scholarly journals Influence of the Halloysite Nanotube (HNT) Addition on Selected Mechanical and Biological Properties of Thermoplastic Polyurethane

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3625
Author(s):  
Maciej Mrówka ◽  
Małgorzata Szymiczek ◽  
Tomasz Machoczek ◽  
Mirosława Pawlyta
Keyword(s):  
Fused Deposition Modeling ◽  
Thermoplastic Polyurethane ◽  
Tensile Modulus ◽  
Biological Properties ◽  
Mechanical Tests ◽  
Halloysite Nanotube ◽  
Fused Deposition ◽  
Transmission Electron ◽  
Scanning Transmission ◽  
Deposition Modeling

Halloysite nanotube (HNT) additions to the thermoplastic polyurethane (TPU) system were thoroughly evaluated in this study. The resultant composites have been designed for future personalized intervertebral disc implant applications, which requires additional technology to obtain the appropriate geometry unique to each patient. These requirements can be fulfilled using 3D printing. In this work, a technology was developed to produce filaments for fused deposition modeling (FDM). Nanocomposites were prepared using variable HNT content (1, 2, and 3 wt.%). The nanostructure of the resultant composites was confirmed using scanning transmission electron microscopy (STEM). Mechanical tests were used to measure the tensile modulus, stress, and elongation the composites and TPU matrix. Nanocomposites with 2% HNT content were able to withstand 26% increased stress and 50% increased elongation compared to pure TPU before fracturing in addition to a 13% reduction in the friction coefficient. A MTT cytotoxicity assay confirmed the cytotoxicity of all tested materials against human epidermal keratinocyte cells (HaCaT).

scholarly journals Fabrication and Characterization of Flexible Medical-Grade TPU Filament for Fused Deposition Modeling 3DP Technology

Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1304 ◽  
Author(s):  
Agnieszka Haryńska ◽  
Iga Gubanska ◽  
Justyna Kucinska-Lipka ◽  
Helena Janik
Keyword(s):  
Fused Deposition Modeling ◽  
Thermoplastic Polyurethane ◽  
Extrusion Process ◽  
Biological Properties ◽  
Fused Deposition ◽  
3D Printers ◽  
Deposition Modeling ◽  
A Chain ◽  
Medical Grade

The possibility of using additive manufacturing (AM) in the medicine area has created new opportunities in health care. This has contributed to a sharp increase in demand for 3D printers, their systems and materials that are adapted to strict medical requirements. We described herein a medical-grade thermoplastic polyurethane (S-TPU) which was developed and then formed into a filament for Fused Deposition Modeling (FDM) 3D printers during a melt-extrusion process. S-TPU consisting of aliphatic hexamethylene 1,6-diisocyanate (HDI), amorphous α,ω-dihydroxy(ethylene-butylene adipate) (PEBA) and 1,4 butandiol (BDO) as a chain extender, was synthesized without the use of a catalyst. The filament (F-TPU) properties were characterized by rheological, mechanical, physico-chemical and in vitro biological properties. The tests showed biocompatibility of the obtained filament as well as revealed no significant effect of the filament formation process on its properties. This study may contribute to expanding the range of medical-grade flexible filaments for standard low-budget FDM printers.

scholarly journals Fabrication and Characterization of Flexible Medical-Grade TPU Filament for Fused Deposition Modeling 3DP Technology

2018 ◽  
Author(s):  
Agnieszka Haryńska ◽  
Iga Gubańska ◽  
Justyna Kucińska-Lipka ◽  
Helena Janik
Keyword(s):  
Fused Deposition Modeling ◽  
Thermoplastic Polyurethane ◽  
Extrusion Process ◽  
Biological Properties ◽  
Fused Deposition ◽  
3D Printers ◽  
Deposition Modeling ◽  
A Chain ◽  
Medical Grade

The possibility of using additive manufacturing (AM) in the medicine area has created a new opportunities in health care. This has contributed to a sharp increase in demand for 3D printers, their systems and materials that are adapted to strict medical requirements. We described herein a medical-grade thermoplastic polyurethane (S-TPU), which was developed and then formed into a filament for Fused Deposition Modeling (FDM) 3D printers during a melt-extrusion process. S-TPU consisting of aliphatic hexamethylene 1,6-diisocyanate (HDI), amorphous α,ω-dihydroxy(ethylene-butylene adipate) (PEBA) and 1,4 butandiol (BDO) as a chain extender, was synthesized without the use of a catalyst. The filament properties were characterized by rheological, mechanical, physico-chemical and in vitro biological properties. The tests showed biocompatibility of the obtained filament as well as revealed no significant effect of the filament formation process on its properties. This study may contribute to expanding the range of medical-grade flexible filaments for standard low-budget FDM printers.

scholarly journals 3D-Printed Soft Structure of Polyurethane and Magnetorheological Fluid: A Proof-of-Concept Investigation of its Stiffness Tunability

Micromachines ◽  
2019 ◽  
Vol 10 (10) ◽  
pp. 655 ◽  
Author(s):  
Seong-Woo Hong ◽  
Ji-Young Yoon ◽  
Seong-Hwan Kim ◽  
Sun-Kon Lee ◽  
Yong-Rae Kim ◽  
...  
Keyword(s):  
Fused Deposition Modeling ◽  
Permanent Magnets ◽  
Thermoplastic Polyurethane ◽  
Three Dimensional ◽  
Magnetorheological Fluid ◽  
Three Dimensional Printing ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
3D Printed ◽  
Dimensional Printing

In this study, a soft structure with its stiffness tunable by an external field is proposed. The proposed soft beam structure consists of a skin structure with channels filled with a magnetorheological fluid (MRF). Two specimens of the soft structure are fabricated by three-dimensional printing and fused deposition modeling. In the fabrication, a nozzle is used to obtain channels in the skin of the thermoplastic polyurethane, while another nozzle is used to fill MRF in the channels. The specimens are tested by using a universal tensile machine to evaluate the relationships between the load and deflection under two different conditions, without and with permanent magnets. It is empirically shown that the stiffness of the proposed soft structure can be altered by activating the magnetic field.

An approach for mechanical property optimization of fused deposition modeling with polylactic acid via design of experiments

2016 ◽  
Vol 22 (2) ◽  
pp. 387-404 ◽  
Author(s):  
Jonathan Torres ◽  
Matthew Cole ◽  
Allen Owji ◽  
Zachary DeMastry ◽  
Ali P. Gordon
Keyword(s):  
Mechanical Properties ◽  
Polylactic Acid ◽  
Fused Deposition Modeling ◽  
Mechanical Tests ◽  
Content Type ◽  
Fused Deposition ◽  
Structural Applications ◽  
3D Printers ◽  
Deposition Modeling

Purpose This paper aims to present the influences of several production variables on the mechanical properties of specimens manufactured using fused deposition modeling (FDM) with polylactic acid (PLA) as a media and relate the practical and experimental implications of these as related to stiffness, strength, ductility and generalized loading. Design/methodology/approach A two-factor-level Taguchi test matrix was defined to allow streamlined mechanical testing of several different fabrication settings using a reduced array of experiments. Specimens were manufactured and tested according to ASTM E8/D638 and E399/D5045 standards for tensile and fracture testing. After initial analysis of mechanical properties derived from mechanical tests, analysis of variance was used to infer optimized production variables for general use and for application/load-specific instances. Findings Production variables are determined to yield optimized mechanical properties under tensile and fracture-type loading as related to orientation of loading and fabrication. Practical implications The relation of production variables and their interactions and the manner in which they influence mechanical properties provide insight to the feasibility of using FDM for rapid manufacturing of components for experimental, commercial or consumer-level use. Originality/value This paper is the first report of research on the characterization of the mechanical properties of PLA coupons manufactured using FDM by the Taguchi method. The investigation is relevant both in commercial and consumer-level aspects, given both the currently increasing utilization of 3D printers for component production and the viability of PLA as a renewable, biocompatible material for use in structural applications.

Embedding 3D Printed Filaments with Knitted Textiles: Investigation of Bonding Parameters

2020 ◽  
pp. 0887302X2098292
Author(s):  
Gozde Goncu-Berk ◽  
Burak Karacan ◽  
Ilke Balkis
Keyword(s):  
Fused Deposition Modeling ◽  
Thermoplastic Polyurethane ◽  
Thermoplastic Elastomer ◽  
New Materials ◽  
Bonding Parameters ◽  
Fused Deposition ◽  
Additive Manufacturing Technology ◽  
Before And After ◽  
Deposition Modeling ◽  
3D Printed

The advancements in additive manufacturing technology and new materials paved the way for 3D printed textile-like structures. However, achieving the comfort and fit of traditional textiles and joining of the 3D printed segments have been challenging. Embedding 3D printed polymers with textiles using fused deposition modeling offers possibilities for innovative hybrid structures and end-products without compromising on the flexibility and unique qualities of the traditional textiles. This study investigates 3D printing of flexible thermoplastic polyurethane, thermoplastic elastomer and rigid polylactic acid filaments on polyester and polyamide knitted textiles, and on laminated neoprene textiles. Perpendicular and shear tensile strength are tested before and after washing the samples manufactured by direct deposition of different filaments onto different textiles in multiple 3D forms. Results show that TPU filament is compatible with all textile surfaces and neoprene shows the best adhesion with all filament types before and after washing.

scholarly journals Fused deposition modeling of polypropylene-aluminium silicate dihydrate microcomposites

e-Polymers ◽  
2022 ◽  
Vol 22 (1) ◽  
pp. 87-98
Author(s):  
Kilole Tesfaye Chaka
Keyword(s):  
Mechanical Properties ◽  
Fused Deposition Modeling ◽  
Tensile Modulus ◽  
Dimensional Accuracy ◽  
Processing Parameters ◽  
Screw Extruder ◽  
Scanning Calorimetry ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
Aluminium Silicate

Abstract Polypropylene (PP) undergoes fast crystallization and resulting in rigorous shrinkage when it is subjected to high temperature likewise of the fused deposition modeling (FDM) process. This research study focuses on the investigation of the processing parameters and factors that decrease the warpage of PP during the FDM process. Aluminium silicate dihydrate (K) microparticles of different ratios were melt blended with PP by a twin-screw extruder, and filaments of about 1.7 mm diameter were extruded in a single screw extruder. Then, the extruded filaments were used to fabricate the dumbbells structure through the FDM process. The effects of optimizing the fused deposition temperature, coating the chamber with thick papers/fabrics, and coating a printer bed with PP material were also investigated in this study. Scanning and transmission electron microscopy, differential scanning calorimetry, melt flow, and mechanical properties testing instruments are used to analyze the microparticles dispersion, crystallization, flow, and mechanical properties of resulting samples. Uniformly dispersed filler and increased printing chamber temperature result in an increase of crystallization temperature and improve the dimensional accuracy of fused deposited specimens. The fused deposited PP-K10 wt% composite showed an improvement of up to 32% in tensile modulus compared to the neat PP.

scholarly journals Electrical and Thermal Conductivity of Polylactic Acid (PLA)-Based Biocomposites by Incorporation of Nano-Graphite Fabricated with Fused Deposition Modeling

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 549 ◽  
Author(s):  
Rui Guo ◽  
Zechun Ren ◽  
Hongjie Bi ◽  
Min Xu ◽  
Liping Cai
Keyword(s):  
Thermal Conductivity ◽  
Polylactic Acid ◽  
Fused Deposition Modeling ◽  
Wood Flour ◽  
Thermoplastic Polyurethane ◽  
Volume Resistivity ◽  
Fused Deposition ◽  
Multi Walled Carbon Nanotubes ◽  
Deposition Modeling ◽  
Walled Carbon Nanotubes

The aim of the study was to improve the electrical and thermal conductivity of the polylactic acid/wood flour/thermoplastic polyurethane composites by Fused Deposition Modeling (FDM). The results showed that, when the addition amount of nano-graphite reached 25 pbw, the volume resistivity of the composites decreased to 108 Ω·m, which was a significant reduction, indicating that the conductive network was already formed. It also had good thermal conductivity, mechanical properties, and thermal stability. The adding of the redox graphene (rGO) combined with graphite into the composites, compared to the tannic acid-functionalized graphite or the multi-walled carbon nanotubes, can be an effective method to improve the performance of the biocomposites, because the resistivity reduced by one order magnitude and the thermal conductivity increased by 25.71%. Models printed by FDM illustrated that the composite filaments have a certain flexibility and can be printed onto paper or flexible baseplates.

Multi-Material Composition Optimization vs Software-Based Single-Material Topology Optimization of a Rectangular Sample under Flexural Load for Fused Deposition Modeling Process

2021 ◽  
Vol 1042 ◽  
pp. 23-44
Author(s):  
Vahid Hassani ◽  
Hamid Ahmad Mehrabi ◽  
Carl Gregg ◽  
Roger William O'Brien ◽  
Iñigo Flores Ituarte ◽  
...  
Keyword(s):  
Fused Deposition Modeling ◽  
Volume Fraction ◽  
Thermoplastic Polyurethane ◽  
Von Mises Stress ◽  
Fused Deposition ◽  
Hard Polymer ◽  
Deposition Modeling ◽  
3D Printed ◽  
Single Material ◽  
Soft Polymers

Additive manufacturing (AM) technologies have been evolved over the last decade, enabling engineers and researchers to improve functionalities of parts by introducing a growing technology known as multi-material AM. In this context, fused deposition modeling (FDM) process has been modified to create multi-material 3D printed objects with higher functionality. The new technology enables it to combine several types of polymers with hard and soft constituents to make a 3D printed part with improved mechanical properties and functionalities. Knowing this capability, this paper aims to present a parametric optimization method using a genetic algorithm (GA) to find the optimum composition of hard polymer as polylactic acid (PLA) and soft polymer as thermoplastic polyurethane (TPU 95A) used in Ultimaker 3D printer for making a rectangular sample under flexural load in order to minimize the von Mises stress as an objective function. These samples are initially presented in four deferent forms in terms of composition of hard and soft polymers and then, after the optimization process, the final ratio of each type of material will be achieved. Based on the volume fraction of soft polymers in each sample, the equivalent topologically-optimized samples will be obtained that are solely made of single-material PLA as hard polymer under the same flexural load as applied to multi-material samples. Finally, the structural results and manufacturability in terms of the generated support structures, as key element of some AM processes, will be compared for the resultant samples created by two methods of optimization.

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