorite showed a ductile failure mode associated with reduced peak tensile strengths. Additionally, the microstructure altered from predominantly intergranular cracking to more trans-granular cracking at 600 °C. The integrity of the granodiorite structure was compromised at 800 °C, the physical parameters deteriorated, and the rock tensile strength was negligible. In this research, the temperatures of 400, 600, and 800 °C were remarked to be typical of three divergent phases of granodiorite mechanical and physical properties evolution. Furthermore, 400 °C could be considered as the threshold limit for Egyptian granodiorite physical and mechanical properties for typical thermal underground applications.


2012 ◽  
Vol 57 (4) ◽  
pp. 951-974 ◽  
Author(s):  
Andrzej Nowakowski ◽  
Mariusz Młynarczuk

Abstract Temperature is one of the basic factors influencing physical and structural properties of rocks. A quantitative and qualitative description of this influence becomes essential in underground construction and, in particular, in the construction of various underground storage facilities, including nuclear waste repositories. The present paper discusses the effects of temperature changes on selected mechanical and structural parameters of the Strzelin granites. Its authors focused on analyzing the changes of granite properties that accompany rapid temperature changes, for temperatures lower than 573ºC, which is the value at which the β - α phase transition in quartz occurs. Some of the criteria for selecting the temperature range were the results of measurements carried out at nuclear waste repositories. It was demonstrated that, as a result of the adopted procedure of heating and cooling of samples, the examined rock starts to reveal measurable structural changes, which, in turn, induces vital changes of its selected mechanical properties. In particular, it was shown that one of the quantities describing the structure of the rock - namely, the fracture network - grew significantly. As a consequence, vital changes could be observed in the following physical quantities characterizing the rock: primary wave velocity (vp), permeability coefficient (k), total porosity (n) and fracture porosity (η), limit of compressive strength (Rσ1) and the accompanying deformation (Rε1), Young’s modulus (E), and Poisson’s ratio (ν).


Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3798
Author(s):  
Meng Sun ◽  
Dong Li ◽  
Yanhua Guo ◽  
Ying Wang ◽  
Yuecheng Dong ◽  
...  

In order to reduce the cost of titanium alloys, a novel low-cost Ti-3Al-5Mo-4Cr-2Zr-1Fe (Ti-35421) titanium alloy was developed. The influence of heat treatment on the microstructure characteristics and mechanical properties of the new alloy was investigated. The results showed that the microstructure of Ti-35421 alloy consists of a lamina primary α phase and a β phase after the solution treatment at the α + β region. After aging treatment, the secondary α phase precipitates in the β matrix. The precipitation of the secondary α phase is closely related to heat treatment parameters—the volume fraction and size of the secondary α phase increase when increasing the solution temperature or aging time. At the same solution temperature and aging time, the secondary α phase became coarser, and the fraction decreased with increasing aging temperature. When Ti-35421 alloy was solution-treated at the α + β region for 1 h with aging surpassing 8 h, the tensile strength, yield strength, elongation and reduction of the area were achieved in a range of 1172.7–1459.0 MPa, 1135.1–1355.5 MPa, 5.2–11.8%, and 7.5–32.5%, respectively. The novel low-cost Ti-35421 alloy maintains mechanical properties and reduces the cost of materials compared with Ti-3Al-5Mo-5V-4Cr-2Zr (Ti-B19) alloy.


2011 ◽  
Vol 183-185 ◽  
pp. 2173-2177 ◽  
Author(s):  
Xin Ying Lv ◽  
Die Ying Ma ◽  
Yong Ming Song ◽  
Zhen Hua Gao

Novel Kraft fiber reinforced unsaturated polyester (UPE) composites were prepared at various molding pressures in order to investigate the effects of molding pressure on resin content, the mechanical properties and creep resistance. The results indicated that the novel composites had much higher mechanical properties and better creep resistances than traditional wood plastic composites because of the applications of strong Kraft fibers as reinforcement and thermosetting UPE as matrix. Molding pressure had various effects on the many properties of composites. With molding pressure increased from 6MPa to 25MPa, the mechanical properties and creep resistances increased gradually until about 20MPa and then decreased, which were attributed to the different interface adhesions between UPE resin and Kraft fibers at various molding pressures as evidenced by DMA analysis. Benefited from the use of low-viscosity UPE resin, the resin content of Kraft fiber reinforced UPE composites could reduce to 28.3% while strength and creep resistance were still much better than that of the thermoplastic wood-plastic composite (WPC) with 40% polymer matrix.


2018 ◽  
Vol 74 (8) ◽  
pp. 936-943
Author(s):  
Galina V. Kiriukhina ◽  
Olga V. Yakubovich ◽  
Ekaterina M. Kochetkova ◽  
Olga V. Dimitrova ◽  
Anatoliy S. Volkov

Caesium manganese hexahydrate phosphate, CsMn(H2O)6(PO4), was synthesized under hydrothermal conditions. Its crystal structure was determined from single-crystal X-ray diffraction data. The novel phase crystallizes in the hexagonal space group P63 mc and represents the first manganese member in the struvite morphotropic series, AM(H2O)6(TO4). Its crystal structure is built from Mn(H2O)6 octahedra and PO4 tetrahedra linked into a framework via hydrogen bonding. The large Cs atoms are encapsulated in the framework cuboctahedral cavities. It is shown that the size of the A + ionic radius within the morphotropic series AM(H2O)6(XO4) results is certain types of crystal structures and affects the values of the unit-cell parameters. Structural relationships with Na(H2O)Mg(H2O)6(PO4) and the mineral hazenite, KNa(H2O)2Mg2(H2O)12(PO4)2, are discussed.


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